The aim of this study is focused on the experimental investigation of dynamic wear behavior of carbon black filled rubber compounds comprising pristine styrene butadiene rubber (SBR) together with incorporated SBR ground rubber (rubber powder). We also analyzed and described quantitatively the service conditions of some dynamically loaded rubber products, which are liable to wear (e.g. conveyor belts, tires). Beside the well-known standard test method to characterize wear resistance at steady-state conditions, we used an own developed testing equipment based on gravimetric determination of mass loss of rubber test specimen to investigate the influence of rubber powder content on dynamic wear depending on varying impact energy levels. Incorporation of SBR rubber powder in SBR rubber compounds increases wear. With increasing rubber powder content the wear at steady-state conditions progressively increases. However, the level of wear at dynamic loading conditions increases only once, but stays constant subsequently even with contents of incorporated rubber powder.

No description available.

During the last years rubber nanocomposites obtained by incorporating anisotropic clay nanoparticles within a rubber matrix to tailor material properties have attracted steadily growing interest. However, one main complication preventing rubber-clay nanocomposites from many potential applications is the difficulty to achieve a high degree of exfoliation particularly in case of melt mixing or compounding (using mixing equipment like internal mixer, two roll mills which can be up-scaled in industry). Albeit commercially available organomodified montmorillonite clays (OMt) are fairly compatible with the polar rubber like Acrylo-nitrile butadiene rubber (NBR), carboxylated nitrile rubber (XNBR), chloroprene rubber (CR) etc., its dispersion in non-polar rubbers like natural rubber (NR), is rather unsatisfactory. Incorporation of only 5 phr of OMt in NR by mechanical mixing leads to very poor dispersions with larger aggregates. Large agglomerates of OMt were observed with bare eyes throughout the matrix. Even in the TEM micrographs, highly agglomerated structures of clay particle were observed. A high degree of exfoliation of such clay is achieved in NR utilizing the so called ‘Propping-open approach’ where stepwise expansion of interlayer spacing of Mt took place. A series of long chain fatty acids (C16-C22) are intercalated into the interlayer space of OMt and a gradual expansion of the interlayer space were observed as the chain length of the fatty acid increased. Wide angle X-ray diffraction (WAXD), Fourier transform infrared spectroscopy (FTIR) and contact angle measurement indicated successful intercalation of the fatty acids into the interlayer space of the clay minerals. Since the fatty acid containing 22 carbon atoms has the largest interlayer distance among the modified samples studied, it has been selected for further study to understand the reinforcing behavior in NR matrix. An unusual mechanical percolation behavior of EOMt nanoparticles was observed in a NR matrix. The value of the mechanical percolation threshold (φp) and the fractal nature of nanoparticle clusters were determined through an analysis of the experimental data based on a theory put forward by Huber and Vilgis. This phenomenon was discussed in terms of fractal dimensions of the nanoparticle cluster. The impact of filler dispersion and rubber-filler interactions on the viscoelastic behavior of NR nanocomposites was systematically investigated. Significant non-linear viscoelastic behavior (Payne effect) was observed at very low EOMt content. Kraus and Maier-Göritz models were utilized to interpret such non-linear viscoelastic behavior. The nanocomposites showed enormous improvement in different physic-mechanical properties in the presence of EOMt. Technical elastomers are generally filled with certain fillers (e.g. carbon black) in order to reinforce the rubber matrix for some typical applications like tires, conveyer belts etc. Such rubber goods are always exposed to cyclic stress and deformations attributed to their dynamic application. Under constant and repeated applied stress, cracks develop at a stress concentration point, which could lead to ultimate failure. Therefore, the crack initiation and propagation behavior in such rubber products is very fundamental and need proper attention. The role of EOMt nanoparticles on the microstructure and fracture mechanical behavior of CB filled NR composites was investigated. Using pure-shear test specimen tear fatigue analysis (TFA) tests under cyclic conditions were carried out to explicate the crack growth behavior of CB filled NR in the presence of EOMt. A significant reduction in crack growth rate was noticed in the presence of only 5 phr of EOMt. Furthermore, instrumented tensile-impact tests (IT-IT) were also performed for the characterization of the crack resistance of the materials under impact-like loading conditions. / Die Einarbeitung von nur 5 phr organisch modifizierten Montmorillonite (OMt) in Naturkautschuk (NR) durch mechanisches Mischen führt zu einer sehr schlechten Verteilung mit größeren Aggregaten. Große Agglomerate von OMt waren mit bloßem Auge in der NR Matrix sichtbar. Sogar in TEM Aufnahmen wurden stark agglomerierte Strukturen beobachtet. Ein hoher Grad der Exfolierung von diesem Clay in NR wird durch die Nutzung des so genannten ‘Propping-open’ Ansatzes erreicht, in dem eine stufenweise Aufweitung des Zwischenschichtabstandes des OMt stattfindet. Eine Reihe langkettiger Fettsäuren (C16 – C22) wurde in die Zwischenschicht des OMt eingefügt. Mit zunehmender Kettenlänge der Fettsäuren wurde eine allmähliche Aufweitung der Zwischenschicht beobachtet. Da OMt, der mit einer Fettsäure mit 22 Kohlenstoffatomen modifiziert wurde, den größten Zwischenschichtabstand aller untersuchten Proben hatte, wurde diese Fettsäure für die weiteren Untersuchungen ausgewählt, um das Verstärkungsverhalten in der NR Matrix zu verstehen. Ein ungewöhliches Perkolationsverhalten der expandierten OMt (EOMt) Nanopartikel wurde in einer NR Matrix beobachtet. Der Wert der mechanischen Perkolationsschwelle (φp) und die fraktale Natur der Nanopartikel Cluster wurden durch eine Analyse der experimentellen Daten bestimmt, wobei eine Theorie, die von Huber und Vilgis vorangetrieben wurde, zur Anwendung kam. Dieses Phänomen wurde in Bezug auf die fraktalen Dimensionen der Nanopartikel Cluster diskutiert. Die Einfluss von EOMt Nanopartikel auf die Mikrostruktur und das mechanische Bruchverhalten von russgefüllten NR Kompositen wurde untersucht. Unter Verwendung reiner Schertestproben wurden Rissermüdungsanalysen unter zyklischer Belastung ausgeführt, um das Risswachstumsverhalten von russgefülltem NR in der Gegenwart von EOMt zu untersuchen und zu erklären. Eine signifikante Reduktion der Rissausbreitungsrate wurde in Gegenwart von nur 5 phr EOMt erreicht. Des Weiteren wurden auch instrumentierte Schlagzugprüfungen zur Charakterisierung des Risswiderstandes von Materialien unter schlagartigen Belastungsbedingungen durchgeführt.

No description available.

No description available.

No description available.

No description available.

Tire, or in its primitive form, Wheel, an important invention for the transportation sector, has evolved from a circular block of hard and durable material to one of the most complex and influential components of an automobile. It is the only means of contact between the vehicle and the road and is responsible for generating forces and moments that impact vehicle performance, stability, and control. Tire tribology is the study of interacting surfaces in relative motion which includes friction and wear. Tire friction is an essential concept for estimating the tractive effort/ traction at the tire-road interface that further helps to determine the control and stability of the vehicle. In contrary, it also results in rolling resistance and wear. Tire and vehicle engineers are henceforth interested in a robust and efficient approach towards estimation of friction and wear. Past experimental observations using tread compound samples have revealed the different factors influencing the friction at the contacting interface. In addition, different mechanisms or components resulting in frictional losses, being Hysteretic, Adhesive and Viscous, and wear being abrasive, fatigue, adhesive and corrosive were also observed. Although experimental and empirical observations have provided us with an accurate estimation of friction and wear parameters, it is very tedious and expensive approach. Recent developments in the computational power encouraged researchers and engineers towards evolution of analytical and numerical models considering the underlying physical mechanisms at the contact interface. Past research studies developed multiscale techniques for estimation of friction coefficient due to hysteretic losses from internal damping of the rubber material because of oscillation from surface undulations. Later, contact mechanics models developed using Hertzian technique or stochastic approach were considered in conjunction with frictional losses to obtain the hysteretic component of friction to consider the effect of surface roughness. Previous studies at CenTiRe focused on surface characterization techniques and estimation of friction for dry surfaces using Persson and Klüppel's approach. Comparative studies unveiled the importance of considering pressure/ normal load towards friction estimation. In addition, it was found that effect of adhesion for estimation of contact mechanics parameters must be considered. The present work focusses on obtaining a conceptual framework to model a comprehensive friction model considering the effect of surface roughness, substrate condition and asperity interaction. A finite element simulation of rubber block sliding on a rough substrate is performed using a multiscale technique for estimation of friction and contact mechanics under dry condition. The estimated contact mechanics and friction is compared with analytical models and experimental measurements obtained using Linear sliding friction tester developed in collaboration with other members of the group. In addition, a FE model is developed to measure the wear properties of rubber material based on continuum damage mechanics and further obtain the wear profile of a rubber block sliding on a rough substrate. / Doctor of Philosophy / Tribology, a recent terminology for an age-old concept of friction, wear, and lubrication. the study of interacting surfaces in relative motion which includes friction and wear. Friction is the resisting force at the contact interface leading to heat build-up and material loss at the contact interface which is known as flash temperature and wear respectively. Tire is one of the most complex and influential components of a vehicle that helps in optimizing its performance for better stability and control. Knowledge of tire friction and wear is important for tire engineering and vehicle dynamics engineers as it helps in characterizing the handling characteristics of the vehicle, characterizing the tire material compounds to understand the tire durability. Rubber is a viscoelastic material, the friction and wear in rubber is intricate as opposed to other elastic materials. Based on experimental observations in the past, friction and wear are influenced by factors like material properties, normal load/ pressure, sliding velocity, temperature, surface characteristics, and environmental conditions. In addition, the frictional losses at the contact interface are considered to compose of adhesion, hysteresis and viscous components and wear is categorized as – adhesive, abrasive, fatigue, corrosive and erosive. Recent developments in computational power encouraged researchers and engineers in developing analytical and computational models that consider the physical mechanisms occurring at the contact interface. The present research focuses on obtaining a comprehensive friction and contact mechanics model considering the effect of surface roughness at different length scales, surface condition (dry/ wet) and asperity interaction. In addition, the developed model in conjunction with a brush model is considered for estimating the tire traction characteristics such as the forces and moments. A finite element simulation of rubber block sliding on a rough substrate is performed using a multiscale technique for estimation of friction, contact mechanics and abrasion parameters under dry condition. The results thus obtained are compared with the analytical model that is developed for wet conditions. Experimental validation of the friction estimated using the analytical and numerical methods will be performed using a linear sliding friction tester developed in collaboration with other members of the group.

In this study of the development of the sugar, rubber, and cotton industries in Brazil, the writer proposes to show the development of these industries from the beginning of the industries to about 1947.

DC resistance and AC conductance and capacitance have been measured under various conditions in an effort to electrically characterize and make electrical-mechanical correlations for 15 carbon black filled rubber samples. Resistance, conductance and capacitance have been monitored as functions of uniaxial compressive stress, time, temperature, and mechanical and thermal history. Capacitance and conductance have also been monitored as functions of frequency under various degrees of compressive loading and before and after specific heat treatments. A direct relationship has been found between sample • conductance and capacitance under any thermal and/or mechanical condition. This is in agreement with previous theories of conduction network formation and percolation. Various conduction mechanisms have been enumerated and an equivalent circuit of a network of lumped R-C "microelements'' has been qualitatively described. Stress, relaxation, frequency, and temperature dependences of the macroscopic parameters measured ( conductivity and capacitance) are discussed in terms of this model. / M.S.