abstract: When air is supplied to a conditioned space, the temperature and humidity of the air often contribute to the comfort and health of the occupants within the space. However, the vapor compression system, which is the standard air conditioning configuration, requires air to reach the dew point for dehumidification to occur, which can decrease system efficiency and longevity in low temperature applications. To improve performance, some systems dehumidify the air before cooling. One common dehumidifier is the desiccant wheel, in which solid desiccant absorbs moisture out of the air while rotating through circular housing. This system improves performance, especially when the desiccant is regenerated with waste or solar heat; however, the heat of regeneration is very large, as the water absorbed during dehumidification must be evaporated. N-isopropylacrylamide (NIPAAm), a sorbent that oozes water when raised above a certain temperature, could potentially replace traditional desiccants in dehumidifiers. The heat of regeneration for NIPAAm consists of some sensible heat to bring the sorbent to the regeneration temperature, plus some latent heat to offset any liquid water that is evaporated as it is exuded from the NIPAAm. This means the NIPAAm regeneration heat has the potential to be much lower than that of a traditional desiccant. Models were created for a standard vapor compression air conditioning system, two desiccant systems, and two theoretical NIPAAm systems. All components were modeled for simplified steady state operation. For a moderate percent of water evaporated during regeneration, it was found that the NIPAAm systems perform better than standard vapor compression. When compared to the desiccant systems, the NIPAAm systems performed better at almost all percent evaporation values. The regeneration heat was modeled as if supplied by an electric heater. If a cheaper heat source were utilized, the case for NIPAAm would be even stronger. Future work on NIPAAm dehumidification should focus on lowering the percent evaporation from the 67% value found in literature. Additionally, the NIPAAm cannot exceed the lower critical solution temperature during dehumidification, indicating that a NIPAAm dehumidification system should be carefully designed such that the sorbent temperature is kept sufficiently low during dehumidification. / Dissertation/Thesis / Masters Thesis Mechanical Engineering 2019

Removal of water vapor from humid streams is an energy-intensive process used widely in industry. Effective dehumidification has the potential to significantly reduce energy consumption and the overall cost of a process stream. Membrane-based separations, particularly dehumidification, are an emerging technology that can change the landscape of global energy usage because they have a small footprint, they are easy to scale up, to implement and to operate. The focus of this thesis is to evaluate new directions for the development and use of materials for membrane-based dehumidification processes. It will show advances in the synthesis of new copolymers, a surprising boost in performance with the addition of 2-D materials, propose the use of polybenzimidazole for challenging dehumidification applications, and show how by tuning the nanostructure of a commercially available block copolymer (BCP) it is possible to increase the performance. The design of novel amphiphilic ternary copolymers comprising P(AN-r-PEGMA-r-DMAEMA) allowed selective removal of water vapors from gaseous streams; the effect of varying PEGMA chain length on membrane performance was studied. The membranes showed an excellent performance when the content of the PEGMA segment was 2.9 mol% with a chain length of 950Da. In the mixed-matrix approach, the inclusion of graphene oxide (GO) nanosheets in a different copolymer enhanced the membrane performance by creating selective tortuous pathways for inert gases. The well-distributed GO nanosheets in the defect-free composite membranes resulted in an 8 fold increase in water vapor/N2 selectivity compared to neat membranes. Thirdly, dense polybenzimidazole membranes showed good water vapor permeability, and the addition of TiO2-based fillers with varying chemistry and geometry enhanced the performance of PBI membranes. Lastly, the effect of tuning the morphology of commercially available BCP on dehumidification was demonstrated successfully. The self-assembled morphology formed with cylindrical hydrophobic cores, and the hydrophilic coronas, formed ion-rich highways for fast water vapor transport. Water vapor permeability improved up to 6-fold with the nanostructure modulation more than any membrane reported in the literature. In summary, the work reported in this dissertation has the potential to lay a framework towards tailor-made next-generation membranes aimed for water vapor removal in various dehumidification applications.

Orientador: Vivaldo Silveira Junior / Dissertação (mestrado) - Universidade Estadual de Campinas, Faculdade de Engenharia de Alimentos / Made available in DSpace on 2018-08-21T19:48:08Z (GMT). No. of bitstreams: 1 Falquetto_PaulaLyra_M.pdf: 2346097 bytes, checksum: 46b1d8899428de4582aaf03fa022871c (MD5) Previous issue date: 2013 / Resumo: Diversos tipos de secagem tem sido utilizados para produtos termossensiveis. O proposito fundamental e a reducao dos custos de transporte, estocagem e o aumento da vida util. Ao mesmo tempo, ha um crescente interesse dos consumidores no uso de ervas e especiarias pelo sabor diferenciado nos alimentos preparados com as mesmas. Em secadores convencionais, o tratamento do ar resulta em temperaturas muito mais altas que a ambiente e umidades absolutas mais baixas, proporcionando maior perda de compostos responsaveis pela cor e sabor, entre outros, durante o processo. Em vista disso, o trabalho teve como objetivos o desenvolvimento e avaliacao de um sistema de tratamento de ar, baseado em uma bomba de calor que produz um ar a baixas temperaturas e pressao de vapor de agua, alimentando um gabinete de bandejas para uso domestico com adaptacao de um refrigerador comercial. Os ensaios foram realizados a pressao atmosferica dentro da cabine. Apos o tratamento do ar (desumidificacao do ar e posterior aquecimento, realizados pela bomba de calor), se obteve uma diferenca das condicoes do ar em comparacao ao ar ambiente de entrada de 22 a 26 oC na temperatura e de 36 a 69% da umidade relativa. O equipamento apresentou bom desempenho na secagem da hortela, produto escolhido para os ensaios, mostrando pouca diferenca na coloracao em relacao a amostra in natura. O tempo de secagem foi de aproximadamente 4 horas, quando se atingiu a umidade do produto desejada, em torno de 6%. O consumo energetico do equipamento no periodo do ensaio ficou em torno de 2 kWh para uma quantidade de 25 g de materia seca / Abstract: Different types of drying are being used for thermosensitive products. The fundamental purpose is the reduction of transportation and storage costs, and increasing of shelf life. At the same time, there is a growing consumer interest in the use of herbs and spices because of the differentiated flavor in distinct foods prepared with them. In conventional dryers air treatment results in higher temperatures that the ambient and lower absolute humidity providing greater loss of compounds responsible for the color and flavor among others during the process. This work had the objective of development and evaluation of an air treatment system, based on a heat pump that operates at low temperatures, feeding a tray cabinet for domestic use with adaptation of a commercial refrigerator. The tests were a source at atmospheric pressure inside the cabin. After treatment of the air (air dehumidification and subsequent heating was done by heat pump), obtaining a difference of air conditions of 22 to 26 °C in temperature and 36 to 69% of moisture with relation to ambient air (input air). The equipment presented good performance in mint drying, the product chosen for the tests, showing differences in coloring low in relation to the fresh sample. The drying time was approximately 4 hours when it has reached the desired product moisture around 6%. The energy consumption of equipment around the time of the test was around 2 kWh for a quantity of 25 g of dry matter / Mestrado / Engenharia de Alimentos / Mestra em Engenharia de Alimentos

The motivation of this research project was in response to problems of re-condensation in drying, reduced drying rate encountered by the food and beverage packaging industry which led to the aim of developing a better performing drying system as well as achieving high energy efficiency. A hybrid dryer suited for rapid drying applications is designed, constructed and experimentally tested and considered in atmospheric environment only. The system employs a heat pump in conjunction with a heat reactivated desiccant wheel to provide an efficient drying capability and supply low dew point temperature (DPT) conditions. The combined system utilises the heat dissipated by the condenser in regenerating the desiccant wheel, to increase the economic feasibility of such a hybrid system. Up to 60% heat energy can be saved by using the hybrid system in the rapid surface drying applications. Mathematical models are developed to obtain the correlations among the design operating and performance parameters of the dehumidification systems. The mathematical models can be used to estimate the performance of the hybrid system as well as the performance of the individual components of the system. A prototype model was designed, fabricated and tested. The experimental facility consisted of a heat pump desiccant dehumidifier with the new ecological R134a as a refrigerant which used the heat dissipated by the condenser. An analysis of the experimental data was conducted to determine the practical relationship between the operational parameters (COP, ma and TR) and performance parameters (SMER, DPT and ε) of the system. The observed behaviours of the test cases are suggested to be governed by a specific combination of the operation parameters. The analysis shows that the proposed hybrid system can deliver supply air at a much lower DPT compared with the single refrigerant circuit and a desiccant wheel. It is shown that the specific moisture extraction rate (SMER) for conventional dryers is 0.5 - 1 kg/kWh and SMER for heat pump based system is 3 - 4 kg/kWh whereas the hybrid system achieves SMER >5 kg/kWh. By operating the combined system in tandem, a greater amount of dehumidification could be realised due to the improved ratio of latent to the total load. The present research also confirms the importance of improving heat recovery to improve the performance of a heat-pump-assisted drying system.

In Gulf Cooperation Council (GCC) countries, a lack of freshwater, poor soil quality, and ambient temperatures unsuitable for cultivation for parts of the year hinders domestic agriculture. The result is a reliance on a fluctuating supply of imported fresh produce which may have high costs and compromised quality. There are agricultural technologies available such as hydroponics and controlled environment agriculture (CEA) that can allow GCC countries to overcome poor soil quality and ambient temperatures unsuitable for cultivation, respectively. Evaporative cooling is the most common form of cooling for CEA and requires a significant amount of water. In water-scarce regions, it is desirable for sea or brackish water to be used for evaporative cooling. Unfortunately, in many coastal desert regions, evaporative cooling does not provide enough cooling due to the high wet-bulb temperature of the ambient air during hot and humid months of the year. A liquid desiccant dehumidification system has been proven to lower the wet-bulb temperature of ambient air in the coastal city of Jeddah, Saudi Arabia to a level that allows for evaporative cooling to meet the needs of heat-sensitive crops. Much of the past research on the regeneration of the liquid desiccant solution has been on configurations that release water vapor back to the atmosphere. Studies have shown that the amount of water captured by the liquid desiccant when used to dehumidify a greenhouse can supply a significant amount of the water needed for irrigation. This thesis studied the regeneration of a magnesium chloride (MgCl2) liquid desiccant solution from approximately 20 to 31wt% by direct contact membrane distillation and explored the possibility of using the recovered water for irrigation. Two microporous hydrophobic PTFE membranes were experimentally tested and modeled when the bulk feed and coolant temperature difference was between 10 and 60°C. In eight experiments, the salt rejection was higher than 99.97% and produced permeate suitable for irrigation with a concentration of MgCl2 less than 94 ppm.

Yes / The use of solar thermal energy for water desalination processes is increasing rapidly, particularly in areas where these resources are plentiful. However, solar energy plants are highly affected by the intermittency of day -night cycles and by low irradiation seasons. Although biomass fuel can be used as source of energy for thermal desalination processes, these resources are becoming increasingly scarce, expensive and seasonally available. Integration of solar-biomass technologies for water desalination process may provide the solution to these challenges. This work investigates design options of the Humidification-Dehumidification desalination system integration with the solar-biomass energies. The investigation is based on simulation of the process models in gPROMS platform. Results show that the solar-biomass integrated plant with a thermal storage system can save up to 57 % of the daily energy cost compared to conventional biomass plant. The integrated plant also cuts the CO2 emission by 59 %. Moreover, it has higher daily production capacity than conventional solar plants. / The authors wish to thank the Commonwealth Scholarship Commission in the UK (CSC) for financial support under PhD Scholarships Plan for Low and Middle Income Countries.

<p dir="ltr">Vapor Compression Systems (VCS) are the most common air conditioning technology. However, the VCS process is energy inefficient due to overcooling and reheating. Liquid Desiccant air conditioning (LDAC) is a potentially more energy-efficient air conditioning technology. LDAC removes vapor in the air using the liquid desiccant’s high-water affinity and controls temperature using an additional cooling device. Additionally, LDAC typically requires heating to regenerate the diluted Liquid Desiccant (LD) for repeated use after absorbing moisture.</p><p dir="ltr">Earlier types of the LDAC systems operated at a relative high concentration and temperature during the dehumidification process, resulting in an increased heat source temperatures required for regeneration, which substantially diminished the energy efficiency advantages of LDAC systems. In the past two decades, researchers have explored a new LDAC system configuration that integrates an LDAC system with a heat pump (HP). The HP can deliver sensible cooling to lower the LD operating temperature and cool the process air. Simultaneously, it provides heating at the condenser side to facilitate the regeneration process. Subsequently, membrane-based dehumidifiers were introduced to separate the LD and airflow using a membrane that permits the passage of water vapor. This approach prevents direct contact, which otherwise would result in LD droplet carryover, addressing concerns related to health and the corrosion of air ducts. An internally cooled membrane-based dehumidifier with enhanced performance garners significant attention, as it essentially functions as a three-stream heat exchanger that facilitates both heat and mass transfer processes. Because of the intricate characteristics of the three-stream heat and mass exchanger, the finite difference models used to analyze the internally cooled membrane dehumidifier is highly detailed and comprehensive. These models are well-suited for assisting in the device’s design but are not suitable for system-level simulations. The lack of simple models for internally cooled membrane-based dehumidifiers limits the evaluation of energy performance at the system level. The limitation becomes particularly pronounced when a HP is integrated, as the model hinders our comprehension of the interactions between the HP and LDAC under the transient operating conditions.</p><p dir="ltr">The thesis research aims to bridge the gaps related to system configuration design, limitations of existing dehumidifier models, and the analysis and assessment of transient system level performance. A model of the internally cooled membrane-based dehumidifier, based on artificial neural networks, was created using data generated through the utilization of a published and detailed finite element dehumidifier model. The resulting model was validated by testing it with out-of-sample data and comparing its results with the validated finite difference model. An LDAC system setup using the internally cooled dehumidifier was established in Modelica using the artificial neural network model created. Furthermore, models of a VCS and an LDAC based on adiabatic dehumidifier were also developed to facilitate performance comparison. The different systems underwent simulation for an entire cooling season spanning from May to September. The internally cooled dehumidifier-based system exhibited superior energy performance, achieving seasonal energy performance levels up to 104% and 34% higher than the VCS and adiabatic dehumidifier systems, respectively. The improved performance in comparison to the VCS is due to the higher temperature operation of the HP. The improvement in comparison to the adiabatic dehumidifier system is due to the improved capacity of the internally cooled dehumidifier to deal with the absorption heat released during dehumidification. Depending on the geographical location, the internally cooled dehumidifier system displayed enhanced performance in the applications characterized by moderate sensible cooling, while its efficiency was relatively lower in arid and hot regions. Additionally, the results demonstrated that the adiabatic system performed similarly to the internally cooled dehumidifier system in locations with high sensible and latent cooling loads.</p><p dir="ltr">This work introduces a pioneering data-driven model for internally cooled membrane liquid desiccant dehumidifiers, representing a significant advancement in the field. The model's computational efficiency and accuracy address the challenges posed by sophisticated and computationally expensive physical models, providing a valuable tool for simulating such devices. The creation of the simple ANN-based dehumidifier model opens the possibility for simulation of internally cooled devices as part of dehumidification systems, whereas as of today its study has been mostly limited to single devices simulations. In the study, a model-based comparison of system performance between an HP-coupled internally cooled dehumidifier-liquid desiccant air conditioning system and HP-coupled adiabatic LDAC, as well as Vapor Compression Systems, elucidates the optimal operational configuration and rationale. Furthermore, a climate sensitivity analysis of system simulations guides researchers toward focusing on the development of HP-coupled internally cooled/heated liquid desiccant systems, particularly in climates that offer the greatest potential for energy savings compared to commonly used vapor compression systems. This comprehensive exploration enhances our understanding and paves the way for more efficient and effective developments in liquid desiccant-based dehumidification technologies.</p>

Les fumées à basse température (<120-150 °C) sortant des procédés industriels pourraient être récupérées pour la production d'électricité et constituent un moyen efficace de réduction de la consommation d'énergie primaire et des émissions de dioxyde de carbone. Cependant, des barrières techniques tels que la faible efficacité de conversion, la nécessité d'une grande zone de transfert de chaleur, et la présence de substances chimiques corrosives liées à une forte teneur en humidité lors du fonctionnement en environnement sévère entravent leur application plus large. Cette thèse porte particulièrement sur les secteurs industriels les plus énergivores rencontrant actuellement des difficultés à récupérer l'énergie des sources de chaleur à basse température dans des environnements hostiles. Des cycles thermodynamiques existants basés sur le Cycle de Rankine Organique (ORC) sont adaptés et optimisés pour ce niveau de température. Deux méthodes de récupération de chaleur classiques sont étudiées plus particulièrement : les déshumidifications à contact direct et indirect. Des méthodes de conception optimisées pour les échangeurs de chaleur sont élaborées et validées expérimentalement. Pour la déshumidification à contact indirect, des matériaux à revêtement anticorrosifs sont proposés et testés. Pour la déshumidification à contact direct, les effets du type et de la géométrie des garnissages sur les performances hydrauliques sont étudiés. Des cycles thermodynamiques innovants basés sur la technologie de déshydratation liquide sont proposés. Un cycle de régénération amélioré (IRC) est développé. Comparé aux technologies de récupération de chaleur classiques, l'IRC proposé améliore à la fois la puissance nette et le taux de détente de la turbine en prévenant par ailleurs les problèmes de corrosion. / Low-temperature waste-gas heat sources (< 120-150°C) exiting several industrial processes could be recovered for electricity production and constitute an effective mean to reduce primary energy consumption and carbon dioxide emissions. However, technical barriers such as low conversion efficiency, large needed heat transfer area, and the presence of chemically corrosive substances associated with high moisture content when operating in harsh environment impede their wider application. This thesis focuses on particularly energy-hungry industrial sectors characterized by presently unsolved challenges in terms of environmentally hostile low-temperature heat sources. Existing thermodynamic cycles based on Organic Rankine Cycle (ORC) are adapted and optimized for this temperature level. Two conventional heat recovery methods are studied more particularly: indirect and direct contact dehumidification. Optimized design methods for heat exchangers are elaborated and experimentally validated. For the indirect contact dehumidification, advanced anti-corrosion coated materials are proposed and laboratory tested. For the direct contact dehumidification, the effects of packing material and geometry on the corresponding hydraulic performances are underlined. Innovative thermodynamic cycles based on the liquid desiccant technology are investigated. An improved regeneration cycle (IRC) is developed. Compared to the conventional heat recovery technologies, the proposed “IRC” improves both net power and turbine expansion ratio besides preventing faced corrosions problems.

O objetivo deste trabalho é realizar uma análise paramétrica do processo de desumidificação de ar comprimido em trocadores de calor compactos com superfícies intensificadoras do tipo aletas deslocadas. A umidade contida no ar comprimido precisa ser retirada do sistema para evitar a formação de condensado nas linhas de distribuição, nos atuadores ou nos dispositivos finais. Utiliza-se o processo de desumidificação por resfriamento onde a temperatura do ar é diminuída até alcançar o ponto de orvalho, resultando em formação de condensado. O desumidificador é constituído por dois trocadores de calor (recuperador e evaporador), sendo cada um deles dividido em duas regiões. Realizou-se a modelagem do processo de transferência de calor para cada um dos trocadores. Utilizou-se o método do potencial de entalpias para determinar os coeficientes globais de transferência de calor de cada trocador. Para a realização da simulação numérica, foi implementado um programa utilizando como ferramenta computacional o programa “Engineering Equation Solver" (EES). O estudo foi feito variando-se os parâmetros geométricos do trocador de calor e verificando sua influência nos coeficientes de transferência de calor, nos calores trocados e nas condições de saída do ar. Primeiramente, cada parâmetro foi analisado individualmente e depois com algumas combinações. Concluiu-se que as dimensões das aletas no recuperador e os comprimentos do recuperador e do evaporador são os parâmetros que mais influenciam nas propriedades do ar comprimido na saída do desumidificador. / The objective of this work is to conduct a parametric analysis of the dehumidification process of compressed air in compact heat exchangers with Offset Strip Fins. The humidity carried by the compressed air should be removed from the system to prevent the condensation in the distribution lines and in the actuators or the final devices. The dehumidification process by cooling occurs when the temperature of the air is diminished until reaching the dew point, resulting in condensation of water vapor. The dehumidifier is constituted by two heat exchangers (recuperator and evaporator), each one of them being divided in two regions. A modeling of the heat and mass transfer process for each heat exchangers, was performed. The enthalpy driving potential method was used to determine the overall heat transfer coefficients of each heat exchanger. The numerical simulation was implemented by using the computational software "Engineering Equation Solver"(EES). The study was made varying the geometric parameters of the heat exchanger and verifying its influences on the heat transfer coefficients, the heat transfer and pressure drop, and the air exit conditions. First, each parameter was analyzed individually and then with some combinations. Its was concluded that the fins dimensions in both regions of the lengths of the recuperator and the evaporator are the parameters that have larger influence on the exit compressed air properties.

Three experimental studies were conducted to quantify the effects of system cycling, evaporator airflow, and condenser coil fouling on the performance of residential air conditioners. For all studies, the indoor dry-bulb (db) temperature was 80°F (26.7°C) db. The cycling study consisted of twelve transient tests conducted with an outdoor temperature of 95°F (35°C) db for cycle times of 6, 10, 15, and 24 minutes. Indoor relative humidities of 40%, 50%, and 60% were also considered. The evaporator airflow study consisted of twenty-four steady-state tests conducted with an indoor condition of 67°F (19.4°C) wet-bulb (wb) for evaporator airflows ranging from 50% below to 37.5% above rated airflow. Outdoor temperatures of 85°F (29.4°C) db, 95°F (35°C) db, and 105°F (40.6°C) db were also considered. The coil fouling study used a total of six condensers that were exposed to an outdoor environment for predetermined amounts of time and tested periodically. Three of the condensers were cleaned and retested during the periodic testing cycles. Testing consisted of thirty-three steady-state tests conducted with an indoor condition of 67°F (19.4°C) wb for outdoor exposure times of 0, 2000, 4000, and 8000 hours. Outdoor temperatures of 82°F (27.8°C) db and 95°F (35°C) db were also considered.