Spelling suggestions: "subject:"composite electrodes"" "subject:"eomposite electrodes""
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Development of Cathode Catalysts for the Production of Synthesis Gas and Ammonia in Solid Oxide Electrolysis CellsDeka, Dhruba Jyoti January 2020 (has links)
No description available.
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Développement d'accumulateurs Li/S / Development of lithium-sulfur batteriesBarchasz, Céline 25 October 2011 (has links)
Ces travaux ont permis d’approfondir les connaissances du mécanisme de déchargepeu conventionnel de l’accumulateur Li/S et de ses limitations. L’ensemble desrésultats a convergé vers une unique conclusion, à savoir que le système Li/S estprincipalement limité par le phénomène de passivation de l’électrode positive en finde décharge. Les polysulfures de lithium à chaines courtes précipitent à la surface del’électrode positive de soufre. Isolants électroniques, ils sont responsables de la perteprogressive de surface active de l’électrode et de la fin prématurée de la décharge.Ainsi, les performances électrochimiques ont pu être significativement améliorées entravaillant sur la morphologie de l’électrode positive, et sur la composition del’électrolyte. En augmentant la surface spécifique de l’électrode, la quantité depolysulfures de lithium qui peut précipiter en fin de décharge est augmentée, et lapassivation totale de l’électrode est retardée. En augmentant la solubilité despolysulfures de lithium dans l’électrolyte, la précipitation des espèces est retardée etla décharge prolongée. Dans cette optique, les solvants de type PEGDME semblentêtre les plus prometteurs à ce jour. Enfin, un mécanisme possible de réduction dusoufre en électrolyte de type éther a pu être proposé. / This work aimed at better understanding the Li/S cell discharge mechanism and itslimiting parameters. A general conclusion was following from these data: the Li/Ssystem is mainly limited by the passivation process of the sulfur positive electrode,occurring at the end of discharge. Insulating lithium polysulfides precipitate on thepositive electrode surface, thus leading to a gradual loss of the electrode activesurface and to the early end of discharge. As a consequence, the electrochemicalperformances can be significantly improved by working either on the positiveelectrode morphology or on the organic electrolyte composition. Increasing thespecific surface of the positive electrode enables to increase the amount ofpolysulfide compounds that can precipitate on the electrode, thus delaying the fullpassivation of the sulfur electrode and the end of discharge. Working on the organicelectrolyte composition enables to increase the polysulfide solubility and to preventthem from quickly precipitating, thus delaying the end of discharge too. To thispurpose, PEGDME solvents seem to be quite promising. Finally, a possiblemechanism for sulfur reduction in ether-based electrolytes could be proposed.
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Development of covalent organic frameworks for energy storage applications : DAAQ-TFP COF and MXene composite electrodes for proton cyclingSingh, Simanjit January 2022 (has links)
The demand for today's material resources for energy storage is rapidly increasing and can result in both environmental and political conflicts that can affect the development of electronic devices due to high prices and limitations of raw materials for batteries. In this study, potential future composite electrodes were synthesised with an ex-situ approach by compositing redox-active 2,6-Diaminoanthraquinone and 1,3,5-Triformylphloroglucinol covalent organic framework (DAAQ-TFP COF) with conductive delaminated Ti3C2Tx MXene to maximise the number of redox-active moieties during cycling. In addition, solvothermal synthesis with the implementation of mechanical grinding as an exfoliation method was used to try to obtain DAAQ-TFP nanosheets to increase both the contact area between the two materials and the number of charge carriers. The sample was analysed with PXRD and BET surface analysis to characterise the crystallinity meanwhile SEM was utilised to study the morphology of the COF and the composite material. The specific capacitance of each electrode was estimated by cyclic voltammetry. The study showed a decrease in reduced specific capacitance with lower MXene content. Hence, this concludes pure Ti3C2Tx sheets have the highest capacitance contribution with a value of 48.79 Fg-1 meanwhile the composite electrode with a ratio of 1:1 was estimated to 32.26 Fg-1 with 0.0928 % of its moieties undergoing a redox reaction. A reduced capacitance with an increased COF-MXene ratio indicates that MXene contributes with more capacity relative to the COF, in combination with a non-successful exfoliation of DAAQ-TFP to single-layered nanosheets, reducing the interactions between the two materials.
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