Biofuels produced from lignocellulosic biomass via the fermentation platform are sustainable energy alternatives to fossil fuels. Process Systems Engineering (PSE) uses computer-based tools and methods to design, simulate and optimize processes. Application of PSE tools to the design of economic biorefinery processes requires the development of simulation approaches that can be integrated with existing, mature PSE tools used to optimize traditional refineries, such as Aspen Plus. Current unit operation models lack the ability to describe unsteady state fermentation processes, link unsteady state fermentation with in situ separations, and optimize these processes for competing factors (e.g., yield and productivity). This work applies a novel architecture of commercial PSE tools, Aspen Plus and MATLAB, to develop techniques to simulate time-dependent fermentation without and with in situ separations for process design, analyses and optimization of the operating conditions. Traditional batch fermentation simulations with in situ separations decouple these interdependent steps in a separate “steady state” reactor followed by an equilibrium separation of the final fermentation broth. A typical mechanistic system of ordinary differential equations (ODEs) describing a batch fermentation does not fit the standard built-in power law reaction kinetics model in Aspen Plus. To circumvent this challenge, a novel platform that links the batch reactor to a FORTRAN user kinetics subroutine (incorporates the ODEs) combined with component substitution (to simulate non-databank components) is utilized to simulate an unsteady state batch and in situ gas stripping process. The resulting model system predicts the product profile to be sensitive to the gas flow rate unlike previous “steady state” simulations. This demonstrates the importance of linking a time-dependent fermentation model to the fermentation environment for the design and analyses of fermentation processes. A novel platform linking the genetic algorithm multi-objective and single-objective optimizations in MATLAB to the unsteady state batch fermentation simulation in Aspen Plus through a component object module communication platform is utilized to optimize the operating conditions of a typical batch fermentation process. Two major contributions are: prior concentration of sugars from a typical lignocellulosic hydrolysate may be needed and with a higher initial sugar concentration, the fermentation process must be integrated with an in situ separation process to optimize the performance of fermentation processes. With this framework, fermentation experimentalists can use the full suite of PSE tools and methods to integrate biorefineries and refineries and as a decision-support tool to guide the design, analyses and optimization of fermentation-based biorefineries.

Submitted by Jesiel Ferreira Gomes (jesielgomes@ufcg.edu.br) on 2018-04-20T20:53:07Z No. of bitstreams: 1 SHIRLENE KELLY SANTOS CARMO – TESE (PPGEQ) 2015.pdf: 3441674 bytes, checksum: 2a66c0c04d01e56f10189d8b206ebc1c (MD5) / Made available in DSpace on 2018-04-20T20:53:07Z (GMT). No. of bitstreams: 1 SHIRLENE KELLY SANTOS CARMO – TESE (PPGEQ) 2015.pdf: 3441674 bytes, checksum: 2a66c0c04d01e56f10189d8b206ebc1c (MD5) Previous issue date: 2015-02-06 / Capes / Grande parte das indústrias apresenta complexidade no que diz respeito ao seu modo de operação. A fim de reduzir os problemas relacionados ao forte acoplamento existente nesses processos, a busca pela incorporação de dispositivos de inteligência artificial vem apresentando uma tendência crescente nos últimos anos. Devido à complexidade de operação e controle em processos multivariáveis, o diagnóstico e monitoramento de falhas nos processos tornaram-se cada vez mais difícil, com isso a aplicação destes dispositivos tem alcançado resultados satisfatórios em relação aos procedimentos executados com operadores humanos. A análise de componentes independentes (ICA) é uma técnica de separação de sinais que se baseia no uso de estatísticas de ordem superior para estimar cada uma das fontes desconhecidas por meio da observação de diversas misturas geradas a partir destas fontes. Embora sejam encontrados trabalhos recentes sobre a utilização do ICA em processos industriais, apenas dois trabalhos até o presente momento, foram aplicados em processos envolvendo colunas de destilação. O presente trabalho tem como objetivo propor uma estratégia de controle a uma coluna de destilação de alta pureza. A estratégia é baseada na técnica de separação de sinais ICA, tornando as malhas de controle desacopladas e facilitando assim o desempenho do controle. O desempenho do sistema de controle utilizando a técnica apresentou excelentes resultados em relação a uma estrutura convencional sem desacoplamento. As estruturas de controle foram implementadas em ambiente Aspen Plus DynamicsTM e Simulink/ Matlab®. O processo foi estruturado em ambiente Aspen Plus Dynamics™ e os controladores foram implementados no Simulink. / Much of the industry presents complexity with regard to its mode of operation. In order to reduce the problems related to existing strong engagement in these processes, the search for the incorporation of artificial intelligence devices has shown an increasing trend in recent years. Due to the complexity of operation and control in multivariate processes, the diagnosis and fault monitoring in the processes have become increasingly difficult, thus the application of these devices has achieved satisfactory results in relation to procedures performed with human operators. The independent component analysis (ICA) is a signal separation technique that is based on the use of higher order statistics to estimate each of the unknown source by observing various mixtures generated from these sources. Although found recent work on the use of the ICA in industrial processes, only two studies to date, have been applied in cases involving distillation columns. This paper aims to propose a control strategy to a high purity distillation column. The strategy is based on the ICA signal separation technique, making decoupled control loops, thus facilitating control performance. The performance of the control system using the technique showed excellent results compared to a conventional structure without decoupling. The control structures have been implemented in Aspen Plus Dynamics™ and Simulink / Matlab® environment. The process was structured environment Aspen Plus Dynamics™ and the controls were implemented in Simulink.

The change in climate as a consequence of anthropogenic activities is a subject ofmajor concerns. In order to reduce the amount of greenhouse gas emissions inthe atmosphere, the utilization of renewable, fossil-free power generationapplications becomes inevitable. Geothermal and solar energy play a major rolein covering the increased demand for renewable energy sources of today’s andfuture’s society. A special focus hereby lies on the Concentrating Solar Powertechnologies and different geothermal concepts. The costs for producingelectricity through Concentrating Solar Power and therefore Parabolic Trough Collectorsas well as geothermal conversion technologies are still comparatively high. Inorder to minimize these expenses and maximize the cycle’s efficiency, thepossible synergies of a hybridization of these two technologies becomeapparent. This thesis therefore investigates the thermodynamic and economicbenefits and drawbacks of this combination from a global perspective. For that,a Parabolic Trough Collector system is combined with the geothermal conversionconcepts of Direct Steam, Single and Double Flash, Organic Rankine as well asKalina Cycles. The solar integrations under investigation are Superheat,Preheat and Superheat & Reheat of the geothermal fluid. The thermodynamicanalysis focuses on the thermal and utilization efficiencies, as well as therequired Parabolic Trough Collector area. The results indicate that in the caseof the Superheat and Superheat & Reheat setup, the thermal efficiency canbe improved for all geothermal concepts in comparison to their correspondinggeothermal stand-alone case. The Preheat cases, with the major contributionfrom solar energy, are not able to improve the cycle’s thermal efficiencyrelative to the reference setup. From an exergy perspective the findings varysignificantly depending on the applied boundary conditions. Still, almost allcases were able to improve the cycle’s performance compared to the referencecase. For the economic evaluation, the capital investment costs and thelevelized costs of electricity are studied. The capital costs increasesignificantly when adding solar energy to the geothermal cycle. The levelizedelectricity costs could not be lowered for any hybridization case compared tothe reference only-geothermal configurations. The prices vary between20.04 €/MWh and 373.42 €/MWh. When conducting a sensitivity analysison the solar system price and the annual mean irradiance, the Kalina Superheatand Superheat & Reheat, as well as the Organic Rankine Preheathybridizations become cost competitive relative to the reference cases.Concluding, it is important to remark, that even if the hybridization of the ParabolicTrough and the different geothermal concepts makes sense from a thermodynamicperspective, the decisive levelized costs of electricity could not be improved.It is, however, possible that these costs can be further reduced under speciallocal conditions, making the addition of Parabolic Trough solar heat tospecific geothermal concepts favorable.

<p>Biomass liquefaction is a nascent field within biorefinery research and has arisen in response to the bottleneck created from materials handling at the front end of the biorefinery. The basic concept is that if the biomass were to be converted into a flowable slurry at the front-end of the process, then the material could smoothly flow into the biorefinery pretreatment and down time due to the material forming a plug would be minimized or eliminated. Three liquefaction routes were studied in this work. These routes were: enzyme route, enzyme mimetic route, and a combined route of enzyme and enzyme mimetic. Through a Techno-economic assessment (TEA), it is possible to determine which route is most-economical to scale up and also to understand the extent to which liquefaction increases/decreases of the price of the biorefinery product.</p> <p>Gasification is a bio-based technology that has recently acquired more attention as it is an efficient conversion process for a variety of feedstocks. As new techniques and process routes are discovered, it is important to analyze which process technique is feasible for commercial scale up, as the highest performing technique may not be the most economical option to pursue. Along the same philosophy, a process concept was developed on Aspen Plus® to treat syn-gas impurities and also recycle the spent solvents. A TEA study was performed to determine the unit cost of treatment and to explore avenues of cost saving.</p>

This dissertation describes the design and optimization of a CO2-capture unit using aqueous amines to remove of carbon dioxide from the flue gas of a coal-fired power plant. In particular we construct a monolithic model of a carbon capture unit and conduct a rigorous optimization to find the lowest solvent regeneration energy yet reported. Carbon capture is primarily motivated by environmental concerns. The goal of our work is to help make carbon capture and storage (CCS) a more efficient for the sort of universal deployment called for by the Intergovernmental Panel on Climate Change (IPCC) to stabilize anthropomorphic contributions to climate change, though there are commercial applications such as enhanced oil recovery (EOR). We employ the latest simulation tools from Aspen Tech to rigorously model, design, and optimize acid gas systems. We extend this modeling approach to leverage Aspen Plus in the .NET framework through Microsoft's Component Object Model (COM). Our work successfully increases the efficiency of acid gas capture. We report a result optimally implementing multiple energy-saving schemes to reach a thermal regeneration energy of 1.67 GJ/tonne. By contrast, the IPCC had reported that leading technologies range from 2.7 to 3.3 GJ/tonne in 2005. Our work has received significant endorsement for industrial implementation by the senior management from the world's second largest chemical corporation, Sinopec, as being the most efficient technology known today. / Ph. D.

Résumé Les rejets des Usines à Zinc de Kolwezi contiennent majoritairement du zinc sous forme réfractaire (ferrite) au traitement hydrométallurgique conventionnel. Ils contiennent d’autres métaux « lourds » qui les rendent dangereux vis-à-vis de l’environnement dans lequel ils sont actuellement entreposés. Ces métaux, dont la plupart peuvent être valorisés, font de ces rejets un véritable gisement secondaire. Il est donc impératif de mettre au point un procédé adéquat de valorisation ; d’où le thème de la présente thèse : « Etude de valorisation des rejets des Usines à Zinc de Kolwezi, RDC ». A l’aide des techniques modernes de caractérisation (physico–chimique, minéralogique et morphologique), nous sommes arrivés à cibler, à adapter et à justifier l’utilisation d’une technique de valorisation des matières minérales existantes. Les minéraux utiles contenus dans les rejets UZK ont été sulfatés par digestion et sélectivement mis en solution après un grillage. La sulfatation s’est avérée l’étape déterminante du procédé et un intérêt particulier a été focalisé sur cette étape en réalisant une étude cinétique approfondie. Les données et informations récoltées tout le long de cette recherche nous ont permis de réaliser une simulation du procédé par le logiciel ASPEN PLUS. Ce qui a permis de faire une ébauche d’un schéma de traitement industriel. Ce dernier s’est avéré souple vis-à-vis de l’utilisation d’autres matières comme les calcines des concentrés sulfurés cuivre-zinc. Residues from the Kolwezi Zinc Plant (Usines à Zinc de Kolwezi UZK) essentially contain zinc in a refractory (ferrite) form, which is difficult to recover by conventional hydrometallurgical methods. « Heavy» metals are also present that make them hazardous towards the environment in which they are currently stored. Most of these metals are valuable; thus, the UZK residues are a real secondary deposit. It is therefore imperative to develop an appropriate method of treatment, hence the theme of the present thesis: « Recovery study of values metals from Kolwezi Zinc Plant residues, DRC ». Using modern techniques of characterization (physical and chemical, mineralogical and morphological), we focused, adapted and justified the use of a technique for efficient recovery of the existing valuable minerals. The minerals contained in UZK residues have been sulphated by digestion and thereafter selectively dissolved after roasting. Sulphatation proved to be the decisive step of the process and a particular attention has been given to this step by performing a detailed kinetic study. The data and information collected throughout this research allowed a simulation of the developed method by using the « Aspen Plus » software. This allowed us to propose a draft scheme of industrial processing. The latter proved flexible towards the use of other materials such as calcines of copper-zinc sulphide concentrates.

No description available.

Increasing the efficiency of conventional power plants is a crucial aspect in the quest of reducing the energy consumption of the world and to having sustainable energy systems in the future. Thus, within the scope of this thesis the possible efficiency improvements for the Wärtsilä 18V50DF model gas engine based combine power generation options are investigated by recovering waste heat of the engine via Organic Rankine cycle (ORC).  In order to this, four different ORC models are simulated via Aspen Plus software and these models are optimized for different objective functions; power output and price per unit of electricity generation. These ORC models are: regenerative Organic Rankine cycle (RORC), cascaded Organic Rankine cycle with an economizer (CORCE), cascaded Organic Rankine cycle with two heat sources (CORC2) and cascaded Organic Rankine cycle with three heat sources (CORC3). In the cascaded cycle models there are two loops which are coupled with a common heat exchanger that works as a condenser for the high temperature (HT) loop and as a preheater for the low temperature (LT) loop. By using this common heat exchanger, the latent heat of condensation of the HT loop is utilized. The engine’s hot exhaust gases are used as main heat source in all the ORC models. The engine’s jacket water is utilized in the CORC2 models as an additional heat source to preheat the LT working fluid. In the CORC3 models engine’s lubrication oil together with the jacket water are used as additional sources for preheating the LT loop working fluid. Thus, the suitability of utilizing these two waste heat sources is examined. Moreover, thermodynamic and economic analyses are performed for each model and the results are compared to each other. The effect of different working fluids, condenser cooling water temperatures, superheating on cycles performance is also evaluated. The results show that with the same amount of fuel the power output of the engine would be increased 2200 kW in average and this increases the efficiency of the engine by 6.3 %. The highest power outputs are obtained in CORC3 models (around 2750 kW) whereas the lowest are in the RORC models (around 1800 kW). In contrast to the power output results, energetic efficiencies of the RORC models (around 30 %) are the highest and CORC3 models (around 22 %) are the lowest. In terms of exergetic efficiency, the highest efficiencies are obtained in CORC2 (around 64.5 %) models whereas the lowest in the RORC models (around 63 %). All the models are found economically feasible since thermodynamically optimized models pay the investment costs back in average of 2 years whereas the economically optimized ones in 1.7. The selection of the working fluid slightly affects the thermodynamic performance of the system since in all the ORC configurations Octamethyltrisiloxane (MDM) working fluid cycles achieve better thermodynamic performances than Decamethyltetrasiloxane (MD2M) working fluid cycles. However, the choice of working fluid doesn’t affect the costs of the system since both working fluid cycles have similar price per unit of electricity generation. The CORC2 models obtain the shortest payback times whereas the CORC3 models obtain the longest Thus the configuration of the ORC does affect the economic performance. It is observed from the results that increasing the condenser cooling water temperature have negative impact on both thermodynamic and economic performances. Also, thermodynamic performances of the cycles are getting reduced with the increasing degree of superheating thus superheating negatively affects the cycle’s performances. The engine’s jacket water and lubrication oil are found to be sufficient waste heat sources to use in the ORC models.

Les rejets des Usines à Zinc de Kolwezi contiennent majoritairement du zinc sous forme réfractaire (ferrite) au traitement hydrométallurgique conventionnel. Ils contiennent d’autres métaux « lourds » qui les rendent dangereux vis-à-vis de l’environnement dans lequel ils sont actuellement entreposés. Ces métaux, dont la plupart peuvent être valorisés, font de ces rejets un véritable gisement secondaire. Il est donc impératif de mettre au point un procédé adéquat de valorisation ;d’où le thème de la présente thèse :« Etude de valorisation des rejets des Usines à Zinc de Kolwezi, RDC ». <p>A l’aide des techniques modernes de caractérisation (physico–chimique, minéralogique et morphologique), nous sommes arrivés à cibler, à adapter et à justifier l’utilisation d’une technique de valorisation des matières minérales existantes. Les minéraux utiles contenus dans les rejets UZK ont été sulfatés par digestion et sélectivement mis en solution après un grillage. La sulfatation s’est avérée l’étape déterminante du procédé et un intérêt particulier a été focalisé sur cette étape en réalisant une étude cinétique approfondie.<p>Les données et informations récoltées tout le long de cette recherche nous ont permis de réaliser une simulation du procédé par le logiciel ASPEN PLUS. Ce qui a permis de faire une ébauche d’un schéma de traitement industriel. Ce dernier s’est avéré souple vis-à-vis de l’utilisation d’autres matières comme les calcines des concentrés sulfurés cuivre-zinc.<p><p>Residues from the Kolwezi Zinc Plant (Usines à Zinc de Kolwezi UZK) essentially contain zinc in a refractory (ferrite) form, which is difficult to recover by conventional hydrometallurgical methods. « Heavy» metals are also present that make them hazardous towards the environment in which they are currently stored. Most of these metals are valuable; thus, the UZK residues are a real secondary deposit. It is therefore imperative to develop an appropriate method of treatment, hence the theme of the present thesis: « Recovery study of values metals from Kolwezi Zinc Plant residues, DRC ».<p>Using modern techniques of characterization (physical and chemical, mineralogical and morphological), we focused, adapted and justified the use of a technique for efficient recovery of the existing valuable minerals. The minerals contained in UZK residues have been sulphated by digestion and thereafter selectively dissolved after roasting. Sulphatation proved to be the decisive step of the process and a particular attention has been given to this step by performing a detailed kinetic study. <p>The data and information collected throughout this research allowed a simulation of the developed method by using the « Aspen Plus » software. This allowed us to propose a draft scheme of industrial processing. The latter proved flexible towards the use of other materials such as calcines of copper-zinc sulphide concentrates.<p> / Doctorat en Sciences de l'ingénieur / info:eu-repo/semantics/nonPublished