Doctor of Philosophy / Department of Mechanical and Nuclear Engineering / Amy R. Betz / Boiling is a very effective way of heat transfer due to the latent heat of vaporization. Large amount of heat can be removed as bubbles form and leave the heated surface. Boiling heat transfer has lots of applications both in our daily lives and in the industry. The performance of boiling can be described with two important parameters, i.e. the heat transfer coefficient (HTC) and the critical heat flux (CHF). Enhancing the performance of boiling will greatly increase the efficiency of thermal systems, decrease the size of heat exchangers, and improve the safety of thermal facilities. Boiling heat transfer is an extremely complex process. After over a century of research, the mechanism for the HTC and CHF enhancement is still elusive. Previous research has demonstrated that fluid properties, system pressures, surface properties, and heater properties etc. have huge impact on the performance of boiling. Numerous methods, both active and passive, have been developed to enhance boiling heat transfer. In this work, the effect of pressure was investigated on a plain copper substrate from atmospheric pressure to 45 psig. Boiling heat transfer performance enhancement was then investigated on Teflon© coated copper surfaces, and graphene oxide coated copper surfaces under various system pressures. It was found that both HTC and CHF increases with the system pressure on all three types of surfaces. Enhancement of HTC on the Teflon© coated copper surface is contributed by the decrease in wettability. It is also hypothesized that the enhancement in both HTC and CHF on the graphene oxide coated surface is due to pinning from micro and nanostructures in the graphene oxide coating or non-homogeneous wettability. Condensation and freezing experiments were conducted on engineered surfaces in order to further characterize the pinning effect of non-homogeneous wettability and micro/nano structure of the surface.

Orientador: Walace Alves de Oliveira / Dissertação (mestrado) - Universidade Estadual de Campinas, Instituto de Química / Made available in DSpace on 2018-08-26T13:24:33Z (GMT). No. of bitstreams: 1 Lima_JoaquimMatiasBittencourt_M.pdf: 2410483 bytes, checksum: eb7f40c8e6feac1eec3059a9a6ccfb12 (MD5) Previous issue date: 1979 / Resumo: Foi desenvolvido o estudo de um padrão ebuliométrico para solventes não aquosos. Benzila foi escolhido como soluto e benzeno como padrão. Foram medidas as elevações na temperatura de ebulição do benzeno, causadas pela adição de benzila, e os coeficientes osmótico e de atividade puderam ser avaliados. A aparelhagem e o método operacional são descritos. São discutidos os diversos tipos de sensores de temperatura que podem ser utilizados e apresentadas as razões pelas quais foram escolhidos termístores para tal fim. Os termistores foram calibrados, e com base em calibração anterior, foram avaliadas as alterações nas suas características. São propostas equações para que, por método analítico, sejam medidas as elevações de temperatura, o coeficiente de atividade e o coeficiente osmótico. Foi discutido o desvio da idealidade apresentado pelo padrão. É proposto um método comparativo para determinação de constante de equilíbrio, permitindo com que, utilizando o padrão ebuliométrico, fosse determinada a constante de dimerização do ácido benzóico em benzeno, cujo resultado, comparado com dados oriundos da literatura, apresentou boa concordância / Abstract: The behavior of benzil as an ebulliometric standard for non-aqueous solvents was studied. Boiling-temperature elevations due to addition of benzil in benzene were measured and osmotic and activity coefficients were calculated. The apparatus and procedure are discussed. Several types of temperature sensors are mentioned and thermistors were chosen to be used. The thermistors were calibrated and the changes in their parameters were evaluated based on results of previous calibration. Equations are given which permit the calculation of boiling-temperature elevation of benzene solutions as well as osmotic and activity coefficients. The departure from ideal behavior is discussed. A comparative method for the ebulliometric determination of equilibrium constants is proposed. The dimerization constant of benzoic acid in benzene was determined by this method and the results are in good agreement with literature values / Mestrado / Quimica Organica / Mestre em Química

A novel method for measuring heat flux of boiling water is designed and built to study critical heat flux (CHF) and observe the response of a heat flux sensor when CHF occurs. A high temperature heat flux sensor is embedded in the wall of a pipe to get a direct measurement of the surface heat flux and sensor temperature. By submerging the pipe in water and applying a controlled heat flux to the inside diameter over the area where the sensor is located, boiling is created on the outer surface while measuring the heat flux. The heat flux is gradually increased up to CHF and the heat flux response is observed to determine if the heat flux sensor could sense CHF when it occurred. The heat flux sensor is able to consistently measure the value for CHF, which is approximately 510 kW/m" for this system. It is also observed during the experiments that the heat flux response undergoes an inflection of the heat transfer coefficient at a consistent temperature just before reaching CHF. This observed inflection caused the heat flux response to deviate from its cubic relationship with the temperature and drastically increase for a very small change in temperature. This inflection response can be used as an indication for approaching CHF and can also be used to approximate its value without prior knowledge of when it occurs. / Master of Science

<p> Determination of boiling heat transfer rate during liquid jet impingement cooling (LJIC) depends on the intensity of bubble generation that is dependent on many flow and surface conditions such as jet velocity, liquid temperature, and surface superheat. Many empirical correlations have been developed previously to determine the total wall heat flux under various LJIC flow velocity, subcooling and surface superheat. However, only few studies have been able to model the governing heat transfer mechanisms associated with LJIC. In many industrial applications, there is a need to determine the effect of any changes in processing parameters on the total rate of heat transfer. Mechanistic heat transfer models can fulfill such need and allow for efficient model modifications at minimum cost and time.</p> <p> Three models have been developed in this study that address the underlying physics associated with jet impingement heat transfer in both single phase and nucleate boiling regimes. The first model accounts for the effect of bubble generation on the overall heat transfer rate at the jet stagnation by introducing a bubble-induced diffusivity (BID). The BID is added to molecular diffusivities in the momentum and energy Equations. The BID model adopts an analogous approach to the eddy diffusivity concept used in turbulence flow modeling. The BID model has been developed to provide a cost effective simulation tool of boiling heat transfer during LJIC by considering bubble generation effect on the overall heat transfer rate while avoiding the need to simulate extremely small time and length scales associated with phase change.</p> <p> The second model is a scenario identification procedure (SIP) that has been developed to predict the bubble growth termination (BGT) scenario. Considering the effect of jet velocity, water subcooling and surface superheat, the SIP identifies whether a bubble would locally collapse or slide by identifying the most probable equilibrium condition (thermal or dynamic) that the bubble would reach first. The main objective of the SIP is to avoid any inaccurate assumption of the probable BGT scenario. In this case, such procedure could improve the predictions of a more comprehensive wall heat flux model of the areas affected by various heat transfer mechanisms.</p> <p> The third model is a mechanistic wall flux partitioning (WFP) model that has been developed to predict the local wall heat transfer rate over the distance between jet stagnation and ten times the jet width. The WFP model assumes that primary heat transfer is due to sensible heating of liquid by forced convection and transient conduction. The WFP model incorporates a unified single-phase heat transfer model that is capable of capturing the observed secondary peaks downstream of stagnation. The WFP model also incorporates a sub-model that predicts abrupt changes in the liquid film thickness due to the formation of hydraulic jumps.</p> <p> The development of these three models have been carried out using experimental data obtained from a set of experiments that has been conducted to investigate the variation of the heat transfer rate and bubble dynamics under a planar free liquid jet. Investigation of bubble dynamics has been conducted using both intrusive optical probe and non-intrusive high speed imaging of the flow filed. The experiments have been conducted at atmospheric pressure, considering jet velocity of 0.4 to 1.7 m/s, degree of water subcooling of 10 to 28 °C, degree of wall superheat of -25 to 30 °C. Such variations have been studied along a heated surface between stagnation and ten times the jet width. Experiments were conducted using a 1 mm x 8 mm planar jet impinging on a heated horizontal flat copper surface. The distance between the jet and the heated surface was 10 mm. The experimental data have been used to develop a group of sub-models for single-phase heat transfer, bubble diameter, bubble population density, bubble release frequency, and bubble growth time. These sub-models have been used in the closure of the aforementioned models.</p> <p> The three models have been validated using independent experimental data. The BID model is capable of predicting stagnation heat flux within -15% and +30%. The SIP model was able to predict the right bubble growth termination scenario of 80% of the investigated cases. The WFP model is capable of predicting the local total wall heat flux within± 30%.</p> / Thesis / Doctor of Philosophy (PhD)

<p> This investigation is an original study in nucleate pool boiling heat transfer, consisting of two parts: an experimental study and a theoretical study. The experimental study was performed with water boiling at atmospheric pressure on a single copper surface. Two different levels of heat flux were investigated. For the lower level of heat flux (92.21 kW/m2), three different levels of subcooling (0, 6.5, 12°C) were studied and for the higher level of heat flux (192.11 kW/m2), two different levels of subcooling (0, 7.5°C) were studied as well. </p> <p> The cross-spectral density function ·and the crosscorrelation function were used to determine the time elapsed (-r) between the start of bubble growth at two neighbouring active sites with separation (S). The experimental results indicate that for the lower level of heat flux at three different levels of subcooling, the separation (S) and the time elapsed (-r) are related. For the higher level of heat flux at 0°C subcooling it was not possible to detect any correlation, but for the 7.5°C subcooled condition a weak correlation was found to exist. For the lower level of heat flux, all the experimental data for the saturated and subcooled boiling conditions plotted as (S-Rd) versus (T-Tg) drew together into a single curve, indicating that a single relationship could fit all the data. </p> <p> Three different theoretical models were devised in an attempt to·explain the experimental observations. The first model involved heat diffusion in the water; the second model was based upon the disturbance caused by the propagation of a pressure pulse in a mixture of water and vapour and finally the third model involved heat diffusion in the solid. The first two models failed to give satisfactory agreement with the experimental results, but the theoretical predictions corresponding to heat diffusion through the solid gave good agreement with the experimental findings. </p> / Thesis / Doctor of Philosophy (PhD)

<p> An experimental study of temperature profiles in the near vicinity of a horizontal copper surface on which water was boiled is reported in this thesis. A series of three tests is reported for heat fluxes of 20,000, 50,000 and 100,000 BTU/HRFT^2 respectively. Four levels of subcooling were achieved in each series in the range of 0°F < θsub < 105°F. Using the superheat-layer thickness. as defined by Han and Griffith, results are reported indicating an increase in superheatlayer thickness for an increase in the degree of subcooling at a constant heat flux and a reverse effect for an increase in heat flux for a constant degree of subcooling. </p> <p> In addition, five tests are reported in which incipience of boiling was achieved. Using this data, Hsu's mathematical model for predicting bubble nucleation is tested. In general, good agreement is found between the Hsu model and the experimental data. </p> / Thesis / Master of Engineering (MEngr)

An experimental investigation was performed to study the confined boiling heat transfer characteristics over a saturated porous structure using distilled water as the working fluid. A thin stainless steel resistive foil stretched between two copper electrodes was used to heat a saturated porous plate with an effective pore size of 50 gm. The temperature distribution on the foil heater was measured using a high speed thermal imaging camera. The effect of the gap height between the heater and the porous plate on the heat transfer was investigated for gap heights ranging from 0 um to 1000 um and for heat fluxes ranging from 11.7 kW/m2 to 58.3 kW/m2. It was observed that the highest heat transfer rate was obtained at a gap height of approximately 600 pm. The main heat transfer mechanism is thought to be confined boiling in the small gap between the heating surface and the saturated porous structure. It was observed that the effect of the subcooled liquid temperature did not have a significant effect on the heat transfer. The effect of the pore size in the porous plate was investigated by repeating the measurements with a porous plate of 200 gm pore size. It was observed that the thermal resistance for the plate with a 200 gm pore size was significantly higher than the plate with 50 gm pores for gaps less than 300 gm. At a larger gap height of 600 gm, similar heat transfer performances were obtained for the two porous media. / Thesis / Master of Applied Science (MASc)

M.S.

An experimental investigation of the flow boiling of water at atmospheric pressure was undertaken, including a high—speed cine photographic study of the flow structure near the Critical Heat Flux (CHF). Experimental tests from single-phase forced convection to burnout were conducted at different flow velocities and inlet subcoolings for water flowing upwards through a vertical channel of rectangular cross—section electrically heated on one wall with a glass window forming the opposite wall. The test surfaces were stainless steel strips of constant dimensions, except that wall thickness ranged from 0.08 mm to 0.20 mm. Quantitative measurements of the bubble parameters for the same heating surface under the same operating conditions with varying levels of heat flux (70&percnt; to 95&percnt; of CHF) were carried out. A nucleation site deactivation/reactivation process was observed with increasing heat flux. A proposed site deactivation mechanism explained this behaviour. A nucleate boiling heat transfer model was proposed for the fully— developed nucleate boiling region, with allowance made for the overlapping areas of bubble influence. It compared favourably with the experimental data. The effect of wall thickness on CHF was investigated: increases in CHF as between the 0.08 mm and the 0.20 mm wall thickness ranging from 38&percnt; to 57&percnt; were observed. An empirical expression for CHF, including wall thickness as a parameter was developed, correlating the experimental data to within 15&percnt; and indicating a limiting value for wall thickness affecting CHF. The flow regimes near burnout were identified as bubbly and slug, these being independent of wall thickness. Other models proposed for the CHF mechanism were tested against the detailed experimental observations at high subcoolings. They were found to be inconsistent with the experimental evidence. A possible alternative for the CHF mechanism points towards stabilisation/ growth of a vapour patch following bubble coalescence as a most likely cause for burnout.

京都大学 / 0048 / 新制・課程博士 / 博士(工学) / 甲第19994号 / 工博第4238号 / 新制||工||1656(附属図書館) / 33090 / 京都大学大学院工学研究科原子核工学専攻 / (主査)教授 功刀 資彰, 教授 佐々木 隆之, 准教授 横峯 健彦 / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DFAM