In this work the roughness and topography evolution of optical materials sputtered with low energy ion beam (≤1 keV) has been investigated. These materials (bulk or thin layer) are used in the manufacturing of mirrors for scientific (ground or space) instruments or for other optical applications. In the first part of the work, the roughness evolution of optical surfaces under sputtering has been investigated in the frame of the industrial process known as Ion Beam Figuring. This technique consists in removing shape errors on optical surfaces with a low energy ion beam (≤1 keV). One disadvantage of this process is a potential increase of roughness for surfaces under treatment. The roughness evolution of some materials relevant to the optical industry has been accurately characterized as function of etching depth down to 5 µm. These sputtering experiments have been carried out at normal incidence, mainly with argon ions (but also in a lesser extent with krypton and xenon ions), ion current density of ~1 mA/cm2 and ion beam energy ranging from 200 eV to 1000 eV. The roughness evolution under sputtering is low for materials with amorphous (glass, electroless nickel), monocrystalline (silicon) or even polycrystalline structure (CVD silicon carbide, PVD gold or nickel film), whereas it is considerably more important for some other metallic materials such as electroplated nickel and aluminium. This work has shown small differences in the roughness evolution of CVD silicon carbide as function of the ion beam energy. The roughness increase is faster at low ion energy (<500 eV) than at higher ion energy (650-1000 eV). The grain structure of this material is less revealed at higher energy, which is supposed to be due to a larger amorphization of the sputtered layer in this case. The influence of the ion mass on CVD silicon carbide and gold films on nickel substrates has been also illustrated. Our measurements have been also compared to scaling laws. Various growth and roughness exponents have been found, sometimes rather different from those foreseen by the KPZ equation. In the second part, we focus on periodically modulated structures (ripples) which developed on many solids when sputtered by an off-normal ion bombardment. In this work, we first observed these ripples on gold films deposited on electroplated nickel (materials used as reflective surfaces for X-ray space telescope) sputtered at grazing incidence. We studied the influence of sputtering parameters (ion beam incidence angle, energy and flux) on the characteristics of ripples induced on gold and silver thin film (~0.2 µm). Ion-induced ripples have also been observed on CdS, an interesting semiconductor crystal for optical applications. The ripples orientation and dimensions (spatial wavelengths from 0.13 µm to 0.29 µm) have been confronted to the Bradley-Harper (B-H) linear model. We used the SRIM software to evaluate the deposited energy and the surface tension coefficient distributions. Our results can be in great part explained by the current theories (Bradley-Harper, Makeev) on morphology of ion-sputtered surfaces. These results can be summarized hereunder: Clear development of ripples for angle of incidence equal or higher than 60° on gold film and 70° on silver film. In this work the ripples wave vector is always perpendicular to the ion beam direction for all angles, whereas the change in ripple orientation beyond a critical angle is usually reported in literature. This is a due to the different shape of the energy distribution function for our sputtering conditions. Different regimes for roughness and topography evolution (grains, ripples) have been observed in function of the angle of incidence. 3 different areas can be distinguished, as predicted by Makeev non-linear model. The diminution of ripple wavelength with ion energy shows that thermal diffusion is the main relaxation mechanism.

The urban near surface atmosphere is of great concern since it affects the climate to which an increasing amount of people are immediately exposed. This study investigated the microclimate in central Stockholm in terms of the thermal conditions in the 0-2.5 m air layer and the water and heat exchange processes at different types of surfaces found within the urban environment. The main objective was to improve our understanding of the urban small-scale climate system. The urban microclimate was measured in terms of vertical air temperature profiles along a horizontal transect running through a vegetated park and its built-up surroundings during three clear and relatively calm summer days. The results showed that the air temperature at 1.2 m height within the park was 0.5 to 1.5 K lower than in the surrounding city blocks, and that the thermal stratification was generally stable (increasing temperature with height) in the park and unstable (decreasing temperature with height) in the built-up areas. In addition, there were a few examples of temperature gradients orientated in different directions within the lowest 2.5 m air layer, indicating horizontal advection between the park and the built-up areas. Climate conditions simulated with a three-dimensional microclimate model agreed well with observations and the model was therefore assumed to provide reasonable representations of important climate processes such as surface-air energy exchange processes. However, there were some discrepancies between observations and simulations that are discussed in terms of differences in real and modelled heat storage processes and wind conditions. Processes that need to be included for a more precise model description of areas such as the Stockholm environment include dynamic heat storage in buildings and dynamic wind forcing during the course of the simulation. A soil-vegetation-atmosphere transfer model was used to study soil water transport, the surface energy balance of an asphalt surface, and the impact of urban climate on evapotranspiration. Based on model calibration to field measurements of soil water content in a till catchment outside Stockholm, new parameter values were estimated that can be used for water flow modelling of till soils. The heat fluxes of an asphalt surface were reliably simulated without knowledge of site-specific calibration and the model was useful in identifying problems with energy balance closure based on measurements only. Simulations of ‘urban’ modifications to the forcing climate conditions demonstrated that increased air temperature, and thereby increased vapour pressure deficit, had most effect on evapotranspiration from tall vegetation, while increased long-wave radiation raised grass evapotranspiration the most. / QC 20100901

This study focuses on the wear of piston rings in a hydraulic radial piston motor. The piston ring has to satisfy increasing demands for reliability and longer service life. It has two contacting surfaces, the face and the flank, and operates under a boundary lubrication state. This first part of the project aimed to detect and characterise piston ring wear. Measurement by weighing gives an overall value for wear defined as loss of mass. Two-dimensional form and surface roughness measurements show the distribution of wear on the piston ring face in contact with the cylinder bore and the piston ring flank in contact with the piston groove. Three-dimensional analyses, both quantitative and qualitative, allow the wear mechanisms to be identified. The wear of piston rings from an actual hydraulic motor was characterised. As well, rig testing was performed in two different test rig set-ups, one simulating the sliding movement of the piston ring and the other the tilting movement at the end of the strokes. Wear during the running-in period was investigated, and the findings indicate that the period when this takes place is of short duration. In the long term, mild wear makes the surfaces smoother than they were when new, resulting in a very low wear coefficient. Significant levels of wear were measured on both contacting surfaces of the piston ring. In cases in which the flank exhibits more wear than the face, the wear on the flank can be reduced by proper design of the piston groove. The second part of the project aimed to evaluate use of a textured surface for the cylinder bore counter surface and a coated surface for the piston ring. Three modelling experiments were performed to characterise the friction and wear properties under lean boundary lubrication conditions. Under such conditions, textured surfaces have the advantage of retaining more lubricant and supplying it over a longer time. Stable friction was also a distinctive feature of the textured surface. Use of a coating could also possibly reduce the amount of wear. Though a smooth surface, like a polished one, is hard to beat for a working texture, a coated surface is far ahead of a smooth uncoated one. Different manufactured and commonly used cylinder bore surfaces, including textured ones, were evaluated in the sliding movement test rig. That allowed favourable wear properties, such as lowest wear coefficient, to be determined with the use of a roller burnished surface. A final part of the research involved simulating wear on the piston ring face throughout the entire service life of a hydraulic motor. This allowed us to determine the roles of surface roughness and coating in prolonging service life and achieving acceptable and secure piston ring operation. The model is simple and realistic, but still needs to be refined so as to correspond even better to reality. / QC 20101007

Stimulus-responsive colloidosomes which completely dissolve upon a mild pH change are developed. pH-Responsive nanoparticles that dissolve upon a mild pH increase are synthesized by a nanoprecipitation method and are used as stabilizers for a double water-in-oil-in-water Pickering emulsion. These emulsions serve as templates for the production of pH-responsive colloidosomes. Removal of the middle oil phase produces water-core colloidosomes that have a shell made of pH-responsive nanoparticles, which rapidly dissolve above pH 7. The permeability of these capsules is assessed by FRAP, whereby the diffusion of a fluorescent tracer through the capsule shell is monitored. Three methods for tuning the permeability of the pH-responsive colloidosomes were developed: ethanol consolidation, layer-by-layer assembly and the generation of PLGA-pH-responsive nanoparticle hybrid colloidosomes. The resulting colloidosomes have different responses to the pH stimulus, as well as different pre-release permeability values. Additionally, fundamental studies regarding the role of particle surface roughness on Pickering emulsification are also shown. The pH-responsive nanoparticles were used as a coating for larger silica particles, producing rough raspberry-like particles. Partial dissolution of the nanoparticle coating allows tuning of the substrate surface roughness while retaining the same surface chemistry. The results obtained show that surface roughness increases the emulsion stability of decane-water systems (to almost twice), but only up to a certain point, where extremely rough particles produced less stable emulsions presumably due to a Cassie-Baxter wetting regime. Additionally, in an octanol-water system, surface roughness was shown to affect the type of emulsion generated. These results are of exceptional importance since they are the first controlled experimental evidence regarding the role of particle surface roughness on Pickering emulsification, thus clarifying some conflicting ideas that exist regarding this issue.

The effect of freestream turbulence on generation of crossflow disturbances over swept wings is investigated through direct numerical simulations.  The set up follows  the  experiments  performed  by Downs  et  al.  in their  TAMU  experi- ment.  In this experiment the authors use ASU(67)-0315 wing geometry which promotes  growth  of crossflow  disturbances.   Distributed  roughness  elements are locally placed near the leading edge with a span-wise wavenumber, to ex- cite the corresponding crossflow vortices.  The response of boundary layer to external disturbances such as roughness heights, span-wise wavenumbers, Rey- nolds numbers and freestream turbulence characteristics are studied.  It must be noted that the experiments were conducted at a very low level of freestream turbulence  intensity  (T u).   In this  study,  we fully  reproduce the  freestream isotropic homogenous turbulence through a DNS code using detailed freestream spectrum data provided by the experiment. The generated freestream fields are then applied as the inflow boundary condition for direct numerical simulation of the wing. The geometrical set up is the same as the experiment along with application of distributed roughness elements near the leading edge to precipi- tate stationary crossflow disturbances.  The effects of the generated freestream turbulence are then studied on the initial amplitudes and growth of the bound- ary layer perturbations.  It appears that the freestream turbulence damps out the dominant stationary crossflow vortices. / <p>QC 20130604</p>

The surface roughness of unfilled rock discontinuities has a major influence on the hydro-mechanical behaviour of discontinuous rock masses. Although it is widely recognized that surface roughness is comprised of large-scale (waviness) and small-scale (unevenness) components, most investigations of surface roughness have been restricted to small fracture surfaces (<1m2). Hence, the large-scale components of roughness are often neglected. Furthermore, these investigations typically define roughness using two-dimensional profiles rather than three-dimensional surfaces, which can lead to biased estimates of roughness. These limitations have led to some contradictory findings regarding roughness scale effects. This thesis aims to resolve some of these issues. The main findings indicate that discontinuity roughness increases as a function of the sampling window size contrary to what is commonly assumed. More importantly, it is shown that the estimated roughness significantly decreases as the resolution of surface measurements decrease, which could lead to the under estimations of roughness and, consequently, discontinuity shear strength.

The effects on heat transfer of piston crown surface finish and use of a metal based thermal barrier coating (TBC) on the piston crown were studied in an SI engine. Measured engine parameters such as power, fuel consumption, emissions and cylinder pressure were used to identify the effects of the coating and its surface finish. Two piston coatings were tested: a baseline copper coating and a metal TBC. Reducing surface roughness of both coatings increased in-cylinder temperature and pressure as a result of reduced heat transfer through the piston crown. These increases resulted in small improvements in both power and fuel consumption, while also having measurable effect on emissions. Oxides of nitrogen emissions were increased while total hydrocarbon emissions were decreased. Improvements attributed to the TBC were found to be small, but statistically significant. At an equivalent surface finish, the TBC performed better than the baseline copper finish.

The effects on heat transfer of piston crown surface finish and use of a metal based thermal barrier coating (TBC) on the piston crown were studied in an SI engine. Measured engine parameters such as power, fuel consumption, emissions and cylinder pressure were used to identify the effects of the coating and its surface finish. Two piston coatings were tested: a baseline copper coating and a metal TBC. Reducing surface roughness of both coatings increased in-cylinder temperature and pressure as a result of reduced heat transfer through the piston crown. These increases resulted in small improvements in both power and fuel consumption, while also having measurable effect on emissions. Oxides of nitrogen emissions were increased while total hydrocarbon emissions were decreased. Improvements attributed to the TBC were found to be small, but statistically significant. At an equivalent surface finish, the TBC performed better than the baseline copper finish.

Geomembranes are one of the most widely used geosynthetics in various civil engineering applications. Their primary function is as a barrier to liquid or vapour flow. Smooth Geomembranes are frequently used in combination with different soils, and due to their low surface roughness, are challenging to design to ensure adequate shear strength along the smooth geomembrane-soil interface. It is important to use the appropriate values of interface shear strength parameters in the design of slopes incorporating one or more geomembranes in contact with soils. The parameters are determined by conducting direct shear test on the geomembrane-soil interface. Laboratory tests of interface shear strength for geomembranes and soil are typically carried out with no provision for measurement of pore pressures at the soil/geomembrane interface. <p>This thesis deals with study of smooth geomembrane-soil interfaces, particularly under unsaturated conditions. The various factors that affect the interface shear behaviour are also studied. The tests were conducted using a modified direct shear box with a miniature pore pressure transducer installed adjacent to the surface of the geomembrane. Geomembranesoil interface shear tests were carried out with continuous measurement of suction in close proximity to the interface during the shearing process thus making it possible to analyze test results in terms of effective stresses. The method was found to be suitable for unsaturated soils at low values of matric suction. <p>Results of interface shear tests conducted using this method show that it is quite effective in evaluating interface shear behaviour between a geomembrane and an unsaturated soil. The results suggest that soil suction contributes to shearing resistance at low normal stress values. At lower normal stress values, the interface shear behaviour appears to be governed only by the magnitude of total normal stress. <p> At high normal stresses, the failure mechanism changed from soil particles sliding at the surface of geomembrane to soil particles getting embedded into the geomembrane and plowing trenches along the direction of shear. A plowing failure mechanism resulted in the mobilization of significantly higher shear strength at the geomembrane soil interface. It was found that placement water contents near saturated conditions results in lower effective stresses, a shallower plowing mechanism and lower values of mobilized interface shear strength.

The surface roughness of unfilled rock discontinuities has a major influence on the hydro-mechanical behaviour of discontinuous rock masses. Although it is widely recognized that surface roughness is comprised of large-scale (waviness) and small-scale (unevenness) components, most investigations of surface roughness have been restricted to small fracture surfaces (<1m2). Hence, the large-scale components of roughness are often neglected. Furthermore, these investigations typically define roughness using two-dimensional profiles rather than three-dimensional surfaces, which can lead to biased estimates of roughness. These limitations have led to some contradictory findings regarding roughness scale effects. This thesis aims to resolve some of these issues. The main findings indicate that discontinuity roughness increases as a function of the sampling window size contrary to what is commonly assumed. More importantly, it is shown that the estimated roughness significantly decreases as the resolution of surface measurements decrease, which could lead to the under estimations of roughness and, consequently, discontinuity shear strength.