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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Svařování rámů dveří pekařských pecí / Welding of baker´s furnaces casings

Šurýn, Michal January 2009 (has links)
This thesis made in the frame of my engineer studies is focused on technologic process of welding the door-case of bakery ovens. The project will suggest and rate used based material and then the choice of filler material, methods, welding characteristics and welding procedure. At the conclusion of the thesis is brief economical analysis.
2

Porovnání navařování svazkem elektronů a plazmou / Comparison of cladding by the electron beam and plasma process

Rudyk, Martin January 2014 (has links)
This diploma thesis deals with plasma cladding and electron beam cladding. The theoretical part is divided into several chapters which is focused on description of these methods of cladding process. In the practical part the particular experiment of electron beam cladding (EBC) and plasma cladding (PC) is described. In the conclusion overall results were assessed, both methods were compared each other and possible exploitation in industry was described.
3

La chimie des carbohydrates en milieu aqueux et dans des solvants bio-sourcés : Utilisation du glycosyloxyméthyl furfural (GMF) et analogues dans la réaction de Baylis-Hillman / Carbohydrate chemistry in aqueous and bio-based solvents : Exploring the use of glycosyloxymethyl furfural (GMF) and analogues in the Baylis-Hillman reaction

Tan, Jia-Neng 24 February 2015 (has links)
Cette thèse est une exploration de l’utilisation d’aldéhydes furaniques biosourcés, tels que l’hydroxyméthyl furfural (HMF) et ses analogues, en tant que substrat pour la réaction de Morita-Baylis-Hillman (MBH). L’étendue de la réaction a été étudiée avec un focus sur la possibilité d’utiliser des milieux aqueux et biosourcés pour effectuer cette transformation. En premier lieu, l’étude a concerné la réaction de MBH du glycosyloxyméthylfurfural (GFM) avec des motifs acryliques, conduisant dans des rendements acceptables à de nouveaux glycodérivés porteurs de motifs α-hydroxyacrylates and α-méthylène-β-amino acrylates. Pour les réactions conduisant aux α-hydroxyacrylates, l’eau peut être utilisée comme solvant, de même que des mélanges d’eau et de diméthylisosorbide (DMI), remplaçant ainsi efficacement le dioxane ou le THF comparativement aux méthodes habituellement employées. Les esters acryliques de départ pouvant être eux-mêmes biosourcés, les glycoacrylates obtenus par la réaction MBH sont donc potentiellement 100% biosourcés. La version aza-MBH de la réaction a été ensuite explorée, associant 3 composants: le GMF, une sulfonamide et un accepteur de Micheal, conduisant à de nouveaux α-méthylène-b-amino carbonyl dérivatives construits sur un motif glucidique. L’étude s’est ensuite focalisée sur le HMF lui-même. Plusieurs solvants biosourcés, en particulier le 2-hydroxymethyl THF et l’isopropylidénéglycerol, se sont révélés efficaces pour la réaction de MBH du HMF avec l’acrylate d’éthyle. Pour le HMF et le furfural, la réaction est améliorée si de l’eau est ajoutée; ce qui permet d’étendre la gamme de solvants biosourcés pouvant être utilisée dans ce processus. Il a aussi été montré que l’imidazolyl alcool bicyclique DPI est un catalyseur très efficace pour la réaction MBH du HMF, du furfural ou du GMF avec des énones cycliques, conduisant à une diversité de nouvelles structures par une voie écorespectueuse et efficacement. / This thesis is an exploration of the use of biosourced furanic aldehydes, namely hydroxymethyl furfural (HMF) and analogues, as a substrate for the Morita-Baylis-Hillman (MBH) reaction. The scope of the reaction has been explored, with a focus on the possibility to perform the reaction in aqueous or biobased medium. First, the MBH reaction of the glucosyloxymethylfurfural (GMF) with acrylic building blocks has been explored, led to two new series of glycoderivatives containing α-hydroxyacrylates and α-methylene-β-amino acrylates in fair yields. For the coupling reaction which produces the α-hydroxyacrylates, water can be used as the solvent. Mixtures of water and dimethylisosorbide (DMI) have also been shown to be possibly used in the reactions, allowing replacement of dioxane or THF compared to previous methods. The strategy is atom-economical. Due to the fact that those acrylic esters are also available from biomass, such kind of glycoacrylates appears as possibly 100% bio-based. The aza-MBH version of the reaction was further explored, studying the reaction involving the three components GMF, sulfonamides and a Micheal acceptor, leading to carbohydrate-based α-methylene-β-amino carbonyl derivatives. The focus was then made on HMF itself. Several biobased solvents, in particular 2-hydroxymethyl THF and isopropylideneglycerol, could be used for the MBH reaction of HMF and ethyl acrylate. For HMF and furfural, the reaction was improved when water was added allowing to widen the range of biobased solvent systems. We have also found that the bicyclic imidazolyl alcohol DPI is an efficient catalyst for the aqueous MBH reaction between HMF, furfural, GMF, and cyclic enones that gives access to a variety of potentially very useful molecules in an efficient and environmentally friendly way.
4

Reibdauerbeanspruchte Stahl-Kontakte: Auslegung und Bewertung mittels systemspezifischer Reibkorrosionsfaktoren

Hauschild, Sven 25 June 2020 (has links)
Die Dissertation beschäftigt sich mit der grundlagenorientierten Untersuchung reibdauerbeanspruchter Stahl-Kontakte und deren Festigkeitsbewertung. Die Besonderheit bei der Bewertung reibdauerbeanspruchter Kontakte stellt die zusätzlich zur spannungsmechanischen Beanspruchung vorliegende tribologische Beanspruchung des Werkstoffes dar. Die ursächlich auf eine Anrissinitiierung in der Bauteiloberfläche zurückzuführende niedrigere Ermüdungsfestigkeit reibdauerbeanspruchter Bauteilverbindungen, zeigt sich in Abhängigkeit des Fugendrucks, des Schlupfes und des Werkstoffes. Basierend auf den genannten Einflussgrößen konnte in der vorliegenden Arbeit ein Berechnungsverfahren erarbeitet werden, welches eine betriebssichere Auslegung reibdauerbeanspruchter Fügeverbindungen ermöglicht. Das Verfahren basiert auf dem örtlichen Konzept der FKM-Richtlinie „Rechnerischer Festigkeitsnachweis für Maschinenbauteile“ und implementiert den Schadenfall der Reibdauerermüdung durch einen Oberflächeneinflussfaktor, dem sogenannten Reibkorrosionsfaktor. Die tribologischen Beanspruchungsparameter Schlupf und Fugendruck werden dabei über eine Worst-Case-Betrachtung berücksichtigt. Durch eine von der Zugfestigkeit des Grundwerkstoffes abhängige Darstellung des Reibkorrosionsfaktors, konnte darüber hinaus eine systemspezifische Berechnung der Ermüdungsfestigkeit erreicht werden. Die Validierung des Berechnungsverfahrens erfolgte an einer Pleuelverbindung. / The doctoral thesis investigates basically the fretting fatigue strength of steel contacts and their strength assessment. Especially the tribological loading conditions which are present at the contact surface cause a specific method of the strength assessment of joined contacts. In this context, the lower fatigue strength of component connections under tribological loading conditions, which is the result of crack nucleation at the component surface, depends on the contact pressure, the slip and the basic-material. Based on these parameters, a calculation method was developed in the present study which allows a reliable design of component connections under fretting conditions. This method is based on the local concept of the FKM-guideline 'Rechnerischer Festigkeitsnachweis für Maschinenbauteile' and introduces the fretting fatigue failure mechanism by a surface factor, the so-called fretting factor. These fretting factors are calculated empirically and based on a worst-case approach of the tribological parameters slip and contact pressure. Furthermore it is possible to determine the fretting factor according to the tensile strength of the basic-material. As a result of this, it is possible to calculate the system-specific fretting fatigue strength of joined steel-components. The improved calculation accuracy of the strength assessment was validated on connecting rods.

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