The ceramic composite system containing Al₂O₃ and SiCw has seen multiple uses depending on its processing method. Both the thermomechanical properties and the electrical properties have piqued the interest for potential commercial applications. These include cutting tool inserts and microwave heating elements. Composite samples made by extrusion were pressureless sintered and characterized as a function of frequency, bias, sample length, and whisker orientation. Dry pressed percolated specimens containing different amounts of sintering aids were hot pressed and spark plasma sintered. The microstructure and electrical properties were compared.

No description available.

This thesis deals with the investigations on the nonlinear electrical and manganetotransport properties of polycrystalline multi-phase ceramic composites of Zno/pervoskite manganite. Multifunctional properties are studied such as the enhanced low-field magnetoresistance(LFMR). magnetically tuneable low-voltage nonlinear current-voltage (I-V) characteristics with larger nonlinearity coefficients suitable for semiconducting and magnetoelectric devices. A brief introduction on the structure-property correlations, electronic and magnetic structures, nonlinear electrical conduction, phase separation, grain size and grain boundary effects on transport properties of manganites are presented. The nonlinear current-voltage characteristics of ZnO based varistors are also summarized. The thesis describes the synthesis of the ceramics and the methodology of different techniques utilized in characterizing the samples. The phase conversions in calcium manganite with changing Ca/Mn ratios as well as the oxygen non-stoichiometry and their influence on electrical transport properties were studied. The realization of low-voltage varistors prepared from ZnO+ CaMnO3 ceramic composites was described. An energy band model consisting of n-p-n heterojunctions of n-ZnO1-γ:Mn/p-CMZO/n-ZnO1 γ:Mn has been proposed in order to explain the large nonlinearity coefficients obtained at low field-strengths of 1.8 to 12 V/mm. The detailed investigationos on the structural identification and physico-chemical analyses of Ca4Mn7Zn3O21-δ(CMZO) phases having the beta-alumina or magnetoplumbite-type structures were carried out. The thesis also embodies the magnetically tuneable nonlinear I-V characteristics and the magnetotransport properties of ZnO/La(Sr)MnO3 and ZnO/La(Ca,Sr)MnO3 ceramic composites. The present investigations demonstrate that the ferromagnetic insulating (FMI) La06 Sr04Mn1-yZnyO3(y = 3 to 8 at.%) when present as minor phase in ZnO1- γ:Mn ceramics enables in attaining magnetically tunealbe nonlinear I-V characteristics. Wherein, the dominant ZnO1- γ:Mn phase remains paramagnetic. The results also indicate that the prevalence of ferromagnetism in ZnO1-γ:Mn is not significant for realizing magnetically tuneable I-V curves. The controversial results related to the existence of ferromagnetism in ZnO(doped)leading to diluted magnetic semiconductors(DMS) have been investigated. Another novel aspect of the present work is the low-field magnetoresistive(LFMR) property of ZnO/La(Sr)MnO3 and ZnO/La(Ca.Sr)MnO3 ceramic composites which been explained on the basis of spin-polarised tunneling across the intergrain regions. The influence of Zn2+ as a diamagnetic substitutent in modifying the crystallographic phase content, electrical transport and magnetic properties of Lao6Sro4MnO3 were studied in detail. The results point towards the fact the large decrease of Tc and Ms at lower Zn contents(≤ 8 at.%)is due to the dominant role played by the excess oxygen vacancy (Vo) as an electron donor in p-type Lao6Sro4Mn1-yZnyO3-δ rather than the charge compensatively predictable values. The modifications of electronic and magnetotransport properties were carried out on Lao6Sro4MnO3 substituted with diamagnetic ions such as Mg2+ - Al3+ - Ti4+ - Nb5+ - Mo6+ or W6+ at Mn-sublattice. The TEM studies including HREM results point to the fact the large ΔT(= Tc-TM-1)is accountable in terms of charge conduction within the electronically heterogeneous phase mixtures of charge ordered insulating (CO1) bi-stripes prevailing within the charge disordered FMI phases.

Tendo como vantagem a elevada resistência ao choque térmico da zircônia:magnésia e a alta condutividade iônica da zircônia:ítria, compósitos dessas cerâmicas foram preparados por meio da mistura, em diferentes concentrações, de eletrólitos sólidos de ZrO2: 8,6 mol% MgO e de ZrO2: 3 mol% Y2O3, compactação e sinterização. A caracterização microestrutural foi feita por meio de difração de raios X e microscopia eletrônica de varredura. A análise do comportamento térmico foi feita por dilatometria. As propriedades elétricas foram estudadas por meio de espectroscopia de impedância. Foi feita uma montagem experimental para monitorar a resposta elétrica gerada em função do teor de oxigênio a altas temperaturas. Os principais resultados mostram que os compósitos cerâmicos são parcialmente estabilizados nas fases monoclínica, cúbica e tetragonal, e apresentam comportamento térmico similar ao apresentado por eletrólitos sólidos de zircônia:magnésia de dispositivos sensores de oxigênio. Além disso, os resultados de análise de espectroscopia de impedância mostram que a adição da zircônia:ítria melhora o comportamento elétrico da zircônia:magnésia, e que resposta elétrica gerada é dependente do teor de oxigênio a 1000 °C, mostrando ser possível construir sensores de oxigênio utilizando compósitos cerâmicos. / Taking advantage of the high thermal shock resistance of zirconia-magnesia ceramics and the high oxide ion conductivity of zirconia-yttria ceramics, composites of these ceramics were prepared by mixing, pressing and sintering different relative concentrations of ZrO2: 8.6 mol% MgO and ZrO2: 3mol% Y2O3 solid electrolytes. Microstructural analysis of the composites was carried out by X-ray diffraction and scanning electron microscopy analyses. The thermal behavior was studied by dilatometric analysis. The electrical behavior was evaluated by the impedance spectroscopy technique. An experimental setup was designed for measurement the electrical signal generated as a function of the amount of oxygen at high temperatures. The main results show that these composites are partially stabilized (monoclinic, cubic and tetragonal) and the thermal behavior is similar to that of ZrO2: 8.6 mol% MgO materials used in disposable high temperature oxygen sensors. Moreover, the results of analysis of impedance spectroscopy show that the electrical conductivity of zirconia:magnesia is improved with zirconia-yttria addition and that the electrical signal depends on the amount of oxygen at 1000 °C, showing that the ceramic composites can be used in oxygen sensors.

This research provides a comprehensive investigation in understanding the effect of the addition of graphene nano-platelets (GNP) on the mechanical, tribological and biological properties of glass/ceramic composites. We investigated two kinds of materials namely amorphous matrices like glasses (silica, bioglass) and polycrystalline matrices like ceramics (alumina). The idea was to understand the effect of GNP on these matrices as GNP was expected to behave differently in these composites. Bioglass (BG) was also chosen as a matrix material to prepare BG-GNP composites. GNP can improve the electrical conductivity of BG which can be used further for bone tissue engineering applications. The effect of GNP on both electrical conductivity and bio-activity of BG-GNP composites was investigated in detail. There were three main problems for fabricating these novel nano-composites: 1) Production of good quality graphene; 2) Homogeneous dispersion of graphene in a glass/ceramic matrix and; 3) Retention of the graphitic structure during high temperature processing. The first problem was solved by synthesising GNP using liquid phase exfoliation method instead of using a commercially available GNP. The prepared GNP were ~1 μm in length with a thickness of 3-4 layers confirmed using transmission electron microscopy. In order to solve the second problem various processing techniques were used including powder and colloidal processing routes along with different solvents. Processing parameters were optimised to fabricate glass/ceramic-GNP composite powders. Finally in order to avoid thermal degradation of the GNP during high temperature processing composites were sintered using spark plasma sintering (SPS) technique. Fully dense composites were obtained without damaging GNP during the sintering process also confirmed via Raman spectroscopy. Finally the prepared composites were characterised for mechanical, tribological and biological applications. Interestingly fracture toughness and wear resistance of the silica nano-composites increased with increasing concentration of GNP in the glass matrix. There was an improvement of ~45% in the fracture toughness and ~550% in the wear resistance of silica-GNP composites with the addition of 5 vol% GNP. GNP was found to be aligned in a direction perpendicular to the applied force in SPS. In contrast to amorphous materials fracture toughness and scratch resistance of alumina-GNP composites increased only for small loading of GNP and properties of the composites decreased after a critical concentration. There was an improvement of ~40% in the fracture toughness with the addition of only 0.5 vol% GNP in the alumina matrix while the scratch resistance of the composite increased by ~10% in the micro-ductile region. Electrical conductivity of the BG-GNP composite was increased by ~9 orders of magnitude compared to pure BG. In vitro bioactivity tests performed on BG-GNP composites confirmed that the addition of GNP to BG matrix also improved the bioactivity of the nano-composites confirmed using XRD analysis. Future work should focus on understanding electrical and thermal properties of these novel nano-composites.

Αρκετές φορές υπήρξαν επιστημονικές ανακαλύψεις που περίμεναν την δημιουργία νέων ή την βελτίωση γνωστών υλικών, προτού βρούν εφαρμογή. Σε άλλες περιπτώσεις πάλι, καινοτομίες στην τεχνολογία των υλικών υπήρξαν το κίνητρο για την ανάπτυξη νέων εφαρμογών και εφευρέσεων. Είναι πράγματι εντυπωσιακό το πόσα από τα σύγχρονα τεχνολογικά επιτεύγματα οφείλουν την ύπαρξή τους στην, τυχαία πολλές φορές, ανακάλυψη ενός πρωτοποριακού υλικού, μιας νέας μεθόδου επεξεργασίας, ή άγνωστων ιδιοτήτων σε γνώριμα υλικά. Σήμερα ο τομέας των υλικών αποτελεί ανεξάρτητο πεδίο επιστημονικής έρευνας με έντονη δραστηριότητα. Παράλληλα επιτελείται σημαντικό έργο με στόχο την αξιοποίηση από την τεχνολογία, των ερευνητικών αποτελεσμάτων της επιστήμης των υλικών. Μία άποψη της δραστηριότητας αυτής είναι η εισαγωγή σε πειραματικό επίπεδο, νέων υλικών σε γνωστές εφαρμογές. Αν και αυτό αποτελεί ένα σημαντικό βήμα, ωστόσο η υιοθέτηση ενός υλικού από την βιομηχανία με την είσοδό του στην παραγωγή, εξαρτάται από πολλούς παράγοντες. Ένας από τους πιο καθοριστικούς, ειδικά όσο αφορά εφαρμογές υψηλής τεχνολογίας, είναι η δυνατότητα προσαρμογής των διαδικασιών σχεδιασμού στις συνθήκες που διαμορφώνονται από τα ιδιαίτερα χαρακτηριστικά της συμπεριφοράς του υλικού, σε συνδυασμό με τις απαιτήσεις της εφαρμογής. Σε αυτό το γενικό πλαίσιο εντάσεται η παρούσα εργασία, η οποία έχει ως αντικείμενο την ανάπτυξη μεθοδολογίας σχεδιασμού, κατάλληλης για εφαρμογή σε στοιχεία από Σύνθετα Κεραμικά Υλικά Συνεχών Ινών (Continuous Fiber Ceramic Composites – CFCC’s) καταπονούμενα από θερμομηχανικά φορτία. Τα ΣΚΥ Συνεχών Ινών αποτελούν εξελιγμένη μορφή των Προηγμένων Κεραμικών Υλικών, τα οποία είναι ίσως τα πλέον ανθεκτικά υλικά σε περιβάλλοντα υψηλών θερμοκρασιών που έχουν αναπτυχθεί έως σήμερα. Τα ΣΚΥ είναι αντικείμενο συνεχούς έρευνας και ανάπτυξης και αναμένεται να επιφέρουν σημαντική πρόοδο σε πολλούς τομείς. Μία από τις πολλές εφαρμογές για τις οποίες θεωρούνται ελκυστικά, είναι οι στροβιλοκινητήρες αεροχημάτων και οι στροβιλομηχανές παραγωγής ενέργειας. Η αντικατάσταση των μεταλλικών κραμμάτων από ΣΚΥ στα «θερμά» μέρη των στροβιλομηχανών εκτιμάται ότι είναι δυνατό να επιφέρει αύξηση του βαθμού απόδοσης έως και 20% με ταυτόχρονη μείωση των εκπεμπόμενων ρύπων. Στην περιοχή αυτή εστιάζεται η παρουσίαση της προτεινόμενης μεθοδολογίας και συγκεκριμένα στον σχεδιασμό και την ανάλυση ενός πρότυπου θαλάμου καύσης στροβιλομηχανής κατασκευασμένου από ΣΚΥ. Η μεθοδολογία αυτή επιχειρεί να καλύψει τις ιδιαίτερες απαιτήσεις της μοντελοποίησης των ΣΚΥ και της ανάλυσης στοιχείων κατασκευών από ΣΚΥ, που προκύπτουν από τα χαρακτηριστικά της συμπεριφοράς τους στις συνθήκες λειτουργίας των στροβιλομηχανών. Ως βασικό στοιχείο της μεθοδολογίας σχεδιασμού συμπεριλαμβάνεται στην παρούσα εργασία και η λεπτομερής περιγραφή του πειραματικού χαρακτηρισμού ενός τύπου ΣΚΥ με μήτρα και ενίσχυση οξειδίων. Στην διαδικασία αυτή εισάγεται και μια πρωτότυπη μέθοδος ποσοτικού χαρακτηρισμού που στηρίζεται σε μη-καταστροφικές δοκιμές με χρήση υπερήχων. Η διαδικασία εφαρμογής της μεθόδου, όσο αφορά το πειραματικό και το υπολογιστικό μέρος της αναπτύχθηκε εξ’ολοκλήρου στα πλαίσια της παρούσας εργασίας και επιτρέπει την ανίχνευση και τον ποσοτικό προσδιορισμό ανισότροπης βλάβης σε ΣΚΥ. Η επεξεργασία των αποτελεσμάτων της διαδικασίας χαρακτηρισμού, οδηγεί στην διαμόρφωση μαθηματικού μοντέλου που περιγράφει την μηχανική συμπεριφορά του υλικού κάτω από δεδομένες συνθήκες λειτουργίας. Συγκεκριμένα, όσο αφορά τα ΣΚΥ με μήτρα και ενίσχυση από οξείδιο του αλουμινίου στα οποία εστιάζεται η εργασία, διαπιστώθηκε υποβάθμιση των ελαστικών ιδιοτήτων και της αντοχής λόγω παραμονής του υλικού σε περιβάλλον υψηλής θερμοκρασίας. Η υποβάθμιση αυτή προσδιορίστηκε ποσοτικά σαν συνάρτηση της θερμοκρασίας και του χρόνου έκθεσης. Η μεθοδολογία σχεδιασμού στηρίζεται σε μεγάλο βαθμό στην ανάλυση και προσομοίωση της λειτουργίας στοιχείων κατασκευών με την μέθοδο των Πεπερασμένων Στοιχείων. Σημαντικό μέρος της παρούσας εργασίας αφορά την ανάπτυξη υπολογιστικού κώδικα ο οποίος επιτυγχάνει την προσαρμογή του πρωτότυπου μοντέλου υλικού σε εμπορικό λογισμικό ανάλυσης με ΠΣ. Επιπρόσθετα ο υπολογιστικός κώδικας εφαρμόζει μοντελοποίηση προοδευτικής αστοχίας που περιλαμβάνει τρείς ξεχωριστούς μηχανισμούς δομικής αστοχίας. Τέλος, ο κώδικας αυτός χρησιμοποιείται στην προσομοίωση της λειτουργίας ενός τυπικού θαλάμου καύσης στροβιλομηχανής παραγωγής ενέργειας σε συνθήκες σταθερής κατάστασης (steady state), κατασκευασμένου από στρωματοποιημένο ΣΚΥ συνεχών ινών και παρουσιάζονται τα αποτελέσματα της ανάλυσης. / -

Made available in DSpace on 2014-12-17T14:58:10Z (GMT). No. of bitstreams: 1 YgorAAF.pdf: 1834910 bytes, checksum: ddd6f585ec4f1145f34bbec8197b2e39 (MD5) Previous issue date: 2006-05-19 / Conselho Nacional de Desenvolvimento Cient?fico e Tecnol?gico / In this work, were produced ceramic matrix composites based in SiCxOy e Al2O3 reinforced with NbC, by hydrosilylation reaction between D4Vi and poly(methylhydrosiloxane) mixtured with Al2O3 as inert filler, Nb and Al as reactive filler. After the mixture and compactation at 80?C (warm pressing), the samples were pyrolised at 1200 and 1400?C and infiltred with ICZ and LZSA respectively, and thermically, physical and structurally characterized by X-ray diffraction, density and porosity, flexural mechanical strength and fracture surface by scanning electron microscopy. The yield ceramic obtained after pyrolysis for studied composition at 1200?C was 95%. The obtained phases had been identified as being Al3Nb, NbSi2 and NbC. The composite material presented apparent porosity varying of 15 up to 32% and mechanical flexural strenght of 32 up to 37,5MPa. After the fracture surface analysis, were observed a phases homogeneous dispersion, with some domains of amorphous and crystalline aspect. The samples that were submitted the infiltration cycle presented a layer next the surface with reduced pores number in relation to the total volume / Neste trabalho foram produzidos comp?sitos de matriz cer?mica baseados em SiCxOy e Al2O3 refor?ados com NbC, a partir da rea??o de hidrossila??o entre os olig?meros D4Vi (1,3,5,7 tetrametil 1,3,5,7 tetravinilciclotetrasiloxano) e D1107 - Poli(metilhidrogeniosiloxano), misturados com Al2O3 como carga inerte, Nb e Al como aditivos reativos. Ap?s a mistura e compacta??o em 80 ?C (warm pressing), as amostras foram pirolisadas ? 1200 e 1400?C e infiltradas com ICZ e LZSA respectivamente, e caracterizadas t?rmica, f?sica e estruturalmente atrav?s de an?lises t?rmicas (TG e DTA), identifica??o de fases cristalinas por difratometria de raios-x, densidade e porosidade, resist?ncia mec?nica ? flex?o e superf?cie de fratura por microscopia eletr?nica de varredura. O Rendimento cer?mico obtido para a composi??o estudada ? 1200?C foi de 95%. As fases formadas ap?s a pir?lise foram identificadas como sendo Al3Nb, NbSi2 e NbC os comp?sitos apresentaram porosidade aparente variando de 15 a 32 por cento e resist?ncia mec?nica a flex?o, de 32 a 37,5MPa. Ap?s a an?lise da superf?cie de fratura observou-se uma dispers?o homog?nea de fases, com algumas regi?es de aspecto amorfo e cristalino. As amostras que foram submetidas a ciclo de infiltra??o apresentaram uma camada pr?xima a superf?cie com reduzido n?mero de poros em rela??o ao volume total

Tendo como vantagem a elevada resistência ao choque térmico da zircônia:magnésia e a alta condutividade iônica da zircônia:ítria, compósitos dessas cerâmicas foram preparados por meio da mistura, em diferentes concentrações, de eletrólitos sólidos de ZrO2: 8,6 mol% MgO e de ZrO2: 3 mol% Y2O3, compactação e sinterização. A caracterização microestrutural foi feita por meio de difração de raios X e microscopia eletrônica de varredura. A análise do comportamento térmico foi feita por dilatometria. As propriedades elétricas foram estudadas por meio de espectroscopia de impedância. Foi feita uma montagem experimental para monitorar a resposta elétrica gerada em função do teor de oxigênio a altas temperaturas. Os principais resultados mostram que os compósitos cerâmicos são parcialmente estabilizados nas fases monoclínica, cúbica e tetragonal, e apresentam comportamento térmico similar ao apresentado por eletrólitos sólidos de zircônia:magnésia de dispositivos sensores de oxigênio. Além disso, os resultados de análise de espectroscopia de impedância mostram que a adição da zircônia:ítria melhora o comportamento elétrico da zircônia:magnésia, e que resposta elétrica gerada é dependente do teor de oxigênio a 1000 °C, mostrando ser possível construir sensores de oxigênio utilizando compósitos cerâmicos. / Taking advantage of the high thermal shock resistance of zirconia-magnesia ceramics and the high oxide ion conductivity of zirconia-yttria ceramics, composites of these ceramics were prepared by mixing, pressing and sintering different relative concentrations of ZrO2: 8.6 mol% MgO and ZrO2: 3mol% Y2O3 solid electrolytes. Microstructural analysis of the composites was carried out by X-ray diffraction and scanning electron microscopy analyses. The thermal behavior was studied by dilatometric analysis. The electrical behavior was evaluated by the impedance spectroscopy technique. An experimental setup was designed for measurement the electrical signal generated as a function of the amount of oxygen at high temperatures. The main results show that these composites are partially stabilized (monoclinic, cubic and tetragonal) and the thermal behavior is similar to that of ZrO2: 8.6 mol% MgO materials used in disposable high temperature oxygen sensors. Moreover, the results of analysis of impedance spectroscopy show that the electrical conductivity of zirconia:magnesia is improved with zirconia-yttria addition and that the electrical signal depends on the amount of oxygen at 1000 °C, showing that the ceramic composites can be used in oxygen sensors.

<p dir="ltr">Ceramic/metal composites are being explored as potential replacements for conventional metal alloys in high-temperature components used in aerospace and power generation applications. Co-continuous ceramic/metal composites can offer attractive combinations of properties, such as improved mechanical toughness and thermal conductivity (relative to monolithic ceramics) and enhanced stiffness and corrosion/erosion resistance (relative to monolithic metals). However, development of cost-effective and scalable manufacturing routes to dense, complex-shaped ceramic/metal composites is a non-trivial challenge.</p><p dir="ltr">Chapter 1 of this dissertation is focused on the fabrication of WC/Cu composites using pressureless Cu liquid infiltration. The microstructure, density, porosity, phase content and properties of the resulting WC/Cu composites have been investigated. Mechanical properties, such as flexural strength and Vickers hardness have been evaluated, and the thermal cycling behavior of the WC/Cu composites have been examined. This study successfully demonstrates the fabrication of near-net-shape WC/Cu composites and provides insights into potential applications for such composites.</p><p dir="ltr">In Chapter 2, the limitations of metal alloy-based heat exchangers are discussed, leading to the exploration of alternative materials such as composite of zirconium carbide (ZrC) and tungsten (W). The favorable properties of ZrC/W composites, such as chemical compatibility, low vapor pressure, high thermal conductivity, stiffness, and thermal cyclability are highlighted. The fabrication of ZrC/W composites using reactive infiltration processes, emphasizing the importance of scalable fabrication methods, is also demonstrated.</p><p dir="ltr">Chapter 3 is focused on the fabrication and characterization of functionally graded ZrC/W – WC/Cu composites. These composites have been prepared by immersing WC/Cu preforms in Zr – Cu liquid at different temperatures, and the microstructures and phase distributions have been evaluated. It is observed with the same immersion time, the thickness of the ZrC/W reaction zone decreases with increasing immersion temperature due to the rapid reaction between WC and Zr at higher temperatures. Additionally, a model has been developed to describe the thermal conductivity of the composites as a function of the distance from the external surface. These findings provide insights into the fabrication and properties of functionally-graded composites for potential heat dissipation applications.</p><p dir="ltr">In Chapter 4, the development of a Ti-bearing, Ni-based active metal braze for joining Al₂O₃/Cr composites to Ni-based alloys is discussed. Joining ceramic components to metal parts poses challenges due to material property mismatches and ceramic brittleness. Conventional brazing materials often suffer from oxidation at high temperatures in air which compromises joint integrity. The focus of this chapter is the evaluation of the oxidation behavior of the developed brazing material to assess the suitability of this braze for reliable joining of ceramic-based composites to Ni-based alloys for use in air at high temperatures. Differential scanning calorimetry (DSC) has also been used to evaluate the solidus and liquidus temperatures of the Ni-19Cr-10Si and Ni-18Cr-10Si-4Ti alloys.</p><p><br></p>

In this thesis, a novel in-situ method for incorporating nanoscale ceramic particles into metal has been developed. The ceramic phase is introduced as an organic-polymer precursor that pyrolyzes in-situ to produce a ceramic phase within the metal melt. The environment used to shield the melt from burning also protects the organic precursor from oxidation. The evolution of volatiles (predominantly hydrogen) as well as the mechanical stirring causes the polymer particles to fragment into nanoscale dispersions of a ceramic phase. These “Polymer-based In-situ Process-Metal Matrix Composites” (PIP-MMCs) are likely to have great generality, because many different kinds of organic precursors are commercially available, for producing oxides, carbides, nitrides, and borides. Also, the process would permit the addition of large volume fractions of a ceramic phase, enabling nanostructural design, and production of MMCs with a wide range of mechanical properties, meant especially for high temperature applications. An important and noteworthy feature of the present process, which distinguishes it from other methods, is that all the constituents of the ceramic phase are built into the organic molecules of the precursor (e.g., polysilazanes contain silicon, carbon, and nitrogen); therefore, a reaction between the polymer and the host metal is not required to produce the dispersion of the refractory phase. The polymer precursor powder, with a mean particle size of 31.5 µm, was added equivalent to 5 and 10 weight % of the melt (pure magnesium) by a liquid metal stir-casting technique. SEM and OM microstructural observations show that in the cast structure the pyrolysis products are present in the dendrite boundary region in the form of rod/platelets having a thickness of 100 to 200 nm. After extrusion the particles are broken down into fine particles, having a size that is comparable to the thickness of the platelets, in the 100 to 200 nm range, and are distributed more uniformly. In addition, limited TEM studies revealed the formation of even finer particles of 10-50 nm. X-ray diffraction analysis shows the presence of a small quantity of an intermetallic phase (Mg2Si) in the matrix, which is unintended in this process. There was a significant improvement in mechanical properties of the PIP-MMCs compared to the pure Mg. These composites showed higher macro-and micro-hardness. The composite exhibited better compressive strength at both room temperature and at elevated temperatures. The increase in the density of PIP-composites is less than 1% of Mg. Five weight percent of the precursor produced a two-fold increase in the room-temperature yield strength and reduced the steady state creep rate at 723 K by one to two orders of magnitude. PIP-MMCs showed higher damping capacity and modulus compared to pure Mg, with the damping capacity increasing by about 1.6 times and the dynamic modulus by 11%-16%. PIP-composites showed an increase in the sliding wear resistance by more than 25% compared to pure Mg.