There are currently three known crystal packing motifs of boronsubphthalocyanine derivatives. Each motif is associated with a particular class of BsubPc derivatives, and none are ideal for organic electronic applications according to the criteria we defined for evaluation: having a continuous pathway for charge-carrier conduction in the solid-state, resistance to hydrolysis, good electrochemical and optical properties, and possession of a robust crystal form. In this thesis, we present five methods for altering the crystal packing structure of phenoxy-BsubPc derivatives in order to meet the above four criteria. We find that neither addition of steric bulk to the axial derivative nor changing the symmetry of the compounds is sufficient for creating a new crystal packing motif. We do find that reducing the symmetry of the axial group does increase the solubility greatly, however. We identify a new motif for BsubPc crystals that occurs when the intermolecular interactions between the axial phenoxy segment and the BsubPc ligand are increased. We present two methods for achieving this new motif, one is through addition of a π-Br interaction and the other is through creation of a strong π-acid/ π-base stacking by making the axial phenoxy more π-electron rich. Unfortunately, the p-bromophenoxy-BsubPc forms this new motif as a kinetic product, isolation of which is unreliable. Attaching a naphthol fragment axially to the BsubPc creates a stable version of this new motif. We also synthesized a new class of BsubPc pseudohalides based on sulfonate derivatives. Of the derivatives in this new class, we found that mesylate-BsubPc forms into a crystal packing structure that possesses a one-dimensional pathway for charge carrier mobility, but is still resistant to hydrolysis under the conditions tested. Overall, we show four compounds that meet the criteria for further study as organic electronic materials: p-methoxyphenoxy-BsubPc, α-naphthoxy-BsubPc, β-naphthoxy-BsubPc, and mesylate-BsubPc.

This thesis aims to investigate different infrared absorbing molecules and how their properties are affected by their incorporation into polymer nanoparticles. Metal-free phthalocyanine-H2Pc, uranyl super phthalocyanine-USPc, and europium bisphthalocyanine were studied-EuPc2; the latter two capable of IR absorption. Due to the discovery of USPc’s moisture sensitivity, only H2Pc and EuPc2 were derivatized to facilitate encapsulation in polystyrene nanoparticles through a miniemulsion polymerization. These novel phthalocyanines attained loadings of up to 41wt% and exhibit substantial broadening of absorption peaks. Furthermore, the EuPc2 loaded particles also reveal an unprecedented gain in extinction coefficient of the NIR and radical absorption peaks. The leaching behavior of the dye was also studied, as this had not been undertaken in the literature, and revealed the need for a method of polymerizing/chemically binding phthalocyanines into nanoparticles; with preliminary steps taken to realize this goal.

The aim of this project was to produce a potential feedstock for biodiesel by developing a process to extract oil from yellow mustard seeds using aqueous and isopropyl alcohol extraction. The aqueous extraction of yellow mustard flour was performed at pH 11 using 4:1 water to flour ratio and constant stirring at room temperature for 30min, with a second washing stage. Oil was separated as oil-in-water emulsion with 37% oil recovery from the flour. The oil in the emulsion was then extracted with isopropyl alcohol. Single and multiple stage extractions were evaluated and the optimal conditions were four-stage extraction at 2:1 IPA:Oil weight ratio, with 96.3% oil recovery from the emulsion. A preliminary evaluation of the final solution of isopropyl alcohol, water and yellow mustard oil concluded that it is indeed a potential feedstock for biodiesel, however it needs to be further processed to meet optimal conditions for transesterification.

Organic solar cells (OSCs) are of interest because the technology offers a significant opportunity to reduce the overall costs of solar energy. OSCs can be very inexpensive to produce given that they rely on non-commodity materials and can use existing manufacturing techniques that are not labour- and capital-intensive. In this research, a financial model, named TEEOS (Technological and Economic Evaluator for Organic Solar), is developed and is used to determine financial indicators, such as simple payback period. These indicators are used to determine technical objectives for the OSCs. Two sample cells are evaluated in Toronto, Canada using historical data. The results show that the cell with a higher efficiency and wider absorptive wavelength range produces a payback period of approximately nine years, while the other cell has a payback period well over 45 years. Stochastic modeling techniques are also used to better replicate electricity price and weather fluctuations.

The historical long-term volatility and return on investment in single-family dwellings was investigated and compared with investments in equity, bonds and T-bill markets. Total return index for equity and fixed-income security indices were obtained from available sources, of course, a proper index for measurement of long-term changes in house prices was unavailable. In an effort to measure the house price changes, a relatively homogeneous pool of houses in the downtown Toronto area was selected and its price tracked over the study period of 44 years. Inflation rate affects the return of investments in everything similarly therefore this was not considered in the calculations. Results of comparing the investment of cash in one's family home versus in other investment vehicles showed that the ratio of investment growth to its volatility for a single-family house exceeded the ratios for other investments by a large margin.

The following thesis demonstrates two isotope tracing experiments that measure oxygen transport through electrochemically polarized solid oxides. Cathode-symmetric ‘button’ cells with yttria stabilized zirconia(YSZ) electrolytes and either strontium doped lanthanum manganate(LSM) or composite LSM/YSZ cathodes were studied. The first experiment measured the residence time distributions(RTD) of 34O2. The measured RTDs were compared at different temperatures(700-800°C) and applied potentials(-2 to -8V). Comparisons with simulated RTDs revealed that oxygen transport was laterally heterogeneous. Delamination of the counter electrode is likely the source of the heterogeneity. The second experiment measured a wave of 18O by exposing an interior cross section and applying ToF-SIMS analysis. A depth profile was produced that spans the cathode and electrolyte interface. The depth profile was compared with a variety of limiting oxygen activation scenarios predicted by a simple 1-D model. Comparisons demonstrated that oxygen activation is likely not restricted to the cathode and electrolyte interface.

Triple fortification of salt with vitamin A, iron, and iodine has been investigated in the past to reduce micronutrient deficiencies in the developing world. The objective is to develop integrated nutrient delivery technology by microencapsulating a self-emulsifying drug delivery system (SEDDS) made of surfactants and a bioactive compound, retinyl palmitate. The SEDDS is used to enhance absorption of the vitamin A through food systems and to achieve targeted release of the active ingredient. Encapsulating vitamin A was difficult when using the spray dryer and the enteric coating, Aquacoat®. Losses of the micronutrient after a three month storage period ranged from 50-99% at both 25°C/20% RH and 45°C/60% RH. The result of a matrix encapsulation and poor coating formation contributed to the high losses. Further investigation of coating systems with the aim of stabilizing all three samples for a six month storage period such as using other encapsulating methods is recommended.

Electrostatic precipitators (ESPs) are commonly used to control particulate emissions from recovery boilers in the kraft pulping process. The electrical resistivity of entrained particulates is known to affect the performance of ESPs. There are many factors which influence resistivity of particulate matter, such as field strength, time of exposure, particle size, particle composition, temperature, and flue gas composition. The objective of this study was to identify the ideal operating conditions and dust particle characteristics which lead to an optimum dust resistivity and maximized ESP efficiency. The effect of these factors was examined through a variety of experimental and analytical techniques on kraft recovery boiler ash samples and synthetically prepared samples. It was concluded that particle composition, gas composition, and ambient temperature had the most pronounced effects, while the other factors, such as field strength and exposure time, had a smaller impact on particle resistivity.

The purpose of this work was to study the ability of the Slacks-Based Model of Data Envelopment Analysis in the prediction of corporate failure of non-manufacturing companies as compared to Altman’s Z’’ score model. This research looks at non-manufacturing firms specifically and attempts to classify companies without looking at the asset size of the firm. A DEA model based on the Altman’s Z’’ score financial ratios was created as well as a revised DEA model. The overall accuracy of the models showed the revised DEA model to be more accurate than the original DEA model as well as the Altman Z’’ score. This indicated that bankruptcy could be predicted without the use of total assets or liabilities as variables. This also showed the ability of an SBM DEA model to predict bankruptcy.

In the present work, the breakage of wastewater particles in orifice flow is investigated through numerical simulations. Using maximum strain rate along particle paths as the breakage criterion, breakage is predicted using computational fluid dynamics. The numerical simulations confirm that nominal orifice strain rate cannot explain the higher particle breakage in single-orifice systems compared to that of multi-orifice systems, instead particle breakage was found to correlate well with the maximum strain rates in the system. On the issue of effect of initial particle location on breakage, numerical modeling shows that particles travelling along the centerline are suspected to break less than those travelling near the wall. However, experiments designed to study the breakage of particles injected at various radial locations proved inconclusive. Finally, results suggest that while single orifice systems are ideal for strong particles, multi-orifice systems may be more effective in breaking weak particles.