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Preparation of novel bitumen nanocomposites out of polymer-modified montmorillonite nanoparticlesBelke, Eduard 02 August 2017 (has links)
To extend the time of service of asphalt roads modified montmorillonite nanoparticles were incorporated into bitumen with the aim of creating a gas barrier inside the bitumen which slows down the diffusion of oxygen through the bitumen. For this purpose [montmorillonite/alkyl-quat-primer] adducts ([MMT/PEI(nkD)xQyR]) were fabricated in which single-montmorillonite platelets were coated by a ultrathin polymer film by reacting montmorillonite particles with poly(ethylenimine) based polycations. The alkyl-quat-primer polymers were synthesised by adding ammonium groups and alkyl chains to hyperbranched poly(ethylenimine)s in a solvent-free reaction. Adducts with fully intercalated polymers were obtained when the polymers were reacted with an aqueous solution of [MMT/CTAB] or by mixing the polymers with montmorillonite and CTAB in an aqueous solution. The polymers replaced the CTAB in an intermediate formed [MMT/CTAB] adduct and adhered strongly to the montmorillonite due to a cooperative electrostatic interaction between the positively charged ammonium moieties of the macromolecules and the negatively charged montmorillonite surface. [MMT/alkyl-quat-primer] and [MMT/CTAB] adducts were incorporated via a single screw extruder into polymer- and non-polymer-modified bitumina to create bitumen-nanocomposites. Composites prepared under optimised conditions exhibited an adduct network inside the bitumen at adduct concentrations larger 5 wt.% and when non-polymer modified bitumina were modified. The aspect ratio of the incorporated montmorillonite platelets depended strongly on the adduct composition and the used bitumen, and was with [MMT/PEI(10kD)10Q80R10] adducts were very high (~ 300 - 1000) but with [MMT/PEI(10kD)10Q60R14] and [MMT/CTAB] adducts considerably lower (~ 30 - 90).
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Synthese von Tetragastrin-CC-1065-Konjugaten und verwandten Verbindungen für eine selektive Krebstherapie / Synthesis of Tetragastrin-CC-1065-conjugates and related compounds for a selective cancer therapyChen, Xiong 04 July 2006 (has links)
No description available.
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Palladium-katalysierte Dominoreaktionen mit Bicyclopropyliden in flüssiger und an fester PhaseNüske, Hanno 30 October 2000 (has links)
No description available.
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Synthese und biologische Evaluierung neuartiger Acronycin-Duocarmycin-Hybride / Synthesis and Biological Evaluation of Novel Acronycine-Duocarmycin HybridHeins, Arne 15 December 2011 (has links)
No description available.
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Final Elucidation of the Absolute Configuration of Hormaomycin - Total Synthesis of Hormaomycin and Analogs / Endgültige Strukturauklärung des Hormaomycins und Totalsynthese von Hormaomycin sowie AnalogaZlatopolski, Boris 05 November 2003 (has links)
No description available.
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Palladium(II)-katalysierte Domino-Reaktionen zur enantioselektiven Synthese von Confluentin, Daurichromen- und Rhododaurichromansäure Untersuchungen zur Synthese von Aglaroxin A / Palladium(II) catalysed Domino Reactions for the enantioselective Synthesis of Confluentin, Daurichromenic and Rhododaurichromanic acid Studies towards the Synthesis of Aglaroxin ABöckemeier, Henning 11 April 2011 (has links)
No description available.
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VERSUCHE ZUR SYNTHESE VON PROTOILLUDAN-SESQUITERPENEN ÜBER UMLAGERUNGSREAKTIONEN: (±)-CERAPICOL, (±)-STERPUREN UND (±)-CERATOPICANOL / SYNTHESIS OF PROTOILLUDANE-SESQUITERPENENES VIA REARRANGEMENT ROUTES: (±)-CERAPICOL, (±)-STERPURENE AND (±)-CERATOPICANOLEl-Hachach, Nizar 30 October 2002 (has links)
No description available.
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Design und Synthese neuer flüssigkristalliner Substanzen mit zentraler Bicyclo[3.1.0]hexaneinheit / Design and synthesis of novel liquid crystalline substances containing a Bicyclo[3.1.0]hexane core moietyLanger, Rainer 07 May 2003 (has links)
No description available.
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Die Zirconiumalkoxid-katalysierte Aldol-Tishchenko-Reaktion von Keton-Aldolen / The zirconium alkoxide-catalyzed aldol-Tishchenko reaction of ketone aldolsHansch, Markus 27 January 2005 (has links)
No description available.
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Aufbau von Bausteinen zur Synthese von Spinosynanaloga / Development of building blocks for the synthesis of Spinosyn analoguesScheffer, Timo 21 February 2012 (has links)
No description available.
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