Ce travail avait pour but de reconstituer l'évolution de la température et du δ¹⁸O des eaux de surface et des eaux de la thermocline dans la Warmpool indo-pacifique (IPWP) en combinant la thermométrie Mg / Ca et la mesure des isotopes stables de l'oxygène sur des foraminifères planctoniques de surface et de sub-surface prélevés dans des carottes de sédiments situées dans l'océan Indien tropical oriental. Ce travail a permis de ré-évaluer les effets des différentes méthodes de nettoyage et de la dissolution in situ sur la thermométrie Mg/Ca des foraminifères planctoniques, mettant en évidence la nécessité de corrections différentes suivant les espèces. L’évolution de l’IPWP au cours des 270 000 dernières années a été reconstituée. Les résultats indiquent que le δ¹⁸O des eaux de surface reflètent principalement l'advection latérale plutôt que l'historique des précipitations régionales, et suggèrent que l'hydrologie de surface IPWP est contrôlée par la migration latitudinale de la zone de convergence intertropicale aux échelles de temps orbitales mais aussi en réponse aux événements climatiques abrupts de l'hémisphère nord (eg. événements de Heinrich). Les variations de salinité de surface sont étroitement corrélées aux changements d’export vers l’Atlantique au niveau du Courant des Aiguilles (Sud de l’Afrique). Puis, les changements dans le transport des eaux de la thermocline issues de l’ITF vers l'océan Indien ont été étudiés. Les résultats montrent que le transport était plus faible pendant les glaciations (ie. MIS 6 et 4-2) que pendant les périodes interglaciaires (ie. MIS 7, MIS 5 et Holocène) et exerçaient une influence significative sur les changements de la température de la thermocline dans l'Océan Indien. / This work aimed at reconstructing the late Quaternary evolution of surface and thermocline temperature and ocean surface water δ¹⁸O in the Indo-Pacific Warm Pool by combining Mg/Ca-thermometry and stable oxygen isotope analyses on surface and thermocline-dwelling planktonic foraminifers retrieved from sediment cores in the eastern tropical Indian Ocean. This study allowed to re-evaluate the effects of different cleaning methods and in-situ dissolution on the Mg-thermometry of planktonic foraminifers, evidencing the need for species-dependent corrections. Then, the IPWP evolution over the last 270,000 years has been explored. Results indicate that surface water δ¹⁸O chiefly reflects lateral advection rather than local precipitation history, and suggest that surface IPWP hydrology is controlled by the latitudinal migration of the Intertropical Convergence Zone at orbital timescale as well as during abrupt northern hemisphere climatic events (i.e. Heinrich events). Ocean surface salinity in the IPWP and Agulhas leakage region varied synchronously, implying their teleconnection through oceanic and atmospheric circulation. Moreover, changes in the transport of thermocline water to the Indian Ocean by the Indonesian Throughflow (ITF) have been reconstructed. Results show that thermocline water transport was weaker during glacials (i.e. MIS 6 and 4-2) than during interglacials (MIS 7, MIS 5 and Holocene), and exerted significant influence on Indian Ocean TWT change.

The main aim of this research is to improve our knowledge of the sea breeze circulation in the complex coastal environments, where more than one mesoscale circulations occur. Interaction of these circulations with each other and with external factors such as topographical features and large scale winds leads to pronounced changes in the thermodynamic structure of the boundary layer. The variations in sea breeze circulation also have distinct effect on the pollutant transport and dispersion mechanisms in the coastal urban areas. In this research, dynamic and thermodynamic characteristics of the sea breeze circulation and their associated air pollution potential have been investigated by utilizing observational data for two summer periods and numerical modelling techniques. Effect of some external factors such as gradient flow and terrain elevation has also been examined. Observed meteorological and air quality data was obtained from a number of monitoring sites within and around Auckland while Advanced Weather Research & Forecasting (WRF) and ‘The Air Pollution Model’ (TAPM) were employed to simulate meteorology and pollutant dispersion in Auckland. WRF is used to investigate the thermally induced mesoscale circulation while TAPM has been employed to examine the pollutant dispersion in the region. Both models were validated against observed data from six different sites within Auckland. Validation results of WRF and TAPM are also compared with surface meteorology. Validation and inter-comparison of the two models show that WRF performed better than TAPM for all the surface meteorology variables. WRF showed a positive bias in predicted winds speed and relative humidity and a cold bias in the near surface Temperature. TAPM on the other hand under-predicted surface winds, while near surface temperature and relative humidity are similar to WRF. Results show that the sea breeze occurred around 20% of the two summer periods of 2006 and 2007. Both observed data analysis and the numerical modelling results confirmed the existence of two thermally induced systems in the Auckland region. Bay breezes are initiated in the morning hours (0800 – 1000 hours) from small bodies of water (Manukau, Waitemata, and Kaipara Harbour, and along the Hauraki Gulf coastline), followed by mature sea breezes from the main bodies of water (Tasman Sea and larger Hauraki Gulf area) in the late morning. The cessation of sea breezes started after 1600 hours. Frequency of sea breeze days was the highest under coast-parallel gradient winds (southeast and northwest), with speeds < 6 m s-1. The predicted depth of the sea breeze inflow ranged between 200 and 600 m, while the depth of the return flow was in the range of 200 – 500 m. Sensible heat flux is an important control in the development of sea breeze over the region. Coastal mountain ranges helped early onset of the sea breeze, but also inhibited inland propagation. Strong jet-like westerly winds along the coastline near the Manukau Harbour are due partly to the narrow opening at the Manukau Head, reduced friction over the harbour water, and divergence of wind due to coastline shape. Gradient winds significantly affect the evolution of the sea breeze and modify many of its dynamics, such as the sea breeze inflow layer, return flow, inland penetration, sea breeze head, etc. Under northerly gradient flow northeast sea breeze lasts longer while under southerly gradient flow cessation of the westerly sea breeze was delayed. Over both east and west coasts, WRF predicted anticlockwise rotation, especially under easterly gradient wind conditions. However, inland stations near Manukau Harbour show partial and complete clockwise rotation, which is primarily due to orographic features of the region. The diurnal rotation of the sea breeze system may contribute to recirculation of pollutants in the morning hours under coast-parallel gradient wind conditions. Pollutants that are emitted during morning peak traffic hours and advected towards Manukau Harbour by the remnants of the land breeze may be returned by bay breezes in the mid morning hours. Mixed layer height over land before arrival of the sea breeze also varied a lot and ranged between 600 to 1400 m. A convective internal boundary layer (CIBL) forms in the surface layer after arrival of the sea breeze. The CIBL under coast parallel gradient winds was relatively shallow (200 – 400 m), while under coasts-normal gradient winds (southwest and northeast), the predicted depth was in the range of 400 to 500 m. However, the inland extent of the CIBL was greater under coast-normal winds, especially under south-westerly gradient winds. The ground level concentration of air pollutants thus can be increased during sea breeze inflow over the region. Both bay breeze and mature sea breeze contribute towards development, extent and strength of the sea breeze convergence zones (SBCZs). Gradient winds and terrain play an important role in the position and strength of SBCZs. Under strong south-westerly gradient flow, a SBCZ is formed along the eastern coastline, while under north-easterly gradient winds a SBCZ is formed along the west coastline. During coast-parallel gradient winds the SBCZ is formed in the middle of landmass, and is then gradually displaced eastward or westward depending on the balance between large scale PGF and surface friction effect. In addition to SBCZs, terrain and coastline-induced convergences were also evident. Higher ground level concentrations of pollutants are expected under coast-normal gradient winds, when SBCZs are formed in the middle of the land mass and the wind speed of the sea breeze inflow and the sea breeze front is relatively low. This may increase pollution concentration, especially in the evening hours, to unacceptable levels. Results of this research suggest that given the size, synoptic meteorology and specific geography of the region, significant recirculation of pollutants is not likely to happen to contribute to next day’s pollution. The pollutant concentration may increase in the SBCZs, but their ability to recirculate the pollutants requires more extensive research. A closed sea breeze circulation cell is unlikely to form in this region due to topographical influences and a strong gradient wind effect. The pollutant plume is expected to be advected in the return flow over the peaks of higher terrain and via the top of the convergence zones, but its remixing in the onshore flow is subject to many factors such as gradient wind speed and direction, direction of the return flow and nature (size and state) of the pollutant. In appropriate conditions, pollution levels may reach to unhealthy levels under coast-parallel gradient wind condition.

Evapotranspiration is a nexus for planetary energy and carbon cycles, as yet poorly constrained. Here I use stable isotopes of oxygen and hydrogen to partition flux of water due to plant transpiration from the direct evaporative flux from soils, water bodies and plant. The study areas, Langat and Kelantan watersheds represent examples of domains dominated by the respective Southwest and Northeast monsoons on the two sides of the main orographic barrier (Titiwangsa mountain range). Mean annual rainfall for the Langat watershed, obtained from 30 years of hydrological data, is 2145 ± 237 mm. Tentatively, 48% of this precipitation returns to the atmosphere via transpiration (T), with 33% partitioned into discharge (Q), 8% into interception (In), and 11% into evaporation (Ed). In the Kelantan watershed, the mean annual rainfall, also based on the 30 year hydrological data, is 2383 ± 120 mm. Similar to Langat, the T accounts for 43% of precipitation (P), 45% is discharged into South China Sea (Q), 12% partitioned into interception (In) and tentatively 0% for evaporation (Ed). Ed for the Langat watershed represents only a small proportion in terms of volumetric significance, up to almost ~11% with strong effect on the isotopic fingerprints of waters associated with the summer Southwest Monsoon (SWM). Note, however, that insignificant Ed for the Kelantan watershed may be an artefact of rain and river water sampling at only coastal downstream portion of the watershed. High humidity (80%) also was recorded for the Malaysian Peninsula watershed. T appropriates about half of all solar energy absorbed by the continents, here ~1000*103 g H2O m-2 yr-1 similar to other tropical regions at 900-1200*103 g H2O m-2 yr-1. The associated carbon fluxes are ~ 1300 g C m-2yr-1, independent of P. Vegetation responses to solar irradiance, via T and photosynthesis reflects the importance of stomatal regulation of the water and carbon fluxes. In order to maintain high transpiration in the tropical region, “constant” water supply is required for continuous pumping of water that delivers nutrients to the plant, suggesting that water and carbon cycle are co-driven by the energy of the sun. The existence of the water conveyor belt may be precondition for nutrient delivery, hence operation of the carbon cycle. Potentially, this may change our perspective on the role that biology plays in the water cycle. In such perspective, the global water cycle is the medium that redistributes the incoming solar energy across the planet, and the anatomical structures of plants then help to optimize the loop of energy transfer via evaporation and precipitation in the hydrologic cycle. The main features of aquatic geochemistry of the Langat and Kelantan rivers inferred from the Principal Component Analysis are controlled by three components that explain 80% and 82% of total variances. These components are reflecting of the geogenic factor with superimposed pollution, the latter particularly pronounced in urbanized sections of the Langat river and dominant in downstream of the Kelantan river. There is no correlation between seasonal variations in major ion chemistry and environmental variables such as precipitation, discharge, temperature or solar activity.

The atmospheric boundary layer (ABL) is the lowest layer of the atmosphere where surface effects are felt on time scales of about an hour. While its properties are determined by the surface characteristics, season and synoptic conditions, they in turn determine convective cloud properties and are required for the representation of cloud processes in atmospheric models. Further, interaction of the ABL with the surface layer of the ocean is a key component of ocean-atmosphere coupling. ABL characteristics over ocean surrounding the sub-continent become very important for understanding the monsoon processes during the monsoon season because the roots of many monsoon systems, that give rain to India, are over there. In this thesis data used are from three major field experiments namely the Bay of Bengal Monsoon Experiment (BOBMEX, 1999), Arabian Sea Monsoon Experiment (ARMEX, in two phases, ARMEX-I during 2002 and ARMEX-II in 2003), and Continental Tropical Convergence Zone (CTCZ) experiment (Pilot in 2009) which were carried out under the Indian Climate Research Programme (ICRP). While there have been few studies on ABL characteristics for individual cruises, a comprehensive study considering all available radiosonde data from the above cruises has been missing. This study fills this gap and focuses on the vertical structure of ABL using more than 400 high resolution Vaisala GPS radiosonde data collected over Bay of Bengal and Arabian Sea. The study attempts at first to look at the ABL characteristics of individual cruises and then compare and contrast them over the Bay of Bengal and Arabian Sea. ABL height Hm, estimated by using virtual potential temperature (θv) profile, shows diurnal variation during weak phase of convection while maximum in early morning during active phase of convection. Different variables i.e. moist static energy (h), specific humidity (q), convective available potential energy (CAPE), virtual potential temperature (θv) and equivalent potential temperature (θe) also differ during weak and active convection periods. Conserved variables mixing line approach gives the height up to which ground thermals penetrate in the vertical. This height, denoted by MH that represents the actual ABL height, is 2-3 times larger than Hm when shallow convective clouds are present. In general both Hm and MH are 20-30% larger over Arabian Sea compares to that over Bay of Bengal. Comparison of surface convective available potential energy (CAPE) and equivalent potential temperature (θe) between normal and deficit monsoon years shows that convective instability was as large in deficit years. This means that dynamic and not thermodynamics, controlled the occurrence of convection.

Evapotranspiration is a nexus for planetary energy and carbon cycles, as yet poorly constrained. Here I use stable isotopes of oxygen and hydrogen to partition flux of water due to plant transpiration from the direct evaporative flux from soils, water bodies and plant. The study areas, Langat and Kelantan watersheds represent examples of domains dominated by the respective Southwest and Northeast monsoons on the two sides of the main orographic barrier (Titiwangsa mountain range). Mean annual rainfall for the Langat watershed, obtained from 30 years of hydrological data, is 2145 ± 237 mm. Tentatively, 48% of this precipitation returns to the atmosphere via transpiration (T), with 33% partitioned into discharge (Q), 8% into interception (In), and 11% into evaporation (Ed). In the Kelantan watershed, the mean annual rainfall, also based on the 30 year hydrological data, is 2383 ± 120 mm. Similar to Langat, the T accounts for 43% of precipitation (P), 45% is discharged into South China Sea (Q), 12% partitioned into interception (In) and tentatively 0% for evaporation (Ed). Ed for the Langat watershed represents only a small proportion in terms of volumetric significance, up to almost ~11% with strong effect on the isotopic fingerprints of waters associated with the summer Southwest Monsoon (SWM). Note, however, that insignificant Ed for the Kelantan watershed may be an artefact of rain and river water sampling at only coastal downstream portion of the watershed. High humidity (80%) also was recorded for the Malaysian Peninsula watershed. T appropriates about half of all solar energy absorbed by the continents, here ~1000*103 g H2O m-2 yr-1 similar to other tropical regions at 900-1200*103 g H2O m-2 yr-1. The associated carbon fluxes are ~ 1300 g C m-2yr-1, independent of P. Vegetation responses to solar irradiance, via T and photosynthesis reflects the importance of stomatal regulation of the water and carbon fluxes. In order to maintain high transpiration in the tropical region, “constant” water supply is required for continuous pumping of water that delivers nutrients to the plant, suggesting that water and carbon cycle are co-driven by the energy of the sun. The existence of the water conveyor belt may be precondition for nutrient delivery, hence operation of the carbon cycle. Potentially, this may change our perspective on the role that biology plays in the water cycle. In such perspective, the global water cycle is the medium that redistributes the incoming solar energy across the planet, and the anatomical structures of plants then help to optimize the loop of energy transfer via evaporation and precipitation in the hydrologic cycle. The main features of aquatic geochemistry of the Langat and Kelantan rivers inferred from the Principal Component Analysis are controlled by three components that explain 80% and 82% of total variances. These components are reflecting of the geogenic factor with superimposed pollution, the latter particularly pronounced in urbanized sections of the Langat river and dominant in downstream of the Kelantan river. There is no correlation between seasonal variations in major ion chemistry and environmental variables such as precipitation, discharge, temperature or solar activity.

Do changes in how cross-equatorial energy transport is partitioned between the ocean and atmosphere impact the hemispheric climate response to forcing? To find out, we alter the cross-equatorial ocean heat transport in a state-of-the-art GCM and ascertain how changes in energy transport and its partitioning impact hemispheric climate and precipitation sensitivity following abrupt CO2-doubling. We further evaluate the applicability our results in CMIP6-class ESMs, where AMOC facilitates the northward cross-equatorial ocean heat transport. In our experiments, changes in ocean cross-equatorial energy transport trigger compensating changes in atmospheric energy transport through changes in the Hadley cells and a shift in the Intertropical Convergence Zone. However, the climate sensitivity in each hemisphere is linearly related to the ocean heat transport convergence, not atmospheric energy transport convergence, due to the impact of ocean heating on evaporation and atmospheric specific humidity. Similarly, we also find that ocean heat transport convergence controls the hemispheric precipitation sensitivity through the impact of ocean heating on surface evaporation. This relationship is also evident in CMIP6 models, where we find differences in hemispheric precipitation sensitivity to be related to the Atlantic Meridional Overturning Circulation (AMOC). Changes in the AMOC control hemispheric differences in upper ocean heat content, which then affect how the hydrologic cycle responds to CO2 forcing in each hemisphere. These results suggest that ocean dynamics impact the hemispheric climate response to CO2 forcing, particularly how much regional precipitation changes with warming. / Graduate