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Pressure Effects on Electric Field Spectra of Molecular Rydberg States

Electric field studies, electrochromism, were used to obtain excited-state data for analogous divalent sulfur compounds. The sulfides investigated were dimethyl sulfide and small cyclic sulfides including the three to six member ring compounds. The excited-state dipole moments and polarizabilities are reported for the first s, p, and d Rydberg absorption bands which occur in the near vacuum ultraviolet region from 230 to 170 nm. The excited-state data are interpreted in terms of the particular excited-state (s, p, or d) for the molecules and the bending differences due to the presence of the ring and the number of atoms in the ring. The next section describes the use of electrochromism to investigate the pressure effect of argon, carbon tetrafluoride and sulfur hexafluoride on the spectra for molecular Rydberg states.

Identiferoai:union.ndltd.org:unt.edu/info:ark/67531/metadc331713
Date12 1900
CreatorsAltenloh, Daniel Dean
ContributorsRussell, Benny, Jones, Paul R., Daugherty, Kenneth E., Redding, Rogers W., Desiderato, Robert, Schwartz, Martin
PublisherNorth Texas State University
Source SetsUniversity of North Texas
LanguageEnglish
Detected LanguageEnglish
TypeThesis or Dissertation
Formatvi, 252 leaves : ill., Text
RightsPublic, Altenloh, Daniel Dean, Copyright, Copyright is held by the author, unless otherwise noted. All rights reserved.

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