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L’étude porte sur la propagation lente de fissure à température ambiante dans deux classes de polymères à l’état vitreux : le PMMA et la résine époxy-amine stœchiométrique DGEBA-IPD comme prototypes respectifs de thermoplastique (TP) et de thermodurcissable (TD). Des mélanges TD/TP présentant une séparation de phase de nano-domaines de thermoplastique dans une phase dominante de thermodurcissable ont été aussi explorés en vue de leur intérêt en tant que matrice à morphologie complexe utilisée dans les composites à renfort de fibre de carbone destinés à l’aéronautique. Un montage expérimental original a été développé pour le suivi in situ de propagation lente de fissures, combinant une caméra optique, un microscope à force atomique (AFM) et un échantillon sollicité en géométrie Double Cleavage Drilled Compression (DCDC). La possibilité d’accéder ainsi à une gamme de vitesses de propagation entre le pm/s et le nm/s a permis de mettre en évidence pour la toute première fois un régime de propagation stationnaire dans les thermodurcissables (résines pures et mélanges TD/TP) analogue au comportement établi pour les thermoplastiques, et de le caractériser en termes d’une loi cinétique reliant la vitesse de propagation au facteur d’intensité des contraintes (SIF). L’analyse in situ AFM a de plus permis de caractériser les différentes modalités de déformation à l’échelle de la zone de process en combinant l’imagerie topographique et des techniques de corrélation d’images numériques (DIC). Un modèle de prédiction des énergies de rupture en propagation stationnaire ainsi qu’en régime de stick-slip a été développé, en intégrant les champs de déformation visco-plastiques mesurés dans la zone de process, la vitesse de déformation locale, et la loi de comportement des matériaux mesurée à l’échelle macroscopique. / This work deals with the slow crack growth in glass polymer materials at room temperature, namely PMMA and stoechiometric epoxy-amine DGEBA-IPD resin as archetypes of thermoplastic (TP) and thermoset (TS) respectively. TS/TP blends developing phases separation in nano-domains of thermoplastic during the cure process have also been studied since they are used as matrix with a complex morphology in carbon fibers reinforced composites materials for aircrafts. An innovative experimental setup has been developed for in situ investigation of slow crack growth by combining optical measurements, in situ atomic force microscopy (AFM) and a Double Cleavage Drilled Compression (DCDC) sample. By this way, a steady state crack propagation regime has been highlighted for a first time in thermosets (pure and TS/TP blends) with crack speed ranging from pm/s to nm/s. Thus crack speed and stress intensity factor (SIF) diagrams were established for each material. Furthermore, in situ AFM images allowed characterizing deformations at the process zone scale by combining topographic imaging with Digital Images Correlation (DIC) technique. Finally, we developed a model for predicting fracture energy for steady state propagation and stick-slip regime, based on the visco-plastic strain fields measured round the process zone, the local strain rate, and the constitutive laws of materials measured at the macroscopic scale.

Given the increasing consumption of plastic materials their reuse becomes a very topical issue. Recycling the single-cleaned plastic waste is simple, these products can be used as raw material or additive in the manufacture of new products. The problem remains the energy, economic and environmental demands in sorting, cleaning and eventual regranulation of waste to a suitable feedstock. This problem can be solved using technology that is able to handle multiple-type waste thermoplastics in further useful products.

The increasing use of polymer-based materials (PBMs) across all types of industry has not been matched by sufficient improvements in understanding of polymer tribology: friction, wear, and lubrication. Further, viscoelasticity of PBMs complicates characterization of their behavior. Using data from micro-scratch testing, it was determined that viscoelastic recovery (healing) in sliding wear is independent of the indenter force within a defined range of load values. Strain hardening in sliding wear was observed for all materials-including polymers and composites with a wide variety of chemical structures-with the exception of polystyrene (PS). The healing in sliding wear was connected to free volume in polymers by using pressure-volume-temperature (P-V-T) results and the Hartmann equation of state. A linear relationship was found for all polymers studied with again the exception of PS. The exceptional behavior of PS has been attributed qualitatively to brittleness. In pursuit of a precise description of such, a quantitative definition of brittleness has been defined in terms of the elongation at break and storage modulus-a combination of parameters derived from both static and dynamic mechanical testing. Furthermore, a relationship between sliding wear recovery and brittleness for all PBMs including PS is demonstrated. The definition of brittleness may be used as a design criterion in selecting PBMs for specific applications, while the connection to free volume improves also predictability of wear behavior.

The Earth’s upper atmosphere is suffused by radiation caused primarily by a bombardment of Cosmic Rays, as a result of which it is hazardous for human beings as well as sensitive electronic equipment on board flight vehicles. A series of ground based as well as airborne experiments were performed using Polylactic Acid (PLA), Acrylonitrile-Butadiene-Styrene (ABS) and High Impact Polystyrene (HIPS), in order to investigate the applicability of polymers that can meet today’s needs for lightweight, multifunctional, and cost efficiency in radiation shielding of electronic equipment. It was found that PLA at 8 mm thickness has an effectiveness of 66% against gamma radiation (i.e., it blocked 66% of the gamma radiation). Therefore, it was decided to proceed with a high altitude balloon experiment with an 8 mm thickness of PLA. The shield was demonstrated to be reasonably effective in attenuating radiation from cosmic rays.

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This dissertation proposes a modi ed internal state variable (ISV) inelastic damage model that was motivated by experimental structure{property relations of thermoplastics. In particular, a new damage model was developed for glassy, amorphous thermoplastics. ISV evolution equations are de ned through thermodynamics, kinematics, and kinetics for isotropic damage arising from two di erent inclusion types: pores and particles. The damage arising from the particles and crazes is accounted for by three processes: damage nucleation, growth, and coalescence. Damage nucleation is de ned as the number density of voids/crazes. The associated ISV rate equation is a function of stress state, molecular weight, fracture toughness, particle size, particle volume fraction, temperature, and strain rate. The damage growth is based upon a single void growing and its growth is de ned by an ISV rate equation that is a function of stress state, strain rate sensitivity, and strain rate. The coalescence ISV equation enables interaction between voids and crazes and is a function of the nearest neighbor distance between voids/crazes, size of voids/crazes, temperature, and strain rate. The damage arising from pre-existing voids employs the Cocks{Ashby void growth rule. The total void volume fraction is a summation of the damage arising from particles, pores, and crazes. Micromechanical modeling results for a single void compare well to experimental ndings garnered from the literature. This formulation is then implemented into a nite element analysis. For damage evolution, comparisons are made between a one-dimensional material point simulator and a three-dimensional nite element (FE) simulation. Finally, good agreement is found between impact experiments and FE impact simulations using the implemented model.