Diferentes resíduos são gerados pelas indústrias siderúrgicas, dentre eles o resíduo dos trituradores de sucata (RTS). O destino mais utilizado para o RTS pelas indústrias siderúrgicas brasileiras é o aterro de resíduos industriais. A pirólise se apresenta como uma alternativa para o reaproveitamento do RTS. O objetivo deste trabalho foi avaliar o efeito de diferentes parâmetros operacionais sobre as propriedades e o rendimento dos produtos do processo de pirólise do RTS para fins de um posterior aproveitamento. Um reator de pirólise de leito fixo foi utilizado e as seguintes variáveis foram testadas fazendo-se uso de um planejamento experimental 2k: temperatura (500, 600 e 700 ºC), taxa de aquecimento (5, 20, 35 ºC/min), vazão de gás inerte (N2) (0,03, 0,44 e 0,76 L/min) e razão CaO/RTS (0, 1 e 2). A utilização de uma taxa de aquecimento menor, associada a presença de CaO, resultou nos maiores rendimentos de gás não-condensável (> 50%). O poder calorífico deste gás, aumentou com o incremento da razão CaO/RTS. Este aumento foi atribuído a captura in situ do CO2. A utilização de uma vazão maior de gás inerte, também favoreceu o aumento do poder calorífico do gás não-condensável. Os maiores valores obtidos (25 MJ/Nm3) são apreciáveis, considerando o poder calorífico de outros combustíveis. Os maiores rendimentos de char (> 24%) foram obtidos nos experimentos com a utilização de uma temperatura menor, associada a ausência de CaO. A utilização de uma taxa de aquecimento mais elevada resultou em maiores rendimentos de voláteis condensáveis. Os menores rendimentos de voláteis condensáveis foram obtidos quando a vazão de inerte foi menor. Também foi possível verificar que, houve um aumento do rendimento de voláteis condensáveis com a presença de CaO para a temperatura de 700 ºC. Este comportamento foi atribuído ao maior rendimento global de estireno nas referidas condições operacionais. O rendimento global de 2,4-dimetil-1-heptano também apresentou comportamento semelhante ao observado para o rendimento de voláteis condensáveis, indicando que o AlCl3 pode ter atuado como catalisador da pirólise do PP presente no RTS. Com o aumento da razão CaO/RTS, houve uma redução da concentração de CO2. A redução da concentração de CO2 na presença de CaO está associada a formação de CaCO3. A retenção de cloro no char foi mais elevada nos ensaios conduzidos na presença de CaO. Verificou-se uma redução da retenção de cloro no char com o aumento da temperatura para os ensaios conduzidos na presença de CaO. Uma diminuição da retenção de metais no char foi verificada nos experimentos conduzidos com CaO para os seguintes metais: Co, Cu, Cr, Fe, Ni e Zn. A remoção do cloro permitiria conduzir o processo de pirólise a temperaturas mais elevadas, aumentando a Eficiência Energética mínima (EE) do processo. Desta forma, fica clara a necessidade da remoção do cloro do RTS antes do processo de pirólise, pois a partir disto o uso do CaO contribuiria para o aumento da EE e da retenção de metais no char, e consequentemente da desejabilidade global. / Different wastes are generated by steel industries, among them the shredder residue (SR). The most commonly used destination for SR by Brazilian steel industry is the landfill of industrial waste. The pyrolysis can be considered a solution to this problem. The aim of this work was to evaluate the effects of different operating parameters upon the properties and yield of the SR pyrolysis process products for later use. A fixed bed pyrolysis reactor was used and the following variables were tested using a 2k experimental design: temperature (500, 600 and 700 ºC), heating rate (5, 20, 35 ºC/min), flow rate of inert gas (N2) (0.03, 0.44 and 0.76 L/min) and CaO/SR ratio (0, 1 and 2). The use of a lower heating rate, associated with the CaO presence, resulted in higher yields of non-condensable gas (> 50%). The calorific value of this gas increased with the growth of the CaO/SR ratio. This increase was attributed to an in situ CO2 capture. The use of a higher flow rate of inert gas also favored the increase in the calorific power of the non-condensable gas. The highest values (25 MJ/Nm3) are appreciable considering the calorific value of other fuels. The highest char yields (> 24%) were obtained in the experiments using a lower temperature associated with the absence of CaO. The use of a higher heating rate resulted in higher yields of condensable volatiles. The lower yields of condensable volatiles were obtained when the inert flow rate was lower. It was also possible to verify that there was an increase in the condensable volatiles yield with the CaO presence at a temperature of 700 ºC.This behavior was attributed to the higher styrene overall yield under these operating conditions. The 2,4-dimethyl-1-heptane overall yield also presented a similar behavior to that observed for the condensable volatiles yield, indicating that the AlCl3 may have acted as a catalyst for the PP pyrolysis present in the SR. With the increase in the CaO/RTS ratio, there was a reduction in the CO2 concentration. The CO2 concentration reduction in the CaO presence is associated with the CaCO3 formation. The chlorine retention in the char was higher in the experiments conducted with CaO presence. A reduction in the chlorine retention in char was observed with increasing temperature for the experiments conducted with CaO presence. A decrease in metal retention in the char was verified in the experiments conducted with CaO for the following metals: Co, Cu, Cr, Fe, Ni and Zn. Chlorine removal would allow the pyrolysis process to be conducted at higher temperatures, increasing the minimum energy efficiency (EE) of the process. Therefore, it is clear the need to remove chlorine from the SR before the pyrolysis process, since, the CaO use would contribute to the EE increase and the retention of metals in the char, and consequently the global desirability.

Ce projet s’intéresse à un objet particulier : l’armure. Celle-ci, dont la fonction première était de protéger le combattant, s’est adaptée entre le XIIIe et le XVIIe siècle aux bouleversements qu’ont connu les pratiques de guerre et l’organisation des armées dans cette période. L’armure pouvait aussi avoir une autre fonction, celle de distinguer socialement son porteur. Ainsi, à la fin du Moyen Âge l’armure est à la fois un objet de grande consommation et d’usage courant mais également un produit de luxe. Sa fabrication, dominée par différents centres de productions internationaux comme les villes Milan et Nuremberg, demandait un savoir-faire spécifique pour travailler et mettre en forme le métal.Dans le but d’éclairer d’une part les techniques et savoir-faire anciens, d’autre part la circulation et les échanges dans l’espace européen, ce projet aborde l’étude de l’armure par sa matérialité, en mettant en œuvre une approche archéométallurgique. Un corpus spécifique, de plus d’une centaine d’objets, caractéristique de l’évolution de l’équipement défensif des combattants mais également des grands centres de production européens a ainsi été constitué. L’analyse du métal a permis de déterminer la nature des matériaux employés ainsi que les techniques de fabrication de ces objets. L’étude des inclusions non métalliques a quant à elle permis de discuter de l’origine géographique du métal utilisé pour la fabrication des pièces.De façon générale, les résultats ont montré l’emploi d’alliages de natures variées, parfois très hétérogènes pour réaliser les plates d’armures. Néanmoins en moyenne le métal employé possède une dureté proche de celle d’un acier homogène à 0,4-0,5% de carbone. Les alliages trempés de dureté élevée demeurent très minoritaires dans le corpus étudié. Des spécificités ont néanmoins été relevées, comme l’utilisation d’un matériau spécifique, associant plusieurs feuilles de métal aux propriétés différentes qui pouvait offrir à l’armure de meilleures propriétés défensives. Les informations acquises ont également permis d’étudier les pratiques mises en œuvre par les armuriers que ce soit pour la fabrication d’une armure complète, la production massive de pièces en « série », ou issues d’un même atelier. Les résultats relatifs à la nature et au travail du métal nous ont ainsi amené à questionner le rôle du maitre armurier qui signait les objets et la signification de cette signature pour un atelier. / The project focuses on a specific object: armor. Between the 13th and early 17th centuries, war practices have undergone major changes, both on the technological level, as well as the organizational one. Accordingly, defensives arms were adapted to the new needs in order to protect their owners. Armor was also in some cases a mark of social distinction. Thus, at the end of the Middle Ages, armor was both an object for everyday military use, massively produced, and a luxury attire. Its fabrication was dominated by several prestigious European centers of production like Milan and Nuremberg and required specific technical skills to shape the metal.In order to shed light on some of the techniques and ancient skills, along with the circulation and exchanges in the European space, this project addresses the study of armor through its materiality, by implementing an archeometallurgical approach. A specific corpus of over a hundred artefacts was collected, characteristic of the evolution of the defensive equipment of the fighters but also of the great European centers of production. Physicochemical analysis of the metal can decipher its nature and reveal the technical skills of the craftsmen. Non metallic phases analysis has allowed to test hypotheses on the provenance of the materials employed.Overall, the results showed the use of alloys of varying nature, sometimes highly heterogeneous, to realize the plates of armor. However, on average the metal employed has a hardness close to a homogeneous steel with 0.4-0.5% carbon. Hardened alloys of high hardness remain very minor in the studied corpus. Specificities were nevertheless noted, such as the use of a specific material, combining several sheets of metal with different properties that could offer better defensive properties. The information acquired also allowed to study the workshop practices implemented by the armorers, whether for the manufacture of a complete set of armor, the mass production of "serial" pieces, or those originating from the same workshop. The results relating to the nature and hammering of the metal have led us to question the exact nature of the intervention of the master armorer who signed the artefact and the significance of the signature of a workshop.

The greatest political, scientific, and engineering challenge of the 21st century is finding a viable solution to limit anthropogenic greenhouse gas emissions (CO2) to curb the effects of global climate change. All sectors of society need to contribute to alleviate this problem, but industrial operations must play a significant leadership role. Some of these industries include: metallurgy, cement, power, agriculture and forestry. In particular, the iron/steel, cement, and power generation industries use coal on account of its high energy density among solid fuels. Coal combustion yields 720 tonne CO2/GWh, and produces fine particulates, sulphur and nitrous oxides, along with excess CO2 contributing to climate change. In comparison, biomass (such as agricultural and forestry residues) has a solid fuel rating of 25-100 tonne CO2/GWh; therefore, biomass fuels are considered more sustainable since the living biomass consumed CO2 in the early part of its life cycle. However, biomass has significant industrial shortcomings for its use as fuel at large scale, including low energy content, density, and hydrophobicity relative to coal. In short, biomass fuels cannot be substituted without major infrastructure changes which add economic penalties that industry is currently unwilling to absorb. Biomass upgrading routes were considered in this thesis. These include densification, torrefaction, and integrated torrefaction and densification (ITD). The first half of the methodology involved converting woody biomass (willow residue and poplar bark), agricultural residue (switchgrass plants), and pulp mill waste via a single pellet/briquette press at different densification temperatures and pressures. The second half of the methodology involved product characterization of each batch of pellets and briquettes. In this work, pellets and briquettes were tested for physical characteristics (density and durability), chemical differences (energy content and hydrophobicity), and transport phenomena characteristics (drying profiles). First, results showed that extrusion of torrefied biomass at 300°C with an estimated pressure of 10 MPa creates partially formed pellets from agricultural residues. Using the concept of ITD (temperature range 220-325°C and pressure range 40 and 215 MPa), the density was found to be 1000-1250 kg/m3 for pellets and briquettes. The degree of compression from the loose biomass was on the order of 3-10 which corresponds with theoretical expectations. Material density increased with increasing pressure. The solid yield of pellets and briquettes decreased with increasing temperature, and results aligned with micro-scale thermogravimetric analysis. The larger ITD briquettes (produced at T = 325°C, P = 40 MPa) were evaluated for calorific value and found to fall in the lignite classification (O/C < 0.4 and H/C < 1.2) on a van Krevelen diagram. The resulting ITD pellets and briquettes were found to have a durability similar to commercial materials (durability > 97%), and to be more hydrophobic (8 wt% moisture absorption compared to 35 wt%). The drying time of ITD materials was faster than commercial torrefied briquettes, with an effective diffusivity of 1.5×10-6 m2/s compared to 7.3×10-9 m2/s likely because of a smaller pore volume in ITD briquettes. Further pilot scale studies would help improve the ITD methodology and make the process more appealing for the replacement of coal fuels.

<p>This thesis is a description of the sales process for Toolox, the newest of four products produced by SSAB Oxelösund. Toolox is a tool steel, sold using eleven external dealers throughout Europe. Each dealer carries a wide range of steel grades for different uses. To increase sales volumes SSAB want to have the right support for their dealers. In this thesis the organizations and individuals who influence in the buying decision are identified as well as their buying behavior and the information that is needed in the sales situations. The requirements on the tool steel derive not only from the toolmaker itself but also from end users of a product further down the product chain. The study indicates that communication of benefits along the chain difficult because is not well integrated. The decision of what steel to buy is often made by the tool designer and these are influenced by a number of other individuals. It is also found that risk aversion and conservatism are barriers for product introductions.</p>

This thesis is a description of the sales process for Toolox, the newest of four products produced by SSAB Oxelösund. Toolox is a tool steel, sold using eleven external dealers throughout Europe. Each dealer carries a wide range of steel grades for different uses. To increase sales volumes SSAB want to have the right support for their dealers. In this thesis the organizations and individuals who influence in the buying decision are identified as well as their buying behavior and the information that is needed in the sales situations. The requirements on the tool steel derive not only from the toolmaker itself but also from end users of a product further down the product chain. The study indicates that communication of benefits along the chain difficult because is not well integrated. The decision of what steel to buy is often made by the tool designer and these are influenced by a number of other individuals. It is also found that risk aversion and conservatism are barriers for product introductions.

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Manufacturing Execution System (MES) is the major tool used to increase the effectiveness and efficiency of the operation management for the Steel Industry. Prior to implementing the MES, correctly estimating the MES Software Project Size is an important first stage and is a complex exercise. Several methods have been proposed to help in evaluating MES Software Project Size before implementation, such as function point analysis and fast function point analysis approaches. Among them, the fast function point analysis is a prominent approach. However, the detailed guideline for the use of it is lacking. Therefore, this study presents a methodology which provides these guidelines and uses it to estimate the MES Software Project Size in the Steel Industry. The research methodology is articulated using the design science research methodology. A usability evaluation is performed using three steel industry cases to demonstrate its applicability. With this enhanced approach, IT professionals or adopting organizations can more easily and systematically estimate the MES software project size.

Steel industry is a highly polluted industry and one of the most important stationary sources in Kaohsiung City. The steel manufacturing process could emit a huge amount of particles, such as the sintering process, the blast furnace operation, and the raw material handling process. Suspended particles emitted from steel industry could deteriorate ambient air quality and cause adverse effects on human health. In order to understand the impact of steel industry on ambient air quality in Siaogang District and to identify potential pollution sources, this study selected a integrated steel manufacturing plant located at Siaogang District to conduct a sampling protocol of suspended particulate matter (PM) at ambient sites (A1~A5) and sensitive sites (S1~S5) from July 2011 to March 2012. The size distribution of suspended particles in four seasons was measured with PM10 high-volume samplers, dichotomous samplers, and MOUDI for 3 days (24 hours for single sampling), and dustfall samplers for one month, to investigate the spatial distribution and temporal variation of PM concentration. After sampling, the physicochemical properties of PM, including mass concentration, particle size distribution, dustfall concentration, water-soluble ionic species, metallic elements, and carbonaceous contents, were further analyzed. Field measurement of ambient PM showed that the averaged ambient PM10 concentration (53.54 - 203.56 £gg/m3) were higher than sensitive sites (55.06 - 140.07 £gg/m3) and the averaged ambient PM2.5 concentration of ambient (23.10 - 120.21£gg/m3) were higher than sensitive sites (12.52 - 65.62 £gg/m3). No matter ambient or sensitive sites, it showed a tendency of lower concentration in summer, indicating that concentration variation of PM10 and PM2.5 were highly affected by meteorological factors (such as wind direction, wind speed, and relative humidity) in Siaogang District. Furthermore, a t-test result showed that ambient and sensitive sites have similar pollution sources since the p-values were in significantly different. Chemical analysis of PM results showed that the most abundant water-soluble ionic species of PM at the ambient and sensitive sites were secondary inorganic aerosols (SO42-, NO3-, and NH4+) and [NO3-]/[SO42-] showed that ionic species were mainly emitted from stationary sources. Fe, Al, K and Ca were the major metallic elements of this study, and the major pollution sources contain industries, traffics, and road dusts. Additionally, the raw material handling process was the major pollution source of PM. Correlation analysis of OC and EC showed that PM at ambient and sensitive sites were originated from primary sources, such as vehicles, industries, road dusts, and human activities. Results obtained from PCA and CMB receptor modeling showed that both PM2.5 and PM10 highly correlated with wind direction in different season and the major pollution sources were industry pollution (including petroleum refineries, power plants, waste incinerators, consistent operating steel mills and electric arc furnace steel mills, etc.), followed by local traffics and derivative. Furthermore, marine aerosols were one of the important pollution sources at sensitive sites (S1, S4, and S5) where close to the ocean.

The objective of this study was to investigate the exposure assessment and health risk of particulate matter emitted from steel industry for high-risk inhabitants living in metro Kaohsiung. A steel plant and an electric arc plant were selected for conducting the sampling of particulate matter (PM). The physical and chemical properties of PM sampled at the working place and at the fence of selected plants were also analyzed to establish the fingerprints of PM in the steel industry. In order to accomplish this study, both personal sampling and environmental sampling were conducted in steel plants. Personal exposure sampling was undertaken at working places, while the conduction of environmental sampling might affected by various uncertain environmental factors (such as meteorological condition and other emission sources), but it could characterize the overall environmental situation and help exposure assessment. Moreover, The exposure of employers (including manufacturing workers and supporting staffs) could be further assessed based on the concentration and duration of PM exposure. Specific metal concentration was obtained from working environment, searching for exposure parameter (such as exposure frequency, exposure duration, body weight, average time, and etc.) and toxicity database (e.g. cancer slope factor and reference dose). The data could be used for assessing both cancer risk and non-cancer risk of specific heavy metal. Sampling data obtained from working places showed that the highest PM concentration were observed during the electric arc process, especially the charging and discharging procedures. The concentration of PM1.0, PM10, and TSP at the working places were 53.3~195.6 £gg/m3 ,365.7~550.0 £gg/m3, and 1085.5~2755.0 £gg/m3, respectively. Measured at the outdoor environments of working places, the highest PM10 and TSP concentration, ranging from 365.7~550.0 £gg/m3 and 1085.5 ~2755.0 £gg/m3, were observed at the sinter plants of a steel manufacturer. Sampling data obtained at the fence of steel plants (a steel plant and electric arc plant) indicated that the concentration of PM10 and TSP exceeded the ambient air quality standards. Modification of manufacturing process and improvement of PM collection system are highly required to reduce the concentration level as well as the emission of PM. Results of fingerprint of PM (PM2.5, PM2.5-10, TSP) obtained from working places showed that iron, calcium, sulfate, nitrate, calcium ion, and elemental carbon were the major chemical content of PM at the melting plant, the sinter plant, and the storage field. While, iron, calcium, sulfate, nitrate, calcium ion, and organic carbon were the major chemical content of PM at electric arc plant. Results of personal exposure concentration and exposure dose of PM showed that the highest exposure level of both manufacturing workers and supporting staffs were observed at the storage field, while the lowest exposure level was found at the sinter plant. Therefore, enforcement of wearing maskers and/or shelters at the storage field is also highly recommended to prevent manufacturing workers from the exposure of high-level PM at working places. Moreover, the cancer risk of manufacturing workers exposured to hexavalent chromium (Cr6+) at the melting plant, the sinter plant, the storage field, and the electric arc plant exceeded acceptable cancer risk standard (10-5~10-6), while the hazard index of manganese (Mn) was much higher than other metals.Meanwhile, exposuring to Cr6+, Ni, and Mn at the electric arc plant also exceeded acceptable standards (Cr6+ and Ni¡G10-5~10-6 , Mn¡G1). Several control strategies, including pollution reduction measures such as the usage of clean fuel, process modification, the improvement of collection system, the enhancement of manufacture management, the conduction of environmental monitoring and exposure assessment, floor cleanup and truck entrance management, are recommended to improve the contamination of PM at working places and surrounding environments for metallurgic industries. Moreover, enforcement of wearing maskers and/or shelters at high-risk environments is also highly recommended to prevent manufacturing workers from the exposure of high-level PM at working places. Keywords: steel industry, particulate matter sampling, physical and chemical characteristics, exposure assessment, health risk

Industrial Networks and Foreign Direct Investment: The Study of Taiwan¡¦s Steel Industry Abstract Facing the changing environment, many Taiwan businesses try to achieve economy of scale and develop their markets by taking foreign direct investment (FDI), especially under poor macroeconomic conditions in Taiwan and the driving force of cheap costs from developing countries. Conventionally, it is considered that big firms take FDI to bring their specific advantages into foreign markets. From the view of industrial networks, FDI is a method for firms to set up a linkage with foreign networks. They need not establish foreign networks by themselves. They can establish and utilize foreign networks through FDI. The steel industry is capital and technology intensive, and with high entry barriers in nature. The industrial networks are very important to a steel firm because it is very difficult to attain all the production resources. The key success factor is the competence to grasp the production resources so as to obtain cost advantages and synergy. In the past decade, facing lack of labor, increasing land cost, and market pull, the down-stream firms took FDI dramatically. The middle- and up-stream firms are also eager to do so. Because of the huge investment scale and other limitations, it is not easy for upstream firms to take FDI. Even China Steel Corporation (CSC) has overcome a lot of obstacles in the past decade and finally acquired ORNA Steel in Malaysia to establish a bridgehead in Southeastern Asia. From the view of industrial networks, this study tries, first, to investigate the network change of the firms of Taiwan¡¦s steel industry after taking FDI, and next examine the change of competitiveness and ways of attaining profit. We construct a model which divides them into four types of firms and their ways of attaining profits. They are: flagship type industry/profit sharing, clan type industry/profit shifting, lone knight type industry/profit capturing, stragglers type industry/profit disappearing. Then, we use this model to examine cases of Taiwan¡¦s up, middle, and down stream steel industry in a dynamic way. Finally, we propose some recommendations for the government and steel industry to improve the competitiveness of the steel industry.