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New corrole–BODIPY conjugates have been synthesized in high yield under mild conditions. Upon excitation at the absorption maximum of the BODIPY antenna chromophore, the fluorescence intensity of the free base corrole–BODIPY conjugate increases by ca. 300%, and significant phosphorescence intensity is observed for the iridium(III) complex of the conjugate, while almost no phosphorescence is observed for the parent iridium(III) corrole, due to through-bond energy transfer from the BODIPY antenna-chromophore to the corrole core. / Original publication is available at http://dx.doi.org/10.1039/c5ra07250f / Arbortext Advanced Print Publisher 9.1.510/W Unicode / Acrobat Distiller 8.1.0 (Windows); modified using iText� 5.3.3 �2000-2012 1T3XT BVBA (AGPL-version)

The problem with which this study is concerned is the investigation of certain selected elements of technological change upon certain selected elements of psychosocial change and the relationship of such changes upon modern man's ability to adjust to these changes. The necessity for psychosocial change and, consequently, adjustment, has risen dramatically in the past few decades as a result of rapid technological and scientific advances for which modern man has been ill-prepared.

Advance Payments of the Share in the Profit of Limited Companies Abstract This thesis deals with advance payments of the share in the profit concerning the limited companies. Its aim is to analyse in more detail this for practice relatively new legal institute, to deal with its relatively brief regulation in the Business Corporations Act, and to offer possible solutions to some still doctrinally unfinished issues. It also attempts to outline the wider context of the current legislation of advances of the share in the profit, especially their historical development, relevant European law and also some foreign legal regulations. The amendment to the Business Corporation Act, which is currently under consideration, is reflected as well. The thesis is divided into four main parts. The first part defines conceptually advances in civil law and advances of the share in the profit. The regulation of advances of the share in the profit and its historical development is introduced, and the possibilities of using this institute are listed. In the second part, the particular conditions for the paying of advances of the share in the profit are analysed in detail. Among other things, the issue of time applicability of the interim financial statements is also examined, together with its possible replacement by an ordinary...

With the increasing popularity of phone application development, a number of features have surfaced that enable users to utilize extended functionalities with their phone. With a single device, a user is now able to have access to the latest trends. As a result, functionalities from various products such as personal computers or GPS devices can now be accessible in one place. While this technology is evolving at a fast rate, it is the embedded technology and hardware that drive it which facilitate the innovative designs and solutions. At the other end of the spectrum of embedded systems, companies continue to maintain legacy products that use embedded chips programmed through their flash memory. With this perceived commitment to stay loyal to their older product designs, it has become rather cumbersome for such companies to stay current with the latest hardware and software trends. The result is higher costs to the customers for their high-end products. While the average user invests in newer and faster Google phones or iPhones, it is unlikely that the same can be said for commercial products such as a refrigerator or a ball machine. What if a development framework existed that allowed customers to have access to better user interfaces and functionalities over the lifetime of their product? In this Masters report, an innovative approach is discussed which demonstrates the latest mobile phone technology combined with an existing embedded device being applied to the conversion of a low-end tennis ball machine into an affordable high-end one. / text

Orientador: Fernando Bastos / Banca: Silvia Luzia Frateschi Trivelato / Banca: Claudio Bertolli Filho / Banca: Ana Maria de Andrade Caldeira / Banca: Roberto Nardi / Resumo: O trabalho corresponde um estudo de caso (Bogdan & Biklen,1994)em que aulas de biologia de uma turma de alunos do 2 º ano do ensino médio foram sistematicamente observadas com o intuito de verificar de que forma surgem e são trabalhadas questões relativas aos avanços recentes em biologia celular e molecular (organismos transgênicos,clonagem,experiências com células tronco,projeto genoma etc.). Atenção especial foi dada às demandas formativas que esse aspecto do ensino de biologia suscita junto aos professores,tanto em nível de aprofundamento de conhecimentos em biologia celular e molecular,quanto em nível de decisões sobre como organizar abordagem e discussão de temas polêmicos e implicações éticas subjacentes.O referencial teórico para o desenvolvimento da pesquisa e análise de dados foi estruturado com base em literatura especializada sobre formação de professores (Schön &Costa,2000; Perrenoud,2000;Zaballa,A.,1998; Carvalho e Gil-Pérez,1995; entre outros). / Abstract: The work corresponds to study of case (Bogdan &Biklen,1994)in which biology classes in group o students from second year in high school were systematically observed on propose to verify how the questions relating to the recent advances in molecular and cellular biology (transgenic organisms,clonating,experiments with stem- cells,genome project,etc.)appear and worked.A special attention was given formative demands that this spect of the teaching in biology rouse among the teachers,both making deeper in the knowledge in molecular and cellular biology and the decisions about how organize the approach and discussion relating to the polemic subjects and ethic implications underlying.The theoretic reference to the development of the research and data analysis was based on specialized literature about teachers graduation (Schön &Costa,2000;Perrenoud,2000;Zaballa,A.,1998;Carvalho e Gil-Pérez,1995; et al.). / Mestre

Technological advances have allowed to collect and store large volumes of data over the years. Besides, it is significant that today's applications have high performance and can analyze these large datasets effectively. Today, it remains a challenge for data mining to make its algorithms and applications equally efficient in the need of increasing data size and dimensionality [1]. To achieve this goal, many applications rely on parallelism, because it is an area that allows the reduction of cost depending on the execution time of the algorithms because it takes advantage of the characteristics of current computer architectures to run several processes concurrently [2]. This paper proposes a parallel version of the FuzzyPred algorithm based on the amount of data that can be processed within each of the processing threads, synchronously and independently.

Yes / This mini-review highlights the latest advances in the chemistry and biology of Pluronic® triblock copolymers. We focus on their applications in medicine, as drug delivery carriers, biological response modifiers, and pharmaceutical ingredients. Examples of drug delivery systems and formulations currently in clinical use, clinical trials or preclinical development are highlighted. We also discuss the role that Pluronic® copolymers may play in the innovative design of new nanomedicines in the near future. / We thank the Leverhulme Trust (Early Career Fellowship no. ECF-2013-414 to NPEB), the University of Warwick (Grant no. RDF 2013-14 to NPEB) and EPSRC (EP/G004897/1 to APB) for support.

Thesis (MAcc)--Stellenbosch University, 2014. / ENGLISH ABSTRACT: Since the recent credit crisis in 2008, innovative lending products have emerged to address the need for enterprises to maintain and improve their cash flows. One such product is the merchant cash advance (MCA). This form of finance is related to debt factoring and is essentially the business equivalent of a payday loan. In its most common form, a lump sum payment is made to a business in exchange for an agreed upon percentage of future credit and/or debit card receivables. A percentage of the merchant’s daily credit or debit card receivables is retained, either directly from the processor that clears and settles the credit or debit card payment or via a debit order from the merchant’s bank account, until the obligation has been met. The future receivables are purchased at a discount and a processing fee is also charged. Many merchant cash advance service providers (MCASP) structure their business in such a way that it resembles traditional debt factoring. In this manner, MCASPs endeavour to distinguish their product offering from traditional loans, in an effort to elude legislation that would affect loans, for example the limiting of interest rates charged. There is however currently a lack of definitive guidance on the taxation consequences from the perspective of the merchant utilising the product and the MCASP providing it. The purpose of this research is to investigate the taxation consequences of MCA transactions in South Africa in an attempt to provide such guidance. The key issue for consideration affecting the taxation consequences of MCAs is the classification of these transactions as either a form of debt factoring or as loans. The research considers and suggests the appropriate classification of these transactions. The taxation treatment is then considered based on this classification from the perspective the merchant utilising the product and the MCASP providing the product. Taxation issues investigated, include the income tax treatment of the discounting cost as “interest”, the availability of deductions allowed by the Income Tax Act and the Value-Added Tax consequences. / AFRIKAANSE OPSOMMING: Sedert die onlangse kredietkrisis in 2008 het innoverende leningsprodukte na vore gekom om te voorsien in die vraag van ondernemings om hul kontantvloei te handhaaf en verbeter. Een van hierdie produkte is die handelaarskontantvoorskot (HKV). Hierdie vorm van finansiering is verwant aan skuldfaktorering en is basies die besigheidsekwivalent van ‘n betaaldaglening. In die mees algemene vorm, word ‘n enkelbdragbetaling aan ‘n besigheid gemaak in ruil vir ‘n voorafbepaalde persentasie van die toekomstige krediet- en/of debietkaartdebiteure. ’n Persentasie van die handelaar se daagliske krediet- of debietkaart debiteure word teruggehou totdat die skuld afgelos is. Invordering vind plaas direk vanaf die verwerker wat die krediet- of debietkaartbetaling goedkeur en betaal, of deur middel van ‘n debietorder direk vanaf die handelaar se bankrekening. Die toekomstige debiteure word teen ‘n diskonto aangekoop en ‘n verwerkingsfooi kan ook gehef word. Baie handelaarskontantvoorskot-diensverskaffers (HKVD) struktureer hul besighede op so ‘n wyse dat dit soos tradisionele skuldfaktorering voorkom. Op hierdie manier beoog HKVD’s om hul produk van tradisionele lenings te onderskei, met die doel om wetgewing vry te spring wat lenings sou beïnvloed, byvoorbeeld beperkings op rentekoerse gehef. Daar is egter tans ‘n tekort aan beslissende leiding, wat die belastinggevolge betref, uit die perspektief van die handelaar wat die produk benut en die HKVD wat dit verskaf. Die doel van hierdie navorsing is om te ondersoek wat die belastinggevolge van HKV’e in Suid-Afrika is in ‘n poging om hierdie leiding te verskaf. Die kernaangeleentheid vir oorweging wat die belastinghantering affekteer, is die klassifisering van HKV-transaksies as ‘n vorm van skuldfaktorering of as lenings. Hierdie navorsing skenk oorweging aan hierdie transaksies en stel ‘n toepaslike klassifikasie voor. Die belastinghantering word dan oorweeg, gebaseer op hierdie klassifikasie uit die perskeptief van die handelaar wat die produk benut en die HKVD wat die produk verskaf. Belastingaangeleenthede wat ondersoek word, sluit die inkomstebelastinghantering van die diskonto gehef as “rente” in, die beskikbaarheid van aftrekkings toegelaat kragtens die Inkomstebelastingwet en die gevolge vir Belasting op Toegevoegde Waarde.