In the light of increasing demand and diminishing supplies a sustainable urban water management for Melbourne and other cities will need to include water recycling and reuse of reclaimed water and stormwater. One key issue in stormwater reuse is the need for storage between times of collection until times of demand. Aquifer storage and recovery (ASR) would be a valuable option as it has limited space requirements and restricts loss from evaporation. However, stormwater commonly contains elevated levels of heavy metals, of which Zn and Cu are the most mobile. Stormwater also contains suspended solids, organic carbon, oxygen and nutrients, which influence the behaviour of injected metals and induce geochemical changes in the aquifer. While stormwater ASR has been practiced in limestone aquifers in South Australia, field data for sandy aquifers, which are more prevalent around Melbourne, are very limited. Risk assessment regarding the potential impact of stormwater ASR on the quality of the aquifer and groundwater resources in sandy aquifer is therefore necessary. After a characterisation of stormwater from different Melbourne catchments confirmed comparatively high concentrations of Zn and Cu in stormwater, three siliceous aquifer sediments were used in a series of batch sorption experiments as well as column experiments imitating one ASR cycle to assess the impact of different parameters on Zn and Cu behaviour. The reactive geochemical transport model PHT3D was then modified to simulate experimental results with the outlook that it could be used as a predictive tool for long term evaluation. The study showed that Zn adsorption was limited and desorption of large fractions occurred, indicating that injected amounts of Zn are mobile and would mainly be recovered. In contrast, Cu adsorption was higher and desorption was limited, indicating that injected amounts of Cu would mainly accumulate in the aquifer. The release of metals was triggered by reduction in pH, increase in ionic strength and particle mobilisation. Metal concentrations were also increased after storage phases, while minor sediment constituents, especially organic matter, significantly reduce metal mobility. The different role of dissolved and solid organic carbon is critical in understanding Cu behaviour during stormwater ASR. Pretreatment of stormwater to reduce the injection of colloids, organic carbon and metals are recommended to limit metal accumulation in the subsurface. Monitoring of water quality throughout the ASR cycle would be encouraged to validate the current findings with field data. Special attention should be paid to backflushed water quality to ensure correct disposal.

Emirate of Abu Dhabi is located in an arid region, where the main source of fresh water is desalination plants. The vulnerability of desalination plants renders planning for an alternative source of freshwater essential. In this study the feasibility of aquifer storage and recovery in the Liwa area, in Emirate of Abu Dhabi, United Arab Emirates was investigated. Based on operational data collected from the pilot project, the model was set up and calibrated. The calibrated model was used to study the affect of various operational parameters, namely storage duration, pumping rate, screen location, multiple cycle operation and periodic recharge, as well as some aquifer characteristics factors: dispersion and salinity profile. This study can be utilized to optimize the operation of the Liwa ASR project. / text

Aquifer storage and recovery (ASR) is a particular scheme of artificial recharge of groundwater by injecting fresh water into aquifers and subsequently recovering the stored water during times of peak demand or extended drought. In the era of combating climate change, ASR, as an effective means for water reuse and sustainable management of water resources in concert with the natural environment, represents a huge opportunity for climate change adaptation to mitigate water availability stress.The success of an ASR scheme is quantified by the recovery efficiency (RE), defined as the volume of stored water that can be recovered for supply purposes divided by the total volume injected. It is not uncommon that RE may be significantly lower than 100% because of the water quality changes as a consequence of the mixing between the injected water and native groundwater and the interaction between injected water and soil. Thus, the key of a successful ASR scheme is (1) to select appropriate aquifers and (2) to design optimal operational processes to build up a bubble of injected water with minimized negative impact from such mixing and interaction. To achieve this, this thesis develops an integrated knowledge base with sound interdisciplinary science and understanding of the mixing processes under operational ASR management in aquifers with various hydrogeological conditions. Analytical and numerical modeling are conducted to improve the scientific understanding of mixing processes involved in ASR schemes and to provide specific technical guidance for improving ASR efficiency under complex hydrogeological conditions. (1) An efficient approach is developed to analytically evaluate solute transport in a horizontal radial flow field with a multistep pumping and examine the ASR performance in homogeneous, isotropic aquifer with advective and dispersive transport processes. (2) Numerical and analytical studies are conducted to investigate the efficiency of an ASR system in dual-domain aquifers with mass transfer limitations under various hydrogeological and operational conditions. Simple and effective relationships between transport parameters and ASR operational parameters are derived to quantify the effectiveness and ascertain the potential of ASR systems with mass transfer limitations.(3) Effects of hydrogeological and operational parameters on ASR efficiency are assessed in homogeneous/stratified, isotropic/anisotropic coastal aquifers. Effects of transverse dispersion are particularly investigated in such aquifers.(4) Finally, we test and study an innovative ASR scheme for improving the RE in brackish aquifers: injection through a fully-penetrated well and recovery through a partially-penetrated well.

Aquifer Storage and Recovery (ASR) involves the injection of water into an aquifer for subsequent recovery from the same well. Whilst ASR provides a competitive alternative to reservoir storage, a lack of precedence of successful schemes and uncertainties with respect to regulatory requirements, and abstracted water quality and quantity have limited its implementation in the UK. The ambition of this research is to improve understanding of these impediments with particular reference to the Sherwood Sandstone aquifer. Drawing on existing project review and risk management approaches, a decision support tool to help scheme designers scope ASR scheme potential and challenges was developed and tested. The tool provides practitioners with a systematic method for early stage evaluation of ASR schemes with testing confirming broad value and alignment with business processes. Limitations on the recovery of recharged water was investigated through a critical literature review on clogging with geochemical, biological, physical and gaseous binding processes identified as the most likely mechanisms to impact an ASR scheme in this aquifer. Water quality changes during storage and the impact of storage period on recovered water quality were investigated in the laboratory using ASR simulating columns, with storage times of 15, 20, 30 and 60 days. Water quality improvements such as biodegradation of disinfection by-products, denitrification and sulphate reduction were observed. However recovered water quality deteriorated with respect to iron, arsenic, manganese, total organic carbon and nickel. These results, together with the review of regulations conducted as part of decision support tool development, suggest that the current interpretation of the Water Framework Directive requirements is overly restrictive and is deterring wider implementation of ASR in the UK. Conclusions focus on the need for a more appropriate approach to regulating ASR schemes, in particular, one which adopts a risk based approach to determining water quality standards.

Aquifer storage and recovery (ASR) involves artificially recharging an aquifer through well(s) using surplus water for later recovery in high-demand months. The operators of the studied ASR system developed the system as a means of receiving additional water rights to supplement their pre-existing water rights for extraction in dry months. However, the region’s water regulators define the performance of this ASR system as the amount of the injected water that is recoverable from the same wells during extraction periods. The study proposes recovery effectiveness (REN) as the performance index of this ASR system. REN equals the injectate proportion that the same wells can recover. Quantifying the system's achievable REN is required to determine the amount of the additional water rights. Similarity between the injected water and native groundwater, however, prevents an accurate REN estimation using on-field techniques. This necessitates the use of computer modeling for estimating REN in this system. The study employs simulation, statistical, and optimization models to quantify and maximize REN in the studied ASR system in Utah.

Lake Okeechobee, the second largest natural freshwater lake in the United States, had experienced a historical drought in 2007-2008 and the inflow to Lake Okeechobee has been reduced by 40% of the average daily mean between warm phase and cold phase due to the impact of Atlantic Multidecadal Oscillation in the past six decades. To cope with this water resources management problem, the US Army Corps of Engineers (USACE) proposed the largest national implementation plan of aquifer storage and recovery (ASR) project in the Kissimmee River Basin. Routine operation of ASR will deliver recovered water from ASR wells into the lake with different water quality parameters resulting in some concerns about the phosphorus stability issues at the sediment bed, which may lead to eutrophication problems. To explore the potential impacts of ASR operation on phosphorus stability in terms of adsorption, desorption, and diffusion processes, this research presented a systematic assessment based on five different mixing ratios between ASR water and lake water, and explored the sensitivity with respect to the chemical equilibrium between lake water and ASR water to predict the phosphorus stability changes in lake sediment. A series of lab-scale batch and column tests in support of a mechanistic modeling analysis provided a holistic chemical assessment as to how the phosphorus stability may be influenced by different mixing ratios. It led to an observation that the ratio of 1:10 between ASR water and lake water proved to be an optical ratio to avoid eutrophication and bring ecological benefits based on a suite of criteria.

In der vorliegenden Dissertation sollten die hydrogeochemischen Prozesse herausgearbeitet werden, die für die Wasserqualitätsänderung während eines ASR Experiments in Bolivar, Südaustralien und während der Versickerung in einem künstlichen Grundwasseranreicherungsbecken in Berlin von Bedeutung waren. Reaktive Stofftransportmodellierung des ASR Experiments in Bolivar, Südaustralien zeigte, dass die hydrochemischen Veränderungen in der direkten Umgebung des Injektionsbrunnens während der Speicherphase nur durch rapide Änderungen der Sauerstoff- und Nitrat reduzierenden Bakterienmasse erklärt werden können. Die hydrochemischen Veränderungen in größerer Distanz zum Injektionsbrunnen wurden überwiegend durch Ionenaustauschprozesse und Kalzitlösung verursacht. Geochemische und hydraulische Messungen unter einem Sickerbecken in Berlin zeigten, dass die beobachteten geochemischen Änderungen im Sickerwasser mit den periodisch auftretenden wassergesättigten/wasserungesättigen Bedingungen unter dem Becken einhergehen. Während der ungesättigten Periode wird Luft unter das Becken gezogen und führt zur plötzlichen Reoxidierung von bereits in der gesättigten Periode gebildeten Eisensulfiden und zur beschleunigten Mineralisation von sedimentärem organischem Kohlenstoff. Reaktive Stofftransportmodellierung auf größerer Skale zeigte, dass allein die saisonalen Temperaturunterschiede im Infiltrationswasser für die beobachtete zeitliche und räumliche Dynamik der Redoxzonen im weiteren Abstrom des Sickerbeckens verantwortlich sind. Das Abbauverhalten der Arzneimittelsubstanz Phenazon hängt ausschließlich von der Verfügbarkeit von gelöstem Sauerstoff und damit indirekt von der Wassertemperatur im Aquifer ab. In der vorliegenden Arbeit wird deutlich, dass ein adäquates Verständnis der wasserqualitätsändernden Prozesse in künstlichen Anreicherungsystemen nur dann erreicht werden kann wenn Strömung, Transport und reaktive Prozesse, im Feld als auch in der Modellierung, simultan betrachtet werden. / In this thesis, three major studies were carried out in order to understand the key factors controlling the water quality changes that occurred during a reclaimed water Aquifer Storage and Recovery (ASR) experiment at Bolivar, South Australia and during ponded infiltration in Berlin, Germany. Multi-component reactive transport modelling of the ASR experiment suggested that during the storage phase, dynamic changes in bacterial mass have a significant influence on the local geochemistry in the vicinity of the injection well. Water quality changes further away from the injection well were mainly driven by ion exchange and calcite dissolution. Geochemical and hydraulic measurements below an artificial recharge pond in Berlin, Germany, showed that the observed dynamic changes of the hydrochemistry within the seepage water are strongly linked to the periodic saturated/unsaturated hydraulic conditions below the pond. During unsaturated conditions, atmospheric oxygen penetrates from the pond margins to the centre below the pond, leading to (i) a sudden re-oxidation of sulphide minerals that have formed previously during saturated conditions and (ii) an enhanced mineralisation of sedimentary particulate organic carbon. Reactive transport modelling showed that at larger scale, seasonal temperature changes of the infiltration water are the key control for the observed temporal and spatial redox dynamics further downstream the recharge pond. Moreover, the degradation behaviour of the pharmaceutically residue phenazone solely depends on the availability of dissolved oxygen, and thus indirectly on the water temperature within the aquifer. Overall this thesis shows that a sound understanding and analysis of the key processes affecting the water quality changes during artificial recharge of groundwater could only be achieved when flow, transport and reactive processes are considered simultaneously, both in the field and during modelling.

No description available.

Ground water resources are heavily used for drinking water supply and often as a receptacle for waste water. One concern is the possible contamination of wetland areas by ground water receiving septic system infiltration. To investigate this, two tracer studies were performed using the bacteriophage PRD-1 by seeding septic systems adjacent to wetlands with the phage and monitoring migration towards wetland areas. Transport velocities were evaluated based on appearance of tracer in sampling wells at various distances from the injection point. Velocities were estimated to be 0.25 m/d and 0.4 m/d at the two sites. Some retardation with respect to the conservative tracer SF6 was observed, with a factor of about 1.5. Due to dry conditions, the water table was well below surface, so transport of the virus into surface water was not observed. Survival of public-health-related microorganisms in ground water is also a concern. The effects of temperature and total dissolved solids (TDS) on survival of 5 groups of indicator organisms were evaluated in controlled experiments. TDS did not have significant effects on inactivation of these microbes up to 1000 mg/l, but there was indication of reduced inactivation of enterococci at TDS concentrations of 3000 mg/l. Increased temperature consistently resulted in more rapid inactivation. Survival in aquifer and reservoir water samples was also evaluated, and significant effects due to water type, temperature, and pasteurization treatment were observed. Inactivation was more rapid in surface water sources, and pasteurization enhanced survival. For enterococci and DNA coliphage, pasteurization effects were more pronounced in surface water. DNA coliphage and perhaps fecal coliform appeared to be the more-conservative indicator organisms for aquifer injection monitoring. Lastly, it was observed that inactivation rates were considerably slower in pore water of saturated limestone than in the bulk water column of similar water sources and conditions, particularly for enterococci and fecal coliform.

The mixing zone developed at freshwater-seawater interface is one of the most important features in complex coastal hydrogeologic systems, which controls subsurface flow and reactive transport dynamics. Freshwater-seawater mixing-zone development is influenced by many physical and chemical processes, such as characteristics of geologic formation, hydrodynamic fluctuations of groundwater and seawater levels, fluid-rock interactions, and others. Wide mixing zones have been found in many coastal aquifers all over the world. However, the mechanisms responsible for wide mixing zones are not well understood. In this thesis, two hypotheses were proposed to explain wide mixing zones in coastal aquifers: (1) kinetic mass transfer coupled with transient conditions, which create the movement of the mixing zone, may widen mixing zones; and (2) aquifer stratification may widen the mixing zone. The hypotheses were tested by both multiscale numerical simulations and laboratory experiments. Numerical simulations were based on a variable-density groundwater model by varying mass transfer parameters, including immobile porosity, mobile porosity, and mass transfer coefficient, and the hydraulic conductivity contrast between aquifer layers. Laboratory experiments were conducted in a quasi-two-dimensional tank, where real beach sands were installed and foodstuff dyes were used to visualize the development of freshwater-seawater mixing zone. Major conclusions included (1) the mixing zone can be significantly widened when the mass transfer timescale and the period of transient boundary is comparable due to the nonequilibrium mass transfer effects; and (2) a thick mixing zone occurs in low-permeability layer when it overlays upon a fast flow layer. These results not only improve the understanding of the dynamics of mixing-zone development and its associated geochemical processes in coastal aquifers, but also identify hydrogeologic conditions for the model of sharp-interface approximation to be valid. In addition to better understanding the mechanisms and dynamics of mixing zone, this thesis also investigates cost-effective management of coastal groundwater resources. To protect and conserve limited water recourses in coastal regions, interest in aquifer storage and recovery (ASR) has been growing in recent years. ASR is a promising strategy for water resources management and has been widely used in many contaminated and saline aquifers. However, its performance may be significantly constrained by mass transfer effects due to the mobilization of solutes initially residing in immobile domains. Better understanding of kinetic mass transfer effects on ASR is needed in order to aid the decision-making process. A numerical model is developed to simulate ASR performance by combining the convergent and divergent dispersion models with a first-order mass transfer model. By analyzing the concentration history at the pumping well, we obtain simple and effective relationships for investigating ASR efficiency under various mass transfer parameters, including capacity ratio and mass transfer timescales, and operational parameters. Based on such relationships, one can conveniently determine whether a site with mass transfer limitations is appropriate or not for ASR and how many ASR cycles are required for achieving a positive recovery efficiency (RE).