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Thesis (M.S. - Hydrology)--University of Arizona, 1982. / Includes bibliographical references (leaves 46-48).

The accurate estimation of atmospheric water vapour and the subsequent derivation of surface spectral reflectance from hyperspectral VNIR-SWIR remotely sensed data is important for many applications. A number of algorithms have been developed for estimating water vapour content from remotely sensed hyperspectral data that do not require in-situ measurements. Two algorithms, the Continuum Interpolated Band Ratio (CIBR) and the Atmospheric Precorrected Differential Absorption (APDA) have proven to be highly effective at estimating atmospheric water vapour. Although highly successful, the two methods still exhibit unwanted or spurious results when challenging conditions are encountered. Such conditions include the estimation of atmospheric water vapour over dark targets, when uncorrected atmospheric aerosols are present and over surfaces with complex spectral signatures.A differential absorption method called the Transmittance Slope Ratio (TSR) has been developed that negates these problems. The TSR method is comprised of a weighted mean radiance that is defined between two atmospheric water absorption features which is divided by a reference channel radiance to produce a measurable ratio value. This, is turn, may be related to a reference curve, such that, the TSR value may be expressed as an atmospheric water vapour content. To test the TSR method over real terrains, AVIRIS and HyMap measured hyperspectral radiometric data were used. Three test sites were used in total with each site allowing different aspects of the water vapour estimation to be critically examined. The sites are, Jasper Ridge and Moffett Field in California and Brukunga in South Australia.The TSR method is found to significantly improve estimated atmospheric water vapour over dark targets (with less than 3.5 % error for reflectances as low as 0.5 %), improvement over nonlinear surfaces, and finally, ++ / improvement in water vapour estimation when atmospheric aerosol conditions are not well known. In the final case the TSR method is found to estimate atmospheric water vapour with an error of less than 2 % when a 5 km visibility is assumed to be 25 km. The final result is at least an order of magnitude better than the CIBR and APDA methods.

The Global Positioning System (GPS) of navigation satellites was first developed for global navigation and position determination purposes. Signals from satellites are delayed by the Earths neutral atmosphere on propagating to ground-based receivers, termed the tropospheric delay. Although an unwanted term for precise positioning, the tropospheric delay may be converted to atmospheric water vapour, which is a vital parameter for weather forecasting.This research investigates the optimum GPS processing strategy to estimate atmospheric water vapour derived from ground-based GPS receivers particularly in the Australian region. For this purpose, GPS data observations from GPS permanent stations across Australia, mainly from the Australian Regional GPS Network, will be processed using scientific GPS software in post-processed mode and near real-time mode.This research shows that by applying high accuracy GPS data processing, the tropospheric delay could be estimated precisely. The quality of GPS data processing is indicated by the station coordinates repeatability since the coordinates can gauge at least a coarse assessment of the ability of the processing method to estimate the tropospheric delay.The precipitable water can be estimated from the wet component after separating the tropospheric delay into dry and wet components. High accuracy GPS data processing is dependent on the best choice of processing strategies, and the correct application of error-correction models and a priori constraints. This research finds that the GPS- PW estimation agrees with Radiosonde-PW estimation with an average of standard deviation at 2.5mm level for post-processed strategy and 2.8mm for near real-time strategy. The standard deviation of tropospheric parameter estimates is 1.1mm for post-processed strategy and 1.5mm for near real-time strategy.

Water scarcity has caused severe impact on the entire ecosphere while the climate change is resulting in high frequency of extreme weather conditions, especially extended period of drought. Due to the even increasing world’s population and the continued societal modernization, water scarcity is now one of the leading global challenges towards the development of human society. On the other hand, atmospheric water, accounting for 6 times the water in all rivers on Earth, is emerging as an alternative water resource. This dissertation thoroughly investigated the fully solar energy driven atmospheric water harvesting (AWH) process in a broad scientific and application context. The light-to-heat conversion process of solar photothermal materials was investigated first with a rationally designed droplet-laser system, which in combination with the calculation of heat of absorption of water vapor for various application scenarios, formed a theoretical basis of this dissertation research. As a result, a series of commonly used hydrated salts and their anhydrous counterparts were judiciously selected and successfully proven to be low-cost AWH materials to generate clean fresh water for arid regions. A hydrogel-deliquescent salt composite was further developed as AWH material with a significantly enhanced fresh water production capacity. A new design of nano-capsule encapsulated deliquescent salt was further put forward to enhance water vapor sorption/desorption kinetics, which enabled, for the first time, multiple sorption/desorption cycles within one day and thus multiplied water production capacity. The first-ever continuous AWH device, as opposed to batch-type one, was rationally designed, fabricated, and successfully tested in field conditions outdoors. At last, the dissertation pioneered a novel concept of atmospheric water sorption and desorption cycle for photovoltaic (PV) panel cooling. This dissertation shines significant light on sorption based atmospheric water harvesting and inspires more research efforts on this important research topic.

Intermolecular complexes between H₂O and atmospheric species HO, HO₂, H₂O₂, O₃, NO and NO₂ have been studied by ab initio molecular orbital methods. The studies have been performed to the MP2 theory level by using 4-31G, 6-31G, D95, 6-31G**, D95**, 6-311G**, 6-311+G**, 6-311++G**, 6-311+G(2d,lp) and 6-311+G(2d,2p) basis sets. The geometries were fully optimized. The vibrational frequencies were calculated. The Basis Set Superposition Error (BSSE) were estimated. Finally, the binding energies of the complexes were predicted with other thermochemical properties. The binding energies of H₂O•HO, H₂O•HO₂, H₂O•H₂O₂, H₂O•O₃, H₂O•NO and H₂O•NO₂ are estimated to be 5.7±0.6, 8.9±1.0, 7.3±1.3, 1.8±0.2, 1.17 (no BSSE correction) and 2.98 (no BSSE correction) Kcal/Mol, respectively. The Kcq for dimerization to yield H₂O•HO, H₂O•HF, H₂O•HO₂, H₂O•H₂O and H₂O•H₂O₂ are estimated to be 0.11, 2.8, 3.3, 0.067 and 0.11 atm¯¹, respectively. The H₂O•HO, H₂O•HF, H₂O•HO₂, H₂O•H₂O and H₂O•H₂O₂ are quite strongly bonded complexes, while H₂O•O₃, H₂O•NO and H₂O•NO₂ are only weakly bonded complexes. The Kcq changes with temperature are discussed, and their importance in atmospheric chemistry are addressed.

Resumo: A quantificação do vapor d'água integrado na atmosfera (IWV - Integrated Water Vapor), ao contrário de outras variáveis meteorológicas, é algo que ainda se apresenta como um grande desafio para as Ciências Atmosféricas. Diversos mecanismos, envolvendo diferentes técnicas, têm sido empregados e testados para esse fim em diferentes regiões do globo por pesquisa dores das mais variadas áreas da ciência. Essa tese apresenta uma contribuição a esse tema ao empregar receptores GPS (Global Positioning System) em bases terrestres, localizados no Brasil, envolvendo instituições de pesquisa na área de Geodésia e de Meteorologia. Os objetivos principais desse trabalho são validar os valores do IWV obtidos a partir das observações GPS e contribuir com a viabilização da utilização de redes ativas de receptores GPS, existentes atualmente e futuras, no monitoramento do IWV como suporte às atividades da Meteorologia e Climatologia no Brasil. Os resultados obtidos mostram que, com a efetivação desse processo, poderá ser obtida uma fonte adicional de informações da umidade para Previsão Numérica de Tempo (PNT). Além disso, é mostrado também que a alta resolução temporal dos valores do IWV obtidos a partir das observações GPS pode contribuir para a melhoria dos resultados gerados por outras técnicas empregadas na mesma tarefa. Em contrapartida, um modelo de PNT é utilizado para gerar previsões da influência da troposfera nos sinais GPS, visando beneficiar aplicações GPS em tempo real. Os resultados gerados nesse trabalho são frutos da sinergia entre as duas áreas envolvidas e mostram que, atualmente, há boas perspectivas para essa parceria no Brasil. / Abstract: Quantification of Integrated Water Vapor (IWV), unlike other meteorological variables, still represents a significant challenge to the Atmospheric Sciences. In this task several techniques using different mechanisms have been employed and tested in different regions of the planet. Many researchers from several areas of science have been involved in this process. This thesis presents a contribution to this theme, employing ground-based GPS receivers installed on Brazilian territory, involving Geodesy and Meteorology research institutes. The main aim of this work is to contribute in order to make enable the use of the existing networks of continuously operating GPS receivers, and those that will be installed in the future, in IWV monitoring to support meteorological and climatological activities in Brazil. The results generated show that in this process it is possible to obtain an additional source of humidity information for Numerical Weather Prediction (NWP). Furthermore, the prospect of using the ground-based GPS receivers to monitor atmospheric water vapor is promising because thehigh temporal resolution of IWV values from GPS observations can improve the results generated from other techniques employed in the same task. At the same time, a NWP model is applied to generate predictions of the atmosphere's influence over radiofrequency signals, to improve real time GPS applications. The results of this work stem from the synergy between the two areas of science involved. They show that the current outlook for this partnership in Brazil is good, and that both Meteorology and Geodesy will benefit. / Orientador: João Francisco Galera Monico / Coorientador: João Augusto Toledo Machado / Banca: José Antonio Aravequia / Banca: Paul J. de Jonge / Banca: José Tadeu Garcia Tommaselli / Banca: Paulo de Oliveira Camargo / Doutor

abstract: Limited access to clean water due to natural or municipal disasters, drought, or contaminated wells is driving demand for point-of-use and humanitarian drinking water technologies. Atmospheric water capture (AWC) can provide water off the centralized grid by capturing water vapor in ambient air and condensing it to a liquid. The overarching goal of this dissertation was to define geographic and thermodynamic design boundary conditions for AWC and develop nanotechnology-enabled AWC technologies to produce clean drinking water. Widespread application of AWC is currently limited because water production, energy requirement, best technology, and water quality are not parameterized. I developed a geospatial climatic model for classical passive solar desiccant-driven AWC, where water vapor is adsorbed onto a desiccant bed at night, desorbed by solar heat during the day, and condensed. I concluded passive systems can capture 0.25–8 L/m2/day as a function of material properties and climate, and are limited because they only operate one adsorption-desorption-condensation cycle per day. I developed a thermodynamic model for large-scale AWC systems and concluded that the thermodynamic limit for energy to saturate and condense water vapor can vary up to 2-fold as a function of climate and mode of saturation. Thermodynamic and geospatial models indicate opportunity space to develop AWC technologies for arid regions where solar radiation is abundant. I synthesized photothermal desiccants by optimizing surface loading of carbon black nanoparticles on micron-sized silica gel desiccants (CB-SiO2). Surface temperature of CB-SiO2 increased to 60oC under solar radiation and water vapor desorption rate was 4-fold faster than bare silica. CB-SiO2 could operate >10 AWC cycles per day to produce 2.5 L/m2/day at 40% relative humidity, 3-fold more water than a conventional passive system. Models and bench-scale experiments were paired with pilot-scale experiments operating electrical desiccant and compressor dehumidifiers outdoors in a semi-arid climate to benchmark temporal water production, water quality and energy efficiency. Water quality varied temporally, e.g, dissolved organic carbon concentration was 3 – 12 mg/L in the summer and <1 mg/L in the winter. Collected water from desiccant systems met all Environmental Protection Agency standards, while compressor systems may require further purification for metals and turbidity. / Dissertation/Thesis / Doctoral Dissertation Civil, Environmental and Sustainable Engineering 2020

Fresh water collection techniques have gained significant attention due to global dwindling of fresh water resources and recent scares such as the 2011-2017 California drought. This project explores the economic viability of actively harvesting water from fog, and techniques to maximize water collection. Vapor compression and thermoelectric cooling based dehumidifier prototypes are tested in a series of experiments to assess water collection capability in foggy environments, and what parameters can increase that capability. This testing shows an approximate maximum collection rate of 1.25 L/kWh for the vapor compression prototype, and 0.32 L/kWh for the thermoelectric cooling prototype; compared to 315 L/kWh for desalination or 12 L/m2/day for passive meshes. Exploration of parameters on the thermoelectric cooling prototype show a potential increase in water collection rate of 29% with the addition of a Teflon coating to the collection surface, 15% by clearing the collection surface, and 89% by tilting certain collection surfaces by 60-75°. In combination, these parameters could push active atmospheric water harvesting into economic viability where significant infrastructure investment is not feasible.

Made available in DSpace on 2014-06-11T19:31:04Z (GMT). No. of bitstreams: 0 Previous issue date: 2005-12-07Bitstream added on 2014-06-13T20:01:31Z : No. of bitstreams: 1 sapucci_lf_dr_prud.pdf: 3782471 bytes, checksum: af4cccfc2f5cb3b6dd4ba86dfb21c180 (MD5) / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) / Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) / A quantificação do vapor d'água integrado na atmosfera (IWV - Integrated Water Vapor), ao contrário de outras variáveis meteorológicas, é algo que ainda se apresenta como um grande desafio para as Ciências Atmosféricas. Diversos mecanismos, envolvendo diferentes técnicas, têm sido empregados e testados para esse fim em diferentes regiões do globo por pesquisa dores das mais variadas áreas da ciência. Essa tese apresenta uma contribuição a esse tema ao empregar receptores GPS (Global Positioning System) em bases terrestres, localizados no Brasil, envolvendo instituições de pesquisa na área de Geodésia e de Meteorologia. Os objetivos principais desse trabalho são validar os valores do IWV obtidos a partir das observações GPS e contribuir com a viabilização da utilização de redes ativas de receptores GPS, existentes atualmente e futuras, no monitoramento do IWV como suporte às atividades da Meteorologia e Climatologia no Brasil. Os resultados obtidos mostram que, com a efetivação desse processo, poderá ser obtida uma fonte adicional de informações da umidade para Previsão Numérica de Tempo (PNT). Além disso, é mostrado também que a alta resolução temporal dos valores do IWV obtidos a partir das observações GPS pode contribuir para a melhoria dos resultados gerados por outras técnicas empregadas na mesma tarefa. Em contrapartida, um modelo de PNT é utilizado para gerar previsões da influência da troposfera nos sinais GPS, visando beneficiar aplicações GPS em tempo real. Os resultados gerados nesse trabalho são frutos da sinergia entre as duas áreas envolvidas e mostram que, atualmente, há boas perspectivas para essa parceria no Brasil. / Quantification of Integrated Water Vapor (IWV), unlike other meteorological variables, still represents a significant challenge to the Atmospheric Sciences. In this task several techniques using different mechanisms have been employed and tested in different regions of the planet. Many researchers from several areas of science have been involved in this process. This thesis presents a contribution to this theme, employing ground-based GPS receivers installed on Brazilian territory, involving Geodesy and Meteorology research institutes. The main aim of this work is to contribute in order to make enable the use of the existing networks of continuously operating GPS receivers, and those that will be installed in the future, in IWV monitoring to support meteorological and climatological activities in Brazil. The results generated show that in this process it is possible to obtain an additional source of humidity information for Numerical Weather Prediction (NWP). Furthermore, the prospect of using the ground-based GPS receivers to monitor atmospheric water vapor is promising because thehigh temporal resolution of IWV values from GPS observations can improve the results generated from other techniques employed in the same task. At the same time, a NWP model is applied to generate predictions of the atmosphere's influence over radiofrequency signals, to improve real time GPS applications. The results of this work stem from the synergy between the two areas of science involved. They show that the current outlook for this partnership in Brazil is good, and that both Meteorology and Geodesy will benefit.