Carbonate reservoirs may have a variety of porosity types created by depositional, diagenetic, and fracture processes. This leads to the formation of complex pore systems, and in turn creates heterogeneities in reservoir performance and quality. In carbonate reservoirs affected by diagenesis and fracturing, porosity and peremeability can be independent of depositional facies or formation boundaries; consequently, conventional reservoir characterization methods are unreliable for predicting reservoir flow characteristics. This thesis provides an integrated petrographic, stratigraphic, and petrophysical study of the 'Canyon Reef' reservoir, a Pennsylvanian phylloid algal mound complex in the Horseshoe atoll. Core descriptions on three full-diameter cores led to the identification of 5 distinct depositional facies based on fundamental rock properties and biota. Fifty-four thin sections taken from the core were described are pores were classified using the Humbolt modification of the Ahr porosity classification. In order to rank reservoir quality, flow units were established on the basis of combined porosity and permeability values from core analysis. A cut off criterion for porosity and permeability was established to separate good and poor flow units. Ultimately cross sections were created to show the spatial distribution of flow units in the field.

Pore type variations account for complex velocity-porosity relationship and intensive permeability heterogeneity and consequently low oil and gas recovery in carbonate reservoir. However, it is a challenge for geologist and geophysicist to quantitatively estimate the influences of pore type complexity on velocity variation at a given porosity and porosity-permeability relationship. A new rock physics-based integrated approach in this study was proposed to quantitatively characterize the diversity of pore types and its influences on wave propagation in carbonate reservoir. Based on above knowledge, permeability prediction accuracy from petrophysical data can be improved compared to conventional approach. Two carbonate reservoirs with different reservoir features, one is a shallow carbonate reservoir with average high porosity (>10%) and another one is a supper-deep carbonate reservoir with average low porosity (<5%), are used to test the proposed approach. Paleokarst is a major event to complicate carbonate reservoir pore structure. Because of limited data and lack of appropriate study methods, it is a difficulty to characterize subsurface paleokarst 3D distribution and estimate its influences on reservoir heterogeneity. A method by integrated seismic characterization is applied to delineate a complex subsurface paleokarst system in the Upper San Andres Formation, Permian basin, West Texas. Meanwhile, the complex paleokarst system is explained by using a carbonate platform hydrological model, similar to modern marine hydrological environments within carbonate islands. How to evaluate carbonate reservoir permeability heterogeneity from 3D seismic data has been a dream for reservoir geoscientists, which is a key factor to optimize reservoir development strategy and enhance reservoir recovery. A two-step seismic inversions approach by integrating angle-stack seismic data and rock physics model is proposed to characterize pore-types complexity and further to identify the relative high permeability gas-bearing zones in low porosity reservoir (< 5%) using ChangXing super-deep carbonate reservoir as an example. Compared to the conventional permeability calculation method by best-fit function between porosity and permeability, the results in this study demonstrate that gas zones and non-gas zones in low porosity reservoir can be differentiated by using above integrated permeability characterization method.

In this study calcium carbonate (CaCO3) particles are surface modified by using plasma polymerized natural gas and effects of surface modification of CaCO3 filler on mechanical properties of CaCO3-PP composites are investigated. Different combination of plasma factors / RF power, natural gas flow rate, and plasma discharge durations, are investigated. Mechanical properties such as tensile strength and Young&rsquo / s Modulus are measured by tensile testing machine. Storage modulus and loss modulus measurements are done by DMA. Some information about structures generated by natural gas plasma surface modification is obtained by FTIR tests. The tensile fracture surfaces of prepared composites are investigated by using SEM micrographs. It is concluded that, despite some enhancement obtained in the moduli / the technique of natural gas plasma surface modification of CaCO3 particles did not introduce significant improvement in mechanical properties of composite as expected. This result may partially be attributed to selected plasma parameters (i.e., flow rate, RF power, and discharge duration).

This study investigates the depositional history of the Late Eocene sedimentary record in the northwest of the Thrace Basin in a sequence stratigraphic approach and estimates the contribution of regional tectonics, basin physiography and eustasy. Late Eocene sedimentary succession was analyzed in two third-order sequences based on two major data sets / seismic reflection and well data sets. Depositional Sequence-1, represented by progradational stacking patterns, comprises the coarse-grained Hamitabat turbidite system. The base of the Sequence-1 was defined as the base of channel fill deposits in the northern shelf setting and the base of slope fan deposits in the slope setting. This boundary separates Lower-Middle and Upper Eocene sediments. In the slope setting, the Hamitabat turbidite system was analyzed in three major depocenters / Western, Northwestern and Northeastern depocenters respectively. Hamitabat turbidite system was controlled by the interaction of regional tectonics, basin physiography and eustatic fluctuations in the Late Eocene. This study highlighted the role of the regional variables / tectonic influence and basin morphology on the submarine canyon formation. The facies distribution was controlled by the high subsidence rate of sea-floor dominantly instead of eustasy. Depositional Sequence-2, represented by mostly retrogradational stacking patterns, is a clastic-carbonate mixed system. Depositional Sequence-2 was subdivided into three higher-order sequences. The lower sequence boundaries were induced by the rapid relative sea-level rise. The upper boundary of the Depositional Sequence-2 was defined as the termination of clastic-carbonate mixed system and a candidate for the Eocene-Oligocene contact.

The objective of this study is to investigate the effects of titanate coupling agents on low density polyethylene (LDPE) and polypropylene (PP) blends and composites in terms of their mechanical and morphological properties. PP and LDPE composites were produced separately in a Brabender internal mixer, and CaCO3 was used as inorganic filler with compositions of 20, 40 and 60 %. PP/LDPE blends were produced in a twin-screw extruder with ratios of 75/25, 50/50 and 25/75. Their composites were prepared with addition of untreated and titanate-treated CaCO3 at 20% filler content. Titanate coupling agent which is appropriate for LDPE, PP and CaCO3 was used to improve the mechanical properties of the blends and composites. For this purpose, &ldquo / Lica 12&rdquo / which is a kind of neoalkoxy organotitanate was used. Two forms of Lica 12 were used: powder form (Capow L12) and pellet form (Caps L12). Samples with and without titanate were prepared and then they were injection molded to make specimens for tensile and impact tests. Tensile fracture surfaces of samples were examined by scanning electron microscopy (SEM). Their mechanical and morphological properties were compared with each other to determine the effects of Lica 12. This study showed that Capow L12 improved strain at break and impact strength of PP/CaCO3 composites and PP/LDPE blends containing 75% and 50% PP. The strain at break value of of PP75 composite with 20% titanate-treated filler increased significantly up to 509% which is the highest value among all blends and composites in this study. Capow L12 exhibited its functions in PP matrix much more effectively than in LDPE matrix.

The purpose of this study is to investigate the Upper Tournaisian substage within the Carboniferous carbonate deposits of the Aladag Unit in the Hadim region (Central Taurides) based on foraminiferal diversity and to study the meter scale cyclicity in order to explain the sequence stratigraphic evolution of the carbonate succession. In this study, a 27.01 m thick stratigraphic section consisting of limestones and shales was measured and 89 samples, collected along this section, were analyzed. Micropaleontological analyses are based on benthic foraminifera. According to the benthic foraminiferal assemblages, two biozones were identified as Zone Ut1 and Zone Ut2 within the Upper Tournaisian. Zone Ut1 is characterized by a poor foraminiferal assemblage while the Zone Ut2 consists of a diverse Upper Tournaisian foraminiferal fauna. In order to construct a sequence stratigraphic framework and appreciate depositional environmental changes, microfacies studies were carried out. Seven microfacies types were recognized and depending on the stacking patterns of these microfacies types, two fundamental types of cycles, A and B, were identified. Through the measured section, twenty-five shallowing-upward meter scale cycles and two sequence boundaries were determined. Quantitative analysis of benthic foraminifera was used to demonstrate the biological response to cyclicity. Since foraminifers are very sensitive to sea level changes, the abundance of benthic foraminifera displays a good response to sedimentary cyclicity. In order to apply a worldwide sequence stratigraphic correlation, the sequence boundaries and the meter scale cycles of this study were compared with those described in South China and Western European platform and the Moscow Syneclise. An Early Tournaisian transgression was followed by a major fall in relative sea level during the Late Tournaisian. Two sequence boundaries recognized in the measured section correspond to global sea level falls in the Late Tournaisian.

The application of carbon-dioxide injection for enhanced oil recovery and/or sequestration purposes has gained impetus in the last decade. It is known that well test analysis plays a crucial role on getting information about reservoir properties, boundary conditions, etc. Although there are some studies related to the well test analysis in the fractured reservoirs, most of them are not focused on the carbon dioxide injection into the reservoir. Naturally fractured reservoirs (NFR) represent an important percentage of the worldwide hydrocarbon reserves and current production. Reservoir simulation is a fundamental technique in characterizing this type of reservoirs. Fracture properties are often not clear due to difficulty to characterize the fracture systems. On the other hand, well test analysis is a well known and widely applied reservoir characterization technique. Well testing in NFR provides two significant characteristic parameters, storativity ratio (&omega / ) and interporosity flow coefficient (&lambda / ). The storativity ratio is related to fracture porosity. The interporosity flow coefficient can be linked to the shape factor which is a function of fracture spacing. In this study, the effects of fracture and fluid flow factors (geometry, orientation and flow properties) on pressure and pressure derivative behavior are studied by applying a reservoir simulation model. Model is utilized mainly for the observation of multiphase flow effects in CO2 flooded fractured reservoirs. Several runs are conducted for various ranges of the aforementioned properties in the CO2 flooded reservoir. Results of well test analysis are compared to the input data of simulation models on a parameter basis.

Carbon nanotubes (CNTs), allotropes of carbon with a cylindrical nanostructure, are one of the most attractive research subjects for scientists and industry because of their extraordinary chemical, electrical, optical, mechanical and thermal properties, and their wide range of potential application areas. Mainly, there are two types of carbon nanotubes: single-walled carbon nanotubes (SWNTs) and multi-walled carbon nanotubes (MWNTs). The most commonly used methods for carbon nanotube production are arc discharge, laser ablation, and chemical vapor deposition (CVD). In the CVD method, CNTs are produced from thermal decomposition of the carbon-containing molecules on a suitable transition metal catalyst. CVD method enables large scale production of high-quality CNTs with low cost compared to other methods. The growth and morphology of CNTs can be controlled by adjusting the reaction parameters. In this study, Co and Mo impregnated CaCO3 catalysts were synthesized at different Co:Mo weight ratios and calcined at different temperatures. XRD results showed that there was mainly CaCO3 compound in the catalysts calcined at 500&ordm / C whereas the catalysts calcined at 700 and 750 &ordm / C were mainly composed of CaO and Ca(OH)2 compounds. In addition to these, CaMoO4, CoO, CoMoO4 and Mo2C were the other solid phases mainly observed in all catalysts. The production of CNTs was performed by chemical vapor deposition of acetylene at a temperature range of 500-700

As high grade iron ore deposits are rapidly depleted, the minerals industry is increasingly obliged to enrich their ores and process lower grade iron ores. Production of large quantities of fine ores as tailings or by-products in mining operations and mineral liberation at fine particle sizes have led to the development of concentration methods employed to fine ores. Selective flocculation is one of the beneficial methods which can be used in recovering of very fine particles It is obvious that process water chemistry has a significant influence on the flocculation efficiency, and the water chemistry is deeply affected by carbon dioxide dissolution. Carbonate content of natural waters regulated by CO2, carbonicacid and solid carbonatesis known as &lsquo / carbonate alkalinity&rsquo / whichmay be an important factor in flocculation especially at alkaline pH. Selective flocculation of iron ores is usually run at around pH 11 where carbonate alkalinity could be rather high. There have been no reports in literature regarding the effect of carbonate alkalinity on the flocculation behavior of iron oxides, mainly hematite. In this study, the flocculation behavior of iron ores with starch under different alkalinities has been investigated. The extent of flocculation has been assessed by settling rate and suspended solid content measurements at different starch doses and pH values. Zeta potential measurements and starch adsorption studies were carried out to explain these effects by carbonate alkalinity. According to the results, flocculation is enhanced by addition of low amount of carbonate alkalinity, less than 2.4 mEq/L. However, adding the higher amount of alkalinity adversely affected the flocculation of hematite. Similar behavior was also observed during the starch adsorption tests, larger amount of starch wasadsorbed by hematite in low alkalinity compared to high alkalinity. Zeta potential measurements indicate that, by increasing the carbonate alkalinity of suspension, zeta potential values of solids will become more negativeleading to an increase in the stability of suspension and then adversely affecting flocculation. Therefore, as carbonate alkalinity has a significant effect on the flocculation of hematite, it should be seriously taken into account to optimize the selective flocculation of hematite ores.

Cyanide-catalyzed aldimine coupling was employed to synthesize compounds with 1,2-ene-diamine and α-imine-amine structural motifs: 1,2,N,N'- tetraphenyletheylene-1,2-diamine (13) and (+/-)-2,3-di-(2-hydroxyphenyl)-1,2- dihydroquinoxaline (17), respectively. Single crystal X-ray diffraction provided solidstate structures and density functional theory calculations were used to probe isomeric preferences within this and the related hydroxy-ketone/ene-diol system. The enediamine and imine-amine core structures were calculated to be essentially identical in energy. However, additional effects-such as π conjugation-in 13 render an enediamine structure that is slightly more stable than the imine-amine tautomer (14). In contrast, the intramolecular hydrogen bonding present in 17 significantly favors the imine-amine isomer over the ene-diamine tautomer (18). Aldimine coupling (AIC) is the nitrogen analogue of the benzoin condensation and has been applied to dialdimines, providing the first examples of cyclizations effected by cyanide-catalyzed AIC. Sodium cyanide promoted the facile, intramolecular cyclization of several dialdimines in N,N-dimethylformamide, methanol, or dichloromethane/water (phase-transfer conditions) yielding a variety of six-membered heterocycles. Under aerobic conditions, an oxidative cyclization occurs to provide the diimine heterocycle. Cyanide-catalyzed aldimine coupling was employed as a new synthetic method for oligomerization. Nine rigidly spaced dialdimines were oxidatively coupled under aerobic conditions to yield conjugated oligoketimines and polyketimines with unprecedented structure and molecular weight (DP = 2 - 23, ~700 -8200 g/mol). The α- diimine linkage was established based on IR spectroscopy, NMR spectroscopy, size exclusion chromatography, and X-ray crystallographic characterization of the model oxidized dimer of N-benzylidene-(p-phenoxy)-aniline. Cyclic voltammetry indicates ptype electrical conductivity, suggesting they are promising candidates for plastic electronic devices. The cyanide-catalyzed benzoin condensation reaction of 4-substituted benzaldehydes followed by oxidation to the diketone, and the Schiff Base condensation of two equivalents of o-aminophenol provides 2,3-(4-X-phenyl)2-1,4-(2- hydroxyphenyl)2-1,4-diazabutadiene. The ligand is given the moniker X-dabphol. These ligands are readily metallated to form M-X-dabphol complexes. The copper complexes catalytically fix CO2 with propylene oxide to yield propylene carbonate. DFT studies along with a comparison with Hammet parameters help validate and elaborate on the catalytic cycle and the catalytic results obtained. The nickel complex is competent for olefin epoxidation. Synthesis, characterization, X-ray structure, DFT analysis, and catalytic activity of the parent nickel dabphol complex are reported.