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Materials Reliability in PEM Fuel CellsMølmen, Live January 2021 (has links)
As part of the global work towards reducing CO2 emissions, all vehicles needs to be electrified, or fueled by green fuels. Batteries have already revolutionised the car market, but fuel cells are believed to be a key energy conversion system to be able to electrify also heavy duty vehicles. The type of fuel cell commercially available for vehicles today is the polymer electrolyte membrane fuel cell (PEMFC), but for it to be able to take a larger market share, the cost must be reduced while sufficient lifetime is ensured. The PEMFC is a system containing several components, made of different materials including the polymer membrane, noble metal catalyst particles, and metallic bipolar plate. The combination of different materials exposed to elevated temperature, high humidity and low pH make the PEMFC components susceptible to corrosion and degradation. The noble metal catalyst is one of the major contributors to the high cost. In this work, the latest research on new catalyst materials for PEMFCs are overviewed. Furthermore, electrodeposition as a simple synthesis route to test different Pt-alloys for the cathode catalyst in the fuel cell is explored by synthesis of PtNi and PtNiMo. The gas diffusion layer of the PEMFC is used as substrate to reduce the number of steps to form the membrane electrode assembly. In addition to cheaper and more durable materials, understanding of how the materials degrade, and how the degradation affects the other components is crucial to ensure a long lifetime. Finding reliable test methods to validate the lifetime of the final system is necessary to make fuel cell a trusted technology for vehicles, with predictable performance. In this work, commercial flow plates are studied, to see the effect of different load cycles and relative humidities on the corrosion of the plate. Defects originating from production is observed, and the effect of these defects on the corrosion is further analysed. Suggestions are given on how the design and production of bipolar plates should be made to reduce the risk of corrosion in the PEMFC. / Som en del av det globala arbetet med at reducera utsläppen av koldioxid måste alla fordon elektrifieras eller tankas med förnybart bränsle. Batterier har redan revolutionerat bilmarknaden, men bränsleceller är en viktig pusselbit för att också elektrifiera tunga fordon. Den typen av bränsleceller för fordon som finns tillgänglig på den kommersiella marknaden i dag är polymerelektrolytbränslecellen (PEMFC). För att PEMFC skall ta en större marknadsandel måste kostnaderna minskas och livslängden förlängas. PEMFC består av ett antal komponenter gjorda av olika material, bland annat polymer membran, ädelmetallkatalysator, och metalliska bipolära plattor. Kombinationen av olika material i tillägg till den höga temperaturen, hög fuktighet och låg pH gör att materialen i bränslecellen är utsatta för korrosion. Ädelmetallkatalysatorn är en av de kostdrivande komponenterna i bränslecellen. I denna studien presenteras en översikt över framstegen inom katalysatormaterial för PEM bränsleceller de senaste två åren. Sedan studeras elektroplätering som en enkel produktionsmetod för nanopartiklar av platina legeringar. Möjligheten att simultant plätera fler metaller, och att använda gasdiffutions-skiktet från bränslecellen som substrat för att reducera antal produktionsteg och därmed reducera kostnader, undersöks. Det möjliggör också snabb testning av olika legeringar för att identifiera den optimala sammansättningen med hög prestanda, lång livslängd och lite platina. I tillägg till att ta fram billigare och tåliga material är det viktigt att förstå hur materialen degraderar och hur degraderingen av ett material påverkar de andra komponenterna. Med den kunskapen kan man utveckla accelererade testmetoder för att bedöma livslängden av hela bränslecellen. Validerade testmetoder är viktigt för att styrka förtroendet till nya teknologier. I denna studien fokuseras det också på korrosion av bipolära plattor, och hur olika lastcykler och fuktnivåer som kan bli applicerad vid accelererad testning påverkar korrosionen. Också effekten av defekter från tillverkningen i den skyddande beläggningen analyseras med hänsyn till korrosion, för att ge mer insikt i hur bipolära plattor kan designas och produceras för att minska korrosionen.
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Effect on Contact Resistance dueto Cross Connection of MC4 Compatible ConnectorTanguturi, Sai Kishan January 2018 (has links)
Electrical connectors are the blocks that connect solar panels together. Whenever a photovoltaic plant commences, the main discussion goes around on solar panels, inverters, charge controllers, etc. But the topic of connectors is usually hardly discussed. Connectors in a photovoltaic system can definitely contribute to improve the overall performance of the system, provided that importance is given while selecting the connectors. The electrical connectors used in photovoltaic systems can be connected in two possible ways. Connectors can be connected either in a pure-connection or in a cross-connection. Male and female connectors from the same brand results a pure-connection (P-C). Male and female connectors from two different brands results in a cross-connection (C-C). There have been discussions in photovoltaic, electrical connector markets and international solar events regarding the risks involved, losses and consequences due to a cross-connection. The main reason behind cross-connections is the unawareness of the installers in knowing the difference between a pure-connection and a cross-connection. Even though the installers are aware of this difference, they are not aware of the consequences of cross-connections. Multi-Contact, a leading electrical connector manufacturer of MC4 photovoltaic connectors affected by the counterfeit products of MC4, due to the sudden boom in the solar market during 2011-12. With the help of TÜV Rheinland, Multi-Contact conducted couple of tests namely temperature increase test and accelerated stress tests to understand the disadvantages of cross-connections. This thesis tried to replicate the tests performed by Multi-Contact in an attempt to understand the test results by using connectors that are used in the Swedish market. Performing temperature increase test and accelerated stress tests on most commonly used connectors in the Swedish market is the main aim of this thesis. The first test, gives an understanding of the temperature variations across various connector sets (four connector sets from various manufacturers used in this thesis) and the latter tests helps to understand the quality of the contact resistance of these connector sets. The four connector set manufacturers used in this test were Multi-Contact (MC), Weidmüller (WM), Blussun solar (BSS) and PBM. The quality of contact resistance of a connector is directly related to the quality of the connector set. During the 20 minutes of the temperature increase test, the connector set from WM performed better than its competitors in the P-C. Whereas, the MC-BSS connector set had performed well in the C-C. The connector type of male MC and female BSS showed its dominance throughout the test. Unfortunately, no conclusions were able to be drawn from this test results due to insufficient information about the test procedure. From the results of accelerated stress tests, the C-C set from MC outperformed its P-C counterpart. All ten connector sets used in this project passed the standard and qualified as connectors with good quality contact resistance. Therefore the best results out of only a P-C connector set does not seems to be completely true. With the standard used in this thesis, it is quite difficult to judge the quality of connectors. Rather than saying a P-C is superior and a C-C is inferior in terms of quality, there is a need to come up with a new method to evaluate the quality of connectors. Matching the connectors based on their tolerances could be a potential solution to the mismatching problem in connectors.
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