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Previous issue date: 2005-10-14 / Conselho Nacional de Desenvolvimento Cient?fico e Tecnol?gico / The chemical nature of the hidrocarbons found in gasoline directly affects the formation of oxidation complexes known as gums. Such complexes are slightly soluble in gasoline and their formation is delayed with the use of inhibitors, known as antioxidants. In this study, a synthetic compound (βnaphtol) and a natural subproduct (hydrogenated cardanol, derived from cashewnut shell liquid CNSL) have been used in order to generate novel antioxidant substances. These compounds were submitted to chemical reactions including alkylation, nitration and reduction, with the purpose of forming the following derivatives: 6(Nethyl,Nethylamino)βnaphtol (AO1); 6(Nethyl,Ndiethylamino)βnaphtol (AO2); aminoβnaphtol (AO3); 2(Nethyl,Nethylamino)pentadecylphenol (AOC1), 2(Nethyl,Ndiethylamino)pentadecylphenol (AOC2) and aminopentadecylphenol (AOC3). The derivatives were subjected to accelerated oxidative stability assays (Potential Gum and Induction Period) and to storage assays (Washed Gum and ASTM Color) during six months, with naphtha provided by the petroleum refinery RPBC (Refinaria Presidente Bernardes de Cubat?o, in Brazil). The results for the derivatives were compared to those for commercial additives [DBPC (2,6ditbutyl4methylpcresol) and PDA (N,N disecbutylpphenylenediamine)], which were also added to the naphtha produced at RPBC at the moment of sampling. From all tested antioxidants, the novel antioxidant AOC1 (derived from hydrogenated cardanol) yielded a better global performance. During the period of time in which the naphtha was stored, an examination of this material was carried out in parallel, using the mass spectrometry technique. This study allowed to monitor the formation of a triolefinic compound, as well as the observation of subsequent formation and rupture of the olefinic constituents. As an eventual result from these experimental investigations, a reaction route leading to gum formation has been suggested / O tipo de hidrocarboneto presente na gasolina influencia diretamente na forma??o de complexos de oxida??o conhecidos como goma. Estes complexos s?o levemente sol?veis em gasolinas e sua forma??o ? retardada atrav?s de uso de inibidor, conhecido como antioxidante. Neste estudo utilizouse um composto de origem sint?tica (βnaftol) e um subproduto natural (cardanol hidrogenado (derivado do l?quido da castanha de caju (LCC)) para obten??o de novas subst?ncias antioxidantes. Os compostos citados foram submetidos a rea??es qu?micas de alquila??o, nitra??o e redu??o para obten??o dos seguintes derivados : 6(Netil,Netilamino)βnaftol (AO1), 6(Netil,Ndietilamino)βnaftol (AO2), Aminoβnaftol (AO3), 2(Netil,Netilamino)pentadecilfenol (AOC1), 2(Netil,Ndietilamino)pentadecilfenol (AOC2) e Aminopentadecilfenol (AOC3). Os novos derivados foram submetidos a ensaios acelerados de estabilidade oxidativa (Goma Potencial e Per?odo de Indu??o) e a testes de estocagem (Goma Lavada e Cor ASTM) durante seis meses com nafta amostrada na RPBC (Refinaria Presidente Bernardes de Cubat?o). Os resultados com os novos derivados foram comparados ?queles obtidos com aditivos comerciais [DBPC (2,6diterbutil (4 metil)pcresol) e PDA (N,N disecbutilpfenilenodiamina)]que tamb?m foram adicionados ?s naftas da RPBC no momento da amostragem. O novo antioxidante AOC1(derivado do cardanol hidrogenado) apresentou melhor desempenho global dentre todos os antioxidantes amostrados. Durante o per?odo em que as naftas amostradas foram estocadas, foi realizado, em paralelo, um acompanhamento deste material atrav?s da t?cnica de Espectrometria de Massas e registrouse, n?o somente, a forma??o de um composto triolef?nico, como tamb?m acompanhouse as forma??es e as rupturas, subseq?entes, de compostos olef?nicos. Este acompanhamento possibilitou a sugest?o de uma rota reacional que leva ? forma??o de goma
| Identifer | oai:union.ndltd.org:IBICT/oai:repositorio.ufrn.br:123456789/15931 |
| Date | 14 October 2005 |
| Creators | Dantas, Michelle Sinara Greg?rio |
| Contributors | CPF:07286937391, http://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4783139Z0&dataRevisao=null, Teixeira, Leonardo Sena Gomes, CPF:67108059568, http://lattes.cnpq.br/5061261000226463, Maciel, Maria Aparecida Medeiros, CPF:37320165449, http://lattes.cnpq.br/5360188002708095, Fonseca, Jos? Luis Cardozo, CPF:90623207753, http://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4788562T6, Oliveira, Edimilson Jesus de, CPF:07622734888, http://lattes.cnpq.br/1939037019646653, Dantas Neto, Afonso Avelino, Dantas, Tereza Neuma de Castro |
| Publisher | Universidade Federal do Rio Grande do Norte, Programa de P?s-Gradua??o em Engenharia Qu?mica, UFRN, BR, Pesquisa e Desenvolvimento de Tecnologias Regionais |
| Source Sets | IBICT Brazilian ETDs |
| Language | Portuguese |
| Detected Language | English |
| Type | info:eu-repo/semantics/publishedVersion, info:eu-repo/semantics/doctoralThesis |
| Format | application/pdf |
| Source | reponame:Repositório Institucional da UFRN, instname:Universidade Federal do Rio Grande do Norte, instacron:UFRN |
| Rights | info:eu-repo/semantics/openAccess |
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