>Magister Scientiae - MSc / Phase change material (PCM) through latent heat of molten salt, is a convincing way for thermal energy storage in CSP applications due to its high volume density. Molten salt, with (60% NaNO3 and 40% KNO3) has been used extensively for energy storage however; the low thermal conductivity and specific heat have limited its large implementation in solar applications. For that, molten salt with the additive of silver nanowires (AgNWs) was synthesized and characterized. This research project aims to investigate the thermophysical properties enhancement of nanosalt (Mixture of molten salt and silver nanowires). The results obtained showed that by simply adjusting the temperature, Silver nanowires with high aspect ratio have been synthesized through the enhanced PVP polyol process method. SEM results revealed a network of silver nanowires and TEM results confirmed the presence of silver nanowires with an average diameter of 129 nm and 16 μm in length.

Solar energy is of huge interest due to the current situation with global warming. A number of solar technologies have been developed, such as photovoltaic, concentrated solar power, and solar water heating systems, to name a few. However, the technologies are being slowly implemented, and Botswana, with generous amounts of sun, is particularly suitable for solar energy. The opportunities were investigated due to the overwhelming and horrifying warnings echoed by many of the world's scientists regarding global warming. First, a handful of solar technologies were thoroughly investigated. A field study at Gakgatla village was then conducted, where the locals were interviewed. The interviews were analyzed, and solutions were suggested based on the identified needs of the locals. The biggest challenges identified were the lack of electricity in many of the households, parental figures not being supportive of the children's education, and theft. Additionally, many locals cooked with firewood. The most helpful solution but difficult to implement is photovoltaic panels. Solar water heating systems would also be helpful to the locals who predominantly had cold water. Additionally, solar cookers could help minimize exposure to hazardous smoke. Lastly, solar lamps could help students study during nighttime. Some locals also showed huge enthusiasm for what the future partnership with Botho University will bring. It is encouraged to develop a prototype of a solar cooker, particularly the parabolic solar cooker, in order to install solar cookers in Gakgatla village. Solar dryers would also greatly benefit the locals and are also suggested developments. Both of the mentioned solutions would help minimize the locals' exposure to the hazards of cooking with firewood. The solar dryers will also help eliminate bacteria by drying the food in a protected space inside a container.

One of the key challenges the world will need to face during the 21st century is global warming and the consequent climate change. Its presence is indisputable, and decarbonizing the gird emerges as one of the required pathways to achieve global sustainable objectives. Solar energy power plants have the potential to revert this situation and solve the problem. One way to harness this energy is through Concentrated Solar Power plants. The major advantage and potential of this technology is its ability to integrate cost-effective Thermal Energy Storage (TES), which is key with such an inherently intermittent resource. On the other hand, the drawback is the high current Levelized Cost of Energy (LCOE). The other main way to harness that highlighted solar energy is the use of Photovoltaic panels, which have recently achieved very competitive LCOE values. On the other hand, the storage integration is still a very pricey option, normally done with Battery Energy Storage Systems (BESS). As a conclusion, a hybrid power plant combining the LCOE of the PV and the TES of the CSP emerges as the key way of achieving a very competitive solution with a big potential. This master thesis aims at exploring the possibilities of a hybrid CSP and PV power plant with a sCO2 power cycle, integrated in the primary, secondary and tertiary electricity markets. To achieve this purpose, firstly, a Python-based Energy Dispatcher was developed to control the hybrid power plant. Indeed, the Dispatcher is the tool that decides when to produce, when to store… following an optimization problem. This can be formulated mathematically, and that was done and integrated into the Python code using Pyomo, a software for optimization problems. As a result, the Dispatcher achieved an effective control of the plant, showing intelligent decisions in detailed hourly analyses. The results were very promising and included optimization functions as maximizing the profitability of the plant or the total production, among others. To proceed with the Techno-economic assessment of the hybrid plant, the electricity markets were studied. The main source of income of any power plant is normally the revenue from selling electricity to the grid, but since there are several markets, there are also other possibilities. In this thesis, it was assessed from a Techno-Economic perspective how the performance and optimal design of the plants vary when providing different services extra to selling electricity to the grid. The conclusion was that even though the Net Present Value (NPV) achieved working on the spot market was already very high, the extra value added from participating in the secondary or tertiary markets was indisputable. Indeed, the profits attained in those markets were between two and four times higher than the ones of the spot market. This is a specific case, but a trend was identified: these hybrid power plants have a huge possibility and a bright future on the service markets. As a consequence, this thesis shows the huge potential of hybrid power plants integrated in the grid participating in several markets. It also lays the foundation for future studies in other locations, under different conditions and with different technologies, among others.

<p>  </p> <p>Concentrated solar power (CSP) is a technology that utilizes focused sunlight to heat a high-temperature medium (such as a molten salt). Heat from this medium can be transferred to a working fluid (such as supercritical CO2) that is then used to drive a turbine to generate electricity. Alternatively, the hot medium/fluid can be pumped into tanks for thermal energy storage (TES), for heat extraction later to generate dispatchable electricity and/or for electricity production at night or on cloudy days. By increasing the fluid temperature to <u>></u>750oC and utilizing TES, CSP can become more cost competitive with fossil-based electricity production. Current CSP systems utilize molten nitrate salts for heat transfer and TES that are known to thermally degrade at temperatures >600oC. To achieve temperatures <u>></u>750oC, molten chloride salts, such as ternary MgCl2-KCl-NaCl compositions, are being considered as heat transfer and thermal energy fluids for next generation CSP plants due to their higher temperature stability, low cost, and availability. </p> <p>In this work, it was demonstrated that MgCl2-containing molten salts are prone to oxidation in ambient air at 750oC, which can enhance corrosion of the containment materials and alter the thermophysical properties of the fluid. An alternative, low-cost, earth-abundant, MgCl2-free, oxidation-resistant molten salt, a eutectic CaCl2-NaCl composition, was developed, along with a corrosion mitigation strategy, to enable the slow growth of protective oxide layers on metals that are resistant to dissolution by such MgCl2-free molten chloride salts. </p> <p>This strategy was expanded to other low-cost, oxidation resistant compositions, such as eutectic BaCl2-CaCl2-KCl-NaCl with tailored chemical and thermophysical properties for CSP and TES. The melting temperature, heat capacity, oxidation resistance, and crystallization behavior were measured for eutectic a BaCl2-CaCl2-KCl-NaCl(17.5-47.8-3.3-31.4 mol%) (BCKN) salt and a MgCl2-KCl-NaCl (40-40-20 mol%) salt. BCKN salt was shown to have a similar melting temperature while having a higher heat capacity and far better oxidation resistance. </p> <p>The corrosion of the nickel-based superalloy Haynes 214 was studied in molten MgCl2-KCl-NaCl (40-40-20 mol%) salt at 750oC under inert atmosphere conditions using a custom-built rotating-disc corrosion testing apparatus that maintained laminar fluid flow on the sample. Non-protective external Cr-, Al-, and Mg- oxide layers were formed on Haynes 214 that were prone to spallation. Internal oxidation of Al was also observed along with Cr depletion zones within Haynes 214.  Corrosion kinetics were evaluated to quantify the role of fluid flow for application of this alloy for use in containment and transportation of this molten chloride salt. </p>

Recently, the supercritical carbon dioxide (s-CO2) Brayton cycle has been identified as a promising candidate for solar-thermal energy conversion due to its potentially high thermal efficiency (50%, for turbine inlet temperatures of ~ 1000 K). Realization of such a system requires development of solar receivers which can raise the temperature of s-CO2 by over 200 K, to a receiver outlet temperature of 1000 K. Volumetric receivers are an attractive alternative to tubular receivers due to their geometry, functionality and reduced thermal losses. A concept of a ceramic pressurized volumetric receiver for s-CO2 has been developed in this work. Computational Fluid Dynamics (CFD) analysis along with a Discrete Ordinate method (DOM) radiation heat transfer model has been carried out, and the results for temperature distribution in the receiver and the resulting thermal efficiency are presented. Issues regarding material selection for the absorber structure, window, coating, receiver body and insulation are also addressed. A modular small scale prototype with 0.5 kWth solar heat input has been designed. The design of a small scale s-CO2 loop for testing this receiver module is also presented in this work. There is a lot of ongoing investigation for design and simulation of different configurations of heat exchangers and solar receivers using s-CO2 as the working fluid, in which wall temperatures up to 1000 K are encountered. While CO2 is considered to be transparent as far as solar radiation spectrum is concerned, there may be considerable absorption of radiation in the longer wavelength range associated with radiation emission from the heated cavity walls and tubes inside the receivers. An attempt has been made, in this study, to include radiation modelling to capture the effect of absorption bands of s-CO2 and the radiative heat transfer among the equipment surfaces. As a case study, a numerical study has been performed to evaluate the contribution of radiative heat transfer as compared to convection and conduction, for s-CO2 flow through a circular pipe. The intent is to provide a guideline for future research to determine the conditions for which radiation heat transfer modelling inside the pipe can be significant, and what errors can be expected otherwise. The effect of parameters such as Reynolds number, pipe diameter, length to diameter ratio, wall emissivity and total wall heat flux has been studied. The effect of radiation modelling on wall temperatures attained for certain amount of heat flux to be transferred to s-CO2 is also studied. The resulting temperature distribution, in turn, affects the estimation of heat loss to the environment

Nowadays, one of the solutions considered in order to face the issue of global warming and to move towards a carbon neutral society relies on the use of solar energy as a renewable and bountiful primary source. And, if photovoltaic technologies account for a large part in the solar energy market, recent years have witnessed the growth of non-concentrated and concentrated solar thermal technologies. Among them, concentrated solar power technology (CSP) which uses the optical concentration of direct solar irradiation to generate high pressure and high temperature steam in the absorber tubes of the plant, has become a promising approach reaching 4.9 GWe of installed capacity by the end of 2015 [1]. However, one of the main challenges faced by CSP technology concerns the variability of solar energy related for example to sunrise, sunset, passing clouds… In addition to that, when it comes to direct steam generation, the presence of a two-phase flow regime inside the absorber tubes leads to a strong dynamic behavior of the steam generation. It is consequently necessary to be able to simulate this dynamic behavior in order to better handle the design and operation of CSP plants. Such simulation tools can then be used for the implementation and the test of reliable control systems aimed at maintaining desired operating conditions in spite of changes in solar irradiation. In this context, the National Institute for Solar Energy (INES), part of the French Alternative Energies and Atomic Energy Commission (CEA) wishes to upgrade their dynamic simulation tool that would enable its teams to reproduce the behavior of a prototype based on the Fresnel solar field technology including direct steam generation which was built and commissioned at Cadarache, Aix-en-Provence. This Master thesis work takes place within this framework and aims at developing a multi-domain dynamic model of the aforementioned prototype. To do so, three models respectively in the thermalhydraulic, the optical and the control-command domains are built and combined using a co-simulation approach relying on an in-house simulation platform called PEGASE. More specifically the development of the following models has been addressed:  a thermal-hydraulic model of the two-phase flow circulating inside the vaporizer field of the prototype and realized with the thermal-hydraulic code CATHARE [2] (Advanced ThermalHydraulic Code for Water Reactor Accidents) applied to solar thermal biphasic issues,  an optical model of the receiver programmed using the Modelica language and the Dymola (Dynamic Modelling Laboratory) simulation software,  control-command models (PID controller, control architecture…) adapted and built upon blocks taken from a modelling library included in the PEGASE platform. Each model was first developed and tested on a standalone basis. These models were then coupled using the PEGASE co-simulation platform. A sunny day was simulated using the multi-domain model and the controllability of the plant was analyzed. At this stage, the study focused on the steam separator level regulation. A thermal-hydraulic study also focused on potential instabilities in the vaporizer that can occur under certain circumstances of water temperature at vaporizer inlet and solar heat flux. This analysis was carried out with a CATHARE standalone model. Perspectives of the present work include a complete validation of the developed models from future experimental data and further developments should aim to extend the modelling scope of the numerical simulator towards a representation of all the hydraulic parts of the CSP prototype. Control schemes and regulation tools would have to be extended as well in order to move towards a more representative control architecture of the prototype. Particularly, the steam quality at vaporizer outlet is an important variable to regulate. Indeed, this parameter is usually kept between 60% and 80% [3]. It must be high enough to limit the power consumption of the recirculation pump but not too high in order to prevent absorber dry-out. / Solenergi, som är en förnybar och riklig primärkälla, är en av de lösningarna som anses kunna lösa problemet med global uppvärmning och bidrar i omvandlingen till ett kolneutralt samhälle. Andelen fotovoltaiska teknologier på energimarknaden är övervägande, men andelen koncentrerad och ickekoncentrerad solterminsteknik har ökat under de senaste åren. Bland solterminsteknikerna är koncentrerad solenergiteknik (CSP), som använder den optiska koncentrationen av direkt strålning för att generera högtrycks- och högtemperaturånga i anläggningens absorberarrör, ett lovande tillvägagångssätt som har nått 4.9 GWe installerad kapacitet i slutet av 2015 [1]. En av de största utmaningarna med CSP-tekniken är solenergins variation vid till exempel soluppgång, solnedgång och passerande moln, vilket beror på varierad tillgång av solljus. Det finns också utmaningar med direkt ånggenerering via tvåfasflödes regimer inuti absorberarrören eftersom det leder till ett starkt dynamiskt beteende vid ånggenereringen. Det är följaktligen nödvändigt att kunna simulera detta dynamiska beteende för att bättre hantera design och drift av CSP-anläggningar. Sådana simuleringsverktyg kan sedan användas för att genomföra tester för att erhålla tillförlitliga styrsystem som upprätthåller önskade driftsförhållanden trots förändringar i solstrålningen I detta sammanhang vill National Institute for Solar Energy (INES), som är en del av den franska alternativa energikommissionen och atomenergi kommissionen (CEA), förbättra dess dynamiskt simuleringsverktyg som skulle möjliggöra för sina team att reproducera beteendet hos en prototyp baserad på Fresnel solfältsteknik inklusive direkt ånggenerering som byggts och beställts vid Cadarache, Aix-enProvence. Denna masteruppsats sker inom ramen för detta och syftar till att utveckla en dynamisk modell med flera domäner av den ovan nämnda prototypen. Tre modeller i termisk-hydraulisk, optisk och kontrollkommando domäner har byggts och kombinerats med hjälp av en co-simuleringsmetod som bygger på en intern simuleringsplattform som heter PEGASE. Mer specifikt om utvecklingen av modellerna enligt nedan:  En termisk-hydraulisk modell av tvåfasflöde som cirkulerar inuti förångarens fält på prototypen har realiserats med termisk-hydraulisk kod CATHARE [2] (Advanced Thermal-Hydraulic Code for Water Reactor Accidents) som appliceras på soltermisk bifasiska frågeställningar.  En optisk modell av mottagaren har programmerats med hjälp av Modelica-språket och simuleringsprogrammet Dymola (Dynamic Modeling Laboratory).  Modeller av kontrollkommandon (PID-kontroller, kontrollarkitektur ...) har byggts och anpassats i moduler som hämtats från modelleringsbibliotek som ingår i PEGASE-plattformen. Varje modell utvecklades och testades på fristående basis. Modellerna kopplades sedan samman i PEGASE-co-simuleringsplattformen. En solig dag simulerades därefter med en flerdomänmodell och styrningsförmågan av anläggningen analyserades. Vid detta stadium fokuserade studien på att reglera nivån av ångseparerande. En termisk-hydraulisk studie fokuserade sedan på potentiella instabiliteter i förångaren som kan uppstå under vissa omständigheter av vatteninloppstemperatur och solvärmeflöde. Denna analys genomfördes med en CATHARE fristående modell. Perspektiven för det aktuella arbetet omfattar en fullständig validering av de utvecklade modellerna med hjälp av framtida experimentella data. Vid en vidareutveckling bör inriktningen vara att utvidga modellernas omfattning av den numeriska simulatorn till att representera alla hydrauliska delar av CSP prototypen. Styrsystem och regleringsverktyg skulle också behöva förbättras för att få en mer representativ kontroll arkitektur av prototypen. I synnerhet är ångkvaliteten vid förångarens utlopp en viktig variabel att reglera. Faktum är att den här parametern vanligtvis hålls mellan 60% och 80% [3]. Det måste vara tillräckligt högt för att begränsa recirkulationspumpens elförbrukning men inte för hög för att förhindra att absorberen torkar ut.