<p> An analysis of reported and theoretical methods of precipitating calcium carbonate from aqueous solution is presented, with emphasis on methods that generate the anion in the presence of Ca(++) ion.</p> <p> A new CaCO3 precipitation method referred to as precipitation from quasi-homogeneous solution and suitable for digital processor control is developed. This technique is then used to investigate the effects of ionic strength and Mg(++) ion on calcium carbonate nucleation.</p> <p> A minicomputer based interactive information system, capable of automatic data logging and processing of experimental results in studies using processor controlled precipitation of CaCO3 from quasi-homogeneous solution, is implemented and tested.</p> / Thesis / Master of Science (MSc)

<p> The McBean Mine is a small gold producer located along the Larder Lake Break. Ore from the open pit consists of massive and gneissic syenite. The highest go I d grades come from highly carbonitized syenitic rocks with abundant fine grained, euhedral pyrite. Petrographic observation shows gold to be found as inclusions in pyrite, platings on pyrite and as free grains in the gangue. XRD analyses show the major carbonate type to be dolomite. In addition to dolomite, minor amounts of calcite are found in auriferous syenitic rocks. SEM microscopy shows carbonate composition to vary with rock types and grain location. Geochemical studies show a high intensity of carbonate alteration and the association of gold with tungsten and uranium. Auriferous syenites were determined to have elevated HREE element abundances compared with unaltered syenite. The mine is therefore characterized by extensive hydrothermal carbonate alteration related to the Larder Lake Break. </p> / Thesis / Bachelor of Science (BSc)

Les nanoparticules ultrafines de carbonate de calcium (NPCC) dont la taille n'excède pas 100 nm peuvent trouver leur utilisation dans un large spectre d'applications. En effet, elles se sont révélées importantes comme additif efficace dans l'industrie papetière et dans l'industrie plastique. Récemment, les NPCC ont ouvert la voie à la libération contrôlée de molécules bioactives. Le développement de NPCC synthétisées spécifiquement pour des besoins particuliers est un nouveau secteur de recherche innovateur qui vient renforcer le domaine déjà attractif des nanotechnologies. L'objectif principal de ce projet de maîtrise est de synthétiser les nanoparticules de carbonate de calcium par différentes méthodes à savoir par précipitation en phase aqueuse, par emulsion simple et par double emulsion. L'effet de paramètres opératoires tels que la vitesse d'agitation, le temps d'agitation, la température et les concentrations en ions calcium et carbonate sur la taille et la morphologie des particules synthétisées a été évaluée. Les particules synthétisées ont été caractérisées par diffraction de rayons X (XRD), microscopie électronique par transmission (TEM) et par analyse thermogravimétrique (TGA). La calcite et l'aragonite sont les principaux polymorphes obtenus tels que révélés par les analyses XRD. L'augmentation du temps d'agitation fait diminuer la taille des particules. L'effet de la vitesse d'agitation se traduit par une diminution de la taille des particules entre 300 et 14000 rpm où la taille minimale est atteinte. Au-delà de cet intervalle, le phénomène d'agrégation produit une augmentation de taille des particules. L'élévation de la température conduit à l'augmentation de la taille des particules par modification de la solubilité de la calcite et l'apparition de l'aragonite à partir de 80°C. Les concentrations des ions calcium et carbonate sont les paramètres clés dans le contrôle de la taille des NPCC à cause du degré de saturation qu'ils apportent en solution. En effet, une augmentation de la concentration d'ions calcium conduit à une diminution de la taille des NPCC alors que le contraire est observé avec celle des ions carbonate.

This thesis describes a sequence of experiments which have been performed with the intention to produce synthetic nacre. Synthetic nacre is a biomimetic material based on nacre, a material which can be found in mollusc shells. Nacre is a nanocomposite which has improved mechanical properties compared to the principal component aragonite (95% wt%). The improved properties of nacre are derived from the polymeric components in the composite which allows from redistribution of forces under load. Carbonates sequester CO2 in the geological CO2-cycle. If precursor are sourced correctly, the CaCO3 in synthetic nacre can temporarily sequester CO2. Crystals with the intended pseudohexagonal morphology have been synthesised. However, subsequent quantitative analysis could not support these findings in a follow-up experiment. This discrepancy might have been caused by differences in the method. Moist nanopaper was found to be mineralisable while maintaining a layered structure.

Shrinking and swelling in Yazoo Clay is a cause of concern for construction projects in Mississippi. This thesis investigated the effects of adding lime and Douglas Fir biochar on the shrinking and swelling capabilities of Yazoo Clay. Samples of Yazoo Clay were mixed with the additives in defined ratios and subjected to the free swell test and the COLE(rod) test. Biochar addition reduced the COLE(rod) of the samples a large amount, while increasing the swelling potential of the clay samples. The addition of lime slightly reduced both the shrinking and swelling potentials of the samples. The mineralogical variability of Yazoo Clay vertically and horizontally could limit the applicability of these results across the formation and is important to be considered before further application. While constrained to one location, this study showed the influence of biochar and lime on the shrinking and swelling capabilities of Yazoo Clay.

Abstract Amorphous Calcium Carbonate (ACC) is a naturally occurring amorphous form of the widely distributed mineral calcium carbonate (CaCO3). ACC has been found increasingly as a precursor phase, calcium storage site, or strengthening structural phase in a wide array of different biomineralizing organisms. An accurate understanding of the widely used classic carbonate-water paleothermometry relies on formation of CaCO3 minerals and associated oxygen isotope effects. Moreover, ACC has oft been pointed to as a possible reason for non-equilibrium isotope effects, also called vital effects, in biogenic carbonates. It is, therefore, vital to understand whether ACC can reach equilibrium with its surrounding solution, as well as the role of ACC precursors in the isotopic composition and evolution of the final crystalline phase they transform into. This study is designed to answer these questions through the precipitation of stable ACC by two methods, the alkaline method (AM) which utilizes high pH to precipitate ACC, and the silica method (SM) which envelopes precipitating ACC particles in silica vesicles to prevent crystallization. These differently precipitated ACCs are then subjected to several different experimental treatments. This is achieved by monitoring the crystallization by X-ray Diffraction (XRD), and isotopic evolution of the ACC precipitates by Isotope Ratio Mass Spectrometry (IRMS) as they age and concurrently crystallize in parent solution, or in 18O enriched re-equilibration solution. This research indicated a marked difference in the crystallization behaviour, isotopic composition, and isotopic evolution of ACC produced by these two precipitation methods. With the AM method, ACC precipitates (AM-ACC) crystallized more predictably to calcite and maintained δ18O signatures that were slightly lower than the equilibrium CO32- and resisted further isotopic exchange with surrounding solution. We propose that the former is mostly due to an incomplete DIC-water oxygen isotope equilibrium prior to the AM-ACC precipitation and the latter is a result of the high pH of the precipitating solution decreasing the solubility of the precipitated ACC phase, disallowing isotope exchange, and favouring crystallization by solid-state transformation. Conversely, while ACC precipitated using the SM (SM-ACC) yielded much more variable results, both in terms of mineralogical identity upon crystallization, and δ18O values. Isotopic results were much closer to the expected equilibrium δ18O value for calcite, hinting at an expedited oxygen isotope exchange between SM-ACC and parent solution. Furthermore, SM-ACC was capable of isotopic exchange with the 18O enriched re-equilibration solution, a feat corresponding AM-ACC was incapable of. Overall, our experimental results gleaned here that precipitation method or precipitation environment play a critical role in the isotopic evolution of precursor ACC to crystalline CaCO3, suggesting ACC as an important source of the vital effect. / Thesis / Master of Science (MSc)

Tinian and Aguijan, Commonwealth of the Northern Mariana Islands (CNMI), are volcanic, back arc islands in the western Pacific formed by Pacific Plate subduction under the Philippine Plate. The islands are composed of Eocene volcanic cores mantled by Plio-Pleistocene carbonate facies and raised Holocene beach and reef deposits. The entire sequence has been tectonically uplifted and contains high-angle normal faults, while isostatic subsidence and scarp failures overprint tectonic brittle failure features. A cave and karst inventory on Tinian and Aguijan surveyed 114 features and is believed to adequately represent the megaporosity (cave) development. Two distinct cave classes were identified: mixing zone caves (flank margin caves and banana holes) and fissure caves. Most mixing zone caves were located in or near scarps and coastlines, often at similar elevations to nearby caves. Fissure caves were located in regions of brittle failure, forming linear features with narrow widths. Three previous sea-level positions were identified based on horizons of mixing zone caves. Seventeen freshwater discharge sites and four allogenic recharge sites were identified on Tinian. Kolmogorov-Smirnov statistical analyses and rose diagram comparisons of orientation trends found significant similarities between megaporosity and geologic structure (brittle failure) on Tinian. Analyses of small regions showed distinct relations between brittle deformation and megaporosity, while at larger scales similarities became less obvious due to the complex geologic history and physiography of the island. Based on similarities in populations of orientation trends, fissure cave development is primarily controlled by brittle failure deformation with development along faults, fractures, and joints, while mixing zone cave development is primarily controlled by fresh-water lens position but significantly influenced by brittle failure deformation. Tinian and Aguijan do not fit neatly into one classification of the Carbonate Island Karst Model. Regions of Tinian best fit the Simple, Carbonate-Cover and Composite Island Karst Models, but none easily fit the entire island. Aguijan must be classified as a Simple Carbonate Island because no geologic data has proved the presence of non-carbonate rocks interfering with the fresh-water lens, however it is probable that Aguijan does contain basement rocks that extend above sea-level as on other carbonate islands in the Marianas.

No description available.

No description available.

No description available.