This research includes the potential for resistance and the expansion that the soil presents, this evaluation was carried out through CBR tests. The soil cement technique was used to improve the physical and mechanical characteristics; this process consists in mixing the material with Portland cement type I. That combination forms soil cement 10%, 15% y 20%, which present an increase of the CBR (max: 138.7% and min: 91.9%) achieving a type of extraordinary subgrade to resist the structure of the pavement and a reduction of 7.18% in the expansion of the samples.

This document studies the stabilization of the soil used as a subgrade, by adding locally available materials such as rice husk ash (RHA) and sugarcane bagasse ash (SCBA). These aggregates were added to the soil in substitution by weight between 5%, 7.5% and 10%. By adding these, the expansiveness is reduced while the maximum dry density increases, in addition the tendency of CBR is increasing and then tends to decrease proportionally to the addition of the aforementioned aggregates. This indicates a peak in CBR and expandability. The best result obtained from CBR was 33.75% with the 5% replacement mixtures.

Os aterros reforçados sobre solo mole de resistência crescente com a profundidade, podem apresentar problemas durante o processo construtivo com respeito às rupturas e aos recalques inesperados. O presente trabalho visa avaliar o comportamento dos aterros reforçados a través de um estudo numérico, levando aos aterros até a ruptura sob condição não-drenada devido ao carregamento rápido, com o objetivo de estimar a influência da rigidez do reforço nas deformações, além disso, estudar o mecanismo da interação solo-reforço para um aterro reforçado. Foi utilizada a metodologia apresentada por Hinchberger & Rowe (2003), que leva em conta os recalques imediatos durante e após a construção. As análises numéricas de tensão-deformação foram realizadas pelo software PHASE 2, a calibração do programa foi feita com a literatura de aterros reforçados. Pretendeu-se mostrar a influência de uma camada superficial de areia sobre a argila mole na altura de ruptura e na deformação do reforço. Pelo método de elementos finitos foi definida uma metodologia para calcular as deformações do reforço para uma altura determinada e avaliar a estabilidade mediante o método de equilíbrio limite. Além disso, essa metodologia pode ser empregada para dimensionar o reforço requerido para um determinado fator de segurança. / Reinforced embankments on soft clayey soil where the strength increases with depth may present problems during construction process relative to failure and unexpected settlements. This study aims to evaluate the embankments behavior with a numerical study; the embankments were taken to failure in the undrained shear strength condition due to rapid upload to study the effect of reinforcement tensile stiffness on the reinforcement strains. Besides, it aimed to study the mechanism of soil-reinforcement interaction for a reinforced embankment. The method of Hinchberger & Rowe (2003) was used, which considers the displacements before and post construction. The numeric analysis of stress-strain was performed by the software PHASE 2; the calibration of the software was made according to published reinforced embankment literature. The study intends to show the influence of a sand layer above the clayey soil, on the failure height and reinforcement strains. Based on finite elements methods, a methodology was defined to estimate the reinforcement strains for a required design height and to study the stability by performing limit equilibrium analysis. Furthermore, this methodology could be used to specify the required reinforcement stiffness for a specific factor of safety.

京都大学 / 新制・課程博士 / 博士(理学) / 甲第23711号 / 理博第4801号 / 新制||理||1688(附属図書館) / 京都大学大学院理学研究科地球惑星科学専攻 / (主査)教授 王 功輝, 教授 釜井 俊孝, 教授 久家 慶子 / 学位規則第4条第1項該当 / Doctor of Science / Kyoto University / DGAM

Os aterros reforçados sobre solo mole de resistência crescente com a profundidade, podem apresentar problemas durante o processo construtivo com respeito às rupturas e aos recalques inesperados. O presente trabalho visa avaliar o comportamento dos aterros reforçados a través de um estudo numérico, levando aos aterros até a ruptura sob condição não-drenada devido ao carregamento rápido, com o objetivo de estimar a influência da rigidez do reforço nas deformações, além disso, estudar o mecanismo da interação solo-reforço para um aterro reforçado. Foi utilizada a metodologia apresentada por Hinchberger & Rowe (2003), que leva em conta os recalques imediatos durante e após a construção. As análises numéricas de tensão-deformação foram realizadas pelo software PHASE 2, a calibração do programa foi feita com a literatura de aterros reforçados. Pretendeu-se mostrar a influência de uma camada superficial de areia sobre a argila mole na altura de ruptura e na deformação do reforço. Pelo método de elementos finitos foi definida uma metodologia para calcular as deformações do reforço para uma altura determinada e avaliar a estabilidade mediante o método de equilíbrio limite. Além disso, essa metodologia pode ser empregada para dimensionar o reforço requerido para um determinado fator de segurança. / Reinforced embankments on soft clayey soil where the strength increases with depth may present problems during construction process relative to failure and unexpected settlements. This study aims to evaluate the embankments behavior with a numerical study; the embankments were taken to failure in the undrained shear strength condition due to rapid upload to study the effect of reinforcement tensile stiffness on the reinforcement strains. Besides, it aimed to study the mechanism of soil-reinforcement interaction for a reinforced embankment. The method of Hinchberger & Rowe (2003) was used, which considers the displacements before and post construction. The numeric analysis of stress-strain was performed by the software PHASE 2; the calibration of the software was made according to published reinforced embankment literature. The study intends to show the influence of a sand layer above the clayey soil, on the failure height and reinforcement strains. Based on finite elements methods, a methodology was defined to estimate the reinforcement strains for a required design height and to study the stability by performing limit equilibrium analysis. Furthermore, this methodology could be used to specify the required reinforcement stiffness for a specific factor of safety.

Submitted by Mario BC (mario@bc.ufrpe.br) on 2017-02-22T13:08:59Z No. of bitstreams: 1 Cidney Barbosa Bezerra.pdf: 2167272 bytes, checksum: 5f0cef27593c95187e77811cdb520cbb (MD5) / Made available in DSpace on 2017-02-22T13:08:59Z (GMT). No. of bitstreams: 1 Cidney Barbosa Bezerra.pdf: 2167272 bytes, checksum: 5f0cef27593c95187e77811cdb520cbb (MD5) Previous issue date: 2016-08-25 / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior - CAPES / The South Agreste Pernambucano has an agricultural and very large land diversification, but the management of the soil used in the production is mostly inadequate, resulting in economic and low productivity losses, allied to it have weather conditions quite different typical of a transitional environment . However the city of Brejão has a special condition with cooler and rainy weather and deeper soils and well structured, with occurrence horizon latosols with the humic something characteristic in this swamp of altitude. So the aim of this study was to investigate the changes in chemical, physical and water attributes of the surface horizon humic an Oxisol subjected to different forms of management in the Swamp region of South Agreste Altitude Pernambuco, and investigate the soil repellency water. The disturbed and undisturbed soil samples were collected in a native forest (MN), pasture 5 years (PA5) and grazing 30 (PA30) in three layers 0 to 10 cm, 10 to 20 cm and 20 to 30 cm and evaluated the chemical, biological, physical and water attributes, as was also done an infiltration test with simple ring. Chemical attributes presented typicality dystrophic yellow latosols, and attributes related to the acidity showing significant results mainly in the surface layer. For biological attributes your changes are more significant in macroaggregates. Have the physical attributes that most change with inadequate management are the bulk density (Ds) and porosity consequently these physical attributes are linked to water retention in the soil and all water dynamics. For the infiltration test it is clear the presence of soil water repellency. / O Agreste Meridional pernambucano possui uma diversificação agropecuária e de solos muito grande, porém o manejo do solo empregado na produção é em sua maioria inadequado, acarretando em perdas econômicas e baixa produtividade, aliadas a isso temos condições climáticas bastante diferentes típicas de um ambiente de transição. No entanto a cidade de Brejão possui uma condição especial, com clima mais frio e chuvoso e solos mais profundos e bem estruturado, com ocorrência de latossolos de horizonte com A húmico algo característico nesse brejo de altitude. Assim o objetivo deste trabalho foi investigar as alterações nos atributos químicos, físicos e hídricos do horizonte superficial A húmico de um Latossolo Amarelo submetido a diferentes formas de manejo na região do Brejo de Altitude do Agreste Meridional pernambucano, e investigar a repelência do solo a água. As amostras deformadas e indeformadas do solo foram coletadas em uma área de mata nativa (MN), pasto de 5 anos (PA5) e pasto de 30 anos (PA30), em três camadas 0 a 10 cm, 10 a 20 cm e 20 a 30 cm e foram avaliados os atributos químicos, biológicos, físicos e hídricos, como também foi realizado um teste de infiltração com anel simples. Os atributos químicos apresentaram tipicidade de latossolos amarelo distróficos, e atributos relacionados com a acidez apresentando resultados significativos principalmente na camada superficial. Para os atributos biológicos suas alterações são mais expressivas nos macroagregados. Já os atributos físicos que mais sofreram alterações com o manejo inadequado são a densidade do solo (Ds) e a porosidade, consequentemente esses atributos físicos estão ligados a retenção de água no solo e toda dinâmica hídrica. Pelo teste de infiltração fica claro a presença de repelência do solo a água.

The aim of this present research is to improve the containment properties of clayey soil by the use of bentonite and polymers as the additives. Clayey soils are generally used for the control of soil and water pollutions as they are inexpensive material. However, their applications are limited when it comes to durability of such liners in the field condition. Addition of additives to increase their efficiency by reducing the hydraulic conductivity can overcome this limitation. Generally, bentonite is used as the effective barrier additives because of their ability to render high swell and reduced hydraulic conductivity to the soil-bentonite mixtures. Due to high specific surface area and large cation exchange capacity, bentonite is always preferred for containment application. Despite their wide applicability in containment barrier, the problem with bentonite is its reduction of swell when the contaminant of interest consists of multivalent ions. Higher valency ions attach to the exchange site of bentonite and thus reduce its efficiency. To overcome these constraints the bentonite has, polymers are being used for containment applications. Normally, anionic polymers are used for such containment applications which help in increase negative charge concentration of the clayey soils. Previous studies have also proved the effectiveness of polymer in increasing the retardation factor of the soil which is due to the adsorption of contaminants to the negatively charged surface of clay. Hence attempt is also made in this thesis to study the effectiveness of super absorbent polymers when used as additive to the clayey soil. In this thesis, effectiveness of the local Bangalore soil for its use as barrier material is studied. Tests are done on the compacted sample to determine its contaminant transport properties. Because of their low hydraulic conductivities, advective flux through the barriers is negligible. In such cases, contaminant migration takes place due to the difference in concentration and this transport mechanism is known as diffusion. Laboratory test have been done to determine the diffusion coefficient of soil when the soil is saturated. For barriers and liner systems which are not fully saturated, suction adds to the hydraulic head. For unsaturated samples, although the liquid phase diffusion have been found to be nominal, head difference caused due to suction facilitates the migration of contaminants. Hence, effects of initial degree of saturation and density in contaminant transport process through soils have been examined. An attempt has been made to study unsaturated transport properties by using saturated transport parameters and unsaturated soil parameters obtained from soil-water characteristics curve. Another focus of this thesis has been towards enhancing the containment property of local soil by using additives. Effects of addition of bentonite and polymer on contaminant transport parameters of the soil have been studied. An attempt has been made to reduce the hydraulic conductivity of soil by using additives like bentonite. In addition, use of super-absorbent polymer as a novel material for barrier application has been studied to determine its suitability for local conditions. Experiments have been conducted to determine free swell, hydraulic conductivity and diffusion coefficient of soil-bentonite and soil-polymer mixes and compare them to those of local soil. To determine the effectiveness of soil-bentonite and soil-polymer mixes under the attack of concentrated solution over a long duration, chemical compatibility tests have been carried out. Micro-structural changes in the soil on addition of bentonite and polymer have been studied with the help of scanning electron microscope (SEM) images. Mineralogical changes occurring in the soil due to the additives have been studied using X-Ray Diffraction (XRD) plots. Effects of salt solution on soil-bentonite and soil-polymer mixes have also been studied by the help of SEM images and XRD plots. The final section of this thesis is on analysis of barrier performance for different conditions of densities, compaction and saturation by using numerical software CODE_BRIGHT. Transport parameters obtained from the experiments conducted in previous sections have been used as input for the analysis. A field condition of Bingipura landfill site in South Bangalore, Bangalore city has been simulated as a case study for this thesis. Time taken for contaminants to migrate from landfill to the nearby water body which is at a distance of about 122 meters is calculated for no barrier case. When barrier is provided, concentration variations of contaminant through the barrier with time are plotted and the results are compared for soil barrier, soil-bentonite barrier and soil-polymer barrier. v

Cette thèse présente un ensemble de résultats expérimentaux sur une argile remaniée non saturée proche de la saturation, dont le degré de saturation est généralement supérieur à 70%.Après une série d’essais de caractérisation physique et mécanique du matériau, plusieurs méthodes expérimentales ont été utilisées pour étudier le comportement et certaines pathologies du sol compacté telles que l’orniérage et le matelassage.Une étude systématique du comportement du sol compacté sur chemins de drainage-humidification dans différents états initiaux a été effectuée, complétée par des mesures de succion par papier filtre et psychromètre. Les essais de porosimétrie par intrusion de mercure ont apporté un éclairage sur la microstructure du sol.La thèse a également permis d’étudier les variations de pression interstitielle du sol compacté sur chemin triaxial non drainé en utilisant la technique de translation d’axes, où quelques améliorations et modifications du montage ont été proposées. / This thesis present an experimental study of an unsaturated clayey soil close to saturation, whose degree of saturation is generally above 70%.After characterizing the physical and mechanical properties of the material, several experimental methods were used to study the behaviour and some pathologies of the compacted soil, such as rutting and quilting.A systematic study of the behaviour of the compacted soil on drying-wetting paths starting from different initial states was carried out, completed by suction measurements using filter-paper and psychrometer. Mercury intrusion porosimetry tests gave an insight of the soil microstructure.The thesis also addressed the question of the pore pressure variations of the compacted soil on undrained triaxial path using the axis-translation technique, where some improvements and modifications of the testing device were proposed.

O objetivo do trabalho foi identificar ferramentas e indicadores adequados ao monitoramento e à otimização de processos de biorremediação, incluindo parâmetros físicos, químicos e microbiológicos definidos em estudos de tratabilidade de solos contaminados por óleo cru em escala de laboratório e comparar estratégias de biorremediação, tais como bioestímulo e bioaumento conduzidas em simulações de biopilhas dinâmicas ou estáticas. Quando três métodos de extração de hidrocarbonetos de petróleo de solo arenoso e franco-argiloso para análise cromatográfica (Soxhlet-SOX, microondas-MARS e extração acelerada por solvente-ASE) foram comparados entre si, concluiu-se que a técnica que promove a melhor recuperação depende da fração de interesse (n-alcanos, HRP, MCNR, HPA), das características texturais do solo (teores de areia, silte e argila) e da idade da contaminação. Dentre os indicadores de densidade populacional microbiana (microrganismos heterotróficos totais-PHT, população de fungos-PF e população microbiana degradadora de óleo (PDO) passíveis de utilização para indicar a taxa de degradação de compostos orgânicos presentes no solo tais como os hidrocarbonetos de petróleo, o PDO mostrou-se o mais adequado em conjunto com a produção de CO2 aferida pelo método respirométrico. Quando a estratégia de biorremediação de solo franco-argiloso contaminado com óleo cru a 3% (m m-1) utilizando bioestímulo (ajuste de pH, umidade e taxa C:N:P) foi comparada ao bioaumento (bioestímulo e adição de inóculo de microrganismos extraídos, enriquecidos e aclimatizados ao óleo cru como fonte de carbono), em sistemas de bancada simulando biopilha dinâmica (microcosmo M) e biopilha estática com aeração forçada (reator B), o tratamento que apresentou melhor remoção (32%) de HTP após 121 dias foi o bioaumento em biopilha estática. Para HPA, o tratamento que alcançou a melhor remoção (33%) foi com bioestímulo também em biopilha estática. A avaliação da taxa de mortalidade (%) de Eisenia andrei exposta tanto a solos recém-contaminados por óleo cru e preparados para bioestímulo (BIOS) e bioaumento (BIOA) a serem tratados em biopilhas dinâmicas e estáticas em escala de laboratório mostrou que após 56 dias de exposição da E. andrei, todos os solos produziram letalidade de 100%, quer fossem os solos recém-contaminados e preparados para os diferentes tratamentos (BIOS M, BIOS B, BIOA M, BIOA B) ou após 121 dias de tratamento. Tal resultado confirma que a biorremediação foi incipiente também do ponto de vista de remoção da ecotoxicidade. Em linhas gerais, a biorremediação de solo franco-argiloso contaminado por óleo cru, contendo tanto contaminação antiga quanto recente, reúne os maiores desafios à biorremediação, tanto do ponto de vista da composição textural do solo quanto da natureza do contaminante. Os processos são aparentemente lentos e requerem ferramentas auxiliares para aceleração dos mesmos. Recomenda-se no futuro, condução de experimentos com o uso de diferentes surfactantes, com ênfase em biosurfactantes / The objective of this investigation was to identify tools and indicators suitable for monitoring and optimizing bioremediation processes, including physical, chemical and microbiological variables defined in treatability studies of crude oil contaminated clayey soils in lab-scale and to compare bioremediation strategies, such as biostimulation and bioaugmentation carried out in lab scale dynamics and static biopiles. When three methods for extraction of petroleum hydrocarbon for chromatography analysis (Soxhlet-SOX, microwaves-MARS and accelerated solvent extraction-ASE) were compared, it was concluded that the most appropriate extraction method depends on the hydrocarbon fraction of interest (n-alkanes, RPH, UCM or PAH), the textural soil characteristics (sand, silt and clay content) and the contamination age. Among the microbiological indicators investigated (total heterotrophic microorganisms-PHT, fungi population-PF and; oil-degrading microorganism population-PDO, the last one was the best indicator for degradation of organic carbon compounds such as petroleum hydrocarbon, together with CO2 generation measured through respirometric method. Bioremediation strategies for oil-contaminated clayey soil (3% m m-1) were compared, including biostimulation (adjustment of pH, C:N:P rate and moisture) and bioaugmentation (biostimulation plus a consortium inoculum extracted from the original aged-contaminated soil, enriched and acclimatized with the crude oil as carbon source) in lab scale system simulating dynamic (microcosms) and static (bioreactors with forced aeration). The treatment which presented the highest TPH removal (32%) after 121 days was the bioaugmented static biopile (BIOA B). For PAH, the most efficient treatment method that removed 33% of PAH was the biostimulated static biopile (BIOS B). The mortality rate (%) for Eisenia andrei exposed to newly contaminated soil prepared for biostimulation (BIOS) and bioaugmentation (BIOA) treatments at day 0 as well as the treated soil in static and dynamic biopiles at different treatment times (after 24, 59 and 121 days) revealed that after 56 of E. andreis exposition, all soils produced mortality of 100%, no matter if newly contaminated or treated (BIOS M, BIOS B, BIOA M, BIOA B). The ecotoxicity tests confirmed that bioremediation as such was incipient also from the toxicity removal viewpoint. In general terms, bioremediation of clayey soils with a complex contaminant such as crude oil raise considerable challenges, both from the soil characteristics as well as the nature of the contaminant. The processes are apparently slow and require auxiliary tools to speed up the process. In the future, it is recommended to test the use of different surfactants, particularly bio-surfactants.

O objetivo do trabalho foi identificar ferramentas e indicadores adequados ao monitoramento e à otimização de processos de biorremediação, incluindo parâmetros físicos, químicos e microbiológicos definidos em estudos de tratabilidade de solos contaminados por óleo cru em escala de laboratório e comparar estratégias de biorremediação, tais como bioestímulo e bioaumento conduzidas em simulações de biopilhas dinâmicas ou estáticas. Quando três métodos de extração de hidrocarbonetos de petróleo de solo arenoso e franco-argiloso para análise cromatográfica (Soxhlet-SOX, microondas-MARS e extração acelerada por solvente-ASE) foram comparados entre si, concluiu-se que a técnica que promove a melhor recuperação depende da fração de interesse (n-alcanos, HRP, MCNR, HPA), das características texturais do solo (teores de areia, silte e argila) e da idade da contaminação. Dentre os indicadores de densidade populacional microbiana (microrganismos heterotróficos totais-PHT, população de fungos-PF e população microbiana degradadora de óleo (PDO) passíveis de utilização para indicar a taxa de degradação de compostos orgânicos presentes no solo tais como os hidrocarbonetos de petróleo, o PDO mostrou-se o mais adequado em conjunto com a produção de CO2 aferida pelo método respirométrico. Quando a estratégia de biorremediação de solo franco-argiloso contaminado com óleo cru a 3% (m m-1) utilizando bioestímulo (ajuste de pH, umidade e taxa C:N:P) foi comparada ao bioaumento (bioestímulo e adição de inóculo de microrganismos extraídos, enriquecidos e aclimatizados ao óleo cru como fonte de carbono), em sistemas de bancada simulando biopilha dinâmica (microcosmo M) e biopilha estática com aeração forçada (reator B), o tratamento que apresentou melhor remoção (32%) de HTP após 121 dias foi o bioaumento em biopilha estática. Para HPA, o tratamento que alcançou a melhor remoção (33%) foi com bioestímulo também em biopilha estática. A avaliação da taxa de mortalidade (%) de Eisenia andrei exposta tanto a solos recém-contaminados por óleo cru e preparados para bioestímulo (BIOS) e bioaumento (BIOA) a serem tratados em biopilhas dinâmicas e estáticas em escala de laboratório mostrou que após 56 dias de exposição da E. andrei, todos os solos produziram letalidade de 100%, quer fossem os solos recém-contaminados e preparados para os diferentes tratamentos (BIOS M, BIOS B, BIOA M, BIOA B) ou após 121 dias de tratamento. Tal resultado confirma que a biorremediação foi incipiente também do ponto de vista de remoção da ecotoxicidade. Em linhas gerais, a biorremediação de solo franco-argiloso contaminado por óleo cru, contendo tanto contaminação antiga quanto recente, reúne os maiores desafios à biorremediação, tanto do ponto de vista da composição textural do solo quanto da natureza do contaminante. Os processos são aparentemente lentos e requerem ferramentas auxiliares para aceleração dos mesmos. Recomenda-se no futuro, condução de experimentos com o uso de diferentes surfactantes, com ênfase em biosurfactantes / The objective of this investigation was to identify tools and indicators suitable for monitoring and optimizing bioremediation processes, including physical, chemical and microbiological variables defined in treatability studies of crude oil contaminated clayey soils in lab-scale and to compare bioremediation strategies, such as biostimulation and bioaugmentation carried out in lab scale dynamics and static biopiles. When three methods for extraction of petroleum hydrocarbon for chromatography analysis (Soxhlet-SOX, microwaves-MARS and accelerated solvent extraction-ASE) were compared, it was concluded that the most appropriate extraction method depends on the hydrocarbon fraction of interest (n-alkanes, RPH, UCM or PAH), the textural soil characteristics (sand, silt and clay content) and the contamination age. Among the microbiological indicators investigated (total heterotrophic microorganisms-PHT, fungi population-PF and; oil-degrading microorganism population-PDO, the last one was the best indicator for degradation of organic carbon compounds such as petroleum hydrocarbon, together with CO2 generation measured through respirometric method. Bioremediation strategies for oil-contaminated clayey soil (3% m m-1) were compared, including biostimulation (adjustment of pH, C:N:P rate and moisture) and bioaugmentation (biostimulation plus a consortium inoculum extracted from the original aged-contaminated soil, enriched and acclimatized with the crude oil as carbon source) in lab scale system simulating dynamic (microcosms) and static (bioreactors with forced aeration). The treatment which presented the highest TPH removal (32%) after 121 days was the bioaugmented static biopile (BIOA B). For PAH, the most efficient treatment method that removed 33% of PAH was the biostimulated static biopile (BIOS B). The mortality rate (%) for Eisenia andrei exposed to newly contaminated soil prepared for biostimulation (BIOS) and bioaugmentation (BIOA) treatments at day 0 as well as the treated soil in static and dynamic biopiles at different treatment times (after 24, 59 and 121 days) revealed that after 56 of E. andreis exposition, all soils produced mortality of 100%, no matter if newly contaminated or treated (BIOS M, BIOS B, BIOA M, BIOA B). The ecotoxicity tests confirmed that bioremediation as such was incipient also from the toxicity removal viewpoint. In general terms, bioremediation of clayey soils with a complex contaminant such as crude oil raise considerable challenges, both from the soil characteristics as well as the nature of the contaminant. The processes are apparently slow and require auxiliary tools to speed up the process. In the future, it is recommended to test the use of different surfactants, particularly bio-surfactants.