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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
101

Assessment of lime-treated clays under different environmental conditions

Ali, Hatim F.A. January 2019 (has links)
Natural soils in work-sites are sometimes detrimental to the construction of engineering projects. Problematic soils such as soft and expansive soils are a real source of concern to the long-term stability of structures if care is not taken. Expansive soils could generate immense distress due to their volume change in response to a slight change in their water content. On the other hand, soft soils are characterised by their low shear strength and poor workability. In earthwork, replacing these soils is sometimes economically and sustainably unjustifiable in particular if they can be stabilised to improve their behaviour. Several techniques have evolved to enable construction on problematic soils such as reinforcement using fibre and planar layers and piled reinforced embankments. Chemical treatment using, e.g. lime and/or cement is an alternative method to seize the volume change of swelling clays. The use of lime as a binding agent is becoming a popular method due to its abundant availability and cost-effectiveness. When mixed with swelling clays, lime enhances the mechanical properties, workability and reduces sensitivity to absorption and release of water. There is a consensus in the literature about the primary mechanisms, namely cation exchange, flocculation and pozzolanic reaction, which cause the changes in the soil characteristics after adding lime in the presence of water. The dispute is about whether these mechanisms occur in a sequential or synchronous manner. More precisely, the controversy concerns the formation of cementitious compounds in the pozzolanic reaction, whether it starts directly or after the cation exchange and flocculation are completed. The current study aims to monitor the signs of the formation of such compounds using a geotechnical approach. In this context, the effect of delayed compaction, lime content, mineralogy composition, curing time and environmental temperature on the properties of lime-treated clays were investigated. The compaction, swelling and permeability, and unconfind compression strength tests were chosen to evaluate such effect. In general, the results of the geotechnical approach have been characterised by their scattering. The sources of this dispersion are numerous and include sampling methods, pulverisation degree, mixing times and delay of compaction process, a pre-test temperature and humidity, differences in dry unit weight values, and testing methods. Therefore, in the current study, several precautions have been set to reduce the scattering in the results of such tests so that they can be used efficiently to monitor the evolution in the properties that are directly related to the formation and development of cementitious compounds. Four clays with different mineralogy compositions, covering a wide range of liquid limits, were chosen. The mechanical and hydraulic behaviour of such clays that had been treated by various concentrations of lime up to 25% at two ambient temperatures of 20 and 40oC were monitored for various curing times. The results indicated that the timing of the onset of changes in mechanical and hydraulic properties that are related to the formation of cementitious compounds depends on the mineralogy composition of treated clay and ambient temperature. Moreover, at a given temperature, the continuity of such changes in the characteristics of a given lime-treated clay depends on the lime availability.
102

Molecular/Nano Level Approaches for the Enhancement of Axial Compressive Properties of Rigid-Rod Polymers

Dang, Thuy Dinh 03 November 2009 (has links)
No description available.
103

Pre-hydration as a technique for the retardation of Roman cement mortars

Starinieri, V., Hughes, David C., Gosselin, C., Wilk, D., Bayer, K. 10 January 2013 (has links)
No / The setting of Roman cement is so rapid as to make the use of retardation essential in most practical mortars. This work reports an approach to retardation of Roman cement mortars by means of a pre-hydration process in which pre-determined amounts of water (de-activation water) are added to the cement prior to subsequent mortar formation. It is shown that this process yields both monocarboaluminate and a carbonated AF(m) phase, the balance of which is modified by storage time; the belite phases are not affected. Increases in both de-activation water and pre-hydrated mix storage time yield a longer workable life and slightly lower strength of the mortar. An increase in de-activation water also yields an increase in shrinkage whilst an increase in storage time results in a reduction in shrinkage. Other parameters such as mixing protocol and re-mixing affect workable life without compromising the strength. (C) 2013 Elsevier Ltd. All rights reserved.
104

Characterization and life cycle assessment of geopolymer mortars with masonry units and recycled concrete aggregates assorted from construction and demolition waste

Kul, A., Ozel, B.F., Ozcelikci, E., Gunal, M.F., Ulugol, H., Yildirim, Gurkan, Sahmaran, M. 24 August 2023 (has links)
Yes / Developing a fast, cost-effective, eco-friendly solution to recycle large amounts of construction and demolition waste (CDW) generated from construction industry-related activities and natural disasters is crucial. The present investigation aims to offer a solution for repurposing CDW into building materials suitable for accelerated construction and housing in developing countries and disaster-prone areas. Feasibility of recycled concrete aggregate (RCA) inclusion in geopolymer mortars constituted entirely from CDW (masonry elements) was investigated via an environmental impact-oriented approach by addressing the composition related key parameters. Mechanical performance was evaluated through compressive strength tests, and scanning electron microscope (SEM) imaging with line mapping analyses were carried out to monitor the interfacial transition zone (ITZ) properties. To investigate the environmental impacts of the geopolymer mortars and highlight the advantages over Portland cement-based mortars, a cradle-to-gate life cycle assessment (LCA) was performed. Findings revealed that roof tile (RT)-based geopolymer mortars mainly exhibited better strength performance due to their finer particle size. Mixtures activated with 15 M NaOH solution and cured at 105 °C achieved an average compressive strength above 55 MPa. RCA size was the most influential parameter on compressive strength, and a smaller maximum RCA size significantly increased the compressive strength. Microstructural analyses showed that the ITZ around smaller RCAs was relatively thinner, resulting in better compressive strength results. LCA proved that CDW-based geopolymer mortars provide the same compressive strength with around 60% less CO2 emissions and similar energy consumption compared to Portland cement-based mortars. / This project has received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement No 894100. The authors also wish to acknowledge the support of the Scientific and Technical Research Council of Turkey (TUBITAK) provided under project: 117M447
105

[pt] O EFEITO DO USO DE ALTAS DOSAGENS DE ESCÓRIA DE ALTO FORNO NA HIDRATAÇÃO DO CIMENTO PORTLAND / [en] THE EFFECT OF HIGH DOSAGE OF SLAG IN THE PORTLAND CEMENT HYDRATION

MARLOS ROMERO ALVES 19 August 2024 (has links)
[pt] O presente trabalho tem como objetivo investigar os efeitos químicos, físicos e mecânicos de altas dosagens de escória granulada de alto forno (85 por cento) como adição em cimentos Portland. Foram feitas quatro amostras, sendo uma do cimento padrão referência conhecido como CP IND e com as dosagens de adição de escória, com 60 por cento de adição de escória (usual do mercado), 85 por cento de escória sem aditivo (branco) e 85 por cento de escória com 7,5 por cento de aditivo ativador (Metassilicato de Sódio Anidro). Os materiais foram caracterizados quanto sua composição química, área superficial e granulometria por ensaios de Fluorescência, Blaine e granulometria laser. Para investigar a formação das fases foram realizadas análises de difratometria de raios-x (DRX) e calorimetria. Finalmente, os cimentos hidratados foram ensaiados em compressão uniaxial para as idades de 1, 3, 7, 28 e 91 dias para medir a resistência à compressão na argamassa padrão de cimento pelo método de argamassa padrão, e em 1, 7 e 28 dias em concreto. O uso desse ativador garantiu a reserva alcalina, elevando a precipitação de produtos de hidratação. As misturas ativadas com 85 por cento de escória apresentaram resultados de resistência à compressão satisfatórios para cimentos Portland Classe de resistência 25 MPa. O cimento com 85 por cento de adição de escória ativado com metassilicato de sódio anidro apresentou um desempenho, na argamassa padrão de cimento, na idade de 1 dia, mais de 4 vezes superior quando comparado ao cimento com 85 por cento de adição de escória sem ativador. Esse desempenho foi diminuindo à medida que hidratação evolui, quando se esperava ao contrário, demonstrando que o percentual utilizado e a granulometria do ativador podem não ter sido a mais adequada, havendo a necessidade de um estudo mais aprofundado tanto nessa relação quanto na verificação da porosidade das misturas. / [en] The present work investigates the chemical, physical and mechanical effects of high dosages of granulated blast furnace slag (85 percent) as an addition to Portland cements. Four samples were made, one of the reference standard cement known as CP IND and with the slag addition dosages, with 60 percent slag addition (usual on the market), 85 percent slag without additive (white) and 85 percent slag with 7.5 percent activating additive (Anhydrous Sodium Metasilicate). The materials were characterized regarding their chemical composition, surface area and particle size by Fluorescence, Blaine and laser particle size tests. To investigate the formation of the phases, x-ray diffractometry (XRD) and calorimetry analyzes were carried out. Finally, the hydrated cements were tested in uniaxial compression at ages of 1, 3, 7, 28 and 91 days to measure the compressive strength in the cement paste, and at 1, 7 and 28 days in concrete. The use of this activator guaranteed the alkaline reserve, increasing the precipitation of hydration products. The mixtures activated with 85 percent slag presented satisfactory compressive strength results for Portland cements Strength Class 25 MPa. The cement with 85 percent addition of slag activated with anhydrous sodium metasilicate presented a performance, in the cement paste, at the age of 1 day, more than 4 times higher when compared to cement with 85 percents lag addition without activator. This performance decreased as hydration progressed, when the opposite was expected, demonstrating that the percentage used and the granulometry of the activator may not have been the most appropriate, with the need for a more in-depth study both in this relationship and in the verification of the porosity of the mixtures.
106

Tests on elliptical concrete filled steel tubular (CFST) beams and columns

Ren, Q-X., Han, L-H., Lam, Dennis, Li, W. 04 May 2014 (has links)
No / This paper presents a series of test results of elliptical concrete filled steel tubular (CFST) beams and columns to explore their performance under bending and compression. A total of twenty-six specimens were tested, including eight beams under pure bending and eighteen columns under the combination of bending and compression. The main parameters were the shear span to depth ratio for beams, the slenderness ratio and the load eccentricity for columns. The test results showed that the CFST beams and columns with elliptical sections behaved in ductile manners and were similar to the CFST members with circular sections. Finally, simplified models for predicting the bending strength, the initial and serviceability-level section bending stiffness of the elliptical CFST beams, as well as the axial and eccentric compressive strength of the composite columns were discussed.
107

The effects of lime content and environmental temperature on the mechanical and hydraulic properties of extremely high plastic clays

Ali., H., Mohamed, Mostafa H.A. 25 April 2018 (has links)
Yes / This paper focuses on monitoring the evolution of lime-clay reactions using geotechnical parameters as a function of lime content and environmental temperature. Lime contents of 5, 7, 9, 11 and 13% by dry weight of expansive clay powder were added to prepare lime-clay specimens. The specimens were prepared at the same dry unit weight of 12.16 kN/m3 and moisture content of 40% except for tests aimed at the determination of dry unit weight as a function of mellowing period. Prepared specimens were mellowed or cured at two different ambient temperatures of 20 °C and 40 °C. Results attained from Unconfined Compressive Strength and permeability tests were employed to assess the impact of lime content on the mechanical and hydraulic properties of lime treated expansive clays. The results revealed that at the beginning, the rate of strength gain is remarkably fast for a particular period of time which is dependent on lime content. Furthermore, the strength gain on specimens cured at 40 °C is 8 times higher than that observed on specimens cured at 20 °C which highlights significant effect for the environmental temperature on accelerating the chemical reactions. Reduced dry unit weight due to increased resistance to compactability is observable with increasing lime content and higher environmental temperature. Accelerated pozzolanic reaction at higher environmental temperature resulted in permeability coefficient of specimens mellowed for 24 h at 40 °C to be higher than those mellowed at 20 °C. The results also highlighted that the permeability coefficient would be relatively stable when expansive clays were treated with small amounts of lime e.g. 5%.
108

A study on the influencing parameters in developing construction and demolition waste-based geopolymer concretes and their sustainability assessment

Alhawat, Musab, Yildirim, Gurkan, Ashour, Ashraf, Ozcelikci, E., Aldemir, A. 26 July 2024 (has links)
Yes / Construction and demolition waste (CDW) has been recently identified as a potential aluminosilicate source for geopolymers. However, the available research has mainly focused on developing CDW-based geopolymer pastes and mortars, while studies on geopolymer concretes sourced from CDW have been very limited. Thus, the current study aimed at experimentally identifying different CDW materials suitable for producing geopolymer concretes. Additionally, the study analysed the mechanical, microstructural, and environmental properties of CDW- based geopolymer concrete produced. In this regard, the effect of relevant parameters on the compressive strength development of CDW-based geopolymer concretes was comprehensively investigated, including those related to precursor types/fineness, alkali activator solution, aggregate type/size and curing regimes. Microstructural analyses were also conducted on the selected samples (100% brick waste, 100% tile waste, 100% concrete waste and 75% brick waste + 25% GGBS). Finally, the environmental impact of geopolymer concrete was assessed and compared with similar traditional concrete. Results showed that employing CDWs alone is not suitable to achieve sufficient strengths under all curing regimes. However, the inclusion of 25% GGBS significantly improved the strength performance of CDW-based geopolymer concrete, in comparison to other supplementary cementitious materials (SCMs) such as Class-C fly ash and calcium hydroxide. The particle size of CDWs and concentration of alkaline activators highly affect the performance of CDW-based geopolymer concretes. Utilization of CDWs with particles finer than 75 μm and high concentrations of NaOH (12 M) is recommended to achieve good performance. The results also indicate that almost similar energy is needed for producing CDW-based geopolymer and OPC-based traditional concrete, whereas a huge reduction in CO2 emission (∼40%) was estimated in the case of geopolymers. The outcomes of the current study are expected to contribute to the advancement of geopolymer concrete derived from CDW in addition to providing valuable insights into this type of concrete for practitioners and academics.
109

Study of Bond Behavior at Rebar and Concrete Interface through Beam-end Specimens with Consideration of Corrosion

Hauff, Derek Allen Johnson 01 May 2022 (has links)
No description available.
110

Guidelines for preliminary design of beams in eccentrically braced frames

Dara, Sepehr 09 November 2010 (has links)
Seismic-resistant steel eccentrically braced frames (EBFs) are designed so that that yielding during earthquake loading is restricted primarily to the ductile links. To achieve this behavior, all members other than the link are designed to be stronger than the link, i.e. to develop the capacity of the link. However, satisfying these capacity design requirements for the beam segment outside of the link can be difficult in the overall design process of an EBF. In some cases, it may be necessary to make significant changes to the configuration of the EBF in order to satisfy beam design requirements. If this discovery is made late in the design process, such changes can be costly. The overall goal of this research was to develop guidelines for preliminary design of EBFs that will result in configurations where the beam is likely to satisfy capacity design requirements. Simplified approximate equations were developed to predict the axial force and moment in the beam segment outside of the link when link ultimate strength is developed. These equations, although approximate, provided significant insight into variables that affect capacity design of the beam. These equations were then used to conduct an extensive series of parametric studies on a wide variety of EBF configurations. The results of these studies show that the most important variables affecting beam design are 1) the nondimensional link length, 2) the ratio of web area to total area for the wide flange section used for the beam and link, 3) the angle between the brace and the beam, and 4) the flexural stiffness of the brace relative to the beam. Recommendations are provided for selection of values for these variables in preliminary design. / text

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