Thesis (Ph.D.) - University of Queensland, 2003. / Includes bibliography.

Thesis (Ph. D.)--Drexel University, 2006. / Includes abstract and vita. Includes bibliographical references.

The Summitville high-sulfidation gold deposit is hosted by a volcanic dome consisting of the South Mountain Quartz Latite that was erupted 23 Ma ago during formation of the Platoro Caldera complex in the San Juan volcanic field of south central Colorado. Alteration and mineralization developed during or shortly after dome emplacement as a result of metal-rich magmatic fluids and vapor emanating from a crystallizing intrusion at depth. Copper, arsenic, silver and gold are enriched in the deposit with two of the last paragenetic stages, the barite-base metal sulfide and goethite stages, containing the highest gold grades. Barite contains magmatic sulfur with a range of δ34S values (19.3 – 31.8 ‰) that reflects SO42– – H2S isotopic equilibration over a temperature range of 115 to 180 °C, which is consistent a calculated temperature of 147 °C based on the sulfur isotopic fractionation between intergrown barite and galena. Barite δ18O values (19.3 – 31.8 ‰) indicate the barite fluids contained a minor component of meteoric water. Barite growth zones with acicular crystals (wires) of emplectite (CuBiS2), a mineral not previously reported from Summitville, contained primary fluid inclusions that yielded a wide range of vapor to liquid homogenization temperatures as a result of stretching but consistent freezing point depressions that infer an average salinity of 5.1 wt. % NaCl equivalent. These data indicate that the barite fluids were modestly enriched in magmatic sulfur and metals (Cu, As, Bi, Pb, Zn, Au, Ag) and that barite precipitation was likely triggered by cooling during mixing with meteoric waters. The goethite stage developed during weathering of the deposit that likely occurred during uplift and exposure around 9 to 7.7 Ma ago based on 40Ar/39Ar dates on jarosite. The assemblage goethite + hematite ± jarosite ± scorodite ± gold filled open spaces and coated barite of the barite-base metal sulfide stage. Inclusions of barite and bladed alunite in the iron oxide/hydroxide (FeOx) matrix have the texture, composition and isotopic values of their earlier formed counterparts in the deposit and therefore represent residual material that survived the weathering event. Three 40Ar/39Ar dates on the bladed alunite ranged from 23.15 to 22.88 Ma, confirming their origin as magmatic hydrothermal alteration alunite. Layers of compositionally zoned, small rhombohedral crystals of alunite were also discovered in the FeOx matrix. Although these could not be successfully dated, they had a distinct texture, chemistry and isotopic composition (δ34S = 0.8 ‰ δ18O = 4.7 ‰) that indicated they formed during the weathering event. The acidic, oxidizing supergene fluids remobilized and broadly enriched the top of the deposit in Cu and Ag and locally in native gold (5 wt. % Ag).

The marked decline in tree island cover across the Everglades over the last century, has been attributed to landscape-scale hydrologic degradation. To preserve and restore Everglades tree islands, a clear understanding of tree island groundwater-surface water interactions is needed, as these interactions strongly influence the chemistry of shallow groundwater and the location and patterns of vegetation in many wetlands. The goal of this work was to define the relationship between groundwater-surface water interactions, plant-water uptake, and the groundwater geochemical condition of tree islands. Groundwater and surface water levels, temperature, and chemistry were monitored on eight constructed and one natural tree island in the Everglades from 2007-2010. Sap flow, diurnal water table fluctuations and stable oxygen isotopes of stem, ground and soil water were used to determine the effect of plant-water uptake on groundwater-surface water interactions. Hydrologic and geochemical modeling was used to further explore the effect of plant-groundwater-surface water interactions on ion concentrations and potential mineral formation. A comparison of groundwater and surface water levels, along with calculated groundwater evapotranspiration rates, revealed that the presence of a water table depression under the islands was concurrent with elevated groundwater uptake by the overlying trees. Groundwater chemistry indicated that the water table depression resulted in the advective movement of regional groundwater into the islands. A chloride budget and oxygen isotopes indicated that the elevated ionic strength of tree island groundwater was a result of transpiration. Geochemical modeling indicated that the elevated ionic strength of the groundwater created conditions conducive to the precipitation of aragonite and calcite, and suggests that trees may alter underlying geologic and hydrologic properties. The interaction of tree island and regional groundwater was mediated by the underlying soil type and aboveground biomass, with greater inputs of regional groundwater found on islands underlain by limestone with high amounts of aboveground biomass. Variations in climate, geologic material and aboveground biomass created complex groundwater-surface water interactions that affected the hydrogeochemical condition of tree islands.

The Térapa fossil vertebrate site, northcentral Sonora, Mexico, provides a rare opportunity to study the paleoenvironmental conditions present in northwestern Mexico during mid-Oxygen Isotope Stage (OIS) 3. Ostracode faunal assemblages and stable oxygen (δ18O) and stable carbon (δ13C) isotope values from ostracode calcite were used to reconstruct the seasonality of precipitation and vegetation cover at Térapa at 40-43 ka. The ostracode fauna was a non-analogue mix of temperate and tropical ostracode species composed of 13 species from 12 genera. The nearctic ostracodes Fabaeformiscandona caudata, Physocypria pustulosa, Cypridopsis vidua and the cosmopolitan ostracode Darwinula stevensoni dominate the assemblage. Two tropical ostracode genera, Chlamydotheca arcuata and Stenocypris sp., were present throughout the deposit and indicate that mean monthly summer temperatures were probably no more than 4°C to 6°C cooler than at present, based on available ecological information. Winter precipitation dominated the hydrologic cycle as evidenced by low ostracode δ18O values (-6‰ to -8‰ VPDB). Low ostracode δ13C values (-7‰ to -8‰ VPDB) suggest that local vegetation was dominated by C3 plants. A previous tooth enamel-based paleoenvironmental reconstruction at the same site favored a summer-dominated or evaporative hydrology and abundant C4 vegetation. The Térapa megafauna site exemplifies the need for multi-indicator paleoclimate reconstructions in desert environments where marked differences in the seasonality of precipitation and vegetation cover may occur.

No description available.

Three different methods were developed to evaluate nutritional status: stable isotopes, near infra-red reflectance spectroscopy (NIRS), and microbial populations. In the first method, hair samples were collected, analyzed, stable isotope content greatly differed (P < 0.01) between pre- and post-weaning samples. The second method used NIRS spectral patterns and analyzed fecal samples, and a difference was found around 2100 to 2250 nm where diets containing milk showed a peak, and non-milk diets showed a plateau. Finally, the third method involved profiling microbial populations from fecal samples as calves experienced dietary shifts. Total anaerobes, enterics, and clostridium were different (P<0.05) from pre to post-weaning states. Total anaerobe samples differed (P < 0.005) from milk, milk-grain diets to grain and grain-hay diets. Total aerobes, streptococci, and clostridium samples differed (P <0.001) from the milk diet to the other diets. In summary, all three methods showed differences when comparing pre- to post-weaning states.

In modern populations, adolescence is recognized as a pivotal part of the life course, but bioarchaeologists have not yet widely considered the experiences of adolescents in the past. This research investigates the biological and social changes during Roman adulescentia for individuals buried at Isola Sacra (1st-4th centuries CE; Italy) and Lisieux-Michelet (4-5th centuries CE; France). To investigate biological changes, this thesis identifies osteological indicators of pubertal timing and peptide analysis to assess biological sex for pre-pubertal individuals (n=264). Results demonstrate that adulescentia experienced an extended period of puberty, from nine to 20 years of age; menarche occurred around 15 years of age. Comparisons between the two archaeological sites demonstrate similar patterns of pubertal timing, suggesting similar exposure to Early Life Stress. To investigate the social changes, this research uses stable isotope analysis of incremental dentine sections in teeth, to investigate dietary change between childhood, adolescence, and adulthood. Incorporating literary sources, observed changes in diet are contextualized in relation to expected social age changes for middle-class individuals within the Roman Empire. At both sites, females exhibit a gradual dietary transition, reflecting a gradual social age change, or that diet is not an appropriate proxy for social age changes for women. For males, changing dietary patterns correspond with the beginning of adulescentia, when these young men took on new roles within their communities and underwent pubertal development. This research demonstrates that adulescentia was an extended period of biological and social change for males and females, which took on different forms depending on one’s sex/gender and social position. This research also demonstrates how investigations of adolescence can permit a more holistic interpretation of this transitional period of the life course and exposes the transitional experiences of these individuals as they come of age in the Roman Empire. / Dissertation / Candidate in Philosophy / There are kids, and there are adults, but what about those in-between? When does one become the other? These are the questions driving this doctoral research, and in applying them to the Roman Empire, I examine patterns of puberty and changes in diet, to better understand when children started to look like and eat like adults in their communities. This research demonstrates that adulescentia (i.e., adolescence) was a period of extended biological development, with puberty occurring between 9 and 20 years of age. Changes in diet, however, occurred in different ways for males and females, and across space and time within the Roman Empire, suggesting that there was not a singular experience or definition of adulescentia, but that lived experiences were more variable and nuanced than ancient literary sources suggest.

No / Although the origins of domestic animals have been well-documented, it is unclear when livestock were first exploited for secondary products, such as milk. The analysis of remnant fats preserved in ceramic vessels from two agricultural sites in central and eastern Europe dating to the Early Neolithic (5900-5500 cal BC) are best explained by the presence of milk residues. On this basis, the authors suggest that dairying featured in early European farming economies. The evidence is evaluated in the light of analysis of faunal remains from this region to determine the scale of dairying. It is suggested that dairying ¿ perhaps of sheep or goats ¿ was initially practised on a small scale and was part of a broad mixed economy.

As a result of the legacy of industrial contamination over the last century, areas of sediment deposition in the St. Lawrence River at Cornwall, ON, contain high concentrations of mercury (Hg). The popular sport-fish species, yellow perch (Perca flavescens) and walleye (Sander vitreus) have been found to contain mercury concentrations exceeding Ontario Ministry of Environment consumption guidelines. Interestingly, a paradox exists between two contaminated sites – despite elevated sediment Hg concentrations at Zone 2, fish from Zone 1 contain higher Hg concentrations. Further research has indicated that these patterns of Hg were not attributed to growth rate, condition factor, diet composition, or trophic position of yellow perch. Rather, Hg concentrations in yellow perch may be described by the heterogeneity of prey contamination and fish bioenergetics. As a result of the paradox between total Hg (THg) concentrations in sediments and biota between two contaminated sites, it was necessary to examine the benthic invertebrate community and how it may transfer Hg from sediments to yellow perch. This apparent paradox now extends to all prey items, since prey items from the stomach contents of yellow perch caught in Zone 1 were significantly more contaminated than those of Zone 2. Use of δ15N and δ13C, measures of trophic position and energy source, respectively, indicated that prey selection, but not food chain length, may also be an important factor in explaining the variation in Hg burdens in yellow perch. Small-scale patterns of biomagnification, as shown by a comparison of δ15N and logTHg, indicated that the rates of biomagnification were similar among zones, but the amount of THg present at the base of the food web was twice as high at Zone 1 as at other contaminated sites. Overall, the relative importance of vertical and horizontal food web structure changed spatially and temporally, highly influencing THg concentrations of prey items and yellow perch. / Thesis (Master, Biology) -- Queen's University, 2007-08-02 08:02:40.26