The mechanical property of polymeric materials changes over time, especially when they are subjected to long-term loading scenarios. To predict the time-dependent viscoelastic behaviors of epoxy-based adhesive materials, it is imperative that reliable accelerated tests be developed to determine their long-term performances under different exposed environments. A neat epoxy resin system and a commercial structural adhesive system for bonding aluminum substrates are investigated. A series of moisture diffusion tests have been performed for more than three months in order to understand the influence of the absorbed moisture on creep behavior. The material properties, such as elastic modulus and glass transition temperature, are also studied under different environmental conditions. The time-temperature superposition method produces a master curve allowing the long-term creep compliance to be estimated. The physics-based Coupling model is found to fit well the long-term creep master curve. The equivalence of the temperature and moisture effect on the creep compliance of the epoxy adhesives is also addressed. Finally, a methodology for predicting the long-term creep behavior of epoxy adhesives is proposed.

The mechanical property of polymeric materials changes over time, especially when they are subjected to long-term loading scenarios. To predict the time-dependent viscoelastic behaviors of epoxy-based adhesive materials, it is imperative that reliable accelerated tests be developed to determine their long-term performances under different exposed environments. A neat epoxy resin system and a commercial structural adhesive system for bonding aluminum substrates are investigated. A series of moisture diffusion tests have been performed for more than three months in order to understand the influence of the absorbed moisture on creep behavior. The material properties, such as elastic modulus and glass transition temperature, are also studied under different environmental conditions. The time-temperature superposition method produces a master curve allowing the long-term creep compliance to be estimated. The physics-based Coupling model is found to fit well the long-term creep master curve. The equivalence of the temperature and moisture effect on the creep compliance of the epoxy adhesives is also addressed. Finally, a methodology for predicting the long-term creep behavior of epoxy adhesives is proposed.

京都大学 / 新制・課程博士 / 博士(理学) / 甲第23711号 / 理博第4801号 / 新制||理||1688(附属図書館) / 京都大学大学院理学研究科地球惑星科学専攻 / (主査)教授 王 功輝, 教授 釜井 俊孝, 教授 久家 慶子 / 学位規則第4条第1項該当 / Doctor of Science / Kyoto University / DGAM

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Rut formation has long been recognized as a distress mechanism in flexible pavements. One of the causes of rut formation in flexible pavements is permanent deformation of uppermost asphalt concrete layers due to repeatedly applied traffic loading. The long term permanent deformation of asphalt concrete under repeated load is commonly called as dynamic creep. The primary objective of this thesis is to examine dynamic creep behavior of asphalt concrete specimens tested in laboratory and also study some suitable mathematical models for representing dynamic creep behavior. In this study, a set of uniaxial repeated load creep tests were performed on standard Marshall specimens prepared at three different bitumen contents. The effects of bitumen content and test condition parameters on dynamic creep behavior are examined. Among several mathematical creep models suggested by researchers, two well known models and a model proposed by the author are selected for representing the laboratory creep behavior. For each of these models, the interactions of the model parameters with varying bitumen content and test conditions are studied to detect probable definite trends, and to evaluate whether some relations for the model parameters as functions of bitumen content and test conditions can be developed or not. The results of analyses showed that all three mathematical models used in this study are successful in representing the laboratory dynamic creep behavior of asphalt concrete. The Power Model which has only two parameters is found to be the most stable and suitable model for parametric study among the three selected models. More consistent and definite interactions are observed between the parameters of this model and test conditions. However, within the scope of this study, no relations could be developed for the parameters of selected models as functions of bitumen content and test conditions because of limited test data.

Using experimentally measured temperature-process-dependent model parameters, the failure analysis and life prediction were conducted for Atmospheric Plasma Sprayed Thermal Barrier Coatings (APS-TBCs) and electron beam physical vapor deposition thermal barrier coatings (EB-PVD TBCs) with Pt-modified -NiAl bond coats deposited on Ni-base single crystal superalloys. For APS-TBC system, a residual stress model for the top coat of APS-TBC was proposed and then applied to life prediction. The capability of the life model was demonstrated using temperature-dependent model parameters. Using existing life data, a comparison of fitting approaches of life model parameters was performed. The role of the residual stresses distributed at each individual coating layer was explored and their interplay on the coating’s delamination was analyzed. For EB-PVD TBCs, based on failure mechanism analysis, two newly analytical stress models from the valley position of top coat and ridge of bond coat were proposed describing stress levels generated as consequence of the coefficient of thermal expansion (CTE) mismatch between each layers. The thermal stress within TGO was evaluated based on composite material theory, where effective parameters were calculated. The lifetime prediction of EB-PVD TBCs was conducted given that the failure analysis and life model were applied to two failure modes A and B identified experimentally for thermal cyclic process. The global wavelength related to interface rumpling and its radius curvature were identified as essential parameters in life evaluation, and the life results for failure mode A were verified by existing burner rig test data. For failure mode B, the crack growth rate along the topcoat/TGO interface was calculated using the experimentally measured average interfacial fracture toughness.

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Le besoin pressant de substitution du plomb dans les alliages de soudure a conduit à une introduction très rapide de nouveaux alliages sans plomb dont la connaissance en termes de comportement n'est pas assez approfondie. En effet, d'autres problématiques sont apparues (l'augmentation de la température du procédé de soudage, trop grand choix disponible dans les alliages alternatifs) alors que les problèmes relatifs aux alliages actuels sont restés sans réponse (le changement incessant de la microstructure des alliages de soudure, la méthodologie empirique prédisant la durée de vie). Tous les paramètres cités ci-dessus modifient la stabilité et la fiabilité des performances spécifiques de l'alliage de soudure et par conséquence, de tout le module électronique.De plus, avec la miniaturisation de l'électronique et les conditions d'environnement de plus en plus sévères, ces obstacles deviennent critiques et les solutions actuelles ne sont plus compatibles. Les demandes de ce marché deviennent donc de plus en plus strictes en termes de prédiction de durée de vie et de contrôle de fiabilité.L'objectif de ce projet est de comprendre et de concevoir une nouvelle formulation d'alliage sans plomb afin de développer une alternative à l'alliage plombé haute température et un alliage pour les applications haute fiabilité et en accord avec les directives gouvernementales. Des approches expérimentales avancées comme la nano-indentation, le suivi de l'évolution de la microstructure par SEM et par EDS mapping, l'étude des effets du vieillissement thermique sur la croissance de la taille des grains avec de la lumière croisée polarisée de microscopie optique etc seront utilisées pour développer un alliage sans plomb qui convienne aux exigences des applications automobile et pipeline / The urgent need for removing lead from solder alloys led to the very fast introduction of lead-free solder alloys without a deep knowledge of their behaviour. As a consequence, additional issues raised (increased thermally induced problems during soldering process, a too wide range of possible available alternative alloy formulations), while problems related to current solder alloys remained unsolved (the constant change of the solder alloy microstructure, empirical predicting lifetime methodology). All the above mentioned issues alter stability and reliability of the application specific performances of the solder alloy, and subsequently of the whole electronic module. These problems become critical and are no longer compatible, as the market goes towards miniaturization and harsh environment conditions. These market trends now require stricter life time prediction and reliability control. Objective of this project is to understand and design a novel lead-free solder formulation to develop a potential alternative to lead-based high temperature melting point solder for high reliability requirements and in accordance with governmental directives. An advanced experimental approach like nanoindentation, microstructure evolution with SEM and EDS mapping, thermal aging effects on continuous grain size growth with cross polarized light of optical microscopy etc. would be implemented to develop doped-SAC lead-free solders for the best-fit to requirements in automotives and pipelines applications

Various anchorage systems including both cast-in-place and post-installed anchors have been developed for fastening both non-structural and structural components to concrete structures. The need for increased flexibility in the design of new structures and strengthening of existing concrete structures has led to increased use of various metallic anchors in practice. Although millions of fasteners are used each year in the construction industry around the world, knowledge of the fastening technology remains poor. In a sustainable society, buildings and structures must, from time to time, be adjusted to meet new demands. Loads on structures must, in general, be increased to comply with new demands, and the structural components and the structural connections must also be upgraded. From the structural connection point of view, the adequacy of the current fastenings for the intended increased load must be determined, and inadequate fastenings must either be replaced or upgraded. The current design models are generally believed to be conservative, although the extent of this behavior is not very clear. To address these issues, the current models must be refined to allow the design of new fastenings and also the assessment of current anchorage systems in practice. The research presented in this thesis consists of numerical and experimental studies of the load-carrying capacity of anchors in concrete structures. Two different types of anchors were studied: (I) cast-in-place headed anchors, and (II) post-installed adhesive anchors. This research focused particularly on the tensile load-carrying capacity of cast-in-place headed anchors and also on the sustained tension loading performance of post-installed adhesive anchors. The overall objective of this research was to provide knowledge for the development of improved methods of designing new fastening systems and assessing the current anchorage systems in practice. For the cast-in-place headed anchors (I), the influence of various parameters including the size of anchor head, thickness of concrete member, amount of orthogonal surface reinforcement, presence of concrete cracks, concrete compressive strength, and addition of steel fibers to concrete were studied. Among these parameters, the influence of the anchor head size, member thickness, surface reinforcement, and cracked concrete was initially evaluated via numerical analysis of headed anchors at various embedment depths. Although these parameters have considerable influence on the anchorage capacity and performance, this influence is not explicitly considered by the current design models. The numerical results showed that the tensile breakout capacity of headed anchors increases with increasing member thickness and/or increasing size of the anchor head or the use of orthogonal surface reinforcement. However, their capacity decreased considerably in cracked concrete. Based on the numerical results, the current theoretical model for the tensile breakout capacity of headed anchors was extended by incorporating several modification factors that take the influence of the investigated parameters into account. In addition, a supplementary experimental study was performed to verify the numerically obtained findings and the proposed refined model. The experimental results corresponded closely to the numerical results, both in terms of failure load and failure pattern, thereby confirming the validity of the proposed model. The validity of the model was further confirmed through experimental results reported in the literature. Additional experiments were performed to determine the influence of the concrete compressive strength and the addition of steel fiber to concrete on the anchorage capacity and performance. These experiments showed that the anchorage capacity and stiffness increase considerably with increasing concrete compressive strength, but the ductility of the anchor decreases. However, the anchorage capacity and ductility increased significantly with the addition of steel fibers to the concrete mixture. The test results also revealed that the tensile breakout capacity of headed anchors in steel fiber-reinforced concrete is significantly underestimated by the current design model. The long-term performance and creep behavior of the post-installed headed anchors (II) was evaluated from the results of long-time tests on adhesive anchors under sustained loads. In this experimental study, adhesive anchors of various sizes were subjected to various sustained load levels for up to 28 years. The anchors were also exposed to several in-service conditions including indoor temperature, variations in the outdoor temperature and humidity, wetness (i.e., water on the surface of concrete), and the presence of salt (setting accelerant) additives in the concrete. Among the tested in-service conditions, variations in the outdoor temperature and humidity had the most adverse effect on the long-term sustained loading performance of the anchors. Based on the test results, recommendations were proposed for maximum sustained load levels under various conditions. The anchors tested under indoor conditions could carry sustained loads of up to 47% of their mean ultimate short-term capacities. However, compared with these anchors, the anchors tested under outdoor conditions exhibited larger creep deformation and failure occurred at sustained loads higher than 23% of their mean ultimate short-term capacities. Salt additives in concrete and wet conditions had negligible influence on the long-term performance of the anchors, although the wet condition resulted in progressive corrosion of the steel. Based on the experimental results, the suitability of the current testing and approval provisions for qualifying adhesive anchors subjected to long-term sustained tensile loads was evaluated. The evaluations revealed that the current approval provisions are not necessarily reliable for qualifying adhesive anchors for long-term sustained loading applications. Recommendations were given for modifying the current provisions to ensure safe long-term performance of adhesive anchors under sustained loads.