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Electroplating of selective surfaces for concentrating solar collectorsZäll, Erik January 2017 (has links)
The optical properties of the absorber pipe in a parabolic trough collector isessential for the performance of the solar collector. The desirable propertiesare high absorptance (α) of solar radiation and low emittance (ε) of thermalradiation. A surface with these properties is known as a solar selective surface. There are several techniques used to produce selective surfaces, but one of the most common ones is electroplating. Research done by Vargas, indicates that optical properties of α = 0.98 and ε = 0.03 [1], which is superior to the best commercial alternatives (α = 0.95 and ε = 0.04 [2]), can be achieved by electroplating a Co-Cr coating on a stainless steel substrate. Additionally, Vargas used an electrolyte of trivalent chromium dissolved in a deep eutectic solvent, as opposed to the traditionally used aqueous electrolytes containing hexavalent chromium, which is toxic and carcinogenic. In this project, a coating of Co-Cr was electroplated on a stainless steel substratewith a method similar to that of Vargas in order to obtain a solar selective surface. The electrolyte was composed of ethylene glycol, choline chloride, CrCl3•6H2O and CoCl2•6H2O in a molar ratio of 16:1:0.4:0.2. The plating process was conducted using chronoamperometric electrodeposition with an applied potential of -1.2 V (against an Ag/AgCl reference electrode) for 15 min. The system was investigated using Cyclic Voltammetry (CV). The total absorptance was measured using UV-Vis spectroscopy, while the emittance was measured using an IR-thermometer. The microstructure and chemical composition was investigated using Scanning ElectronMicroscopy (SEM), Focused Ion Beam (FIB), Energy-Dispersive X-ray Spectroscopy (EDS), X-ray Photoelectron Spectroscopy (XPS) and Raman spectroscopy. The thermal stability of the coating was investigated by exposingit to 400°C in air for 24 h. The electroplated coating is approximately 2.8 μm thick and exhibits a porousstructure with a surface of fine fiber-like flakes. The coating consists largely of Co hydroxides with low concentrations of Cr compounds, Co oxides and metallic Co. Hence, a satisfactory co-deposition was not accomplished, as the Cr concentration is low. The coating is not thermally stable up to 400°C, exhibiting signs of at least partially melting in the annealing process. The compounds in the coating were largely oxidized in the process. The electroplated surface does however exhibits strong selectivity, with a total solar absorptance of α = 0.952 and total emittance of ε = 0.32 at 160°C.
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Concentrating Collector for Torsång District Heating SystemFilatov, Artem January 2018 (has links)
In this thesis report for Dalarna University in Borlange and Absolicon company the study of a possibility to add an array of concentrating solar collectors to a Torsång district heating system was done. The whole idea of this work was to make a simulation of this kind of system, trying to get 15-20% of solar fraction, and make an economical evaluation. At the same time, another goal was to make two comparisons: between concentrating and flat-plate collector in the same system, and between two tools for collector analysis – Polysun and Absolicon tool, based on TRNSYS, which was designed to estimate the output of the collector for a certain temperature, without any load. During the study, the analysis of the simulating tools was made and the combination of those two tools was used. Using long iteration cycles, involving changing the field layout, number of collectors and distance between collector rows in flat-plate collector case, both types of collectors were analyzed. The method of the analysis was to get an equal output of the field and see the differences, which appear while using different collector types.
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Evaluation of Convection Suppressor for Concentrating Solar Collectors with a Parabolic Trough / Utvärdering av konvektionsreducerare för koncentrerande solfångare med ett paraboliskt trågNyberg, Fanny January 2018 (has links)
Absolicon Solar Collector AB in Härnösand, Sweden, develops concentrating solar collectors with a parabolic trough. In the solar collector trough, there is thermal loss due to convection. A convection suppressor was made and used as a method to reduce thermal loss due to convection in the trough. The objective of the project was to evaluate the convection suppressor for solar collectors with a parabolic trough and its impact on the performance (thermal loss characteristics) in two different orientations of the trough, horizontal and inclined. The performance of the solar collector was first measured without the convection suppressor; these results were compared to two previous quasi-dynamical tests of the solar collector performance made by two different institutes, Research Institute of Sweden and SPF Institut für Solartechnik (Switzerland). The comparison was made to validate the test results from the tests without the convection suppressor, which matched. Secondly, when the convection suppressor was made and tested in the two different orientations, the results of the performance with and without the convection suppressor was evaluated as well as the convection suppressor itself. The results showed a significant improvement of the solar collector performance in the aspect of reduced thermal loss when the convection suppressor was used, hence higher efficiency. / Absolicon Solar Collector AB I Härnösand, Sverige, utvecklar koncentrerande solfångare med ett paraboliskt tråg. I solfångarens tråg uppstår termiska förluster som en följd av konvektion. En konvektionsreducerare tillverkades och användes som metod för att minska de termiska förlusterna i tråget. Målet med projektet var att testa och utvärdera konvektionsreduceraren för koncentrerande solfångare med ett paraboliskt tråg samt dess inverkan på verkningsgraden i två olika positioner för tråget, horisontell och lutande. För att kunna mäta konvektionsreducerarens inverkan på solfångaren mättes först solfångarens prestanda utan konvektionsreduceraren i de två olika positionerna, detta resultat användes som referens efter validering. Valideringen gjordes genom att resultatet jämfördes sedan med två andra prestandamätningar (quasi-dynamical test) av solfångaren gjorda av två olika institut, Research Institute of Sweden och SPF Institut für Solartechnik (Schweiz). Därefter, när konvektionsreduceraren var tillverkat och testad i de olika positionerna på samma sätt som mätningarna utan konvektionsreducerare, jämfördes resultaten med och utan konvektionsreducerareet samt att en utvärdering gjordes av dess inverkan. Resultatet visade en signifikant förbättring av solfångarens prestanda i form av minskade termiska förluster när konvektionsreduceraren användes och därav ökad verkningsgrad.
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