Recent interests on the plastic deformation of strontium titanate (SrTiO3) are derived from its unusual ductile-to-brittle-to-ductile transition (DBDT). The transition is divided into three regimes (A, B and C) corresponding to the temperature range of 113 K to 1053 K (-160oC to 780oC), 1053 K to ~ 1503 K (780oC to ~ 1230oC) and ~ 1503 K to 1873 K (~ 1230oC to 1600oC), discovered by Sigle and colleagues in the MPI-Stuttgart. We report the dislocation substructures in (001) single crystal SrTiO3 deformed by Vickers indentation at room temperature, studied by scanning and transmission electron microscopy (SEM and TEM). Dislocation dipoles of screw and edge character are observed and confirmed by inside-outside contrast using g-vector by weak-beam dark field imaging. They are formed by edge trapping, jog dragging and cross slip-pinching off. Similar to dipole breaking off in deformed sapphire (£\-Al2O3) at 1200oC and £^-TiAl intermetallic at room temperature, the dipoles pinch off at one end, and emit a string of loops at trail. Two sets of slip systems {110}<-11 0> and {100}<011> are activated under both 100 g and 1 kg load. The suggestion is that plastic deformation has reached the stage II work hardening, which is characterized by multiplication of dislocations through cross slip, interactions between dislocations, and operating of multiple slip systems. In nanoindentation experiments, it is generally believed that the shear stress at the onset of plasticity can approach the theoretical shear strength of an ideal. Here we report direct evidence that plasticity in a single crystal SrTiO3 can begin at very small forces, remarkably. However, the shear stresses associated with these very small forces is excess the theoretical shear strength of SrTiO3 (16.1 GPa). Our observations entail correlating quantitative load¡Vdisplacement measurements with individual stage microstructure during nanoindentation experiments in a transmission electron microscope. We also report direct evidence that with the prevalent notion that the first obvious displacement excursion in a nanoindentation test is indicative of the onset of plastic deformation. The SrTiO3 deforms elastically before the pop-in depth, but exhibits a plastic-elastic behavior after that. TEM observations reveal that the slip band is the predominant deformation mechanism in SrTiO3 during indentation. The cracks usually initiate at the intersection of slip bands to produce the sessile dislocations with Burger vectors [1-10] (or [110]) along the (110) (or (1-10)) crack plane. In addition, theoretical analysis confirms that the pop-in event is associated with the onset plasticity of SrTiO3. The plastic deformation of (001) single crystal SrTiO3 is investigated using compression along [001] at room temperature. A total plastic strain of ~19+2% is consistently obtained. The stress-strain curve exhibiting four work-hardening stages are describable using the stage 0 of axis rotation, the stage I ¡§easy glide¡¨, the stage II multiple slip and the wall-and-cell structure, and the stage III work softening and dynamic recovery before sample fracture takes place. It is revealed by analyzing the microstructure for each work-hardening stage that the plastic deformation of single crystal SrTiO3 closely resembles that of metals. The primary slip systems of [011](0-11) and [01-1](011) predominate in stage I where plastic deformation occurs by the migration of kink pairs in collinear partial dislocations. The activation of multiple slips including [101](-101) and [10-1](101), and [011](0-11) and [0-11](011) in stage II produces the cell-and-wall structure which is also characteristic of plastically deformed metals. In stage III with decreasing work-hardening rate, the bow-out dislocation interaction from opposite walls results in annihilation. The reaction between dislocations from adjacent walls produces the resultant dislocations with b = [-110] parallel to the load axis [001]. These dislocations are sessile, which eventually leads to sample fracture. We have analyzed the microstructure of <001> SrTiO3 single crystal deformed using compression at room temperature using transmission electron microscopy. A representative stress-strain (£m-£`) curve is established, similar to that for metals it consists of three hardening stages before failure occurs at a strain £` = 19+2%. Dislocation analysis suggests that the primary slip systems in [011](0-11) and [0-11](011) are activated in the £m-£` curve stress plateau region usually addressed as easy glide. Three characteristic features are identified from samples deformed to stage I hardening by easy glide: (a) rectangular glide loops, (b) collinear partials, and (c) kink pairs. Dislocations have predominantly pure edge character. Kink pairs are observed only on the edge segments suggesting that screw dislocations have higher mobility. In easy glide, the migration and annihilation of kink pairs occurring on both the trailing and leading partials lends support to a previous report by Castillo-Rodriguez and Sigle (2011) that dislocation glide is controlled by the long-segment limit of a kink-pair model. Pure edge dislocations are dissociated into collinear partials with b = 1/2[011] (or 1/2[0-11]) by glide in (0-11) (or(011)), and kink pairs are formed on both leading and trailing partials. The suggestion is that in the low-stress regime hardening by dislocation pile-up in stage I is compensated for by kink pair nucleation and migration. The overall hardening rate thus remains unchanged at approximately zero, resembling easy glide in the deformation of metals, over an increasing strain of £` ? 4% before reaching stage II hardening. Microcrack nucleation and propagation behavior in the crack tip was investigated by using transmission electron microscopy (TEM) through compressive test and Vickers indenter. Observation results showed that fracture process was completed in this <001> SrTiO3 single crystal material by connecting dislocations. The crack were nucleated and developed in the dislocation free zone (DFZ) or super thinned area ahead of crack tip under local high stress concentration. The cracks were linked with each other by mutual dislocation emission which expedites the propagation of crack tips effectively. We suggested a dislocation based the Hirsch et al. model of plastic-zone evolution in which dislocations emitted from the crack tip glide away to form a crack-tip plastic zone. Each emitted dislocation reduces the crack tip stress intensity via elastic interactions (the ¡¥¡¥shielding¡¨ effect).

The detection of corrosion in pipes is of major importance to the oil and chemical industries. Current methods involving point-by-point inspection are available for the detection of general wall loss associated with corrosion, but unfortunately the current methods tend to be very slow, limited to single positions, thus make the inspection of the kilometers of pipeline typically found in industrial plants virtually impossible. Ultrasonic guided waves provide an attractive solution to this problem because they can be excited at one location on the pipe and will propagate many meters along the pipe, returning echoes indicating the presence of corrosion or other pipe features. Nevertheless such techniques still have many practical difficulties in application due to the complex characteristics of guided waves such as dispersion and mode conversion. This thesis studies guided waves influenced by the welded supports, a.k.a. pipe shoe. A research of the reflection of mode-converted guided waves from pipe shoes on pipes in the frequency range 18-32 kHz has been carried out. Measurements are made on a 6 inch bore diameter, 7.1mm wall thickness pipe. The axisymmetric symmetric T(0,1) mode is incident on the pipe shoes and the mode-converted guided waves are received in reflection. In parallel, a finite element model is used to simulate the experiments by using Ansys. Received signals are separated into single-mode with a mode extraction technique. This research reveals that when T(0,1) propagates through the pipe shoe, the energy of T(0,1) passes into the pipe shoe. The leakage phenomenon results in the complexity and misinterpretation of the echo.

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Crack healing in quartz has been investigated by optical microscopy and interferometry of rhombohedral ( 1 1 10 ) cracks in polished Brazilian quartz prisms that were annealed hydrothermally at temperatures of 250°C and 400°C for 2.4 to 240 hours, fluid pressure Pf = Pc = 41 MPa, and varying pOH- (from 5.4 to 1.2 at 250°C for fluids consisting of distilled water and NaOH solutions with molalities up to 1). Crack morphologies before and after annealing were recorded for each sample in plane light digital images. Crack apertures were determined from interference fringes recorded using transmitted monochromatic light (l = 598 nm). As documented in previous studies, crack healing is driven by reductions in surface energy and healing rates are governed by diffusional transport; sharply defined crack tips become blunted and split into fluid- filled tubes and inclusions. A rich variety of fluid inclusion geometries are also observed with nonequilibrium shapes that depend on initial surface roughness. Crack healing is significant at T=400°C. Crack healing is also observed at T=250°C for smooth cracks with apertures <0.6 mm or cracks subject to low pOH-. The extent of crack healing is sensitive to crack aperture and to hackles formed by fine-scale crack branching during earlier crack growth. Crack apertures appear to be controlled by hackles and debris, which prop the crack surfaces open. Upon annealing, crack apertures are reduced, and these reduced crack apertures govern the kinetics of diffusional crack healing that follows. Hackles are sites of either enhanced or reduced loss of fluid-solid interface, depending on slight mismatches and sense of twist on opposing crack surfaces. Hackles are replaced either by healed curvilinear quartz bridges and river patterns surrounded by open fluid-filled crack, or by fluid- filled tubes surrounded by regions of healed quartz. For a given temperature, aperture and anneal time, crack healing is enhanced at low pOH- ( £ 1.2) either because of changes in the hydroxylated quartz- fluid interface that enhance reaction rates or because of increased rates of diffusional net transport of silica at high silica concentrations.

The focus of this research is on the control of random cracking in concrete paving by using sawcut notch locations in the early stages of construction. This is a major concern in concrete pavement construction. This research also addresses a probabilistic approach to determine the optimum time and depth of sawcutting for newly constructed portland cement concrete pavements. Variability in climate conditions and material characteristics during the hardening process affects the potential of cracking at any sawcut depth. Several factors affecting the probability of crack initiation are material strength parameters, method and quality of curing, slab/subbase stiffness, the amount and depth of steel reinforcement, friction between the slab and the subbase, and concrete shrinkage. Other factors relevant to concrete mixture characteristics such as cement content and type of coarse aggregate affect development of early aged stresses caused by shrinkage and thermally induced contraction. A probabilistic analysis of the factors that affect crack control using sawcut notches is presented in relation to different weather conditions (concrete placement temperature) at the time of construction, and concrete mixture characteristics such as fly ash replacement (FA) and cement factor (CF). Both of these significantly affect sawcut timing and depth requirement. The determination of crack initiation is based on fracture mechanics. Estimation of the time of cracking is based on predicted tensile strength and stress in the concrete at the bottom of the sawcut notch to assess the feasibility of crack control in the early stages of construction.

Capillary bridge formation between adjacent surfaces in humid environments is a ubiquitous phenomenon. Capillary forces are important in nature (granular materials, insect locomotion) and in technology (disk drives, adhesion). Although well studied in the equilibrium state, the dynamics of capillary formation merit further investigation. Here, we show that microcantilever crack healing experiments are a viable experimental technique for investigating the influence of capillary nucleation on crack healing between rough surfaces. To demonstrate the effects, a custom micromachine characterization system is built that allows for full environmental control (pressure, humidity, and gas composition) while retaining full micromachine characterization techniques (long working distance interferometry, electrical probe connectivity, actuation scripting capability). The system also includes an effective in situ surface plasma cleaning mechanism. The average spontaneous crack healing velocity, ̅, between plasma-cleaned hydrophilic polycrystalline silicon surfaces of nanoscale roughness is measured. A plot of ̅v versus energy release rate, G, reveals log-linear behavior, while the slope |d[log(v)]/dG| decreases with increasing relative humidity. An interface model that accounts for the nucleation time of water bridges by an activated process is developed to gain insight into the crack healing trends. This methodology enables us to gain insight into capillary bridge dynamics, with a goal of attaining a predictive capability for this important microelectromechanical systems (MEMS) reliability failure mechanism. A variety of alcohol vapors significantly reduce or perhaps eliminate wear in sliding micro-machined contacts. However, these vapors may increase adhesion due to the capillary forces. Equilibrium adhesion energies at various partial pressures are found for n-pentanol (long chain molecule) and ethanol (short chain molecule). For low partial pressures (p/ps=0.3), adhesion energy of n-pentanol is even larger than water.

The aim of this study was to use the finite element method to model crack, corrosion, and Crack-in-Corrosion defects in a pipeline. The pipe material under investigation for this study was API 5L X60, 508 mm diameter with a wall thickness of 5.7 mm. The pipe material was evaluated using Tensile, Charpy, and J testing in order to model the defects and to establish the numerical failure criteria. Corrosion defects were modeled as flat-bottomed grooves. The collapse pressure was predicted when the deepest point in the bottom of the defect reached a critical stress. Based on this criterion, the FE corrosion failure pressure predictions were conservative compared to the experimental failure pressures, conducted by Hosseini [9], with an average error of 10.13%. For crack modeling, the failure criteria were established considering the plastic collapse limit and the fracture limit. Both the Von Mises stress in the crack ligament and the J-integral values around the crack were monitored to predict the failure pressure of the model. The crack modeling was done based on two approaches, the uniform depth profile and the semi-elliptical profile. The crack with uniform depth profile was done because the uniform shape is the logical equivalent shape for a colony of cracks. The crack with the semi-elliptical profile was done to have a less conservative results and because the experiments were done with semi-elliptical cracks. The FE crack modeling results were conservative compared to the experimental collapse pressure with an average error of 19.64% for the uniform depth profile and 5.35% for the semi-elliptical profile. In crack-in-corrosion (CIC) defect modeling, the crack was modeled with uniform depth because it was very difficult to model the semi-elliptical crack profile when the crack defect is coincident with a corrosion defect. The results were conservative compared to the experimental results with an average error of 22.18%. In general, the FE modeling provides the least conservative failure pressure prediction over the existing analytical solutions for pipe with longitudinal corrosion, crack, and CIC defects.

This project is designed as a case study investigating the relationship and practices between residents and police officers in the William Wells Brown neighborhood of Lexington, Kentucky toward the issue of drug-related crime. Employing Michel Foucault‘s work on governmentality and his concept of Splendor, I explore how governance is practiced within the daily negotiations of the WWB neighborhood. I approach this project through the lens of policing because some residents, especially those who comprise the William Wells Brown Neighborhood Association, form a limited partnership with the police department in combating the threat of drug crime in the neighborhood. Drug-related crime is defined as the purchasing, selling or using of illegal drugs. In my research, the illegal drug most commonly referred to is crack cocaine. Through my analysis, I explore the importance of visual appearances and spatial regulation in the policing of individuals.

No description available.

Glass Fibre-Reinforced Polymer (GFRP) bars offer a feasible alternative in locations where steel is not the suitable reinforcement; namely locations that are sensitive to corrosion. In this study 60 specimens, 52 GFRP reinforced and 8 steel reinforced, were constructed and tested under direct tension in order to investigate the tension stiffening and cracking behaviour. The effects of different variables such as the bar type, the bar diameter, the reinforcement ratio and the concrete strength on tension stiffening and crack spacing were studied. The current code provisions for tension stiffening, namely ACI-440 and CEB-FIP were evaluated against the obtained test data. It was determined that the current code provisions significantly overestimate tension stiffening in GFRP reinforced specimens. A new tension stiffening model was, therefore, developed that provides better simulation of the test data. The CEB-FIP 1978 model for crack spacing was also modified for GFRP reinforced members.