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Th.--Sci. polit.--Genève, 1978, n°294. / Bibliogr. p. 405-416.

Th. doct.-ing.--Nancy, I.N.P.L., 1978.

High-resolution three-dimensional (3D) shape reconstruction of objects has huge potential for applications in the field of design, security, entertainment, biomedicine, industrial quality control etc. Of the available techniques, optical methods have the distinctive advantage of facilitating non-contact and non-intrusive measurements. Of late, integration of optical measurement system with the computer based data processing has improved the quality of the results. Of the available techniques, structured-light illumination (Fringe Projection) is the most effective, owing its simplistic experimental architecture and analysis. Traditional Fringe Projection techniques function with the use of fringes generated using interferometric methods. With the advent of digital light projectors, digitally generated fringes have taken the place of interferometry based fringes. Despite the technological advances that this field has witnessed over last couple of decades, digital fringe projection technique still suffers from various shortcomings. This thesis presents a strategic solution to the challenges faced by the technique in its application to out-of-plane deformation measurement of objects under impact loading. First part of the thesis reports the developmental work on building an LED-Grating based optical projection system for implementation of linear-fringe projection profilometry. Successful use of the developed system in measuring out-of-plane deformation experienced by multiple targets under impact loading with a time sapling of 20,000 frames per second is re-ported. However, for performing ballistic impact measurements using the liner-fringe projection method, an order of magnitude higher time-sampling is needed. This is due to the disadvantages associated with linear fringe projection technique: (1) results in wrapped phase map (2p ambiguity) estimation, and (2) the deformation/shift of the recorded fringe pattern in the modulation direction sets a limit on unambiguously measurable whole-plane displacement. Typically, fringe pitch dictates the limit of maximum detectable displacement, and thus to be able to capture larger deformation from the earlier state, coarser fringe pitch is required to be projected; while this adversely affects the resolution of measurement system. Hence, there is a need to develop a fringe projection system which has capability for whole-plane displacement without affecting the resolution and/or necessitating higher temporal-sampling. Circular Fringe Projection (CFP) technique is proposed in the second part of the thesis as a novel solution to address the above issues. CFP technique offers additional advantage of relaxing the temporal resolution requirements of the imaging system by decoupling the maximum measurable deformation rate and the frame rate of camera. A new image analysis method is also developed to extract the underlying phase distribution of the recorded circular-fringe patterns, as the conventionally used single-frame linear-fringe analysis methods are incompetent at demodulating the circular fringes. Experimental results obtained in 3D shape measurement and whole-field out-of-plane displacement measurements of a deforming object reported in this thesis, not only confirms the ability of the proposed CFP technique in overcoming the shortcomings of the widely used linear-fringe projection technique, but also its suitability for deployment in ballistic-impact measurements.

A third of adults in the UK admit to using controlled substances at least once hi their lives and the most commonly abused drug was found to be cannabis, followed by the opiates and ecognine derivatives. Forensic laboratories are continually trying to reduce the turnaround time for samples submitted for analysis, to less than the current time of four days. One of the main aims of this work was to reduce the time taken to prepare, extract and analyse hair for target analytes. A new method combining supercritical fluid extraction and solid phase micro-extraction (SFE/SPME) is introduced. This coupled procedure utilises the advantages of using supercritical carbon dioxide as an extraction solvent and collecting the extract on a selected SPME fibre. Together the combined techniques provide a method that is solvent-free and highly selective, whilst reducing sample preparation to a minimum. Digested hair samples are examined by SEM to find the best method. Alkali hydrolysis and enzyme digestion using proteinase K were found to be the most effective pre-extraction methods. Solid hair samples with the addition of a derivatization reagent (BSTFA) gave the best results using the coupled technique. After optimisation and validation, the extraction from both real and spiked samples resulted in recoveries between 60% to 80% for the target analytes A9 -tetrahydrocannabinol (A9- THC) , cannabinol (CBN) and cannabidiol (CBD). Other forensic applications such as the extraction of polycyclic aromatic hydrocarbons and pesticides from environmental and food samples and the examination of fire debris for the presence of accelerants are also carried out. PAH could easily be extracted from complex matrices to give recoveries of up to 97% for some analytes at the optimized conditions of 90°C at 4500 psi over a 10 minute dynamic extraction period. Pesticide extraction gave recoveries of 60 - 80% while the extraction of accelerants from fire debris clearly showed that accelerants such as diesel can be identified over the coincidental PAH and hydrocarbon peaks found in burnt debris. The coupling of SFE to SPME provides an exciting technique that has a wide range of applications and creates potential for a fully automated on-line system.

From Introduction: Creative images which are normally called 'art' can be distinguished as either 'plastic' or visual. Both these forms throughout the history of art have relied to a greater or lesser degree on the use of colour. It is my intention to investigate specifically the changing role which colour has played in sculpture - the 'plastic' media of the visual arts and to chart the technical and aesthetic reasons for the use of colour. This investigation will encompass the historical perspective, the material qualities, aesthetic considerations, transitional codes and methods of approach in sociological frameworks and the examination of colour as a metaphysical element in the presentation of three dimensional media.