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京都大学 / 新制・課程博士 / 博士(エネルギー科学) / 甲第23535号 / エネ博第426号 / 新制||エネ||81(附属図書館) / 京都大学大学院エネルギー科学研究科エネルギー社会・環境科学専攻 / (主査)教授 河本 晴雄, 教授 石原 慶一, 教授 川那辺 洋 / 学位規則第4条第1項該当 / Doctor of Energy Science / Kyoto University / DFAM

This thesis broadly addresses the issue of materials sustainability in the production of Portland cement concrete. Two methods are presented, both aimed at achieving more sustainable concrete through the use of waste and recycled materials. The first method involves utilizing reclaimed asphalt pavement (RAP) as an aggregate in structural concrete, and the second method involves utilizing waste quarry fines as partial replacement of Portland cement in concrete mixes. Many efforts have been made in recent years to justify the use of RAP aggregates in concrete. All previous efforts appear to unanimously report a reduction in concrete performance with varying proportions of RAP usage. The poor performance of RAP aggregates in concrete is attributed mainly to a larger, more porous interfacial transition zone (ITZ) and to the cohesive failure of the asphalt. It is hypothesized that the detrimental impact on the ITZ is attributable to organic compounds leached from the asphalt in the high pH pore solution. This study proves the presence of organic compounds in the pore solution and demonstrates that there is an apparent retardation of cement hydration. This study also attempted to pretreat the RAP in a sodium hydroxide (NaOH) solution to pre-leach the organic compounds. The pretreatment demonstrated that organic compounds were leached and that NaOH modified the asphalt surface chemistry. However, only a marginal improvement in compressive strength was observed by completing the pretreatment. Replacement of Portland cement by filler products is a practice aimed at reducing the carbon footprint of concrete, such as is common with Type IL Portland limestone cement. This study investigates the impact of replacing cement with seven different quarry fines materials. The quarry fines were used to replace cement at 5% to 20% by volume in either cement paste or mortar samples that were then analyzed for various physicochemical properties. It was found that all the quarry fines had detrimental impact on the hydration kinetics of cement pastes. The inclusion of quarry fines was also found to cause varying degrees of reduction in mortar compressive strength. While further analyses of the quarry fines are required, quarry fines 2, 5 and 7 did display encouraging signs to suggest the potential for use as a filler material in blended cements. / Master of Science / This thesis broadly addresses the issue of sustainability in the cement and concrete industry. Sustainability is a significant problem for the cement and concrete industry due to the large amount of carbon emissions produced in the manufacturing process of Portland cement. One method to reduce the carbon footprint of concrete is to use recycled aggregates, and reclaimed asphalt pavement (RAP) is investigated in this thesis as a recycled aggregate option. Previous studies have shown that the use of RAP in concrete results in poor mechanical performance when compared to conventional concrete. In this thesis, the RAP was pretreated by soaking it in sodium hydroxide (NaOH) to see if any improvement is noted. It was determined that the pretreatment resulted in marginal improvements in concrete performance. Another method to reduce the carbon footprint of concrete is through the use of substitutions of Portland cement. In this thesis, quarry fines from around Virginia were investigated for potential as substitutive material. Quarry fines are a by-product from quarrying operations and are often considered a waste material because they have limited applications. This study analyzed the performance of cementitious materials prepared with various substitutive percentages of quarry fines and found that, in general, the inclusion of quarry fines resulted in a decrease of mechanical performance. In total, seven quarry fines were tested and only two showed potential for use as a substitution in Portland cement concrete. These two investigations are essential in reaching the goal of reducing the carbon footprint of the cement and concrete industry.