Call number: LD2668 .T4 1978 T66 / Master of Science

Eskom provides 98% of South Africa’s ever increasing electricity demand. The mining sector is a vital contributor to the economy, but also consumes vast amounts of electricity. This sector is responsible for almost 15% of the country’s electricity usage. Mines heavily depend on the supply of cold water and air. Refrigeration systems are therefore constantly operational and can account for 25% of a mine’s electricity costs. The need therefore exists to investigate possible energy savings initiatives. Refrigeration systems are typically used to lower the temperature of water and air. Bulk Air Coolers (BACs) are used to produce cold air. The aim of this study is to investigate possible electricity cost savings in a mine refrigeration system. This can be achieved by enabling equipment to dynamically adapt to changes in their environment. Electricity usage reduction has the greatest financial impact if it occurs during Eskom peak periods. Time-dependent schedules of operation are therefore used to achieve this objective. Due to the lack of such a controller in the mining industry, the focus of this study is a BAC control system. A BAC controller would be able to follow guidelines that could lead to electricity cost savings. It was therefore developed and incorporated in the Real-time Energy Management System (REMS). The BAC controller combines various inputs and constraints to determine the output. An electricity usage reduction during the Eskom evening peak period was consequently achieved. The BAC controller was implemented on three sites. Electrical energy usage during the evening peak period was reduced via the load shifting method. This aids Eskom in their effort to reduce the peak period demand. Air temperature and dam levels were closely monitored during the peak period. If any preset condition was violated, the load shifting was abandoned for that day. It was shown that a total power reduction of 7 MW is possible between the three sites. The electricity savings occurred in the evening peak period. A calculation was made to determine the possible annual savings by using the achieved daily cost savings. The winter months were not included in the calculation. An annual cost saving of R1 166 694.41 is therefore possible without having to reduce output quantities. / MIng(Computer and Electronic Engineering), North-West University, Potchefstroom Campus, 2015

Eskom provides 98% of South Africa’s ever increasing electricity demand. The mining sector is a vital contributor to the economy, but also consumes vast amounts of electricity. This sector is responsible for almost 15% of the country’s electricity usage. Mines heavily depend on the supply of cold water and air. Refrigeration systems are therefore constantly operational and can account for 25% of a mine’s electricity costs. The need therefore exists to investigate possible energy savings initiatives. Refrigeration systems are typically used to lower the temperature of water and air. Bulk Air Coolers (BACs) are used to produce cold air. The aim of this study is to investigate possible electricity cost savings in a mine refrigeration system. This can be achieved by enabling equipment to dynamically adapt to changes in their environment. Electricity usage reduction has the greatest financial impact if it occurs during Eskom peak periods. Time-dependent schedules of operation are therefore used to achieve this objective. Due to the lack of such a controller in the mining industry, the focus of this study is a BAC control system. A BAC controller would be able to follow guidelines that could lead to electricity cost savings. It was therefore developed and incorporated in the Real-time Energy Management System (REMS). The BAC controller combines various inputs and constraints to determine the output. An electricity usage reduction during the Eskom evening peak period was consequently achieved. The BAC controller was implemented on three sites. Electrical energy usage during the evening peak period was reduced via the load shifting method. This aids Eskom in their effort to reduce the peak period demand. Air temperature and dam levels were closely monitored during the peak period. If any preset condition was violated, the load shifting was abandoned for that day. It was shown that a total power reduction of 7 MW is possible between the three sites. The electricity savings occurred in the evening peak period. A calculation was made to determine the possible annual savings by using the achieved daily cost savings. The winter months were not included in the calculation. An annual cost saving of R1 166 694.41 is therefore possible without having to reduce output quantities. / MIng(Computer and Electronic Engineering), North-West University, Potchefstroom Campus, 2015

Bulk modulus of hydraulic oil represents the resistance of hydraulic oil to compression and is the reciprocal of compressibility. The bulk modulus is a basic thermodynamic property of hydraulic oil that has a very important influence on work efficiency and dynamic characteristics of hydraulic systems, especially for the hydraulic systems at ultra-high pressure or ultra-high temperature. In this study, a bulk modulus experimental equipment for hydraulic oil was designed and manufactured, two types of hydraulic oil were selected and its isothermal secant bulk modulus were measured at pressures to 140MPa and temperatures of 20~180°C. Compared the experimental results with the calculated results from the prediction equations of liquid bulk modulus that proposed by Klaus, Hayward, and Song, it is found that the experimental results are not completely identical with the calculated results.

This work presents an automatic cost-analysis system for an implicitly parallel skeletal programming language. Although deducing interesting dynamic characteristics of parallel programs (and in particular, run time) is well known to be an intractable problem in the general case, it can be alleviated by placing restrictions upon the programs which can be expressed. By combining two research threads, the “skeletal” and “shapely” paradigms which take this route, we produce a completely automated, computation and communication sensitive cost analysis system. This builds on earlier work in the area by quantifying communication as well as computation costs, with the former being derived for the Bulk Synchronous Parallel (BSP) model. We present details of our shapely skeletal language and its BSP implementation strategy together with an account of the analysis mechanism by which program behaviour information (such as shape and cost) is statically deduced. This information can be used at compile-time to optimise a BSP implementation and to analyse computation and communication costs. The analysis has been implemented in Haskell. We consider different algorithms expressed in our language for some example problems and illustrate each BSP implementation, contrasting the analysis of their efficiency by traditional, intuitive methods with that achieved by our cost calculator. The accuracy of cost predictions by our cost calculator against the run time of real parallel programs is tested experimentally. Previous shape-based cost analysis required all elements of a vector (our nestable bulk data structure) to have the same shape. We partially relax this strict requirement on data structure regularity by introducing new shape expressions in our analysis framework. We demonstrate that this allows us to achieve the first automated analysis of a complete derivation, the well known maximum segment sum algorithm of Skillicorn and Cai.

<p>An increasing number of chemicals are being transported by ships along the Swedish coastline. Many of these chemicals may pose a threat to the environment. Accidents and spills are luckily rare, but nonetheless it is important to be prepared for a possible chemical spill. The Swedish Coast Guard is responsible for responding to chemical spills at sea, and has both equipment and trained personnel for the purpose. In order to prepare for a possible accident one also needs to know what is currently being transported at sea. The aim of this project is therefore to survey the chemical transports in Swedish waters.</p><p>The survey shows that many of the chemicals transported at sea are environmentally harmful and may harm the environment in the event of a spill. The number of accidents that occur is difficult to determine since not all of the smaller ones are reported. It is clear, however, that the main reasons for accidents are groundings and collisions. The collection of information about chemical transports has been difficult because many of the companies and ports are unwilling to give their information. This is part because of concurrence and part due to the fact that it is considered too much work to gather the data.</p><p>The project also aims to make a risk analysis for chemical transports at sea. Because of the insufficient data the risk analysis has only dealt with qualitative assessments for certain chemicals. These assessments show that chemicals which are less environmentally harmful may still pose a threat because of the safety issues for the personnel may delay or even prevent a response action.</p><p>International regulations for transports at sea can sometimes be complicated to apply because of the vast number of different chemicals. The classification process takes time because of the extensive research which is needed. Furthermore, many of the chemicals transported are classified in different systems and these do not always correspond. It is therefore difficult to conclude which chemicals that are actually a threat to the environment.</p> / <p>Varje år transporteras allt större mängder kemikalier med fartyg längs Sveriges kust. Många av dessa kan vara farliga för miljön. Olyckor och utsläpp sker lyckligtvis ganska sällan men det krävs ändå en beredskap för att kunna ta hand om ett eventuellt utsläpp. I Sverige har Kustbevakningen ansvaret för miljöräddningstjänst till sjöss och har både utrustning och personal som är speciellt utbildad för att bekämpa just kemikalieutsläpp. För att kunna förbereda sig på en eventuell olycka måste man dock också ha en aktuell bild av vilka kemikalier det är som transporteras till sjöss. Detta projekt har därför syftat till att kartlägga kemikalietransporterna i svenska farvatten.</p><p>Kartläggningen visar att flera av de kemikalier som transporteras till sjöss är miljöfarliga och kan skada miljön vid ett utsläpp eller en olycka. Hur många olyckor som sker är svårt att veta eftersom många av de mindre olyckorna inte rapporteras. Däremot kan man tydligt se att de vanligaste olycksorsakerna är kollisioner och grundstötningar. Att få tag i uppgifter om hur mycket kemikalier som transporteras har visat sig vara svårt eftersom flera företag och hamnar inte vill tala om hur mycket som transporteras. Det beror dels på konkurrensen mellan kemikalieföretag och dels på att man tycker att det är för jobbigt att behöva sammanställa informationen.</p><p>Projektet har också syftat till att göra en riskanalys över kemikalietransporterna. På grund av det bristfälliga underlaget har riskanalysen endast behandlat kvalitativa bedömningar av ett antal olika kemikalier. Dessa bedömningar visar att även kemikalier som är mindre miljöfarliga kan utgöra en stor risk eftersom de säkerhetsmässiga riskerna för insatspersonalen kan försena eller till och med förhindra en bekämpningsinsats.</p><p>De internationella reglerna kring transporter till sjöss kan ibland vara svåra att tillämpa eftersom det finns ett stort antal olika kemikalier. Klassningen av de olika kemikalierna tar också lång tid då det krävs omfattande underlag. Många av kemikalierna som transporteras är dessutom klassade enligt flera olika system och det är inte alltid dessa system överensstämmer. Det kan därför vara svårt att ta reda på vilka kemikalier som egentligen kan anses vara miljöfarliga.</p>

Tyres are highly engineered complex rubber composite products. They are constructed from a wide range of different materials in addition to the rubber. In different parts of the tyre's construction, the rubber elements are expected to perform different functions and as a consequence many different types of rubber are used, each of which will have its own specific detailed compound formulation. These different regions of a tyre's construction are joined together by different types of molecular bonding. This variety of materials introduces potential sources of failure both in the homogenous regions within the tyre's construction but also at the interfaces between them. This thesis investigates the crack growth resistance of the rubber materials used in different regions of a tyre's construction as well as the interfaces that are found between the different parts of the tyre. A fracture mechanics framework was used to investigate the fatigue behaviour of bulk rubber and some of the interfaces. The loading of a tyre is periodic in nature as a consequence of the wheel's rotation therefore the materials were characterised over a range of loading conditions. The effect of cyclical loading frequency on the fatigue behavior of the bulk rubber was also investigated. This work discovered that the amount of crack growth per cycle was comprised from two different crack growth contributions. The first is related to the steady tear which is related to the length of time the load is applied. The second resulted from additional damage caused by the repeated loading and unloading of the material. Potential reasons for this additional crack growth contribution are discussed. The interfacial fatigue properties between adjoining and potentially dissimilar rubber compounds were examined using a fatigue peeling experiment. A novel test piece geometry was developed to evaluate the fatigue properties of interfaces in tyres and it was also used to investigate how different processing parameters such as the pressure at the interface during vulcanisation alter the interfacial strength. A significant effect was observed and this was related to the different phenomena occurring when two rubbery polymers are brought into contact. Finally, a fracture mechanics approach was also used to derive the value of the tearing energy, the variable governing crack growth propagation in the rubber materials found in tyres, using submodelling technique in finite element analysis. The tearing energy values at different locations within a tyre were calculated and are shown not to exceed the minimum energy criteria for crack propagation under normal service conditions.

Philosophiae Doctor - PhD / The continuous increase in energy consumption and decrease in fossil fuels reserves are a primary concern worldwide; especially for South Africa. Therefore, there is an urgent need for alternative energy resources that will be sustainable, and environmentally friendly in order to tackle the ecological degradation generated by the use of fossil fuels. Among many energy ‘niches’, solar energy appears to be one of the most promising and reliable for the African continent because of the constant availability of sun light. Organic conjugated polymers have been identified as suitable materials to ensure proper design and fabrication of flexible, easy to process and cost-effective solar cells. Their tendency to exhibit good semiconducting properties and their capability to absorb photons from the sunlight and convert it into electrical energy are important features that justify their use in organic photovoltaic cells. Many different polymers have been investigated as either electron donating or electron accepting materials. Among them, poly(3-hexylthiophene) is one of the best electron donor materials that have been used in organic photovoltaic cells. It is a good light absorber and its Highest Occupied Molecular Orbital (HOMO) energy level is suitable to allow electron transfer into an appropriate electron acceptor. On the other hand, the molecular ordering found in dendrimers attracted some interest in the field of photovoltaics as this feature can ensure a constant flow of charges. In this work, I hereby report for the first time, the chemical synthesis of a highly crystalline dendritic star copolymer generation 1 poly(propylene thiophenoimine)-co-poly(3-hexylthiophene) (G1PPT-co-P3HT) with high molecular weight and investigate its application as donating material in bulk heterojunction organic photovoltaics.

For decades man has been interested in selection and hybridization of crop plants, but it has not been until in comparatively recent years that anything of importance has been done toward the improvement of perennial forage grasses. Replies to questionnaries on grass breeding submitted to various agricultural institutions in 1936 revealed the fact that selection for improvement was then under way with a large number of grasses. Limited activities in this field have been in progress for 16 years or more, but organized and intensive grass breeding activities, for the most part, have been inaugurated only within the last ten years. Many improved strains of grasses have been developed by selective breeding in foreign countries but very few of these have shown outstanding value in the United States. In fact, they are generally inferior. There is a great deal of interest at the present time in this country in the field of grass breeding, but the smallness of the floral parts of some grasses makes the work of controlled hybridization tedious and slow. A simple, inexpensive, accurate method for bulk hybridization would be useful and would speed up the work. The study herein reported was designed to throw further light on the possibility of bulk hybridization. The technic involves immersion of inflorescences in water heated to specific temperatures to effect enactivation of pollen. As a necessary corollary, the desired pollen is then applied by any of several methods. Several investigators, mentioned below, have shown that controlled heat treatments applied to inflorescences near the time of anthesis are effective in seriously reducing the viability of pollen without having a similar effect on the female gametophyte. However, none has demonstrated good female fertility following complete male sterilization. It has become apparent that influences of the plants' environment other than the heat of the emasculation treatment must be taken into consideration. In the present study, which was conducted on three important forage grasses, smooth bromegrass (Bromus intermis), crested wheatgrass (Agrpyron cristatum), and bluestem wheatgrass (Agropyron smithii), the general findings of earlier investigators are substantiated and in addition evidence is presented to show (1) the sterilizing effect of the isolation bag and (2) the existence of a daily cycle in the efficiency of emasculation of treatments at critical temperatures.

Philosophiae Doctor - PhD / Investigation of the acoustic impedance variations in the upper shallow marine sandstone reservoirs was extensively studied from 10 selected wells, namely: F-O1, F-O2, E-M4, E-CN1, E-G1, E-W1, F-A10, F-A11, F-A13, and F-L1 in the Bredasdorp Basin, offshore, South Africa. The studied wells were selected randomly across the upper shallow marine interval with the purpose of conducting a regional study to assess the variations in the acoustic impedance across the reservoirs using wireline log and core data. The datasets used in this study were geophysical wireline logs, conventional core analysis, geological well completion reports, core plugs, and core samples. The physical rock properties such as lithology, fluid type, and hydrocarbon bearing zone were identified while different parameters like the volume of clay, porosity, and water saturation were quantitatively estimated. The reservoirs were penetrated at a different depth ranging from a shallow depth of 2442m at well F-L1 to a deeper depth of 4256.7m at well E-CN1. The average volume of clay, average effective porosity from wireline log, and average water saturation ranged from 8.6%- 43%, 9%- 16% and 12%- 68%, respectively. Porosity distribution was fairly equal across the field from east to west except in well F-A10, F-A13, and F-A11 where a much higher porosity was shown with F-A13 showing the highest average value of 16%. Wells E-CN1, E-W1, F-O1, F-L1 and E-G1 had lower porosity with E-CN1 showing the lowest average value of 9%. The acoustic properties of the reservoirs were determined from geophysical wireline logs in order to calculate acoustic impedance and also investigate factors controlling density and acoustic velocities of these sediments. The acoustic impedance proved to be highest on the central to the western side of the field at E-CN1 with an average value of 11832 g/cm3s whereas, well F-A13 reservoir in the eastern side of the field proved to have the lowest average acoustic impedance of 9821 g/cm3s. There was a good linear negative relationship between acoustic impedance and porosity, compressional velocity vs porosity and porosity vs bulk density. A good linear negative relationship between acoustic impedance and porosity was obtained where the reservoir was homogenous, thick sandstone. However, interbedded shale units within the reservoir appeared to hinder a reliable correlation between acoustic impedance and porosity. The cross-plots results showed that porosity was one of the major factors controlling bulk density, compressional velocity (Vp) and acoustic impedance. The Gassmann equation was used for the determination of the effects of fluid substitution on acoustic properties using rock frame properties. Three fluid substitution models (brine, oil, and gas) were determined for pure sandstones and were used to measure the behaviour of the different sandstone saturations. A significant decrease was observed in Vp when the initial water saturation was substituted with a hydrocarbon (oil or gas) in all the wells. The value of density decreased quite visibly in all the wells when the brine (100% water saturation) was substituted with gas or oil. The fluid substitution affected the rock property significantly. The Vp slightly decreases when brine was substituted with water in wells F-A13, F-A10, F-O2, F-O1 F-A11, F-L1, and E-CN1. Wells E-G1, E-W1, and E-M4 contain oil and gas and therefore showed a notable decrease from brine to oil and from oil to gas respectively. Shear velocity (Vs) remained unaffected in all the wells. The acoustic impedance logs showed a decrease when 100% water saturation was replaced with a hydrocarbon (oil or gas) in all the wells. Clay presence significantly affects the behaviour of the acoustic properties of the reservoir rocks as a function of mineral type, volume, and distribution. The presence of glauconite mineral was observed in all the wells. Thirty-two thin sections, XRD and SEM/EDS from eight out of ten wells were studied to investigate lithology, diagenesis and the effect of mineralogy on porosity and acoustic properties (Compressional velocity and bulk density) within the studied reservoir units. Cementation (calcite and quartz), dissolution, compaction, clay mineral authigenesis, and stylolitization were the most significant diagenetic processes affecting porosity, velocity, and density.Well E-CN1 reservoir quality was very poor due to the destruction of intergranular porosity by extensive quartz and illite cementation, and compaction whereas well F-A13 show a highly porous sandstone reservoir with rounded monocrystalline quartz grain and only clusters of elongate to disc-like, authigenic chlorite crystals partly filling a depression within altered detrital grains. Overall, the results show that the porosity, lithology mineralogy, compaction and pore fluid were the major factors causing the acoustic impedance variations in the upper shallow marine sandstone reservoirs. / 2021-09-01