Wang Jun. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2003. / Includes bibliographical references (leaves 74-79). / Abstracts in English and Chinese. / Acknowledgements --- p.i / List of publications --- p.ii / Abstract (In English) --- p.iii / Abstract (In Chinese) --- p.v / Table of contents --- p.vii / List of figures --- p.x / List of tables --- p.xiv / Chapter Chapter I --- Introduction --- p.1 / Chapter Chapter II --- Dye-doped sol-gel zirconia and zirconia-organically modified silicate waveguides --- p.6 / Chapter 2.1 --- General sol-gel process --- p.6 / Chapter 2.2 --- Dye-doped sol-gel zirconia and zirconia-ORMOSIL waveguides --- p.7 / Chapter Chapter III --- Basic theory and experiment setup of distributed feedback waveguide lasers --- p.13 / Chapter 3.1 --- Coupled-wave theory of distributed feedback lasers --- p.13 / Chapter 3.2 --- Introduction on the theory of planar optical waveguide --- p.16 / Chapter 3.3 --- Experiment setup design of DFB waveguide lasers --- p.19 / Chapter Chapter IV --- Zirconia and zirconia-organically modified silicate distributed feedback waveguide lasers tunable in the visible --- p.23 / Chapter Chapter V --- Tunable multi-wavelength distributed feedback zirconia waveguide lasers --- p.35 / Chapter 5.1 --- Brief introduction on multi-wavelength lasers --- p.35 / Chapter 5.2 --- R6G-doped zirconia multi-mode waveguides --- p.36 / Chapter 5.3 --- Experimental results and discussion --- p.39 / Chapter 5.3.1. --- Dual- and quadruple-wavelength DFB waveguide lasers --- p.39 / Chapter 5.3.2. --- The dispersion characteristics of multi-wavelength DFB waveguide lasers --- p.44 / Chapter 5.3.3. --- Determination of waveguide parameters by the DFB technique --- p.48 / Chapter 5.4 --- Summary --- p.51 / Chapter Chapter VI --- Distributed feedback laser action in sol-gel glass symmetric waveguides --- p.53 / Chapter 6.1 --- The fabrication of dye-doped glass symmetric waveguides --- p.54 / Chapter 6.2 --- Experimental results and discussion --- p.56 / Chapter 6.2.1. --- DFB laser action in sol-gel glass symmetric-asymmetric waveguide --- p.56 / Chapter 6.2.2. --- Dispersion characteristics of DFB symmetric and asymmetric waveguide lasers --- p.61 / Chapter 6.3 --- Summary --- p.65 / Chapter Chapter VII --- Summary --- p.69 / References --- p.74

Supported metal oxides (SMOs) are important catalytic materials that find numerous applications in important industrial processes. Improving the structural properties of SMOs is a challenging objective due to material synthesis and characterization limitations. Recent developments in the characterization of SMOs, specifically tungstated zirconia (WO x /ZrO 2 ), have revealed structural information that renewed scientific interest in developing more sophisticated synthetic protocols for SMOs. The current work aims to provide a robust characterization of WO x /ZrO 2 by using different characterization techniques and probe reactions. Conventional and non-conventional synthetic methods are investigated to cover the whole spectrum of published methods in order to understand the properties and limitations of these techniques. In the second part of this work, a new synthetic approach is presented that successfully produces ultrasmall (smaller than 2 nm) tungsten oxide nanoparticles (WO x NPs). By using conventional tungsten precursors and oleylamine, WO x NPs are synthesized, characterized, and finally supported to test their propene metathesis activity. Conventional WO x /ZrO 2 catalysts were prepared and extensively studied by probing their n -pentane isomerization activity and methanol dehydration activity. WO x /ZrO 2 prepared via incipient wetness impregnation shows maximum n -pentane isomerization turnover rates ( TOR ) at intermediate surface densities ( � surf ). This method delivers the most active n -pentane isomerization WO x /ZrO 2 catalysts since it maximizes the number density of the active sub-nm slightly distorted Zr-WO x sites at � surf between 5.2-6.2 W/nm 2 . By comparing the n -pentane isomerization activity with the methanol dehydration activity of WO x /ZrO 2 , n -pentane isomerization is shown to be an excellent probe reaction for qualitatively identifying the relative (to the other species) population density of Zr-WO x clusters. Bimolecular n -pentane isomerization is the prevailing mechanism and requires a higher population density of Zr-WO x clusters than methanol dehydration. In the second part of this work, a new solvothermal synthesis route for the preparation of ultrasmall tungsten oxide nanoparticles (WO x NPs) is introduced. By using ammonium polyanionic salts and oleylamine, high yields (92±5%) of oleylaminecoated WO x NPs were consistently synthesized. The co-addition of an organic oxidant during the synthesis led to smaller WO x NPs thereby providing insight into the NP synthesis mechanism. Deposition and activation of the NPs on SiO 2 support by removal of oleylamine allows better control over the WO x domain size than conventional methods. Oleylamine suppresses WO x NP sintering during calcination and prevents the formation of larger polytungstates present in conventional catalysts. The supported WO x NPs were found to be up to 3 times more selective for metathesis products than conventionally prepared tungstated silica likely due to their controlled structure.

The purpose of this work is to extend the functionality of the Master Sintering Curve (MSC) such that it can be used as a practical tool for predicting sintering schemes that combine both a constant heating rate and an isothermal hold. Rather than just being able to predict a final density for the object of interest, the extension to the MSC will actually be able to model a sintering run from start to finish. Because the Johnson model does not incorporate this capability, the work presented is an extension of what has already been shown in literature to be a valuable resource in many sintering situations. A predicted sintering curve that incorporates a combination of constant heating rate and an isothermal hold is more indicative of what is found in real-life sintering operations. This research offers the possibility of predicting the sintering schedule for a material, thereby having advanced information about the extent of sintering, the time schedule for sintering, and the sintering temperature with a high degree of accuracy and repeatability. The research conducted in this thesis focuses on the development of a working model for predicting the sintering schedules of several stabilized zirconia powders having the compositions YSZ (HSY8), 10Sc1CeSZ, 10Sc1YSZ, and 11ScSZ1A. The compositions of the four powders are first verified using x-ray diffraction (XRD) and the particle size and surface area are verified using a particle size analyzer and BET analysis, respectively. The sintering studies were conducted on powder compacts using a double pushrod dilatometer. Density measurements are obtained both geometrically and using the Archimedes method. Each of the four powders is pressed into 1/4 inch diameter pellets using a manual press with no additives, such as a binder or lubricant. Using a double push-rod dilatometer, shrinkage data for the pellets is obtained over several different heating rates. The shrinkage data is then converted to reflect the change in relative density of the pellets based on the green density and the theoretical density of each of the compositions. The Master Sintering Curve (MSC) model is then utilized to generate data that can be utilized to predict the final density of the respective powder over a range of heating rates. The Elton Master Sintering Curve Extension (EMSCE) is developed to extend the functionality of the MSC tool. The parameters generated from the original MSC are used in tandem with the solution to a specific closed integral (discussed in document) over a set range of temperatures. The EMSCE is used to generate a set of sintering curves having both constant heating rate and isothermal hold portions. The EMSCE extends the usefulness of the MSC by allowing this generation of a complete sintering schedule rather than just being able to predict the final relative density of a given material. The EMSCE is verified by generating a set of curves having both constant heating rate and an isothermal hold for the heat-treatment. The modeled curves are verified experimentally and a comparison of the model and experimental results are given for a selected composition. Porosity within the final product can hinder the product from sintering to full density. It is shown that some of the compositions studied did not sinter to full density because of the presence of large porosity that could not be eliminated in a reasonable amount of time. A statistical analysis of the volume fraction of porosity is completed to show the significance of the presence in the final product. The reason this is relevant to the MSC is that the model does not take into account the presence of porosity and assumes that the samples sinter to full density. When this does not happen, the model actually under-predicts the final density of the material.

M. Tech. Department of Chemical and Metallurgical Engineering. / Aims to understand and study the tribology and tribocorrosion behaviour of the adaptive titanium-nickel-zirconia composite coatings deposited on AISI 316 stainless steel using laser surface deposition technique under various laser processing speeds. The research aim is meant to be achieved through the following objectives: 1. Determine appropriate procedure for laser feedstock deposition ; 2. Investigate tribological performance of laser composites under various loads ; 3. Evaluate the corrosion of the laser composites coatings. and 4. Assess tribocorrosion behavior of the composite coatings

No description available.

Thesis (Ph. D.)--Ohio State University, 2007. / Title from first page of PDF file. Includes bibliographical references (p. 216-224).

Thesis (M.S.M.S.E.)--University of Central Florida, 2009. / Adviser: Nina Orlovskaya. Includes bibliographical references (p. 87-93).

Thesis (M.S.)--Mississippi State University. Dave C. Swalm School of Chemical Engineering. / Title from title screen. Includes bibliographical references.

Thesis (Ph. D.)--Delft University of Technology, 1999. / Includes bibliographical references.

Thesis (Ph. D.)--Mississippi State University. Dave C. Swalm School of Chemical Engineering. / Title from title screen. Includes bibliographical references.