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The Nanoinjector Lance Array has been developed to inject foreign material into thousands of cells at once using electrophoresis to attract and repel particles to and from the electrically-charged lances. A mathematical computer model simulating the motion of attracted or repelled proteins informs the design of the nanoinjection lance array system. The model is validated by accurately predicting protein velocity in electrophoresis experiments. A complete analysis of parameters is conducted via simulations and specific research questions regarding the counter electrode of the nanoinjector lance array system are explored using the model. A novel technique for fabricating lance arrays from collapsed carbon nanotube forests is explored and detailed. Experiments are conducted using the Nanoinjector Lance Array, attempting to inject three different kinds of protein molecules into a culture of HeLa cells. The experimental results are encouraging and suggest possibilities for future success. Other recommendations are made for future research regarding the model, carbon nanotube fabrication, and experimental testing.

A method is described for ultrasonically spraying thin films of carbon nanotubes that have been suspended in organic solvents. Nanotubes were sonicated in N-Methyl-2-pyrrolidone or N-Cyclohexyl-2-pyrrolidone and then sprayed onto a heated substrate using an ultrasonic spray nozzle. The solvent quickly evaporated, leaving a thin film of randomly oriented nanotubes. Film thickness was controlled by the spray time and ranged between 200-500 nm, with RMS roughness of about 40 nm. Also described is a method for creating thin (300 nm) conductive freestanding nanotube/polymer composite films by infiltrating sprayed nanotube films with polyimide.

As individual health monitors continue to become more widely adopted in helping individuals make informed decisions, new technologies need to be developed to obtain more biometric data. Spectroscopy is a well-known tool to gain biological information. Traditionally spectrometers are large and expensive making personal or wearable health monitors difficult. Here we present the development and characterization of a miniaturized short wavelength infrared spectrometer for wearable applications. We present a carbon nanotube parallel hole collimator can effectively select a narrow set of allowed angles of light to be separated by a linear variable filter and detected at a photodiode array making a spectrometer. We will go over the calibration of the spectrometer showing a resolution of 13 nm at 1300 nm. Improvements on the original collimator data will be discussed, including carbon nanotube growth without infiltration and growth on transparent substrates. We will also show measurements made on human subjects yielding a pulse.

Composite materials are extensively used as an advanced engineering material, particularly in aerospace, automotive, and buildings industries due to its superior properties such as high strength to weight ratios and resistance to corrosion. As composite materials are rapidly replacing traditional materials in aircraft manufacturing, improved methods of identifying damage and critical failure is in development. One of the most commonly used procedures utilizes a health monitoring system that relies on transducers to monitor transmitted waves generated by ultrasonics. By replacing this method with a nanotechnology-based one, it is possible to efficiently detect damage without the time-extensive process of scanning the structure. This research investigated the development of a nanomaterial-based sensor for health monitoring of composite structures. To develop the sensor, carbon nanotube/epoxy mixture (2%wt CNT) was coated on a strand of E-glass fibre to be adhered onto a fiberglass composite specimen. The selection of E-glass fibre and fibreglass plate was largely due to its electrical insulating properties to demonstrate that the carbon nanotube is driving the sensing capabilities through its highly conductive nature. In addition, by adhering the coated E-glass fiber to a fibreglass coupon, the homogeneity and material properties were approximately maintained. Tensile testing of the specimen conducted through a Lloyd LD50 tensile testing machine provided data on the actual strain which was correlated with the experimental differential resistances measured by a multimeter, both at the same specified tensile loading conditions. With two sets of data, the experimental resistance data was calibrated with the actual strain data collected. Ultimately, the experimental sensors created a sample of gauge factors which represents 91.24% probability of replicating the observed range of gauge factors by using the same manufacturing procedures, providing a valid alternative and consistent method to detecting composite damage.

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Carbon nanotube templated microfabrication (CNT-M) is a method that allows high-aspect ratio structures to be made for microelectromechanical systems (MEMS) devices. One concern when making monolithic electrical devices using CNT-M is that the aluminum oxide diffusion barrier will create too large of a resistance in the device. However, in developing CNT based MEMS devices, it has been observed that an electrical DC current is capable of transport from a conductive substrate, across the aluminum oxide, and through to the CNT structure grown on top of it. This thesis attempts to determine the mechanisms responsible for current being able to cross the aluminum oxide diffusion barrier easily through sample characterizations. Principally, current-voltage measurements, electron microscopy, XEDS, and SIMS analysis are used to characterize the various samples and determine the process responsible for the observed phenomenon. Through these techniques, it is determined exposure to ethylene gas during the CNT growth recipe used in our lab, regardless of whether CNTs grow on the sample or not, is necessary to cause a drop in resistance across the aluminum oxide, but the that the overall content of iron and carbon in the aluminum oxide do not correlate with this drop in resistance.