The objective of this thesis is to explore the properties of supercritical carbon dioxide (CO2). In addition, the feasibility of building a small-scale low cost system will be explained. A supercritical fluid is a fluid which exhibits properties between liquid and gas with liquid like densities and viscosities similar to a gas. Since the discovery of supercritical fluids in 1822, the use of supercritical fluids, specifically supercritical CO2, has grown in popularity. The application of supercritical CO2 has continued to grow in industrial applications since the 1970’s. Supercritical CO2’s has many beneficial properties as a “green” solvent. Supercritical CO2 as a solvent is able to be implemented in a wide range of applications from aerospace, microchip manufacturing, food production, biomedical, pharmaceutical, dry-cleaning, and many more. This thesis project included designing, building and testing a supercritical CO2 extraction apparatus that examines the use of supercritical CO2 as a solvent in the extraction process of decaffeinating coffee. Due to the fact that supercritical CO2 requires high pressure operating conditions, the apparatus design is important not only for function but also for safety. In the description portion of this paper, design considerations related to each component’s function and their specific roles in the overall system are clearly stated. Furthermore, the build process is outlined along with the overall step-by-step operation of the apparatus. Different methods of data measurements are taken while the system is running, in order to interpret the apparatus’ overall functionality. Through the exploration of this experimental data, the results were compared between different operating parameters. In order to determine the feasibility of the supercritical apparatus, the devise was tested by applying the supercritical CO2 as a solvent for the extraction of caffeine from coffee beans. Analysis of the analytical data recorded from experimental testing confirms that the apparatus produced supercritical CO2. After testing specific operating conditions, it is proven that the supercritical CO2 is able to function as a “green” solvent in this small-scale system. The experimental results from these analytical runs are compared with theoretical maximums in order to determine the efficiency of the devise. Lastly, the paper presents an overview including lessons learned from the design process and from the information gathered. Data from experimental testing is interpreted and the system design is reevaluated with suggestions for future improvements.

In gas quenching, metal parts are rapidly cooled from hightemperatures, and the convection heat transfer coefficientdistributions are of importance for the hardness and thedistortion (the shape nonuniformities) of the quenched parts.Thermochromic liquid crystals (TLC) and a thin foil techniques,were investi- gated and used for studies of a circular cylinderin axial flows, affected and not affected by upstream owmodifying inserts. Quadratic prisms in cross ows were alsostudied, a single prism, two prisms arranged in-line, and forfour prisms arranged in a square pattern. In this study,particle image velocime- try (PIV) was used for visualizationof the flow, giving physical insight to the convection heattransfer data. Further, relations of the typeNu=CReewere established. The TLC and thin foil techniques werealso used to indicate the dimensions of separated flowregions. Descriptors:Fluid mechanics, wind-tunnel, turbulence,gas quenching, con- vection heat transfer, thermochromic liquidcrystals, calibration, temperature measurement errors, thinfoils, particle image velocimetry, cylinder in axial flow, flowmodifying inserts, quadratic prisms in cross flow

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No description available.

This proposes a model for a microwave heated fluidized bed by ceramic pellets to highlight the possibility to obtain a temperature gradient between the gas and the pellets. After a review of the recent work on microwave effects on chemical reactions, a short description of fluidization is given for a better understanding of the phenomena, followed by a development of a model of the heat transfer processes taking place in the fluidized bed. A parameter study describes the trends that should be expected despite the numerous restrictions and assumptions. Also, a set of parameters is proposed for optimal conditions that are close to the real conditions often encountered in practice. Numerous figures and tables are added, completing the main argument advanced in the thesis: it is possible to obtain a temperature difference between the gas and the pellets of a chemical bed reactor heated by microwaves by carefully choosing the following parameters: pellet diameter, bed height, gas velocity, pellet density and electric field. / Master of Science

Convective heat transfer to CO2 flowing upward in electrically heated vertical tubes at supercritical pressures was studied for wall heat fluxes q within ranges that included values corresponding to the onset of heat transfer deterioration (HTD). The inlet pressure was P = 8.35 MPa, the mass flux was in the range 200 kg/m2s ≤ G ≤ 1500 kg/m2s, and the inlet temperature was in the range 0 ◦C ≤ Tin ≤ 35 ◦C. Wall temperature measurements were collected in three tubular test sections, having inner diameters of D = 4.6, 8, and 22 mm. The abilities of three different HTD identification methods to separate the entire data set into deteriorated and normal heat transfer modes were tested. Two types of buoyancy parameters were tested as HTD detection methods, and correction factors for changes in mass flux were devised. The minimum heat flux at HTD onset was found to follow a power law of mass flux with the same exponent for all three sections and the same proportionality coefficient for the two smaller sections but a smaller one for the larger test section. For heat flux values that were larger than this minimum, HTD was found to occur only within a limited range of Tin, whose width increased with increasing heat flux. The heat transfer coefficient for normal heat transfer was expressed as an exponential function of the diameter.

An average heat transfer coefficient, h_bar, is often used to solve heat transfer problems. It should be understood that this is an approximation and may provide inaccurate results, especially when the temperature field is of interest. The proper method to solve heat transfer problems is with a conjugate approach. However, there seems to be a lack of clear explanations of conjugate heat transfer in literature. The objective of this work is to provide a clear explanation of conjugate heat transfer and to determine the discrepancy in the temperature field when the interface boundary condition is approximated using h_bar compared to a local, or variable, heat transfer coefficient, h(x). Simple one-dimensional problems are presented and solved analytically using both h(x) and h_bar. Due to the one-dimensional assumption, h(x) appears in the governing equation for which the common methods to solve the differential equations with an average coefficient are no longer valid. Two methods, the integral equation and generalized Bessel methods are presented to handle the variable coefficient. The generalized Bessel method has previously only been used with homogeneous governing equations. This work extends the use of the generalized Bessel method to non-homogeneous problems by developing a relation for the Wronskian of the general solution to the generalized Bessel equation. The solution methods are applied to three problems: an external flow past a flat plate, a conjugate interface between two solids and a conjugate interface between a fluid and a solid. The main parameter that is varied is a combination of the Biot number and a geometric aspect ratio, A_1^2 = Bi*L^2/d_1^2. The Biot number is assumed small since the problems are one-dimensional and thus variation in A_1^2 is mostly due to a change in the aspect ratio. A large A_1^2 represents a long and thin solid whereas a small A_1^2 represents a short and thick solid. It is found that a larger A_1^2 leads to less problem conjugation. This means that use of h_bar has a lesser effect on the temperature field for a long and thin solid. Also, use of ¯ over h(x) tends to generally under predict the solid temperature. In addition is was found that A_2^2, the A^2 value for the second subdomain, tends to have more effect on the shape of the temperature profile of solid 1 and A_1^2 has a greater effect on the magnitude of the difference in temperature profiles between the use of h(x) and h_bar. In general increasing the A^2 values reduced conjugation.

The extreme operating conditions in deepwater drilling lead to serious relative problems. The knowledge of subsea temperatures is of prime interest to petroleum engineers and geo-technologists alike. Petroleum engineers are interested in subsea temperatures to better understand geo-mechanisms; such as diagenesis of sediments, formation of hydrocarbons, genesis and emplacement of magmatic formation of mineral deposits, and crustal deformations. Petroleum engineers are interested in studies of subsurface heat flows. The knowledge of subsurface temperature to properly design the drilling and completion programs and to facilitate accurate log interpretation is necessary. For petroleum engineers, this knowledge is valuable in the proper exploitation of hydrocarbon resources. This research analyzed the thermal process in drilling or completion process. The research presented two analytical methods to determine temperature profile for onshore drilling and numerical methods for offshore drilling during circulating fluid down the drillstring and for the annulus. Finite difference discretization was also introduced to predict the temperature for steady-state in conventional riser drilling and riserless drilling. This research provided a powerful tool for the thermal analysis of wellbore and rheology design of fluid with Visual Basic and Matlab simulators.

The fundamental physics governing wildland fire spread are still largely misunderstood. This thesis was motivated by the need to better understand the role of radiative and convective heat transfer in the ignition and spread of wildland fires. The focus of this work incorporated the use of infrared thermographic imaging techniques to investigate fuel particle response from three different heating sources: convective dominated heating from an air torch, radiative dominated heating from a crib fire, and an advancing flame front in a laboratory wind tunnel test. The series of experiments demonstrated the uniqueness and valuable characteristics of infrared thermography to reveal the hidden nature of heat transfer and combustion aspects which are taking place in the condensed phase of wildland fuelbeds. In addition, infrared thermal image-based temperature history and ignition behavior of engineered cardboard fuel elements subjected to convective and radiative heating supported experimental findings that millimeter diameter pine needles cannot be ignited by radiation alone even under long duration fire generated radiant heating. Finally, fuel characterization using infrared thermography provided a better understanding of the condensed phase fuel pyrolysis and heat transfer mechanisms governing the response of wildland fuel particles to an advancing flame front.

The current study is part of a long term experimental project devoted to investigating single-phase flow pressure drop and heat transfer, flow boiling pressure drop and heat transfer, flow boiling instability and flow visualization of de-ionized water flow in microchannels. The experimental facility was first designed and constructed by S. Gedupudi (2009) and in the present study; the experimental facility was upgraded by changing the piping and pre-heaters so as to accommodate the objectives of the research. These objectives include (i) modifying the test rig, to be used for conducting experiments in microchannels in single and two-phase flow boiling heat transfer, pressure drop and visualization, (ii) redesign metallic single microchannels using copper as the material. The purpose of the redesign is to provide microchannels with strong heaters, high insulation performance and with test sections easy to dismantle and reassemble, (iii) obtaining the effect of hydraulic diameter on single-phase flow, flow pattern, heat transfer and pressure drop, (iv) studying the effects of heat flux, mass flux,and vapour quality on flow pattern, flow boiling heat transfer and pressure drop, (v)comparing experimental results with existing correlations. However, the main focus in this present study is to investigate the effects of hydraulic diameter, heat flux, mass flux and vapour quality on flow pattern, flow boiling heat transfer coefficient and pressure drop. In addressing (iii) many possible reasons exist for the discrepancies between published results and conventional theory and for the scatter of data in published flow boiling heat transfer results: 1. Accuracy in measuring the dimensions of the test section, namely the width, depth and length and in the tested variables of temperature, pressure, heat flux and mass flux. 2. Variations in hydraulic diameter and geometry between different studies. 3. Differences in working fluids. 4. Effects of hydrodynamic and thermal flow development 5. Inner surface characteristics of the channels. Three different hydraulic diameters of copper microchannels were investigated: 0.438mm, 0.561 mm and 0.635 mm. For single-phase flow the experimental conditions included mass fluxes ranging from 278 – 5163 kg/m2 s, heat fluxes from 0 - 537 kW/m², and inlet temperatures of 30, 60 and 90°C. In the flow boiling experiments the conditions comprised of an inlet pressure of 125 kPa (abs), inlet temperature of 98°C (inlet sub-cooling of 7 K), mass fluxes ranging from 200 to 1100 kg/m²s, heat fluxes ranging from 0 to 793 kW/m² and qualities up to 0.41. All measurements were recorded after the system attained steady states. The single-phase fluid flow results showed that no deviation of friction factors was found from the three different hydraulic diameters. The effect of fluid temperature on friction factor was insignificant and the friction factors themselves were in reasonable agreement with developing flow theory. The typical flow patterns observed in all three test sections were bubbly, slug/confined churn and annular, however, based on the observation performed near the outlet, the bubbly flow was not detected. The effects of mass flow and hydraulic diameter on flow pattern for the three test sections investigated in the range of experimental conditions were not clear. The single-phase heat transfer results demonstrated that smaller test sections result in higher heat transfer coefficients. However, for heat transfer trends presented in the form of Nusselt number versus Reynolds number, the effect of hydraulic diameter was insignificant.The flow boiling experiments gave similar heat transfer results; they exhibited that the smaller hydraulic diameter channels resulted in higher heat transfer coefficients. The nucleate boiling mechanism was found for all three test sections, evidenced by the significant effect of heat flux on the local heat transfer coefficient. Moreover, the heat flux had a clear effect on average heat transfer coefficient for the 0.561 mm and 0.635mm test sections, whilst for the 0.438 mm test section, there was no discernible effect. At the same heat flux, increases in mass flux caused heat transfer coefficients to decrease. This could be due to the decrease of pressure inside the test section. When a higher mass flux was tested, the inlet pressure increased, and in reducing the inlet pressure to the original value, a decrease in system pressure resulted. Consequently, the outlet pressure and local pressure became lower. Existing flow pattern maps, flow boiling heat transfer and pressure drop correlations were compared with the experimental results obtained for all three test sections. The comparison showed that the flow pattern map proposed by Sobierska et al. (2006) was the most successful in predicting the experimental data. The local heat transfer coefficient data were compared with existing published correlations. The correlations of Yu et al. (2002), Qu and Mudawar (2003) and Li and Wu (2010) are found to predict the current local heat transfer coefficient better than other correlations tested. Pressure drop results showed that as the heat flux and mass flux were increased, the two-phase pressure drop increased too. These were due to the increase in bubble generations and the inertia momentum effect. As the channel was reduced, the twophase pressure drop increased because the pressure drop related inversely with the channel hydraulic diameter. The pressure and pressure drop fluctuations were indentified in this project, however, the maximum pressure fluctuation was found in the 0.438 mm channel whilst the minimum fluctuation was attained in the 0.561 mm channel. This indicated that the effect of decreasing in hydraulic diameter on pressure and pressure drop fluctuations is not clear and needs to be investigated further. The two-phase pressure drop data were compared with selected correlations. The Mishima and Hibiki (1996)’s correlation was found to predict the current two-phase pressure drop better than the other correlations examined in this study.