The aerospace industry strives to develop new methods of refining gas turbine engines by increasing power and thermal efficiencies while simultaneously reducing cost. Turbine engines operate under high temperatures and therefore thermal barrier coatings (TBCs) composed of yttria-stabilized zirconia (YSZ) play an important role in improving the performance of the components that make up the engine. Failure of the TBC could lead to catastrophic events, thus requiring consistent and accurate characterization for supplier qualification and production quality assurance. However, due to porosity and the anisotropic behavior of the coating and variability in processing of TBCs, consistent characterization has proven to be extremely challenging. One of the reoccurring issues is the inconsistency in measuring percent porosity, which stems from the difficulty in distinguishing filled pores from damaged, unfilled voids. Sample preparation of TBCs involves sectioning, mounting, grinding, polishing, and characterization. Eliminating variability in characterization begins with mounting which is a critical step to protect the surface integrity and edge retention of the coating during grinding and polishing. The curing kinetics of a slow cure two part epoxy was investigated and the TBC samples were mounted and cured at heating rates of 2, 5, and 10°C/min to 55°C and 70°C. Grinding and polishing procedures simulated industry practices followed by characterization with optical microscopy. Results showed that heating rates of 2°C/min to 55°C and 70°C have the best impregnation properties while uncontrolled or high heating rates of 10°C/min had an increase in the amount of pullouts and lack of infiltration from the epoxy. The curing kinetics of the epoxy needs to be controlled to eliminate the ambiguity of filled and unfilled pores. / Master of Science

<p>This thesis describes the synthesis and characterization ofbranched semi-crystalline polymers. Included in this work isthe SEC characterization of a series of dendrimers. Thebranched semi-crystalline polymers were synthesized in order toinvestigate the concept of their use as powder coatings resins.This concept being that the use of branched semi-crystallinepolymers in a UV-cured powder coating system may offer a lowertemperature alternative thus allowing the use of heat sensitivesubstrates and the added benefit of a reduced viscositycompared to linear polymers.</p><p>A series of branched poly(ε-caprolactone)’s (PCL)(degree of polymerization: 5-200) initiated from hydroxylfunctional initiators were synthesized. The final architectureswere controlled by the choice of initiator structure;specifically the dendritic initiators yielded starbranchedPCL’s while the linear initiator yielded comb-branchedPCL’s. The dendritic initiators utilized were: (1) a3rd-generation Boltorn H-30, commercially availablehyperbranched polyester with approximately 32 hydroxyl groups,(2) a 3rd-generation dendrimer with 24 hydroxyl groups, and (3)a 3rd-generation dendron with 8 hydroxyl groups. Linear PCL wassynthesized for comparison. All dendritic initiators are basedon 2,2- bis(methylol) propionic acid. The comb-branchedpolymers were initiated from a modified peroxide functionalpolyacrylate. The resins were end-capped withmethylmethacrylate in order to produce a cross-linkable system.The polymers and films were characterized using 1H NMR, 13CNMR, SEC, DMTA, DSC, FT-IR, FT-Raman, rheometry and a rheometercoupled to a UV-lamp to measure cure behavior.</p><p>The star-branched PCL’s exhibited considerably lowerviscosities than their linear counterparts with the samemolecular weight for the molecular region investigated (2-550kg mol-1). It was also found that the zero shear viscosityincreased roughly exponentially with M.</p><p>The PCL star-branched resins are semi-crystalline and theirmelting points (Tm) range from 34-50°C; films can beformed and cured below 80°C. The viscoelastic behaviourduring the cure showed that the time to reach the gel point, afew seconds, increased linearly with molecular weight. Thecrossover of G’and G’’was used as the gelpoint. Measurement of mechanical properties of films showedthat the low molecular weight polymers were amorphous whilethose with high molecular weight were crystalline after cure.The polymerization of 5,5-dimethyl-1,3-dioxane-2-one (NPC) fromoligo- and multifunctional initiators was evaluated utilizingcoordination and cationic polymerization. Two tin basedcatalysts, stannous(II) 2-ethylhexanoate and stannous(II)trifluoromethane sulfonate, were compared with fumaric acid.Fumaric acid under bulk conditions resulted in lowerpolydispersity and less chance of gelling. The synthesis ofstar-branched polymers was confirmed by SEC data. The starpolymers exhibited a Tg at 20-30°C and a Tm at about100°C.</p><p>All semi-crystalline resins exhibited a fast decrease inviscosity at Tm. Blends of combbranched semi-crystalline resinsand amorphous resins exhibited a transition behavior inbetweenthat of pure semi-crystalline resins and that of amorphousresins.</p><p>The SEC characterization of a series of dendrimers withdifferent cores and terminal groups showed that the core had animpact on the viscosimetric radius of the core while theterminal groups appeared to have no effect.</p><p><b>Keywords:</b>star-branched, semi-crystalline,comb-branched, ring-opening polymerization,poly(ε-caprolactone), dendritic, thermoset, lowtemperature curing, powder coating, UVcuring,poly(5,5-dimethyl-1,3-dioxane-2-one), size exclusionchromatography, rheology, dendritic aliphatic polyester</p>

This thesis describes the synthesis and characterization ofbranched semi-crystalline polymers. Included in this work isthe SEC characterization of a series of dendrimers. Thebranched semi-crystalline polymers were synthesized in order toinvestigate the concept of their use as powder coatings resins.This concept being that the use of branched semi-crystallinepolymers in a UV-cured powder coating system may offer a lowertemperature alternative thus allowing the use of heat sensitivesubstrates and the added benefit of a reduced viscositycompared to linear polymers. A series of branched poly(ε-caprolactone)’s (PCL)(degree of polymerization: 5-200) initiated from hydroxylfunctional initiators were synthesized. The final architectureswere controlled by the choice of initiator structure;specifically the dendritic initiators yielded starbranchedPCL’s while the linear initiator yielded comb-branchedPCL’s. The dendritic initiators utilized were: (1) a3rd-generation Boltorn H-30, commercially availablehyperbranched polyester with approximately 32 hydroxyl groups,(2) a 3rd-generation dendrimer with 24 hydroxyl groups, and (3)a 3rd-generation dendron with 8 hydroxyl groups. Linear PCL wassynthesized for comparison. All dendritic initiators are basedon 2,2- bis(methylol) propionic acid. The comb-branchedpolymers were initiated from a modified peroxide functionalpolyacrylate. The resins were end-capped withmethylmethacrylate in order to produce a cross-linkable system.The polymers and films were characterized using 1H NMR, 13CNMR, SEC, DMTA, DSC, FT-IR, FT-Raman, rheometry and a rheometercoupled to a UV-lamp to measure cure behavior. The star-branched PCL’s exhibited considerably lowerviscosities than their linear counterparts with the samemolecular weight for the molecular region investigated (2-550kg mol-1). It was also found that the zero shear viscosityincreased roughly exponentially with M. The PCL star-branched resins are semi-crystalline and theirmelting points (Tm) range from 34-50°C; films can beformed and cured below 80°C. The viscoelastic behaviourduring the cure showed that the time to reach the gel point, afew seconds, increased linearly with molecular weight. Thecrossover of G’and G’’was used as the gelpoint. Measurement of mechanical properties of films showedthat the low molecular weight polymers were amorphous whilethose with high molecular weight were crystalline after cure.The polymerization of 5,5-dimethyl-1,3-dioxane-2-one (NPC) fromoligo- and multifunctional initiators was evaluated utilizingcoordination and cationic polymerization. Two tin basedcatalysts, stannous(II) 2-ethylhexanoate and stannous(II)trifluoromethane sulfonate, were compared with fumaric acid.Fumaric acid under bulk conditions resulted in lowerpolydispersity and less chance of gelling. The synthesis ofstar-branched polymers was confirmed by SEC data. The starpolymers exhibited a Tg at 20-30°C and a Tm at about100°C. All semi-crystalline resins exhibited a fast decrease inviscosity at Tm. Blends of combbranched semi-crystalline resinsand amorphous resins exhibited a transition behavior inbetweenthat of pure semi-crystalline resins and that of amorphousresins. The SEC characterization of a series of dendrimers withdifferent cores and terminal groups showed that the core had animpact on the viscosimetric radius of the core while theterminal groups appeared to have no effect. Keywords:star-branched, semi-crystalline,comb-branched, ring-opening polymerization,poly(ε-caprolactone), dendritic, thermoset, lowtemperature curing, powder coating, UVcuring,poly(5,5-dimethyl-1,3-dioxane-2-one), size exclusionchromatography, rheology, dendritic aliphatic polyester / <p>NR 20140805</p>

The eco-friendly alternatives use is increasing momentum in a conscious effort towards sustainability. In this regards, the relevance and the economic value of using copper slag as a concrete aggregate are explored in this study in order to contribute towards metallurgical waste recycling. Emphasis is placed on the evaluation of the concretes strengthening prepared with copper slag contents and produced under four curing methods: water immersion, water spraying, plastic sheet covering and air-drying. In each curing case excluding for water immersion, was duplicated in indoors (i.e. in the laboratory) and outdoor exposure (so was prone to varying environmental conditions). This was specifically aimed at capturing the effects of tropical weather conditions typical of the Lualaba province in the Democratic Republic of Congo. The control mix was designed to reach 25 MPa of compressive strength. Copper slag was successively incorporated as sand replacement at the following mass fractions: 20 %, 40 % and 60 %. Freshly mixed concrete samples were evaluated for workability. Cube specimens were cast accordingly, cured for 28 days and then tested for density and compressive strength. Results indicated an increase in strength up to 20 % of replacement rate for all the curing methods. Further additions resulted in reduction in the strength, but the rate of reduction depended on curing conditions. The increase in strength was mainly credited to the physical properties of copper slag that could have contributed to the cohesion of the concrete matrix. It has been found that appropriate ways of curing can still achieve greater results than that of the control mix since 80 % of humidity is ensure. The two-way ANOVA test performed on the 28-days compressive strength values confirmed the significant influence of the curing methods, of copper slag content and the interaction between them. It has been found that considerable influence is attributed to copper slag content and that warm environmental conditions further extend the concrete strengthening. / College of Engineering, Science and Technology / M. Tech. (Chemical Engineering)

The aim of the work reported here was to determine the influence of an amine curing agent, and postcure cycle on the mechanical and thermal properties of diglycidyl ether of bisphenol A (DGEBA) epoxy resin. The results of this initial study were then used as the basis for selecting material to obtain optimum toughness in epoxy/glass fibre systems. These basic materials were further used to make comparisons with the properties of modified resin systems which contained commercial elastomers. Differential Scanning Calorimetry (DSC), Dynamic Mechanical Thermal Analysis (DMTA), Fourier Transform Infrared Spectroscopy (FTIR), flexural and interlaminar shear tests, Instrumented Falling Weight Impact (IFWI), visual observation, Scanning Electron Microscopy (SEM), and Transmission Electron Microscopy (TEM) were all used to investigate various properties and the structures which gave rise to them. The properties of cured products were found to be affected by the amounts of curing agent, curing times and temperatures, and the structure of the elastomers. Not surprisingly the maximum thermal and mechanical properties tended to be found in the stoichiometric (standard) mix systems. However, postcuring at higher than room temperature, which was used as the basic curing temperature, led to more conversion. This effect improved the thermal and mechanical properties of both the unmodified and modified resin systems. The maximum flexural strength of 104 MPa of the unreinforced resins was found in the stoichiometric mix ratio after postcure at 150°C for 4 hr. However, the maximum flexural modulus and glass transition temperature (Tg) were found after postcuring at the same temperature for 48 hr. This was believed to be due to increased crosslinking, but unfortunately the longer curing time led to degradation of the resins. In the systems modified with -20 phr of polyetheramine elastomers, the one modified with the lowest molecular weight (2000) was found to have the highest flexural strength (85.8 MPa) and modulus (2.5 GPa). The impact properties of all the composites with modified resin matrices were found to be higher than the unmodified resin matrix composites. The best impact properties were, however, obtained with the elastomer modifier with a molecular weight of 4000. The impact energy at maximum force increased from 11.9 to 16.4 J, and energy at failure increased from 18.7 to 21.6 J. This increase in impact properties was due to the increase in areas of phase separated elastomer particles over similar systems with lower molecular weight modifier.

O objetivo deste estudo ex vivo foi avaliar, por meio de teste de pull out, a influência de diferentes potências de fotoativação, associadas a diferentes técnicas de inserção, na retenção da restauração de resina composta em raízes fragilizadas. Foram utilizadas quarenta raízes de caninos superiores humanos padronizadas em 15 mm de comprimento, que foram submetidas à fragilização por meio de brocas 718PM; 730PM e 720PM, com auxílio de paralelômetro numa extensão de 8 mm. O tratamento endodôntico foi realizado por meio de instrumentos manuais tipo K, apenas no remanescente radicular não tocado pela fragilização. A obturação foi realizada pela técnica de condensação lateral com cimento AH Plus, seguida de corte dos cones, no comprimento correspondente à área da fragilização, e toalete da cavidade. Os espécimes foram distribuídos em quatro grupos (n= 10) de acordo com a técnica de inserção e a potência de fotoativação: Grupo I, resina composta inserida em incremento único; Grupo II, resina composta inserida em dois incrementos. Estes grupos foram fotoativados em baixa potência (500 mW/cm²); Grupo III, resina composta inserida em incremento único; Grupo IV, resina composta inserida em dois incrementos. Estes grupos foram fotoativados em alta potência (1200 mW/cm²). Em todos os grupos as raízes foram restauradas internamente com resina composta fotopolimerizável Z100, com fotoativação auxiliada por pinos plásticos fototransmissores, no comprimento de 8 mm, removidos após a polimerização, para a cimentação dos pinos metálicos pré-fabricados Reforpost com cimento resinoso Relyx ARC, o que proporcionou a obtenção do reforço radicular (resina composta + pino metálico). As raízes foram submetidas ao teste de pull out numa máquina universal de ensaios (Intron 3345) à velocidade de 1mm/min até deslocamento do reforço radicular. Os valores de resistência à tração foram expressos em MPa e submetidos à Análise de Variância dois fatores (&alpha;=0,05). A resistência à tração foi influenciada pela potência de fotoativação (P<0,05), mas não pela técnica de inserção da resina composta e nem pela interação dos fatores em estudo (P>0,05). A fotoativação em alta potência apresentou altos valores de resistência à tração (4,38±1,57) em comparação com a fotoativação em baixa potência (2,19±0,82), enquanto que a técnica de inserção em incremento único (3,62±1,60) ou dois incrementos (2,95±1,70) apresentou valores estatisticamente semelhantes. Concluiu-se que o aumento da potência de fotoativação influenciou positivamente na retenção da resina composta utilizada na restauração de raízes fragilizadas, independente da quantidade de incrementos utilizados / The aim of this ex vivo study was to evaluate by pull out test the influence of different curing light intensities, associated to different insertion techniques on the composite resin restoration retention of weakened roots. For this purpose forty maxillary human roots were used. The minimum length was standardized at 15 mm. The roots were weakened using 718PM; 730PM e 720PM drills with the aid of a parallelometer up to a depth of 8mm. Endodontic treatment was performed with K-type hand files only in the root section unreached by the weakening. Root canal filling was performed according to the lateral condensation technique using AHPlus sealer. Then cones were cut up to weakening length and cavity was cleaned.. The samples were assigned to four groups (n= 10) according to the insertion technique and curing light intensity: Group I, composite resin placed in bulk placement; Group II, composite resin placed in two increments. These groups were photoactivated with low intensity curing light (500 mW/cm²); Group III, composite resin placed in bulk placement; Group IV, composite resin placed in two increments. These groups were photoactivated with higth intensity curing light (1200 mW/cm²). In all groups the roots were restored internally with Z100 light-cured composite resin and photoactivated using light-transmitting plastic posts up to a depth of 8 mm. After polymerization the light-transmitting posts were removed. Then prefabricated metal posts were cemented with Relyx ARC resin-based cement, which provided the achieviment of root reinforcement (composite resin + metal post). The roots were subjected to pull out test by a universal testing machine (Intron 3345) at a speed of 1 mm/min until the root reinforcement was dislodged. Resistance values were expressed in Mpa and were subjected by 2-way Analysis of Variance (&alpha;=0,05). Curing light intensity influenced the tensile strength (p<0,05), however for composite resin insertion technique and for interaction between factors under study (P>0,05) no influence was found. Higth intensity curing light showed high tensile strength values (4,38±1,57) compared with low intensity curing light (2,19±0,82) whereas composite resin insertion technique using bulk placement (3,62±1,60) or two increments (2,95±1,70) showed similar values. Increasing the curing light intensity had positive influences on composite resin restoration retention in weakened roots, regardless of the amount of increments used.

De modo geral, os ciclos de cura para resina epóxi demandam algumas horas e elevadas temperaturas. Em busca de novas soluções para a otimização de processos sem perda de qualidade, bem como a economia de energia, diversos processos de cura de resina epóxi não convencionais foram desenvolvidos ao longo dos anos. O uso de irradiação de micro-ondas teve início após a Segunda Guerra Mundial, com a invenção do RADAR. A radiação de micro-ondas é uma radiação não-ionizante, com bom poder de penetração e boa transferência de calor em materiais absorvedores, ou materiais com cargas absorvedoras. A frequência usualmente utilizada em trabalhos de pesquisa e desenvolvimento é de 2,45GHz, a mesma disponível nos equipamentos comerciais e industriais existentes. Para a cura de resinas epóxi não são necessárias alterações no sistema reativo, com iniciadores específicos sensíveis a micro-ondas. O \"efeito micro-ondas\" proporciona um aumento da velocidade de colisão entre os reagentes que, associada à energia absorvida pelo sistema reacional, acelera a reação de cura, possibilitando a cura de resinas de tempo de uso longo (superior a 24 horas, em temperatura ambiente) em questão de minutos. Neste estudo foi utilizado inicialmente um sistema epóxi do tipo DGEBA, com endurecedor à base de anidrido e acelerador à base de amina, nas mesmas condições comerciais indicadas pelo fabricante. Testes iniciais com os fornos de micro-ondas selecionados foram realizados previamente a operação com sistemas epóxi. A cura do sistema já catalisado foi realizada em dois diferentes fornos de micro-ondas adaptados para uso em laboratório. A temperatura de degradação, e a temperatura de transição vítrea, foram avaliadas por técnicas de análise térmica. Cargas, pigmentos e aditivos também foram avaliados, no sentido de determinar suas influências em misturas com o sistema epóxi escolhido. Após estudos preliminares com o sistema epóxi puro, foram realizados testes em compósitos reforçados com fibra de vidro. Os resultados indicam que o processo é promissor, correspondendo ao observado em diversos artigos na literatura. / Generally, the cure cycles epoxy resin demand for few hours, and elevated temperatures. In search of new solutions for process optimization without loss of quality as well as energy saving, various processes of curing epoxy resin unconventional were developed over the years. The use of microwave irradiation began after World War II, with the invention of RADAR. The microwave radiation is non-ionizing radiation, with good power of penetration and good heat transfer in absorbing materials, or materials with absorbing fillers. The frequency usually used in research and development is of 2.45 GHz, the same is available in commercial equipment. For curing epoxy resins are not necessary changes in the system reactive with specific initiators sensitive to microwaves. The \"microwave effect\" provides increased on collision velocity between the reactants, which combined with energy absorbed by the reaction system, its accelerates the reaction curing, allowing the resin to cure long pot-life (times greater than 24 hours) in minutes. In this study, a DGEBA epoxy resin with an anhydride based hardener, and an initiator based on amine was used under the same conditions indicated by the manufacturer. Preliminary tests with the microwave ovens selected were executed before the operation with epoxy systems. The curing of the catalyzed system was performed in two different adapted microwave ovens for use in laboratory. The degradation temperature and the glass transition temperature were evaluated by thermal analysis techniques. Fillers, pigments and additives also were evaluated to determinate the influences with and without the epoxy system. After previous tests with the epoxy system alone, it was realized tests in composites form with glass fiber. The initial results indicate that the curing process by microwave irradiation is promising, and corresponding with the literature.

O tratamento térmico em compósitos restauradores diretos foi realizado a fim de verificar a influência sobre algumas propriedades, tais como a sorção, solubilidade, tenacidade à fratura e grau de conversão. Foram utilizados três compósitos: um nanoparticulado, um microhíbrido e um microparticulado. Duas fontes de luz (Halógena e LED) e dois períodos (48h e 28dias) de armazenagem, com exceção da solubilidade. O tratamento térmico foi realizado em estufa convencional (170o C por 5min), sendo metade dos corpos de prova (cps) tratados e a outra, apenas fotoativada.Para sorção e solubilidade, foram confeccionados 60 cps de acordo com os fatores analisados (n=5) em uma matriz metálica circular de dimensões 15 mm x1 mm. Para o cálculo da sorção e solubilidade, os cps foram pesados em uma Balança Analítica,inicialmente após a confecção do cp, 1hora, 24h, 48h, 7d, 14, 21 e 28d, a fim de estabelecer Massa Inicial (Mi) Massa absorvida (Ma) e Massa dessecada (Md). Para a tenacidade à fratura, foram confeccionados 240 cps de acordo com os fatores analisados (n=10) em uma matriz metálica de dimensões internas 25 mm x 5mm x 2,8 mm. O método utilizado foi o Single Edge Notch-Beam(SENB), com um entalhe de 2,3 mm posicionado no centro da matriz. Os cps eram levados à máquina universal para o ensaio de flexão e, após a ruptura, as superfícies de fratura eram analisadas no estereomicroscópio, para, em seguida, obter as imagens e calcular as dimensões do cps para inserir naequação da tenacidade à fratura.Já para o grau de conversão foram confeccionados 36 cps em uma matriz de acetato circular de 15 mm x 1 mm, posicionados entre duas lâminas microscópicas (n=3). O cálculo do grau de conversão foi determinado por espectroscopia no infravermelho (FTIR).Em geral, os estudos apresentaram uma influência significante do tratamento térmico, Dos resultados para a sorção o compósito, em geral, diminuiu,comparado aos grupos somente fotoativados em ambos os períodos. Entre as interações analisadas (Fonte de Luz X Período) foi significante para todos os grupos. Para a solubilidade a interação (Fonte de luz X Tratamento térmico foi significante para todos os grupos. Quanto à tenacidade à fratura, apenas o fator tratamento foi significante para os compósitos nanoparticulado e microhíbrido. Já para os microparticulados, houve influência dos fatores principais e dasinterações(Fonte de Luz X Período) e Fonte de Luz X Tratamento Térmico). De maneira geral, houve um aumento dos valores de tenacidade para todos os grupos. Já para o grau de conversão, houve um aumento significativo com relação ao tratamento e os períodos analisados dos compósitos. O tratamento térmico, em geral, influenciou positivamente as propriedades estudadas. Sendo assim, a opção de realizar o tratamento térmico nos compósitos de acordo com as propriedades e fatores analisados, torna a técnica passível de ser recomendada. / The post-curing heat treatment in direct composite treatment was done to verify the influence on some properties like sorption, solubility, fracture toughness and the degree of conversion. During the referred study it was used three composites: nanoparticle, a microhybrid and a microfill. Two sources of light (Halogen and LED) and two periods (48 hours and 28 days) for each one, but not to solubility. The postcuringwas done in dry heat sterilizer of 170º C for five minutes for, half of the test samples (TS) were treated and the other half were only photoactivated. It was made 60 TS to sorption and solubility according to the analyzed factors (n=5) in a 15mm x 1mm round metal matrix. To calculate sorption and solubility the TS were weighted in a analytical balance, right after the beginning of the production in 1 hour, 24 hours, 7days, 14 days, 21 days and 28 days respectively in order to establish the initial absorbed mass (Mi), the absorbed mass (Ma) and the desiccated mass (Md ). It was produced 240 TS to the fracture toughness according to factors (n=10) in a 25mm x 5mm x 2,8mm in metallic matrix. The Single Edge Notch-Beam (SENB), was the used method during this study with a notch of 2,3mm placed in the center of the matrix. The TS were taken to a universal machine to flexural test so after the rupture referred surface fractures were analyzed in a stereomicroscope and then it was possible to get the images to calculate the size of the TS to insert the calculus of the fracture toughness. To degree conversion were made 36 TS in a 15mm x 1mm circular acetate matrix placed between two microscopes slides (n=3). The degree conversion was determined a infrared spectroscopy (FTIR). In general the study showed a significant influence in relation post-curing heat treatment. In both periods the sorption of the composites have decreased in general comparison to the photoactivated only. The interactions(light source versus period) was significant for all groups. To solubility the interaction (light source versus post-curing heat treatment) was significant for all groups. In reference to fracture toughnessonly post curing heat treatment factor was significant to the nanoparticle and microhybrid composites. In other hand the microfill composite were influenced by the main factors and by the interactions (light source X periods) and (llght source X heat cured). In general there was an increase of the fracture toughness value in all groups. In relation to the degree conversion there was an increase significant of the composite during heat cured and analyzed periods. The post-curing heat treatment influenced all the studied properties of the direct composite in a positive way. Therefore the option of doing the heat cured treatment in the composites according to the properties and the analyzed factor is technically possible to be done.

Submitted by Maicon Juliano Schmidt (maicons) on 2015-03-30T18:22:27Z No. of bitstreams: 1 Israel de Oliveira.pdf: 2249672 bytes, checksum: 651678b57093fe8cfdec97b6e6da1274 (MD5) / Made available in DSpace on 2015-03-30T18:22:27Z (GMT). No. of bitstreams: 1 Israel de Oliveira.pdf: 2249672 bytes, checksum: 651678b57093fe8cfdec97b6e6da1274 (MD5) Previous issue date: 2014-01-31 / JTI Processadora de Tabaco do Brasil Ltda / Programa de Bolsas de Estudo Talentos Tecnosinos / O Brasil é um dos maiores produtores mundiais de tabaco de estufa e a região sul é a maior responsável por essa produção, principalmente o estado do Rio Grande do Sul. Uma das etapas do processo de beneficiamento desse produto é a secagem (cura) das folhas, que utiliza essencialmente lenha como fonte de energia. Esse trabalho apresenta um estudo dos aspectos energéticos que envolvem a cura de tabaco da espécie Virgínia, os resultados e análises das simulações realizadas no software TRNSYS, de um sistema solar térmico com aquecimento de água para complemento energético desse processo de cura. A partir de dados experimentais obtidos em processos de cura, foram definidos os parâmetros mais importantes para a determinação da carga térmica necessária e calculadas as perdas térmicas envolvidas. Os resultados apresentados pelas simulações mostraram que o sistema de energia solar proposto, atuando como fonte auxiliar de energia em uma estufa do tipo bulk, é capaz de atender completamente a carga térmica da primeira fase do processo de cura e contribuir com o aumento da temperatura na estufa necessário à cura dessa espécie de tabaco, gerando reduções no consumo de lenha do processo da ordem de 18 a 39 %, considerando que esse ocorra em um período de sete dias ensolarados no verão, na região de Santa Cruz do Sul-RS. / Brazil is one of the largest barn tobacco producers and the southern region is largely responsible for this production, especially the state of Rio Grande do Sul. One of the steps involved in this product’s processing chain is the leaves drying (curing), which essentially uses firewood as energy source. This work presents a study of the energy aspects involving the curing of Virginia tobacco, the results and analysis of simulations, using the TRNSYS software, of a solar thermal energy system with water heating to complement this curing process. From the experimental data obtained in curing processes, the most important parameters for the determination of thermal load were defined and the heat losses involved were calculated. The results presented by these simulations showed that the proposed solar energy system, acting as an auxiliary power source of a bulk type barn, can completely meet the thermal load of the first phase of the curing process and contribute to the increase of temperature in the barn necessary to cure this kind of tobacco, reducing 18-39 % the firewood consumption in the process, assuming a seven sunny days period during the summer at the region of Santa Cruz do Sul – RS.

Made available in DSpace on 2017-07-24T19:22:22Z (GMT). No. of bitstreams: 1 VeridianaCamilotti.pdf: 624713 bytes, checksum: f2d0756374875dd344e9aeeecdaac9cc (MD5) Previous issue date: 2005-12-15 / The following study aims to evaluate the influence between the different light sources in curing light of resin cement. The occlusal surfaces of twenty recently extractew undamaged third human molars were removed in order to expose dentine surface. Immediately after, the bond system (Adper Single Bond/3M ESPE ) and resin cement (RelyX ARC/ 3 M ESPE) was applied in accordance with manufacturer instructions. Second generation laboratory resin of 4 mm thickness was applied over tooth and light curing proceeded. According to light sources employed the teeth were divided in four groups: G1 – Control Optilux 401/ Demetron (QTH); G2 – L.E.Demetron/Demetron (LEDs ); G3 – Ultra-Lume LED5 (LEDs) e G4 – Optilight CL/ Gnatus (LEDs). Restored teeth were stored in physiologic serum for 24 h. After stored, teeth were sectioned into vestibule-tongue and mesial-distal to delimit an area with approximately 1 mm², the third cut was made on the base of the tooth in order to release the samples. The microtensile test was employed to reveal the bond strength values in MPa. The data underwent statistical analysis with p<0,05. No statistical significancent difference was found betweem the groups. In conclusion the resin cement bon strength of dual fotoative with LEDs showed similar adhesive resistance test those revelead when halogen lamp was used, and that there also were not differences among the different apparels LEDs used in that study. / Avaliou-se a influência de diferentes fontes de luz na fotoativação de um cimento resinoso dual. A superfície oclusal de 20 terceiros molares humanos hígidos foi removida para expor a superfície dentinária. Em seguida, foi aplicado sistema adesivo (Adper Single Bond/3M ESPE ) e cimento resinoso dual (RelyX ARC/ 3 M ESPE), de acordo com as recomendações do fabricante. A resina laboratorial de segunda geração (Gradia™ GC® América Inc), com espessura de 4 mm, foi adaptada sobre o dente e procedeu-se à fotoativação. De acordo com o aparelho de luz empregado, os elementos dentais foram divididos em 4 grupos: G1 – controle Optilux 401/ Demetron (QTH); G2 – L.E.Demetron 1/Demetron (LEDs ); G3 – Ultra- Lume LED5/Ultradent (LEDs) e G4 – Optilight CL/ Gnatus (LEDs). Os dentes restaurados foram armazenados em soro fisiológico por 24 h. Após o armazenamento, os dentes foram seccionados no sentido vestíbulo-lingual e mésiodistal, para delimitar uma área de 1 mm². Um terceiro corte na base do dente foi realizado com o objetivo de “soltar” os espécimes. O teste de micro-tração foi empregado para fornecer os valores da resistência adesiva em MPa. Os dados foram submetidos à análise estatística pelo teste ANOVA com p<0,05. Não houve diferenças estatisticamente significante entre os grupos testados. Concluiu-se que a resistência adesiva da interace adesiva fotoativado com LEDs foi semelhante à resistência adesiva obtida quando a lâmpada halógena foi utilizada e que também não houve diferenças entre os diferentes aparelhos LEDs empregados nesse estudo.