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Investigations of the C8S3 J-aggregateWallack, Matthew Niles 28 February 2013 (has links)
This research project entails analyses of both alcoholic route C8S3 J-aggregate bundles and the interactions of a polyethylene glycol additive with alcoholic route C8S3 J-aggregates. First, the C8S3 J-aggregate bundles are characterized by both polarized and non-polarized spectroscopy methods. Orientation of the tubular bundled molecular complex was achieved, depending on the experiment, through a combination of flow cell experiments and cover slip deposited sample analysis. Next, isolated alcoholic route C8S3 J-aggregates were investigated using a polyethylene glycol (PEG) additive which has been shown, through absorbance and fluorescence emission spectroscopy, to selectively and reversibly remove the outer wall of the J-aggregate tubule. Spectroscopic analyses have indicated that the addition of a PEG additive left behind an in-tact inner wall tubule without the use of oxidizing agents, a feat never before accomplished with the C8S3 monomer. / text
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Quantum chemical studies of spectroscopy and electrochemistry of large conjugated molecular systemsCho, Sangik 03 September 2009 (has links)
The molecular identity of the green emission of polyfluorene is investigated in the view point of the molecular interactions between modeled segments. The semi-empirical quantum methods, ZINDO/S and AM1 (AM1-CIS), are used in combination to provide reasonable explanations for experimental spectroscopic properties of monodisperse fluorene oligomers and fluorene oligomers with a central keto defect in dilute solutions. Applying the same method, the molecular interactions between model segments are found to exist and are significant. However, the spectroscopic property change from the molecular interactions is negligible. In addition, the effects of mechanical stress and multi-defects on fluorene oligomers are investigated. On the other hand, the redox mechanisms proposed for the oxidation of an amphiphilic cyanine (C8S3) J-aggregates immobilized at ITO electrode and the subsequent dehydrogenated dimmer formation during cyclic voltammetry based on analysis of absorption spectra during the process are verified with the combined semi-empirical quantum methods similar to the previous methods. The absorption spectra assigned by experiment for electrochemical species involved in the proposed mechanism show reasonable match to the theoretically estimated absorption energies of the corresponding simplified model systems. In addition, the standard reduction potentials of the fairly large molecules, C8S3 monomer and its dehydrogenated dimer, are pursued with quantum mechanical calculations. The free energy difference between the oxidized and reduced states of the target systems is decomposed to electronic energy, solvation energy and temperature-dependent free energies terms. Based on AM1 ground state geometries and with the corresponding temperature dependent free energies, the electronic energies and the solvation energies are each evaluated by two different methods. The electronic energies are calculated with AM1 method and DFT calculation and, also, the solvation energies are obtained based on the atomic partial charges from AM1 and DFT wavefunctions with continuum dielectric solvent approximation. The four calculation schemes from the combinations of the electronic and solvation energy estimation methods are tested with the redox compounds with various molecular weights and the estimations are compared with the corresponding experimental redox potentials. The relative redox potentials between two different redox systems are found to be reasonably estimated with the four calculation schemes. / text
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Structure and optical properties of complex aggregate-structures of amphiphilic dye-systemsAl-Khatib, Omar 18 October 2012 (has links)
In dieser Arbeit werden Untersuchungen an selbstorganisierten, tubulären J-Aggregaten amphiphiler Cyaninfarbstoffe, 3,3’-bis(2-sulfopropyl)-5,5’,6,6’-tetrachloro-1,1’-dioctylbenzimidacarbocyanine, im Weiteren C8S3 genannt, dargestellt. Ziel der Arbeit ist es an die Aggregate eine Lage Polyelektrolyte zu adsorbieren, sowie nachzuweisen, dass diese Methode geeignet ist, um einen Energietransfers zwischen dem Aggregat und funktionellen Gruppen in der Adsorbatschicht zu erreichen. Die tubulären Aggregate sind supramolekulare Strukturen, die sich spontan und selbstorganisiert aufgrund des amphiphilen Charakters der Cyaninfarbstoffe in wässrigen Lösungen bilden. Die Farbstoffe ordnen sich in einer Doppelschicht an, die die Wand der Röhren bildet mit etwa 13 nm Durchmesser und Längen bis zu 1 µm und mehr. Die Aggregate bilden exzitonische Anregungen aus, die sich in einer typischen Rotverschiebung (J-Aggregat) der optischen Absorption sowie einer charakteristischen Aufspaltung in mehrere schmale Banden zeigt. Die negative Oberflächenladung der Aggregate wird genutzt, um positiv geladene Polyelektrolyte (PE) anzulagern. Drei exemplarische PE, die sich in Ladungsdichte und Persistenzlänge unterscheiden, werden untersucht. In allen drei Fällen ist es gelungen Aggregate mit einer 2-3 nm dicken Polyelektrolytschicht zu umhüllen, wobei die molekulare Ordnung der Aggregate nur geringfügig gestört wird. Durch Einsatz von Farbstoffdotierten Polyelektrolyten konnten Experimente zum Nachweis des Förster-Energietransfer durchgeführt werden. Die Farbstoffdotierungen sind kovalent an die PE gebunden, wodurch sie in der PE-Umhüllung lokalisiert sind. Durch Wahl geeigneter Farbstoffe konnte ein Energietransfer vom Farbstoff (Donator) zum Aggregat als auch umgekehrt vom Aggregat zum Farbstoff (Akzeptor) nachgewiesen werden. Es ergeben sich hohe Transferraten, da die Farbstoffe in der PE-Schicht deutlich dichter am Aggregat liegen, als die theoretisch berechneten Förster-Radien. / The following dissertation deals with investigation on tubular J-aggregates of amphiphile cyanine-dyes, 3,3’-bis(2-sulfopropyl)-5,5’,6,6’-tetrachloro-1,1’-dioctylbenzimidacarbocyanine (C8S3). Aim of this work is to adsorb a layer of polyelectrolyte on C8S3-aggregates and to proof the capability of this method to establish an energy-transfer between the aggregate and functional groups in the adsorbate-layer. The tubular aggregates are supramolecular structures, that form entirely spontaneous and self-organized due to amphiphilic character of the investigated cyanine-dye derivative in aqueous solution. These dyes arrange themselves in a double-layer, assembling the hull of the tubular structure, with outer tube-diameters of approximately 13 nm and length of more than 1 µm. Due to the regular and dense arrangement of the dyes excitonic excitation establishs with the structure, that causes a J-aggregate typical red-shift in absorption and a characteristic band-splitting. The aggregates offer a negative surface-charge in aqueous solution. This is utilized to adsorb oppositely charged polyelectrolytes (PE) by electrostatic adsorption. It is shown exemplarily for three different kinds of PE that differ in charge-density and persistence-length. In all three cases a successful PE-wrapping of 2-3 nm thickness has been performed. The molecular order within the aggregates has been disturbed only weakly. Dye-labelled PE experiments proof Förster-energytransfer. The dye-labels are covalently bound to PE, fixing and localizing the labels in the wrapping-layer. With appropriate dye-labels an energy-transfer from labels in the coating (donor) towards the aggregate and vice versa, from aggregate to the dye-labels (acceptor) has been revealed. Caused by the localisation of the labels within the PE-coating, the distances of aggregate and label are always smaller than the theoretically calculated Förster-radii, resulting in a high efficiency of the transfer-rates.
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