Title: Comparative analysis of the kayak forward stroke Objectives: The aim of this study is to describe and to compare the kayak forward stroke performed in the pool with countercurrent and on the flat water. Methods: The research was conducted in an intentionally chosen sample of eight kayakers with high level of performance in whitewater slalom. We watched activity of twelve selected muscles during kayak forward stroke performed in the counterflow pool and on the flat water by surface electromyography and kinematic analysis. Study evaluates intraindividual and subsequently interindividual muscle timing and the size of the muscle activation due to maximal voluntary contraction. Results: The results proved the same timing of muscles in counterflow pool and on flat water. The muscle activity in the counterflow pool was bigger than on flat water. Key words: kayak, counterflow pool, surface electromyography, paddling

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Made available in DSpace on 2017-07-21T13:42:50Z (GMT). No. of bitstreams: 1 LUCIANE JUSTUS DOS SANTOS.pdf: 4314143 bytes, checksum: 1c42de92698f42744a030a9cc7778538 (MD5) Previous issue date: 2015-06-01 / Understanding the appropriations process interactions from readers in newspapers and how these counterflow impact the news of the construction process is the objective of this study. It is considered the interface between the print platform and online journalism feature printed on the twenty-first century, and the focus is on interaction materialized based on their action via comments on the direction of the newspaper deals - what is published daily. Empirical research carried out in the newspapers dos Campos and Gazeta do Povo, gathers empirical data that make up the analysis. That is, it is a look at the offers (opinions) of players, the management and appropriations that the newspaper realizes from them. Through systematic observations have been identified elements that enable and / or determine the intensity and the way the newspaper perceives and appropriates the offers generated in the communication process from the perspective of consumption and circulation. This perspective offers a position to identify the flows and counterflow, tensions between production and reception systems. In this case, analyzing the strategies and protocols that both develop or establish to establish their exchanges and produce their speeches. The elements in the process of appropriation of the offers and considered for the analysis are the available interest channels, filters and the selection process / editing of comments and how they are again offered for consumption (reframed). The study considers the issue of new ambiences of discursive circulation while widen participation and promote new circuits that the productive system, in turn, does not account for control with traditional constituents protocols of their reading contracts. Importantly, not carried out a study on the content of news or comments, but the structure and protocols that enable the circulation of the "opinion of readers." Reflection on the subject is grounded in the theoretical contributions of gatekeeping and the theory of enunciation problematized with the specifics of journalistic practice. / Compreender os processos de apropriações das interações dos leitores nos jornais e como esses contrafluxos impactam no processo de construção da notícia é o objetivo deste estudo. Considera-se a interface entre a plataforma impressa e online, característica do jornalismo impresso no século XXI, e o foco é a interação materializada a partir das manifestações via comentários sobre as ofertas de sentido do jornal - aquilo que é diariamente publicado. A pesquisa empírica, realizada nos jornais Diário dos Campos e Gazeta do Povo, reúne dados empíricos que compõem a análise. Ou seja, trata-se de um olhar sobre as ofertas (opiniões) dos leitores, do manejo e das apropriações que o jornal realiza a partir das mesmas. Através de observações sistemáticas foram identificados elementos que possibilitam e/ou determinam a intensidade e o modo como o jornal percebe e se apropria das ofertas geradas no processo comunicacional pela perspectiva do consumo e da circulação. Tal perspectiva oferece condições de identificar, nos fluxos e contrafluxos, tensões entre os sistemas produtivo e de recepção. Neste caso, analisar as estratégias e os protocolos que ambos desenvolvem ou estabelecem para estabelecer suas trocas e produzir os seus discursos. Os elementos contidos no processo de apropriação das ofertas e considerados para as análises são os canais de participação disponibilizados, os filtros e o processo de seleção/edição dos comentários, bem como a forma como são novamente ofertados para o consumo (ressignificado). O estudo considera a problemática das novas ambiências de circulação discursiva ao passo que ampliam a participação e promovem novos circuitos que o sistema produtivo, por sua vez, não dá conta de controlar com os tradicionais protocolos constituintes de seus contratos de leitura. Importante ressaltar que não se realiza um estudo sobre o conteúdo das notícias ou dos comentários, mas da estrutura e dos protocolos que viabilizam a circulação da “opinião dos leitores”. A reflexão sobre o objeto está embasada nos aportes teóricos do gatekeeping e da teoria da enunciação problematizadas com as especificidades da prática jornalística.

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A pulsed Nd:YAG laser is used to study laser spark ignition of methane counter-flow diffusion flames with the use of helium and argon as diluents to achieve a wide range of variations in transport properties. The global strain rate and Damkohler number on successful ignition were investigated for the effects of Lewis number and transport properties, which are dependent on the diluent type and dilution level. A high-speed camera is used to record the ignition events and a software is used for pre-ignition flow field and mixing calculations. It is found that the role of effective Lewis number on the critical global strain rate, beyond which ignition is not possible, is qualitatively similar that on the extinction strain rate. With the same level of dilution, the inert diluent with smaller Lewis number yields larger critical global strain rate. The critical Damkohler number below which no ignition is possible is found to be within approximately 20% for all the fuel-inert gas mixtures studied. When successful ignition takes place, the ignition time increases as the level of dilution of argon is increased. The ignition time decreases with increasing level of helium dilution due to decreases in thermal diffusion time, which causes rapid cooling of the flammable layer during the ignition process. However, the critical strain for ignition with helium dilution rapidly decreases as the dilution level is increased. The experimental results show that with the increase of strain rate the time to steady flame decreases, and that with the increase of dilution level time for the flame to become steady increases. For the same level of dilution, the time for steady flame is observed to be longer for He-diluted flames than for Ar-diluted flames due to its thermal diffusivity being larger than that of Ar.

Extensive research on amino acids, and even other biochemical assays usually present in low concentration and volume face challenges using known analytical techniques for analysis of traces amounts. Some limiting factors are the achievable efficiency, sensitivity (resulting from instrument limit of detection and/or experimental methods), volume requirement, and total analysis time. Counterflow electrofocusing techniques combining forces of electrophoresis and bulk flow (pressure driven flow and/or electroosmotic flow) provides a basis for the development of alternative detection techniques geared towards improving peak efficiency, sensitivity and time. The work presented gives a vivid description of recently developed capillary counterflow techniques: gradient elution isotachophoresis (GEITP) using UV detection, GEITP coupled to Capillary Zonal Electrophoresis (GEITP-CZE), temperature gradient focusing (TGF), and temperature gradient denaturing focusing (TGDF). A first demonstration of GEITP using UV detection was applied to enrichment and separation of tyrosine and tryptophan under optimized conditions. Primarily, separation is achieved as the result of the difference in electrophoretic velocity of analytes in a discontinuous buffer system. First, a plug of sample is allowed to preconcentrate (or enrich) between high mobility leading electrolyte (LE) and low mobility trailing electrolyte (TE) under controlled hydrodynamic pressure and continuous injection. This preconcentration is initiated outside the capillary in a conductivity bubble. Although analyte focus according to their electrophoretic velocity, the inclusion of spacer molecule in sample matrix was instrumental in achieving separation with tradeoff between analyte resolution and enrichment. Gradient produced results from reduction in pressure as sample is loaded on column. Separation using this technique is a one step process. A hybrid method marking the first successful coupling of GEITP to CZE with laser induced fluorescence detection was used for separation of six fluorescently labeled amino acids (which formulates the Mars-7). An eleven minute separation was achieved under optimized conditions. A proof-of-concept demonstration of TGF with LIF detection showed focusing and separation of fluorescein and carboxyfluorescein dye molecules, and carboxyfluorescein-labeled glutamate and aspartate. The generation of null focusing points along the thermal separation column (set between 80-20oC) was produced in collaboration with continuous sample injection, discontinuous buffer system and balancing of counterflows (electrophoresis and bulk flow). Preliminary results showed stability in instrument. The TGDF method carried out on a TGF apparatus is a modification to the temperature gradient gel electrophoresis and denaturing gradient gel electrophoresis methods. In principle, TGDF primarily achieves focusing and separation on a thermal separation column (set between 20 to 80 oC) as a result of conformational changes. It is currently being developed for the detection and simultaneous separation of single and double stranded DNA. Preliminary results show enrichment of wildtype and mutant synthetic DNA strands (containing twenty-four base pairs in sequence) in different buffer matrices. / Chemistry

Cette étude est consacrée à l'élaboration d'une méthodologie de détermination des vitessesfondamentales des flammes laminaires, en utilisant un diagnostic de Vélocimétrie par Imagerie deParticules (PIV). Ce dernier est appliqué aux écoulements réactifs avec point de stagnation, permettant lastabilisation de flammes planes, stationnaires et en conditions quasi adiabatiques. Les effets d’étirementssubits par la flamme sont également quantifiables et parfaitement maîtrisés. L’approche ici développée atout d’abord été appliquée aux mélanges méthane/air pour validation. Une comparaison exhaustive desrésultats obtenus avec les données de la littérature est effectuée. Les codes de combustion 1D (PREMIX,OPPDIF) et 2D (Fluent©) ont été utilisés afin de confirmer la fiabilité et la précision de l’approche proposée.Une attention particulière a été accordée à la caractérisation du mouvement des particules ensemencéesdans les écoulements réactifs divergents, avec notamment la prise en considération de la force dethermophorèse. La méthode développée a ensuite été appliquée à la détermination des vitesses deflammes laminaires de divers mélanges de syngas (H2+CO). Une étude comparative sur ces mélanges aété conduite en utilisant des approches expérimentales multiples comprenant : les flammes à contrecourant,les flammes à propagation sphérique ainsi que les flammes stabilisées coniques. Les résultatsobtenus pour chaque approche ont été confrontés et la sensibilité à l’étirement des flammes de syngas aété caractérisée pour une large gamme de richesses (E.R.=0.4 to 5.0) et de compositions de mélanges(5/95 to 50/50 % H2/CO). / In the context of CO2 emission reduction, the present study is devoted to the development of alaminar flame speed measurement methodology, using the Digital Particle Image Velocimetry (DPIV)diagnostic. The latter is applied to stagnation flow flames, seen to have considerable assets for suchstudies. Indeed, flames stabilized in these diverging flows are planar, steady and in near-adiabaticconditions, while subtraction of strain effects on flame is intrinsically allowed. The methodology developedherein has been applied to the well-characterized methane/air mixtures for validation. An extensivecomparison with the literature datasets has been provided. Both 1D (PREMIX, OPPDIF) as well as 2D(Fluent©) numerical tools have been used to confirm the reliability and accuracy of the developed approach.A particular attention has been given to the characterization of the seeding particle motion within thediverging flow, with consideration of the often-neglected thermophoretic force. Fundamental flame velocitiesof various syngas (H2+CO) mixtures have been investigated using multiple experimental approachesincluding the aforementioned counterflow methodology as well as spherical and conical flameconfigurations. Performed measurements from the different approaches have been confronted and flamesensitivities to stretch have been characterized for a wide range of equivalence ratios (E.R.=0.4 to 5.0) andmixture compositions (5/95 to 50/50 % H2/CO).

<p dir="ltr">Reverse osmosis (RO) is emerging as the world’s leading desalination technology due to its superior energy efficiency and the shift towards renewable electrification. However, RO systems need to further improve efficiency, increase operating flux, reach higher salinities (>7.5% w.t.), and minimize component complexity. Treating RO as a dynamical system, this dissertation invents new processes for high-efficiency desalination that achieve milestones for low downtime and high final salinity. It also introduces modeling methods that include more detail (e.g. salt retention, time-varying salinity, concentration polarization, salt transport, temporal multi-staging, etc.) and the first use of certain optimization methods in RO.</p><p dir="ltr">Batch RO is an unsteady, pressure driven process that efficiently desalinates a saline feed volume over time by continuously recirculating the brine through the membrane module. A tank houses the concentrating feed and mediates the streams entering and leaving the membrane module. Most studies so far have concentrated on the high-pressure tank design that requires finite downtime at the end of each stroke. A scalable pressure exchanger batch RO (PX-BRO) configuration using atmospheric tanks that practically has zero downtime and produces permeate even while flushing is first described in this dissertation.</p><p dir="ltr">To achieve high recovery at nominal RO pressures, osmotically assisted RO processes have both sides of the membrane saline and the streams usually in counterflow. The first unsteady osmotically assisted process based on the high-pressure piston tank design, batch counterflow RO (BCFRO) is introduced which dramatically reduces the energy needs. To address the issue of high component count in spatial multi-staging, the first “temporally multi-staged” BCFRO process is also introduced. The new process uses the pressure ex- changer and atmospheric pressure tank design for scalability and operational flexibility.</p><p dir="ltr">For membranes with low salt rejection, it becomes imperative to integrate the salt trans- port dynamics for deciding operating and initial conditions. Trajectory optimization is used to match salinity and volume between stages of temporally multi-staged BCFRO. Treating the process as an optimal control problem, a framework for obtaining time varying flux pro- files that minimize the specific energy consumption is also developed. Both reduced order and discretized models are developed to analyze these new batch RO configurations.</p>

Soot prediction from combustion systems is still a major challenge in high-fidelity simulations of reactive flows, especially in turbulent conditions. Among the critical aspects, due to its slow characteristic formation times, soot sensitivity to strain rate and turbulence-chemistry interaction models for combustion closure can be found. Starting from the laminar problem, Soot Formation (SF) and Soot Formation Oxidation (SFO) counterflow flames are studied, allowing assessment of the roles of the different underlying phenomena concurring at soot formation with varying strain rates, depending on their relevance in each configuration. Attention is devoted to the inception model, which always regulates the onset of soot formation, and entirely determines the soot sensitivity to strain rate in the SF configuration through nucleation and condensation. Besides, surface growth and oxidation are analyzed in the SFO configuration, where they are predominant. The corresponding models are fine-tuned and generalized, and improved predictions are obtained in both configurations. Afterwards, a 2-points flame-controlling continuation method with soot module inclusion is developed to build a tool capable of flamelets generation inclusive of soot effects on the gas phase. The implementation is first tested discussing general features of the S-curve and verifying the consistency with previous works. The tool is finally used to compute the S-curve of ethylene pressurized sooting flames. The models and tools developed are incorporated into an OpenFOAM-based solver to perform Computational Fluid Dynamic (CFD) simulations of sooting turbulent flames. These are studied in pressurized, highly turbulent environments, to validate the soot model at a fundamental level but with practically relevant operative conditions. The numerical results are found to satisfactorily depict the soot volume fraction (SVF) formation, even though a few quantitative and qualitative discrepancies are discussed. Furthermore, soot intermittency and pressure scaling are analyzed. Finally, an alternative turbulence-chemistry interaction model for combustion closure is explored. A generalized partially-stirred reactor model is developed which accounts for all chemical times in a consistent manner. While the applicability of available models is confined to specific turbulence-chemistry interaction regimes, the incorporation of detailed chemistry description in the proposed approach improves synergistic predictions of all species and makes it suitable for systems with characteristic times very different from each other, such as soot and NOx.

För att skapa ett bra inomhusklimat i flerbostadshus ställs höga krav på ventilationssystemet för att ta hand om den fukt som skapas. Det finns således anledning att undersöka om Boverkets byggreglers krav för minsta luftflöde är tillräckligt ur fuktsynpunkt. Syftet är att uppmärksamma problem med ökande fukttillskott i nyproducerade flerbostadshus vilket skulle kunna förändra projekteringen av ventilation i framtiden. För att kunna undersöka om Boverkets byggreglers krav är tillräckligt ur fuktsynpunkt analyseras relativ fuktighet och fukttillskott i fyra flerbostadshus i Jönköping. Det framgår att flera lägenheter erhöll höga värden för fukttillskott och relativ fuktighet vilket kan skada byggnaden och påverka människors hälsa. Boverkets byggreglers krav för minsta luftflöde var otillräckligt ur fuktsynpunkt i flera av de undersökta flerbostadshusen. / To create a good indoor climate in apartment buildings, high demands are made on the ventilation system to take care of the moisture that is created. There is therefore reason to investigate if Boverket, the Swedish National Board of Housing, Building and Planning, requirements for minimum airflow are sufficient from a moisture point of view. The purpose is to rise awareness about increasing additional moisture in newly built apartment buildings, which could change the project planning of ventilation systems in the future. In order to investigate whether requirements of the Boverket building regulations are sufficient from a moisture point of view, relative humidity and additional moisture were analyzed in four apartment buildings in Jönköping. Several apartments received high values of additional moisture and relative humidity which could damage the building and affect human health. The requirements of Boverket building regulations for minimum airflow should therefore be reviewed.