Thèse de doctorat : Chimie : Strasbourg 1 : 2007. / Thèse soutenue sur un ensemble de travaux. Titre provenant de l'écran-titre. Bibliogr. p. 210-232.

Thèse doctorat : Géochimie-Minéralogie : Strasbourg 1 : 2006. / Titre provenant de l'écran-titre. Bibliogr. 21 p.

Tez (Yüksek Lisans) - Süleyman Demirel Üniversitesi, Fen Bilimleri Enstitüsü, Çevre Mühendisliği Anabilim Dalı, 2009. / Kaynakça var.

Liquefaction is a phenomenon that occurs in loose saturated sand deposits that are subjected to earthquake loading. This phenomenon can cause massive displacements and significant destruction. Many methods for mitigating liquefaction have been proposed and investigated including compaction, drainage, and grouting. One such liquefaction mitigation technique involves the addition of bentonite fines to the pore spaces of a loose, saturated sand via permeation of an engineered clay suspension. This method of soil improvement has provided the basis and motivation for this research. Also, the effect of plastic and non-plastic fines on the static and cyclic response of sands is somewhat contradictory throughout the literature. Thus, the primary objective of this study was to characterize the affect of an engineered bentonite pore fluid on the undrained monotonic response of loose, saturated Ottawa sand in order to determine its feasibility for use as an effective method for liquefaction mitigation. The permeation of engineered bentonite suspensions is proposed as a passive site remediation technique. Thus, the suspensions were delivered to loose Ottawa sand specimens in the laboratory by permeation in a newly designed three-way split mold. This split mold was used to create easily tested specimens that would have an initial soil fabric similar to that expected after permeation in the field. The bentonite suspensions were treated with sodium pyrophosphate to reduce the initial yield stress and viscosity in order to allow for permeation. Three different bentonite suspensions were utilized throughout this study each having different properties and delivering slightly different amounts of bentonite to the loose, saturated sand. The affect of this engineered pore fluid on the undrained shear response of loose, saturated Ottawa sand was compared to the undrained shear response of clean sand and dry-mixed sand and bentonite. The specimen preparation method (dry-mixed or permeated) was shown to have a significant effect on the response of the sand specimens. While the dry-mixed specimens produced larger and more sustained positive pore water pressures than the clean sand (resulting in an increased tendency to flow), the permeated specimens showed a marked decrease in the generation of excess pore water pressures, displayed a more dilative response, and thus resulted in a soil structure that was less likely to flow. Finally, the results of tests on specimens permeated with engineered bentonite suspensions show that there is little to no change in the effective friction angle at critical state. A method for effectively testing permeated soil specimens was developed in this study. This method has laid the framework for further investigations into the use of engineered bentonite suspensions for liquefaction mitigation by permeation grouting. / text

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Atomic Energy of Canada Limited’s Underground Research Laboratory was built to allow study of concepts for the long-term disposal of Canada’s used nuclear fuel in a deep geological repository. The underground portion of the facility was decommissioned and permanently closed in 2010. Decommissioning included the installation of a seal at the intersection of the access shaft with a hydraulically active fracture zone located at 275 m depth. The objective of the shaft seal is to limit potential groundwater mixing above and below the fracture zone. This project provided a unique opportunity to study the hydro-mechanical evolution of a full-scale shaft seal installed under conditions similar to those in a deep geological repository. This thesis provides an overview of the instrumentation and data logging techniques that have been successfully used to monitor the initial behaviour of the shaft seal in this unique underground environment.

Atomic Energy of Canada Limited’s Underground Research Laboratory was built to allow study of concepts for the long-term disposal of Canada’s used nuclear fuel in a deep geological repository. The underground portion of the facility was decommissioned and permanently closed in 2010. Decommissioning included the installation of a seal at the intersection of the access shaft with a hydraulically active fracture zone located at 275 m depth. The objective of the shaft seal is to limit potential groundwater mixing above and below the fracture zone. This project provided a unique opportunity to study the hydro-mechanical evolution of a full-scale shaft seal installed under conditions similar to those in a deep geological repository. This thesis provides an overview of the instrumentation and data logging techniques that have been successfully used to monitor the initial behaviour of the shaft seal in this unique underground environment.

Bentonite is a smectite type clay mineral and swells in water. In this thesis, the effect of acetone, methyl-ethyl ketone, n-hexane on the properties of bentonite was determined by thermal analysis and water absorption tests. The tests indicated no significant change with treating bentonite with organic liquids. Because of the swelling property, only small amount of bentonite can be suspended in water. This may limit certain applications of bentonite. In this thesis, feasibility of suspending large quantities of bentonite in a non-aqueous media was studied. The concentrations for a pumpable high solid bentonite slurry were determined. As aqueous slurry showed pumpable properties up to 30-35 pounds/barrel, this concentration was as high as 125-150 pounds/barrel for acetone, 175-200 pounds/barrel for methyl-ethyl ketone and 325-350 pounds/barrel for n-hexane. Bentonite deposite has a complicated composition, containing free silica minerals, such as quartz, cristobalite, and opal / silicate minerals, such as feldspar, mica, and zeolite / carbonates or sulfates of alkaline earth metals, such as calcite, dolomite, and gypsum / and, in addition, iron compounds and humus. As mined it is primarily broken and dried and then pulverized by means of an attrition grinding machine. In this study dispersion of raw bentonite by high shear blending and shaking forces in the presence of acetone, methyl-ethyl ketone and n-hexane and eliminating the non-clay impurities by screening were studied. Many attempts have been made to provide a bentonite composition retaining the full swelling properties of the bentonite by the addition of non-aqueous liquids for obtaining a flexible waterproofing sheet. In this research the possible method for deposition of bentonite in a sponge by saturating the sponge with bentonite using organic liquids was investigated.

Expansion or swelling behavior of expansive soil has always created problems in the field of geotechnical engineering. When any construction has been carried out on expansive soil without pre-knowledge of their properties under various environmental conditions, the damage is severe. One of the methods to find out swelling potential of expansive soil is the expansive index (EI). The present study investigates the reduction of EI for the two commercially available expansive soils i.e., kaolinite and bentonite when mixed with Ottawa sand and Class C fly ash. The percentages of Ottawa sand and Class C fly ash mixed with kaolinite and bentonite were 0 to 50% by weight. The results show that there is a significant reduction in the swelling properties of expansive soil with the addition of Ottawa sand and Class C fly ash. The reduction in expansive index ranged approximately from 10 to 50% and 4 to 49% for kaolinite and bentonite, respectively. Also the maximum swelling pressure of kaolinite and bentonite soil decreased approximately 93% and 64%, respectively with the addition of various percentages of Ottawa sand and Class C fly ash. These results help to identify the swelling potential and swelling pressure of expansive soil with different percentages of sand and fly ash which will be beneficial to the geotechnical engineer. Standard index properties test such as liquid limit, plastic limit and shrinkage limit test was conducted to see the characteristic of expansive soil when mixed with less expansive sand and Class C fly ash. Also, for these expansive soils one dimensional (1-D) consolidation characteristics was studied with sand and Class C fly ash mixtures and the results were compared with pure kaolinite and bentonite soil. Pre-consolidation (Pc) behavior, compression index (Cc) and recompression or swelling index (Cs) properties were also studied for the different percentages of sand and Class C fly ash with expansive soil.