Electric field studies, electrochromism, were used to obtain excited-state data for analogous divalent sulfur compounds. The sulfides investigated were dimethyl sulfide and small cyclic sulfides including the three to six member ring compounds. The excited-state dipole moments and polarizabilities are reported for the first s, p, and d Rydberg absorption bands which occur in the near vacuum ultraviolet region from 230 to 170 nm. The excited-state data are interpreted in terms of the particular excited-state (s, p, or d) for the molecules and the bending differences due to the presence of the ring and the number of atoms in the ring. The next section describes the use of electrochromism to investigate the pressure effect of argon, carbon tetrafluoride and sulfur hexafluoride on the spectra for molecular Rydberg states.
| Identifer | oai:union.ndltd.org:unt.edu/info:ark/67531/metadc331713 |
| Date | 12 1900 |
| Creators | Altenloh, Daniel Dean |
| Contributors | Russell, Benny, Jones, Paul R., Daugherty, Kenneth E., Redding, Rogers W., Desiderato, Robert, Schwartz, Martin |
| Publisher | North Texas State University |
| Source Sets | University of North Texas |
| Language | English |
| Detected Language | English |
| Type | Thesis or Dissertation |
| Format | vi, 252 leaves : ill., Text |
| Rights | Public, Altenloh, Daniel Dean, Copyright, Copyright is held by the author, unless otherwise noted. All rights reserved. |
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