京都大学 / 0048 / 新制・課程博士 / 博士(理学) / 甲第18779号 / 理博第4037号 / 新制||理||1581(附属図書館) / 31730 / 京都大学大学院理学研究科物理学・宇宙物理学専攻 / (主査)教授 川上 則雄, 教授 佐々 真一, 教授 前野 悦輝 / 学位規則第4条第1項該当 / Doctor of Science / Kyoto University / DFAM

京都大学 / 0048 / 新制・課程博士 / 博士(工学) / 甲第19011号 / 工博第4053号 / 新制||工||1624(附属図書館) / 31962 / 京都大学大学院工学研究科高分子化学専攻 / (主査)教授 赤木 和夫, 教授 秋吉 一成, 教授 金谷 利治 / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DGAM

<p>Let p be a prime number and F be a finite extension of Q_p. We established an algorithm to compute the semisimplification of the reduction of some irreducible two dimensional crystalline representations with two parameter {h,a_p} when v_p(a_p) is large enough. We improve the known results when p|h. We also extend the algorithm to the two dimensional semistable and non-crystalline representation. We compute the semi-simplification of the reduction when v_p(L) large enough and p=2. These results solve the difficulties with the case p=2. The strategies are based on the study of the Kisin modules over O_F and Breuil modules over S_F. By the theory of Breuil and Theorem of Colmez-Fontaine, these modules are closely related to semistable representations.</p>

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The commodity plastics industry is dominated by semicrystalline polymers, which generally display high toughness relative to amorphous polymers but typically suffer from low strength and modulus. Researchers have shown that the addition of nanoparticles (NPs) to these semicrystalline matrices can result in materials with enhanced properties relative to the neat systems. The arrangement of these NPs into anisotropic sheet-like structures appears to endow these processed polymer nanocomposites (PNCs) with further improved mechanical properties relative to PNCs where the NP morphology remains well-dispersed. However, there is currently no appropriate methodology in the literature with which to quantitatively correlate the extent of NP organization to the enhancement in mechanical properties. Additionally, isothermal crystallization (the current processing technique of choice for this class of PNCs) results in numerous grain boundaries. While entanglements across grains can limit issues associated with failure, grain boundaries can also be undesirable for the modulus of the material. In this dissertation, we methodically investigate several key topics related to the above. We first present our modifications to the correlation function approach of Strobl and Schneider, which was originally developed to characterize the structural parameters of neat semicrystalline polymers and their blends, that allow us to apply it to isothermally crystallized poly(ethylene oxide) (PEO) PNCs. We select PEO due to the relative ease with which mobile silica NPs can be dispersed within the matrix. Next, we characterize these materials using the generally used large beam size typical of laboratory-scale and synchrotron X-ray scattering instruments. In this study, we show that our adaptations to the correlation function approach allow for the quantitative evaluation of the NP ordering process as a function of isothermal crystallization temperature. The same systems are then characterized with a microfocus synchrotron X-ray scattering beam guided by an autonomous experimentation protocol, which allows for a detailed, granular mapping of the structural parameters of these materials. The much smaller beam reveals spatial morphological heterogeneity in both the neat and PNC systems due to the grain size being on the order of the dimensions of the microbeam as opposed to those of the larger beam. Hence, the combination of the large and microfocus beam provides a comprehensive view of these systems, with varying degrees of granularity. We also find quantitative evidence that demonstrates that NPs organize parallel to the direction of polymer crystal growth, a phenomenon which has previously only been shown in the literature in a qualitative fashion. Having established the physics of the NP ordering process in isothermally crystallized PNC systems, we turn to the zone annealing (ZA) technique as inspiration to approach more uniform, unidirectionally oriented NP morphologies. ZA, which has found extensive use in the production of ultra-pure semiconductors for electronics applications, proceeds by translating a sample at a constant velocity over a well-defined temperature gradient. This directional processing technique has been shown to result in the reduction of grain boundaries when applied to semicrystalline polymers. Since the PNC is a more complicated system than the neat matrix, we first perform studies of zone annealed neat PEO. Our experimental, analytical, and numerical investigations validate a crucial directional crystallization theory proposed by Lovinger and Gryte, who were among the first to apply ZA to semicrystalline polymers; our experimental evidence confirms the existence of a critical ZA velocity (v_crit) below which directional crystallization occurs and above which the process is closer in spirit to isothermal crystallization. Having determined the mechanism driving the ZA of neat PEO, we then turn to the ZA of PEO-based PNCs. Through our studies, we find that it is imperative to minimize or eliminate sample flow during the procedure, as otherwise the NPs order in disparate directions. Our subsequent redesign of the sample preparation protocol, such that the material is pressed between two glass coverslips separated by Teflon spacers, leads to extensive unidirectional organization of NPs that persists throughout the film at slow enough ZA velocities, as evidenced from X-ray scattering experiments. Hence, this dissertation systematically examines questions relevant to understanding how to obtain uniform, unidirectional NP organization in semicrystalline PNCs, with relevance to applications requiring enhanced properties.

Vatten är en livsviktig resurs för allt liv. I Sverige kommer hälften av allt dricksvatten från grundvatten. I kustnära områden begränsas grundvattentillgången av omgivningens lagringsförmåga och begränsad tillrinningsyta och det leder till att tillgången på vatten ett växande problem. Det är därför viktigt att förstå alla parametrar som påverkar grundvattnet, både för nutida och framtida brukare. Förändringen av grundvatten i geologiskt blandad miljö är svårt att kartlägga på grund av lagerföljder, materialens heterogenitet, låg kinematisk porositet och okunskap om strömningen mellan olika lager. Grundvattennivåerna skiftar dessutom med klimatet, både över året och över längre tid. Även människans påverkan är av stor betydelse. Rapportens syfte är att se hur dessa parametrar påverkar grundvattenytan i förhållande till varandra. För att undersöka dessa parametrar har tre olika geografiska, kustnära områden jämförts: Stor, Blidö, och Insjön, Rådmansö, i Norrtälje kommun samt Klintemåla i Oskarshamns kommun. För att sätta vattenanvändningen i ett sammanhang har uppgifterna relaterats till vattenexploateringsindexet (WEI). Uppgifter har hämtats från SGU, SMHI och Lantmäteriets arkiv. I två fall har kompletterande fältundersökningar genomförts. Informationen har bearbetats i Excel och programmet GWBal. I dessa områden råder lokal akut eller total vattenbrist under vissa sommarmånader. Förekomsten av vatten är en fråga om lokal tillgång och en generellt god situation i Sverige döljer stora regionala och lokala obalanser. Vad fritidsboende gör spelar större roll än permanentboende då det är under sommarsäsongen problemen är störst. Mindre reservoarer är känsligare när parametrar för klimat, vattenförbrukning och kemisk sammansättning förändras. De klimattendenser som nu uppvisas leder till konklusionen att grundvattentillgången i områdena under den kritiska perioden kommer att minska. / Water is a vital resource for all human life. Half of all drinking water in Sweden comes from groundwater and in some coastal areas, the access to water is a growing problem. It is therefore crucial to properly understand all parameters that affect the access to water, both for present and future users. The change in groundwater level in geologically varied environments is hard to get a complete picture of. Stratification, heterogeneity of soil and rock, low kinematic porosity and flow between the layers are partially unknown parameters and therefore highly uncertain. Groundwater levels also change with the climate, both over the year and over longer period of time. The impact of humans is of great importance. The objective is to see how these parameters effects groundwater level in relation to each other. To analyze these factors, three different geographic areas in Sweden will be compared: Stor, Blidö, and Insjön, Rådmansö, in Norrtälje kommun and Klintemåla in Oskarshamns kommun. To put the water use and potential stress in context, the results will be related to the Water Exploitation Index (WEI). Data was obtained from the archives of SGU, SMHI and Lantmäteriet. In two cases, the information was supplemented with field investigation. The information was processed in Excel and the program GWBal. Overall, the local shortage of water in these areas is urgent during some summer months. The water supply is a local resource and the generally good situation in Sweden conceals major regional and local imbalances. The part time residents have a much greater impact since the problem is at its peak during summer. Changes in the climate, withdrawal of water and chemical composition have greater impact on small reservoirs then on big ones. With today’s trend in climate, the conclusion is that the availability of groundwater in the areas will decrease.

<p> The motion of energetic charged particles inside a crystalline solid is strongly dependent upon the orientation of the ion beam and target. This effect is commonly known as the "channeling" effect. In this report, the development of a computer code is presented which simulates the 3-D ion scatterings experienced by energetic particles moving in a crystalline solid. A Monte Carlo technique is incorporated in the code to calculate scattering angles, range distribution, backscattering distribution and angular distribution of incident ions. The Thomas-Fermi interatomic potential is used for binary collision process and the continuum potential is used for the potentials experienced by the channeled ions inside crystal lattices. </p> / Thesis / Master of Engineering (MEngr)