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Thesis (DPhil (Electrical and Electronic Engineering))--University of Stellenbosch, 2011. / ENGLISH ABSTRACT: The Karoo Array Telescope (KAT) will be used by South Africa in its bid to host the international Square Kilometre Array (SKA). As the SKA will have orders of magnitude greater sensitivity than existing radio telescopes, it will also be concomitantly more sensitive to radio frequency interference (RFI). The influence of RFI on a differential mode (DM) KAT conductive system is an unavoidable phenomenon. In this context, the conductive or galvanic system can, in its most basic form, consist of a source, a load, and connecting conductors. It can also, in the case of the KAT-7 seven-dish interferometer, consist of each telescope, its functional cabling, and the main correlator connecting the telescopes together. However, additional connections between the system and the environment exist. These might be an intentional connection made to the earthing layout, or unintentional connections due to parasitic capacitances and inductive connections. As a result of this, additional conductive systems are created which carry common mode (CM) currents. Interference present in such CM paths enters the DM system through the transfer impedance (Zt) between them. To reduce or eliminate this interference in the DM system, Zt has to be minimised. The use of an earthed parallel conductor (EPC as commonly referred to) in the form of a cable tray is considered to be one of the principal methods to reduce Zt. The properties of cable trays as EPCs at wavelengths which are greater than the tray length are well documented. One main focus in this dissertation is on cable tray mid-span and end connections. They are not well described in the literature over the wide range of frequencies that is expected for KAT developments. The influence of the most common connections on the measured and computed Zt of the cable tray is determined. Computer Simulation Technology’s Microwave Studio (CST MWS) is employed to validate the measured results and also to enable visualisation of the fields and currents. Recommendations for the best connection to use for any cable tray installation is given. The overall shielding ability of optimally-connected cable trays has been evaluated using a physical and computational model. In both cases the induced voltage on a victim conductor, and far-field gain functions for varying angles of incidence onto the model, are determined. The results also show that for certain scenarios, most of the coupling to the victim conductor, takes place inside the end enclosure and not the cable tray. In general, properly-connected cable trays do provide protection to their enclosed conductors, even at frequencies were the wavelength is much shorter than the width of the tray. The second main focus arises from an on-site radio frequency (RF) current audit undertaken on two of the seven KAT-7 telescopes. Shielding measures, such as interface barriers at the floor and roof of the lower telescope pedestal, are studied. The investigation is facilitated by the development of an accurate physical and computational scale model of the dish. Direct current injection and plane wave illumination methods are used to excite the system. The measured CM current distributions are compared and comments made regarding the validity of the measurement procedure. The CM currents, measured around the outside of the lower pedestal show higher levels when a direct current path to ground is established, as opposed to when no clear path exists. This finding suggests at least two methods of preventing CM interference entering or leaving the pedestal: harden the floor and roof barriers, or manage current paths outside the telescope. Related to this, CM currents measured either side of the telescope interface barriers, are used to determine the level of shielding the interface provides. When compared to the common definition of shielding effectiveness, the current measurement provides more conservative shielding estimates. The research in this dissertation has influenced, and will continue to influence, the layout of galvanic systems for the present KAT-7 structures and the anticipated developments to MeerKAT. / AFRIKAANSE OPSOMMING: Die Karoo Array Telescop (KAT) sal gebruik word deur Suid-Afrika in sy poging om die bod te kry om die internasionale Square Kilometre Array (SKA) te huisves. Aangesien die SKA ordes meer sensitief sal wees as bestaande radioteleskope, sal dit terselfdertyd ook meer sensitief wees vir radio frekwensie steurnisse. Die invloed van radio frekwensie steurnisse op die differentiëlemodus KAT geleidende netwerk is iets onvermydeliks. Binne hierdie konteks kan die geleidende netwerk, in sy mees basiese vorm, bestaan uit ʼn bron, ʼn las, en verbindingsgeleiers. Dit kan ook, in die geval van die KAT-7 sewe-teleskoop interferometer, bestaan uit elke teleskoop, sy funksionele bekabeling, en die korrelator wat die verbinding is tussen al die teleskope. Daar is egter, addisionele verbindings tussen die netwerk en die onmiddellike omgewing rondom dit. Hierdie verbindings kan opsetlik gemaak word deur byvoorbeeld, verbinding van die netwerk se aardkabel aan die res van die beaarding, of onopsetlik deur parasitiese kapasitansies en induktiewe verbindings. As gevolg hiervan word addisionele geledende netwerke geskep waarin gemenemodus strome kan vloei. Indien daar wel strome in die gemenemodus netwerk vloei, word dit oorgedra aan die differentiëlemodus netwerk deur ʼn oordragimpedansie (Zt) wat teenwoordig is tussen die twee. Om dus die steurnisse in die differentiëlemodus netwerk te verminder of te elimineer, moet Zt tot ʼn minimum beperk word. Die gebruik van ʼn geaarde parallelle geleier in die vorm van ʼn kabelkanaal, word beskou as een van die mees doeltreffendste metodes om Zt te verminder. Die eienskappe van kabelkanale as geaarde parallelle geleiers by frekwensies waar die golflengtes langer is as die van die kabelkanaal, is volledig gedokumenteer. Een van die belangrikste fokuspunte in hierdie verhandeling is rakende die kabelkanale se middel en eindpuntverbindings. Hulle word nie goed beskryf in die beskikbare literatuur nie, en weliswaar vir wyeband doeleindes wat vir KAT ontwikkelinge verwag word. Die invloed van die mees algemeenste kabelkanaal verbindings op gemete en berekende Zt word bepaal. Computer Simulation Technology’s Microwave Studio (CST MWS) word eerstens, gebruik om die akkuraatheid van die gemete resultate te bewys en tweedens, deur visualisering van E-veld en gemenemodus oppervlak strome. Aanbevelings vir die beste verbindings vir enige kabelkanaal opstelling word gegee. Die algemene afskerminsvermoeë van ʼn idiaal-verbinde kabelkanaal word bepaal deur middel van metings en simulasies. In beide gevalle word die geïnduseerde spanning op ʼn slagoffer kabel, en die verveld aanwins funksie bepaal vir verskillende invalshoeke op die model. Die resultate toon verder dat vir spesifieke gevalle wat beskou word, die meeste koppeling binne die kabinet aan die einde van die kabelkanaal plaasvind. Oor die algemeen verskaf goed verbinde kabelkanale wel ʼn sekere vlak van beskerming aan kabels binne die kabelkanaal, selfs by frekwensies waar die golflengte baie korter is as die breedte van die kabelkanaal. Die tweede belangrike fokuspunt spruit voort uit ʼn radio frekwensie stroomoudit, wat twee van die KAT-7 teleskope evalueer het. Afskermingsmatreëls soos die kabelhindernisse op die vloer en dak van die onderste teleskoop voetstuk, word bestudeer. Tesame met die metings op die werklike teleskoop wat geneem is, word ʼn akkurate fisiese en simulasie skaalmodel geskep om die metings beter te analiseer. Direkte stroominspuitings metode en platvlakgolf beligting word gebruik om gemenemodus strome op die teleskoop se struktuur te induseer. Die gemenemodus stroomverspreiding vir beide tegnieke word vergelyk in ʼn poging om kommentaar te lewer rakende die geldigheid van die meettegniek. Die gemenemodus strome wat aan die buitekant van die teleskoop voetstuk gemeet word, is hoër wanneer ʼn direkte stroompad na grond op die voetstuk geskep word in vergelyking met ʼn ongedefinieerde pad. Hierdie verskynsel dui daarop dat ten minste twee metodes bestaan om die ongevraagde gemenemodus strome te verhoed om aan die binnekant van die teleskoop voetstuk te vloei. Die een is die verbetering van die vloer en dak kabelhindernisse, en die ander is verbetering van die stroompad (stroompaaie) aan die buitekant van die voetstuk sodat ʼn meer direkte pad na grond geskep word. Die gemiddelde gemenemodus strome weerskante van die kabelhindernis, kan gebruik word op te bepaal hoeveel afskerming die hindernis bied. Indien die berekende waardes by verskillende frekwensies vergelyk word met die tradisionele filter doeltreffendheid (Zt), word ʼn meer konserwatiewe beraming verkry. Die navorsing in hierdie verhandeling het alreeds, maar sal ook die toekomstige uitleg van galvaniese stelsels vir KAT-7 asook die verwagte MeerKAT beïnvloed.

O trabalho visa o desenvolvimento do sistema para medidas de distribuição de corrente e ampliação de escala (50 cm²) buscando aperfeiçoar as condições de preparação do conjunto eletrodo membrana (MEA) quanto às condições de operação da célula e avaliar a melhor geometria. Foram realizados estudos de síntese de catalisadores de Pt-M e avaliação do desempenho desses materias e das rotas de síntese utilizadas com objetivo de aplicar estes materias em sistemas de maior escala. A insuficiência do desempenho e estabilidade dos catalisadores são fatores que ainda inviabilizam o uso em larga escala das células a combustível de eletrólito polimérico sólido, destacando-se as perdas associadas ao desempenho do cátodo. Os catalisadores preparados foram nanopartículas bimetálicas PtM/C (M = Fe, Co e Ni) suportadas em carbono de elevada área superficial, por duas rotas sintéticas. Foram utilizadas as rotas: ácido fórmico e etilenoglicol modificado (EG). Em ambas as rotas se buscou catalisadores com alto grau de incorporação do segundo metal, tamanho de partícula pequeno e bom desempenho catalítico do cátodo. Observou-se que pela rota do ácido fórmico com modificações no processo de síntese é possível obter a incorporação nominal do segundo metal no catalisador, porém há desvantagem de o tamanho de partícula ser elevado. Pela rota do EG obteve-se catalisadores com pequeno tamanho de partícula, porém a incorporação do segundo metal mostrou-se ineficiente. Os estudos de ampliação de escala foram realizados em células de 50 cm2 variando-se as condições de operação; i) diferentes placas de distribuição de gás, e ii) diferentes valores de fluxo dos gases reagentes. Foi observado que a baixos fluxos de gases a quantidade de reagente é insuficiente para ser difundida por todo eletrodo, o que ocasiona reação apenas na região de entrada de gases no sistema, ocasionando uma rápida limitação em obter-se densidades de corrente alta. Pode-se observar que a diferença de desempenho entre as placas é pequena, porém a placa serpentina 6 apresentou melhor desempenho. O desempenho dos cátodos preparados com catalisadores comerciais e os sintetizados no laboratório nas células de 50 cm² mostrou sofrer bastante influência das condições de operação comparada com as células de 4,6 cm². / The work aims at the development of the system for current distribution measurements and scale (50 cm²) seeking to improve the conditions of preparation of the membrane electrode assembly (MEA) as the cell operating conditions and evaluate the best geometry. We were performed catalyst synthesis studies of Pt-M and performance evaluation of these materials and the synthetic routes used in order to apply these materials in larger-scale systems. The failure of the performance and stability of the catalysts are factors that make yet infeasible the scale up use for solid polymer electrolyte fuel cells, highlighting the losses associated with the performance of the cathode. The nanoparticles of bimetallic catalysts Pt-M/C (M = Fe, Co and Ni) supported on high surface area carbon were prepared by two different synthetic routes. The synthesis route utilized were formic acid and modified ethylene glycol (EG). In both route search catalysts with a high degree of incorporation of the second metal, small particle size and good catalytic performance. It was observed that the route of formic acid with modifications in the synthesis process it is possible to obtain the average incorporation of the second metal in the catalyst, but there is a disadvantage of the particle size is high. The route of EG modified was obtained catalysts with small particle size, but incorporation of the second metal was inefficient. The scale-up studies were performed in 50 cm2 cell varying operating conditions: i) different gas distribution plates and ii) different values of flow of reactant gases. It was observed that at low gas flows the amount of reagent is insufficient to be spread throughout the electrode, causing reaction only in the region of entry of gases in the system, causing a fast limitation in obtain high current densities. It can be observed that the performance difference between the plates is small, but the plate serpentine 6 showed the best performance. The performance of the cathodes prepared with commercial catalysts and synthesized in the laboratory in 50 cm² cells showed considerable influence the operating conditions compared to cells 4,6 cm².

Cette thèse a été dirigée par le Professeur Kauffmann de l’Université de Franche-Comté. Le co-directeur de l’Ecole Royale Militaire était le Docteur Johan Gallant et les essais à l’Institut franco-allemande de recherches de Saint-Louis (ISL) étaient encadrés par le Docteur Markus Schneider.Un lanceur à rails conventionnel est composé de deux rails conducteur connecté par un projectile. L’interaction entre le champ magnétique induit par le courant dans les rails et le courant dans le projectile résulte en une force électromagnétique accélérant. Dans cette thèse on utilise un projectile avec deux ponts de courant. Pour un lanceur à rails conventionnel la méthode la plus efficace pour augmenter la force sur le projectile est d’augmenter le courant dans les rails. Mais la densité de courant est limitée. L’échauffement des contacts entre les rails et les ponts de courant par l’effet Joule et la force de frottement, peut résulter dans la transformation d’un contact solide dans un contact plasma, ce qui est à éviter. Une possibilité d’adresser ce problème est d’ajouter des ponts de courant pour améliorer la distribution de courant. Une autre possibilité est d’appliquer un champ magnétique extérieur généré par un circuit extérieur qui nous permet d’augmenter la force électromagnétique sans augmenter le courant dans le circuit intérieur. Dans cette thèse l’objectif est d’étudier la distribution de courant et de température dans un projectile à deux ponts de courant pour un lanceur augmenté. Comme les deux ponts de courants et les rails du circuit intérieur forment un circuit fermé, le champ augmenté va induire un courant de circulation qui influence la distribution de courant entre les brosses. Le premier modèle de simulation est un modèle global du lanceur en PSpice qui nous permet de déterminer les courants globaux, la force électromagnétique, la position et la vitesse du projectile et la température moyenne des brosses. Le modèle global prend en compte l’effet de peau dû à la vitesse et est validé par des résultats expérimentaux. Le deuxième modèle est un modèle local en ANSYS, un code à éléments finis, pour un projectile fixe. Ce modèle permet une étude locale de la distribution de courant et de température. Un modèle pour la zone de contact entre les rails et la brosse est introduit. Le modèle local est utilisé pour calculer les coefficients de l’équation de force dans le modèle global. Les résultats des deux modèles de simulation sont cohérents.Le lanceur LARA, utilisé pour les essais, a une longueur de 1.5 m et un calibre de 15 mm. On disposait de trois bancs de condensateurs pour l’alimentation du lanceur en configuration non-augmenté et augmenté. Les vitesses à la bouche obtenues varient entre 48 et 214 m/s. Pour la détermination de la distribution de courant nous avons utilisé une méthode proposée par [SCH05a]. Cette méthode est une combinaison d’une mesure de tension entre deux pins dans les rails et dans une boucle. Nous avons constaté que les signaux obtenus avec cette méthode, appliquée dans ce régime de vitesse, sont perturbés par les courants de Foucault induits avant le projectile et les résultats ne répondent pas à nos attentes. Une méthode analytique basée sur la mesure de tension dans la boucle a été développée. Les résultats expérimentaux sont comparés avec les simulations. Nous avons constaté une bonne correspondance entre les valeurs des courants maximaux dans les rails calculés avec PSpice et les valeurs expérimentales, mais le courant calculé avec PSpice est plus faible dans la phase décroissante du courant. Les erreurs sur la vitesse sont inférieures à 10 %. Les deux modèles de simulation et les essais montrent que la brosse avant porte la plus grande partie du courant. La dernière partie de cette thèse est une étude paramétrique avec ANSYS pour l’avant-projet du circuit intérieur d’un lanceur à rail existant. / This thesis was supervised by Professor Jean-Marie Kauffmann of the University of Franche-Comté. The co-director at the Royal Military Academy was Dr. Johan Gallant and the experiments at Franch-German Research Institute ISL were directed by Dr. Markus Schneider. A conventional electromagnetic railgun is composed of two conducting rails connected by a projectile. The magnetic field generated by the current in the rails interacts in the projectile resulting in an electromagnetic force accelerating the projectile. The projectile used in this thesis is two brush projectile. For a conventional railgun the most efficient way to increase the force on the projectile is to increase the current in the rails. But the current density is limited. The heating of the sliding contacts between the brushes and the rails due to the Joule losses and the friction can cause the contacts and can result in contact transition which we want to avoid. One way to reduce the heating is to add more current brushes to obtain a better current distribution between the brushes. Another way is to add an extra pair of rails and create an additional magnetic field. This augmenting field allows us to increase the electromagnetic force without increasing the current through the projectile. In this thesis the current and heat distribution in a two brush projectile in a parallel augmented railgun is studied through simulations and experiments. Because the current brushes and the inner rails form a closed loop, the augmenting field will induce a loop current and influence the current distribution between the brushes. The first simulation model is a global model of the railgun in PSice which allows us to predict the global currents as well as the average temperature in the brushes, the force on the projectile and the position and the velocity of the projectile. The model takes into account the velocity skin effect and was validated based on experiments. The second model is a finite element model in ANSYS for a fixed projectile. This model allows a local study of the current and temperature distribution in the projectile. A model for the contact between the rails and the projectile is introduced. The local model is used to calculate the time-dependent coefficients for the force equation used in the global model. Both simulation models are compared and a good correspondence is found. The LARA railgun of ISL with a length of 1.5 m and a square caliber of 15 mm has been used for the experiments. A maximum of three capacitor banks was used for the non-augmented and the augmented configuration. The muzzle velocities obtained in the experiments vary between 48 and 214 m/s. To determine the current distribution between the brushes a technique proposed by [SCH05a] has been used. It is based on the measurement of the voltage between two pins in the rails in combination with the voltage in a loop. When applied to this velocity range, the eddy currents in front of the projectile hamper the interpretation of the signals and the results are not what we expected. An analytical method for the determination of the current distribution based on the voltage in the loop was introduced. The results are then compared with the results of the simulations. The maximum current in the rails found with PSpice shows a good correspondence with the experiments, the calculated decrease of the current is slightly overestimated. The errors on the velocities are less than 10%. Both simulation models and experiments show that the brush towards the breech carries the greater part of the current for the non-augmented as well as the augmented railgun. In the last part a parametric study is carried out with ANSYS for the preliminary design of an augmenting circuit for an existing railgun.

Elkhorn and Staghorn corals (Acropora palmata, A. cervicornis) were listed as threatened species under the Endangered Species Act (ESA) in 2005. The threatened status of these species is unprecedented given the vital role they historically played as major constructors of western Atlantic and Caribbean coral reefs. The goal of my study was to evaluate the current extent of habitat of the two species using a database of reported in situ observations. From these observations, potential habitat maps were produced based on benthic substrata and depth parameters throughout the Florida reef tract using GIS software. Locations of 99% of A. palmata observations and 84% of A. cervicornis observations coincided with previously mapped reef or hardbottom habitat. These results indicate that potential habitat for A. palmata is currently well defined and that potential habitat for A. cervicornis is more variable than that for A. palmata. This study provides a starting point in the creation of a revised critical habitat delineation for Acropora spp. in Florida. Using the mapped reef and hardbottom classifications throughout the Florida reef tract, probable habitat maps were generated using buffers that incorporated 95% and 99% of reported observations of colonies of Acropora spp. One of the most important differences between the previously generated critical habitat map and the new probable habitat map is observed in the southeast Florida region, where probable habitat extends further north than critical habitat and, thus, encompasses additional habitat for A. cervicornis and potentially A. palmata.

Es werden die Ergebnisse der Untersuchungen von Stromverteilungen an Solarzellen und Solarmaterial durch magnetische, elektrische und optische Messmethoden gezeigt. Die neue magnetfeldtopographische Messmethode CAIC wird hierbei erläutert und deren Stromverteilungen mit Ergebnissen der IR-Durchlichtmikroskopie, der LBIC- und der LIT-Methode verglichen und ausgewertet. Auf Basis der durchgeführten Untersuchungen und der Annahme des Vorhandenseins einer Korngrenzendekoration werden die Stromverlaufsmodelle einer elektrisch aktiven Korngrenze für eine Probe mit pn-Übergang sowie für eine Probe ohne pn-Übergang gezeigt. Anhand von CAIC-Messungen können die Position und die Orientierung leitfähiger und oberflächennaher SiC- und Si₃N₄-Ausscheidungen in mc-Silizium ohne pn-Übergang ermittelt werden. Hierfür wird ein Stromverlaufsmodell gezeigt. Weiterhin werden Zellmikrobrüche, Fehler in der Kontaktstruktur und Layoutunterschiede der Kontaktstruktur durch CAIC-Messungen an Solarzellen eindeutig nachgewiesen.

Made available in DSpace on 2015-03-26T13:35:22Z (GMT). No. of bitstreams: 1 texto completo.pdf: 1377074 bytes, checksum: 9d0bcaa0daae6ad97072fe3a335f2cad (MD5) Previous issue date: 2007-02-26 / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior / The quantum Hall effect (QHE) remains the target of an immense research effort twenty six years after its discovery. In fact this phenomenon has been a source of fundamental questions. Among the open problems in the field is the spatial distribution of the electric current in the quantum Hall effect. This question has been in debate since its discovery. Some experimental and theoretical results indicate the Hall current is distributed uniformly across the width of a Hall bar. Contradictorily, other results suggest the current flows mostly in a narrow region along the device s edges. Prominent works by Yahel et al. [PRL 76, 2149 (1996) and PRL 81, 5201 (1998)] shed new lights on the subject by using an experimental technique that came to known as inductive coupling . This method is based on the measurement of the nanovoltage signal induced by an alternating Hall current in a compact coil, carefully positioned above one edge of a Hall bar. It is perhaps the least invasive method available to study the current distribution in the QHE. It remained nonetheless a challenging experiment, as regards the positioning and making of the coil and the measurement of the minute induced voltage. We showed with calculations that it is possible to greatly simplify the aforementioned technique and make it more sensitive and useful by fabricating the coil on the chip containing the Hall bar. The concept was tested experimentally replacing the semiconductor Hall bar with a metal strip whose current distribution is known to be uniform from the electrodynamics. The voltage induced by the current in the metal strip in a nearby coil fits was measured. It fits in precisely, in magnitude and phase, with the values calculated. As our most important contribution, we found out that the presence of a two dimensional electron gas (2DEG), located 200 nm underneath the coil, increases the induced signal by thirty times. The magnitude and phase of the signal indicate it comes mostly from the current induced in the 2DEG by the alternating Hall current. This amplification effect renders a stronger signal with a sample containing a milimetric size Hall bar and a coil with ten turns, conveniently fabricated by simple optical lithography, than the signal measured by Yahel, using a ten times larger Hall bar and a handcrafted coil with 3,000 turns. We speculate that the effect of the 2DEG shall allow the use of our technique to map the current distribution in the QHE and also to study nanoscopic magnetic systems. / O efeito Hall quântico (EHQ) permanece como foco de um imenso esforço de pesquisa vinte e seis anos após sua descoberta. De fato este fenômeno tem levantado uma série de questões fundamentais. Entre os problemas em aberto nesse campo está a distribuição espacial de corrente elétrica durante o efeito Hall quântico. Esta questão tem sido continuamente debatida desde a sua descoberta. Alguns experimentos e modelos teóricos indicam que a corrente se distribui uniformemente pela largura da ponte Hall. Contraditoriamente, outros resultados sugerem que a corrente flui predominantemente nas bordas do dispositivo. Trabalhos importantes de Yahel et al. [PRL 76, 2149 (1996) e PRL 81, 5201 (1998)] trouxeram novas pistas sobre o assunto usando a técnica experimental que ficou conhecida como "acoplamento indutivo . O método é baseado na medida da tensão induzida (da ordem de dezenas de nanovolts) por uma corrente Hall alternada em uma bobina compacta, cuidadosamente posicionada acima de uma das bordas da ponte Hall. Ele é talvez o método menos invasivo disponível para estudar a distribuição de corrente no EHQ. Entretanto, trata-se de uma técnica experimentalmente desafiadora no que se refere ao posicionamento e a fabricação da bobina e a medida tênue da tensão induzida. Mostramos com cálculos que é possível simplificar grandemente a técnica mencionada e fazê-la mais sensível e útil fabricando a bobina no mesmo chip da ponte Hall. O conceito foi testado experimentalmente substituindo a ponte Hall semicondutora por uma tira metálica cuja distribuição de corrente é conhecida a priori da eletrodinâmica. Medimos a tensão induzida pela corrente na tira metálica na bobina vizinha. O resultado ajusta-se perfeitamente, em magnitude e fase, aos valores calculados. Como nossa contribuição mais importante, descobrimos que a presença de uma gás bidimensional de elétrons (2DEG), localizado a 200 nm abaixo da bobina, aumenta o sinal induzido por um fator de trinta. A magnitude e a fase do sinal indicam que ele tem origem na corrente induzida no 2DEG pela corrente Hall alternada. O efeito de amplificação fornece um sinal mais forte em uma amostra contendo uma ponte Hall com dimensão milimétrica e com uma bobina com dez voltas, convenientemente fabricada por litografia óptica, do que o sinal medido por Yahel, usando uma ponte Hall dez vezes maior e uma bobina manufaturada com 3000 voltas. Especulamos que o efeito do 2DEG poderá permitir que a nossa técnica seja usada para mapear a distribuição de corrente no EHQ e também no estudo de sistemas magnéticos com dimensões nanométricas.

La modélisation mathématique des systèmes électrochimiques, et en général la modélisa- tion des systèmes fluidiques réactifs en présence de champs électriques, est un problème d’une complexité telle que des solutions analytiques n’existent que dans des cas très simpli- fiés et la solution numérique est, malgré toute la puissance de calcul moderne, encore très difficile. À ce jour, les avancées dans la modélisation au niveau des modèles d’écoulement sont majeures, mais la modélisation couplée de l’écoulement, avec le champ électrique en présence de solutions concentrées demeure encore un défi de taille. Le couplage des diffé- rents champs décrits par les modèles mathématiques devient critique dans les régions où ont lieu les réactions hétérogènes aux interfaces chargées modélisées par l’équation non linéaire de Butler-Volmer. Les logiciels commerciaux modernes commencent à permettre de coupler les modules d’électrochimie avec la mécanique des fluides numérique (CFD), mais l’ impossibilité d’ac- céder au code source ne permet pas au chercheur de modifier à volonté la formulation des modèles. Par conséquent, le projet de recherche actuel vise le développement d’une plate-forme logicielle ouverte (open-source) comme OpenFOAM, qui peut garantir une complète accessibilité au code-source, la liberté des utilisateurs à faire des modifications, la transparence des détails des modèles, et tous les autres développements qui sont requis pour chaque problème rencontré par les chercheurs. Le développement de modèles reposant sur des lois physiques établies permettra la modéli- sation des systèmes électrochimiques complexes, et la compréhension des phénomènes qui s’y déroulent. Il vise la modélisation du transfert de masse d’une cellule où l’écoulement de la solution concentrée (molten salt) est turbulent, biphasique et incompressible, et les réactions électrochimiques de surface sont calculées en utilisant une distribution tertiaire de densité de courant. Le principal enjeu sur le plan scientifique, dans le cadre de ce projet, demeure donc de développer un modèle qui soit bien calé sur le problème technologique visé afin qu’il puisse reproduire de façon réaliste les systèmes électrochimiques. Il vise éga- lement à amener la modélisation à un point où l’outil pourra être utilisé comme instrument de prédiction et de validation de nouveaux concepts des systèmes électrochimiques. / Abstract: The modeling of electrochemical systems, and in general the modeling of reacting flows ex- posed to electric field, is a complex problem to the point that analytic solutions exist only for simplified cases despite the increasing computer power. The state of art shows major improvements in the fluid-dynamics of electrochemical reactors; but the full coupling of the flow with the electric field in presence of concentrated electrolytic solutions still needs to be properly investigated. The coupling gets even more critical along the charged in- terfaces where heterogeneous reactions are modeled through the non-linear Butler-Volmer equation. Commercial software are slowly try to connect electrochemical modules to the well val- idated CFDs, but most of the time costly licenses, and poor accessibility to the source code, do not allow a deep integration between the two. Instead, this research study pro- poses an open-source code implemented in OpenFOAM, that guarantees full accessibility to the source code, user’s modifications, full transparency of the model’s details, and any possible further developments required by the specificity of the problem. The final code implements the mass transfer of a cell where the concentrated solution (molten salt) is a two-phase turbulent incompressible flow and the electrochemical surface reactions consider tertiary current distributions. The aim of this work is to create an open source platform to predict and analyze industrial reactor’s performances. The advanced modeling can be later exploited and used as a validation instrument for new electrochemical concepts.

O trabalho visa o desenvolvimento do sistema para medidas de distribuição de corrente e ampliação de escala (50 cm²) buscando aperfeiçoar as condições de preparação do conjunto eletrodo membrana (MEA) quanto às condições de operação da célula e avaliar a melhor geometria. Foram realizados estudos de síntese de catalisadores de Pt-M e avaliação do desempenho desses materias e das rotas de síntese utilizadas com objetivo de aplicar estes materias em sistemas de maior escala. A insuficiência do desempenho e estabilidade dos catalisadores são fatores que ainda inviabilizam o uso em larga escala das células a combustível de eletrólito polimérico sólido, destacando-se as perdas associadas ao desempenho do cátodo. Os catalisadores preparados foram nanopartículas bimetálicas PtM/C (M = Fe, Co e Ni) suportadas em carbono de elevada área superficial, por duas rotas sintéticas. Foram utilizadas as rotas: ácido fórmico e etilenoglicol modificado (EG). Em ambas as rotas se buscou catalisadores com alto grau de incorporação do segundo metal, tamanho de partícula pequeno e bom desempenho catalítico do cátodo. Observou-se que pela rota do ácido fórmico com modificações no processo de síntese é possível obter a incorporação nominal do segundo metal no catalisador, porém há desvantagem de o tamanho de partícula ser elevado. Pela rota do EG obteve-se catalisadores com pequeno tamanho de partícula, porém a incorporação do segundo metal mostrou-se ineficiente. Os estudos de ampliação de escala foram realizados em células de 50 cm2 variando-se as condições de operação; i) diferentes placas de distribuição de gás, e ii) diferentes valores de fluxo dos gases reagentes. Foi observado que a baixos fluxos de gases a quantidade de reagente é insuficiente para ser difundida por todo eletrodo, o que ocasiona reação apenas na região de entrada de gases no sistema, ocasionando uma rápida limitação em obter-se densidades de corrente alta. Pode-se observar que a diferença de desempenho entre as placas é pequena, porém a placa serpentina 6 apresentou melhor desempenho. O desempenho dos cátodos preparados com catalisadores comerciais e os sintetizados no laboratório nas células de 50 cm² mostrou sofrer bastante influência das condições de operação comparada com as células de 4,6 cm². / The work aims at the development of the system for current distribution measurements and scale (50 cm²) seeking to improve the conditions of preparation of the membrane electrode assembly (MEA) as the cell operating conditions and evaluate the best geometry. We were performed catalyst synthesis studies of Pt-M and performance evaluation of these materials and the synthetic routes used in order to apply these materials in larger-scale systems. The failure of the performance and stability of the catalysts are factors that make yet infeasible the scale up use for solid polymer electrolyte fuel cells, highlighting the losses associated with the performance of the cathode. The nanoparticles of bimetallic catalysts Pt-M/C (M = Fe, Co and Ni) supported on high surface area carbon were prepared by two different synthetic routes. The synthesis route utilized were formic acid and modified ethylene glycol (EG). In both route search catalysts with a high degree of incorporation of the second metal, small particle size and good catalytic performance. It was observed that the route of formic acid with modifications in the synthesis process it is possible to obtain the average incorporation of the second metal in the catalyst, but there is a disadvantage of the particle size is high. The route of EG modified was obtained catalysts with small particle size, but incorporation of the second metal was inefficient. The scale-up studies were performed in 50 cm2 cell varying operating conditions: i) different gas distribution plates and ii) different values of flow of reactant gases. It was observed that at low gas flows the amount of reagent is insufficient to be spread throughout the electrode, causing reaction only in the region of entry of gases in the system, causing a fast limitation in obtain high current densities. It can be observed that the performance difference between the plates is small, but the plate serpentine 6 showed the best performance. The performance of the cathodes prepared with commercial catalysts and synthesized in the laboratory in 50 cm² cells showed considerable influence the operating conditions compared to cells 4,6 cm².