No description available.

No description available.

The work outlined in this thesis describes how rheological techniques can be used to gain insight into the behaviour of complex hydrating systems. These techniques are currently used to elucidate interparticle interactions of concentrated colloidal dispersions. Those used here were stress relaxation, pulse shearometry and oscillation. These enabled parameters such as the dynamic moduli, relaxation moduli, relaxation spectrum and limiting moduli to be obtained. These all give a measure of the strength of interaction of the colloidal system under different conditions, without reducing these interactions by inducing flow. Calorimetric data was obtained for a hydrating cement paste. The particle and floc size of this cement was also measured. The data were found to be in accord with one another, and with current theories of the hydration processes of cement. In combination with the rheological parameters measured this enabled the extent and strength of attraction between the particles of a cement paste to be determined, as a function of the age of the paste. The adsorption characteristics of surfactant on cement were measured, as was the effect of surfactant on the particle and floc size of hydrating cement. Coupled with a measure of the rheological parameters of the cement-surfactant system, an understanding of the effect of surfactant on a hydrating cement paste was obtained. Similarly the effect of the addition of styrene-butadiene polymer latex particles, with and without excess added surfactant, was able to be determined. This information was obtained for hydrating cement pastes, both in the presence and absence of added polymer, at both ambient and non-ambient temperatures.

No description available.

The objective of this research was the development of an efficient method for the preparation of silver-polymer nanocomposites containing finely dispersed silver nanoparticles. The surface of nanosilver was functionalized by thiolation with 2-aminoethanethiol. Amino-modified nanosilver was covalently bonded to polyacrylic acid, biodegradable polymers like acid terminated polylactic acid, ester terminated poly(DL-lactide-co-glycolide) and acid terminated poly(DL lactide-co-glycolide) in the presence of diisopropylcarbodiimide by carbodiimide method. Esterification of the carboxyl groups of Ag-polyacrylic acid by hydrochloric acid in methanol resulted in the formation of a stable colloidal dispersion of Ag nanoparticles in the polymer matrix. It was observed that not just acid terminated polymers but also ester terminated polymers could react with functionalized nanosilver. This unusual reaction was due to the aminolysis of the ester bond in the polymer chain by the surface amino groups. Silver-polymer nanocomposites obtained with acid terminated polylactic acid and poly(DL-lactide-co-glycolide) contained highly dispersed nanosilver in the polymer matrix in comparison with the ester terminated poly(DL-lactide-co-glycolide). Chemical and structural characteristics of the obtained materials were studied by instrumental methods. Attained biodegradable materials confirmed X-ray contrast and bactericidal properties, which could be eventually used for biomedical applications.

No description available.

Silver-polymer composite material containing highly dispersed silver nanoparticles (AgNPs) of 20-100. nm diameter can be obtained from bare nanosilver. The synthesis consists of three steps. The first step is modification of AgNPs by 2-aminoethanethiol. Second, polyacrylic acid is bonded to the silver 2-aminoethanethiolate by the carbodiimide method. Then esterification of the remaining carboxyl groups of the product by methanol results in formation of a stable colloidal dispersion of AgNPs in the polymer matrix. The method allows obtaining of nanocomposites with silver contents up to 1.4. wt%.

Over fifty small sinkholes (~1 meter in depth and width) were found in conjunction with structural damage to homes in an area south of Cleveland, TX. The local geology lacks carbonate and evaporite deposits associated with normal sinkhole development through dissolution. The morphology and distribution of sinkholes, and the geologic setting of the site are consistent with piping erosion. However, the site lacked the significant hydraulic gradient or exit points for sediment associated with traditional piping erosion. In areas of sinkholes, geophysical measurements of apparent electrical conductivity delineated anomalously high conductivity levels that are interpreted as a brine release from a nearby oil-field waste injection well. The contaminated areas have sodium adsorption ratios (SAR) as high as 19, compared to background levels of 3. Sodium has been shown to cause dispersion of soil colloids, allowing for sediment transport at very low velocities. Thus, subsurface erosion of dispersed sediment could be possible without significant hydraulic gradients. This hypothesis is backed by the observation of the depletion of colloidal particles within the E-horizon of sinkholes. However, there is a lack of precedence of waste brines initiating colloid dispersion. Also, sodium dispersion is not thought to be an important process in piping erosion in humid settings such as this one. Therefore, laboratory experiments on samples from the site area, designed to simulate field conditions, were conducted to measure dispersion verses pH, SAR and electrical conductivity (EC). Analysis of the experimental data with neural networks showed that an increase in SAR did increase dispersion. A dispersion prediction map, constructed with the trained neural network and calibrated geophysical data, showed correlation between sinkhole locations and increased predicted dispersion. This research indicates that a contaminant high in sodium content has caused colloidal dispersion, which may have allowed nontraditional subsurface erosion to occur in an area lacking a significant hydraulic gradient.

Over fifty small sinkholes (~1 meter in depth and width) were found in conjunction with structural damage to homes in an area south of Cleveland, TX. The local geology lacks carbonate and evaporite deposits associated with normal sinkhole development through dissolution. The morphology and distribution of sinkholes, and the geologic setting of the site are consistent with piping erosion. However, the site lacked the significant hydraulic gradient or exit points for sediment associated with traditional piping erosion. In areas of sinkholes, geophysical measurements of apparent electrical conductivity delineated anomalously high conductivity levels that are interpreted as a brine release from a nearby oil-field waste injection well. The contaminated areas have sodium adsorption ratios (SAR) as high as 19, compared to background levels of 3. Sodium has been shown to cause dispersion of soil colloids, allowing for sediment transport at very low velocities. Thus, subsurface erosion of dispersed sediment could be possible without significant hydraulic gradients. This hypothesis is backed by the observation of the depletion of colloidal particles within the E-horizon of sinkholes. However, there is a lack of precedence of waste brines initiating colloid dispersion. Also, sodium dispersion is not thought to be an important process in piping erosion in humid settings such as this one. Therefore, laboratory experiments on samples from the site area, designed to simulate field conditions, were conducted to measure dispersion verses pH, SAR and electrical conductivity (EC). Analysis of the experimental data with neural networks showed that an increase in SAR did increase dispersion. A dispersion prediction map, constructed with the trained neural network and calibrated geophysical data, showed correlation between sinkhole locations and increased predicted dispersion. This research indicates that a contaminant high in sodium content has caused colloidal dispersion, which may have allowed nontraditional subsurface erosion to occur in an area lacking a significant hydraulic gradient.

Liquid crystals (LCs) are an interesting class of materials that are attracting significant attention due to their ever-growing applications in a wide variety of fields such as liquid crystal display (LCD) technology, materials science and bioscience. In recent years, along with the developments of materials at the nanoscale, doping LCs with nanoparticles (NPs) has emerged as a very promising approach for improving LC properties. Nanoparticle additives can introduce novel effects on optical and electro-optical properties of nematic liquid crystals (N-LCs), such as altered molecular alignment, faster response time and increased efficiency. This thesis studies the impacts that the inclusion of metallic NPs made of gold or semiconductor CdSe quantum dots (QDs), have on optical and electro-optical properties of N-LCs. Using polarized optical microscopy and detailed capacitance and transmittance measurements of nematic mixtures in electro-optic test cells, characteristics such as optical texture, phase transition temperatures, switching voltages and dielectric anisotropy are investigated in pure as well as doped samples. Surface ligands in NPs and their chemical functionalization play an important role in the LC-NP interactions, largely by determining the dispersibility of NPs and stability of the nanocomposites. One important objective of this thesis is to investigate and prepare a series of gold nanoparticles (Au NPs) with specially formulated robust coatings that maximizes solubility and stability in LC medium. Silanization of NPs is developed as a method to overcome the stability challenge. The functionalization of silanized NPs with aliphatic ligands or liquid crystalline molecules, provides chemically and thermally stable NPs with hydrophobic and structurally compatible surfaces required for dispersion in N-LCs. After complete characterization the synthesized particles are used to make the new nematic nanocomposites. By analysis of the structure-property relationships governing LC-nanomaterial composites and by comparison of new results and data from previous studies on other types of NPs, this thesis will further reveal the mechanism of the interrelations between host LC molecules and NP, considering the role of variables such as core composition, size and surface chemistry of NPs (e.g. siloxane shell, aliphatic ligand vs. liquid crystalline ligand) in achieving stable LC composites with desired optical and electro-optical properties.