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Estimation of Petrophysical Properties from Thin Sections Using 2D to 3D Reconstruction of Confocal Laser Scanning Microscopy Images.Fonseca Medina, Victor Eduardo 12 1900 (has links)
Petrophysical properties are fundamental to understanding fluid flow processes in hydrocarbon reservoirs. Special Core Analysis (SCAL) routinely used in industry are time-consuming, expensive, and often destructive. Alternatively, easily available thin section data is lacking the representation of pore space in 3D, which is a requisite for generating pore network models (PNM) and computing petrophysical properties. In this study, these challenges were addressed using a numerical SCAL workflow that employs pore volume reconstruction from thin section images obtained from confocal laser scanning microscopy (CLSM). A key objective is to investigate methods capable of 2D to 3D reconstruction, to obtain PNM used for the estimation of transport properties. Representative thin sections from a well-known Middle-Eastern carbonate formation were used to obtain CLSM images. The thin-sections were specially prepared by spiking the resin with UV dye, enabling high-resolution imaging. The grayscale images obtained from CLSM were preprocessed and segmented into binary images. Generative Adversarial Networks (GAN) and Two-Point Statistics (TPS) were applied, and PNM were extracted from these binary datasets. Porosity, Permeability, and Mercury Injection Porosimetry (MIP) on the corresponding core plugs were conducted and an assessment of the properties computed from the PNM obtained from the reconstructed 3D pore volume is presented. Moreover, the results from the artificial pore networks were corroborated using 3D confocal images of etched pore casts (PCE). The results showed that based on visual inspection only, GAN outperformed TPS in mimicking the 3D distribution of pore scale heterogeneity, additionally, GAN and PCE outperformed the results of MIP obtained by TPS on the Skeletal-Oolitic facies, without providing a major improvement on more heterogeneous samples. All methods captured successfully the porosity while absolute permeability was not captured. Formation resistivity factor and thermal conductivity showcased their strong correlation with porosity.
The study thus provides valuable insights into the application of 2D to 3D reconstruction to obtain pore network models of heterogeneous carbonate rocks for petrophysical characterization for quick decision. The study addresses the following important questions: 1) how legacy thin sections can be leveraged to petrophysically characterize reservoir rocks 2) how reliable are 2D to 3D reconstruction methods when predicting petrophysical properties of carbonates.
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Topological study of reservoir rocks and acidification processes using complex networks methods / Estudo topológico de rochas de reservatório e processos de acidificação por métodos de redes complexasAndreeta, Mariane Barsi 29 September 2017 (has links)
The X-Ray imaging technology opened a new branch of science in which the internal porous structure can be captured and the reconstructed volume can be used for fluid flow simulations and structural measurements. However, there is still the question of how the internal structure of the pore space impacts in the observed simulations. A way to characterize this internal structure is by simplifying it into well-defined elements and the interaction between them, describing it as a network. The interaction between elements are the edges of the network and elements are the nodes. This opens the possibility of applying complex network theory on the characterization of porous media which has proven to give powerful insights into how the structure of porous materials influences on the dynamics of the permeating fluid. The problem with this description is in definition of the basic elements that will compose the network, since there isnt a consensus on this definition. The purpose of this work is to provide a method to analyze μCT data through networks in which the separation of the space is done in a semi-continuous method. The recovering of the pores local geometry is captured through a network analysis method of centrality, instead of a geometrical definition. This way the intrinsic morphology of the samples is what governs the pore-space separation into different entities. The method developed is based on the network extraction method Max Spheres Algorithm (MSA). The volumetric data is recovered through a network composed by sphere cells. The output of this process are two distinct networks: the complete volume network and a network which represents the variation of the channels diameter. These networks give unbiased real information on pore connectivity and can provide important data to better understand the morphology and topology of the samples. This method was successfully applied to samples of Berea sandstone, Estaillades carbonate, and to characterize the morphology of wormholes. Wormhole is the denomination of the channel formed after the application of an acid treatment as a stimulation procedure of an oil reservoir, a method of EOR (Enhanced oil recovery). This treatment consists of a reactive fluid flow injected in the inner rock of the reservoir, which creates a preferential path (wormhole) that optimizes the extraction of the hydrocarbon fluids. / A microtomografia de raios-X permitiu a evolução de uma nova área da ciência aplicada a meios porosos: a Rocha Digital. Através desta técnica, todo o espaço poroso é recuperado, e é possível entender a dinâmica do fluido que o permeia através de simulações computacionais. No entanto, ainda há a questão de como a estrutura do meio influencia nos resultados observados. Entender questões como connectividade e clusterização de regiões podem dar informações valiosas sobre como a origem do meio poroso influencia na dinâmica do fluido que o permeia. Esta avaliação do meio é possível através da simplificação do mesmo em uma rede de conexão de elementos básicos e as interações entre estes. O problema com a descrição do meio poroso em uma rede de conexão é que não existe um consenso na definição destes elementos básicos. O propósito deste trabalho foi encontrar uma maneira de descrever o meio que fosse aplicável a qualquer litologia, e que se aproximasse ao máximo dos dados extraídos pela micro tomografia para a análise das topologias de diferentes rochas através de teoria de redes complexas.Para isso, utilizamos o algoritmo robusto de extração de redes de poros, esferas máximas, como base para dividir o espaço-poroso em células esféricas. Desta forma, todo o volume do espaço poroso observado através da micro tomografia é recuperado e descrito em uma rede de conexão. O resultado final do método aplicado é uma rede que descreve o meio completo e uma rede que descreve o eixo medial das interconexões entre poros. A geometria local dos poros é recuperada através de um critério de centralidade de rede, assim a separação é governada pela morfologia intrínseca das amostras, ao invés de fatores geométricos.Desta forma podemos analisar o efeito da tortuosidade real do meio, assim como a interconexão entre poros, com relação a permeabilidade do meio.O método se mostrou eficaz na análise de rochas com diferentes litologias: arenito (Berea) e carbonato (Estaillades). O método também foi aplicado na avaliação da estrutura de canais formados pelo processo de acidificação de rochas (wormholes).
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Topological study of reservoir rocks and acidification processes using complex networks methods / Estudo topológico de rochas de reservatório e processos de acidificação por métodos de redes complexasMariane Barsi Andreeta 29 September 2017 (has links)
The X-Ray imaging technology opened a new branch of science in which the internal porous structure can be captured and the reconstructed volume can be used for fluid flow simulations and structural measurements. However, there is still the question of how the internal structure of the pore space impacts in the observed simulations. A way to characterize this internal structure is by simplifying it into well-defined elements and the interaction between them, describing it as a network. The interaction between elements are the edges of the network and elements are the nodes. This opens the possibility of applying complex network theory on the characterization of porous media which has proven to give powerful insights into how the structure of porous materials influences on the dynamics of the permeating fluid. The problem with this description is in definition of the basic elements that will compose the network, since there isnt a consensus on this definition. The purpose of this work is to provide a method to analyze μCT data through networks in which the separation of the space is done in a semi-continuous method. The recovering of the pores local geometry is captured through a network analysis method of centrality, instead of a geometrical definition. This way the intrinsic morphology of the samples is what governs the pore-space separation into different entities. The method developed is based on the network extraction method Max Spheres Algorithm (MSA). The volumetric data is recovered through a network composed by sphere cells. The output of this process are two distinct networks: the complete volume network and a network which represents the variation of the channels diameter. These networks give unbiased real information on pore connectivity and can provide important data to better understand the morphology and topology of the samples. This method was successfully applied to samples of Berea sandstone, Estaillades carbonate, and to characterize the morphology of wormholes. Wormhole is the denomination of the channel formed after the application of an acid treatment as a stimulation procedure of an oil reservoir, a method of EOR (Enhanced oil recovery). This treatment consists of a reactive fluid flow injected in the inner rock of the reservoir, which creates a preferential path (wormhole) that optimizes the extraction of the hydrocarbon fluids. / A microtomografia de raios-X permitiu a evolução de uma nova área da ciência aplicada a meios porosos: a Rocha Digital. Através desta técnica, todo o espaço poroso é recuperado, e é possível entender a dinâmica do fluido que o permeia através de simulações computacionais. No entanto, ainda há a questão de como a estrutura do meio influencia nos resultados observados. Entender questões como connectividade e clusterização de regiões podem dar informações valiosas sobre como a origem do meio poroso influencia na dinâmica do fluido que o permeia. Esta avaliação do meio é possível através da simplificação do mesmo em uma rede de conexão de elementos básicos e as interações entre estes. O problema com a descrição do meio poroso em uma rede de conexão é que não existe um consenso na definição destes elementos básicos. O propósito deste trabalho foi encontrar uma maneira de descrever o meio que fosse aplicável a qualquer litologia, e que se aproximasse ao máximo dos dados extraídos pela micro tomografia para a análise das topologias de diferentes rochas através de teoria de redes complexas.Para isso, utilizamos o algoritmo robusto de extração de redes de poros, esferas máximas, como base para dividir o espaço-poroso em células esféricas. Desta forma, todo o volume do espaço poroso observado através da micro tomografia é recuperado e descrito em uma rede de conexão. O resultado final do método aplicado é uma rede que descreve o meio completo e uma rede que descreve o eixo medial das interconexões entre poros. A geometria local dos poros é recuperada através de um critério de centralidade de rede, assim a separação é governada pela morfologia intrínseca das amostras, ao invés de fatores geométricos.Desta forma podemos analisar o efeito da tortuosidade real do meio, assim como a interconexão entre poros, com relação a permeabilidade do meio.O método se mostrou eficaz na análise de rochas com diferentes litologias: arenito (Berea) e carbonato (Estaillades). O método também foi aplicado na avaliação da estrutura de canais formados pelo processo de acidificação de rochas (wormholes).
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Application of Machine Learning and Deep Learning Methods in Geological Carbon Sequestration Across Multiple Spatial ScalesWang, Hongsheng 24 August 2022 (has links)
Under current technical levels and industrial systems, geological carbon sequestration (GCS) is a viable solution to maintain and further reduce carbon dioxide (CO2) concentration and ensure energy security simultaneously. The pre-injection formation characterization and post-injection CO2 monitoring, verification, and accounting (MVA) are two critical and challenging tasks to guarantee the sequestration effect. The tasks can be accomplished using core analyses and well-logging technologies, which complement each other to produce the most accurate and sufficient subsurface information for pore-scale and reservoir-scale studies. In recent years, the unprecedented data sources, increasing computational capability, and the developments of machine learning (ML) and deep learning (DL) algorithms provide novel perspectives for expanding the knowledge from data, which can capture highly complex nonlinear relationships between multivariate inputs and outputs. This work applied ML and DL methods to GCS-related studies at pore and reservoir scales, including digital rock physics (DRP) and the well-logging data interpretation and analysis.
DRP provides cost-saving and practical core analysis methods, combining high-resolution imaging techniques, such as the three-dimensional (3D) X-ray computed tomography (CT) scanning, with advanced numerical simulations. Image segmentation is a crucial step of the DRP framework, affecting the accuracy of the following analyses and simulations. We proposed a DL-based workflow for boundary and small target segmentation in digital rock images, which aims to overcome the main challenge in X-ray CT image segmentation, partial volume blurring (PVB). The training data and the model architecture are critical factors affecting the performance of supervised learning models. We employed the entropy-based-masking indicator kriging (IK-EBM) to generate high-quality training data. The performance of IK-EBM on segmentation affected by PVB was compared with some commonly used image segmentation methods on the synthetic data with known ground truth. We then trained and tested the UNet++ model with nested architecture and redesigned skip connections. The evaluation metrics include the pixel-wise (i.e. F1 score, boundary-scaled accuracy, and pixel-by-pixel comparison) and physics-based (porosity, permeability, and CO2 blob curvature distributions) accuracies. We also visualized the feature maps and tested the model generalizations.
Contact angle (CA) distribution quantifies the rock surface wettability, which regulates the multiphase behaviors in the porous media. We developed a DL-based CA measurement workflow by integrating an unsupervised learning pipeline for image segmentation and an open-source CA measurement tool. The image segmentation pipeline includes the model training of a CNN-based unsupervised DL model, which is constrained by feature similarity and spatial continuity. In addition, the over-segmentation strategy was adopted for model training, and the post-processing was implemented to cluster the model output to the user-desired target. The performance of the proposed pipeline was evaluated using synthetic data with known ground truth regarding the pixel-wise and physics-based evaluation metrics. The resulting CA measurements with the segmentation results as input data were validated using manual CA measurements.
The GCS projects in the Illinois Basin are the first large-scale injection into saline aquifers and employed the latest pulsed neutron tool, the pulsed neutron eXtreme (PNX), to monitor the injected CO2 saturation. The well-logging data provide valuable references for the formation evaluation and CO2 monitoring in GCS in saline aquifers at the reservoir scale. In addition, data-driven models based on supervised ML and DL algorithms provide a novel perspective for well-logging data analysis and interpretation. We applied two commonly used ML and DL algorithms, support vector machine regression (SVR) and artificial neural network (ANN), to the well-logging dataset from GCS projects in the Illinois Basin. The dataset includes the conventional well-logging data for mineralogy and porosity interpretation and PNX data for CO2 saturation estimation. The model performance was evaluated using the root mean square error (RMSE) and R2 score between model-predicted and true values. The results showed that all the ML and DL models achieved excellent accuracies and high efficiency. In addition, we ranked the feature importance of PNX data in the CO2 saturation estimation models using the permutation importance algorithm, and the formation sigma, pressure, and temperature are the three most significant factors in CO2 saturation estimation models.
The major challenge for the CO2 storage field projects is the large-scale real-time data processing, including the pore-scale core and reservoir-scale well-logging data. Compared with the traditional data processing methods, ML and DL methods achieved accuracy and efficiency simultaneously. This work developed ML and DL-based workflows and models for X-ray CT image segmentation and well-logging data interpretations based on the available datasets. The performance of data-driven surrogate models has been validated regarding comprehensive evaluation metrics. The findings fill the knowledge gap regarding formation evaluation and fluid behavior simulation across multiple scales, ensuring sequestration security and effect. In addition, the developed ML and DL workflows and models provide efficient and reliable tools for massive GCS-related data processing, which can be widely used in future GCS projects. / Doctor of Philosophy / Geological carbon sequestration (GCS) is the solution to ease the tension between the increasing carbon dioxide (CO2) concentrations in the atmosphere and the high dependence of human society on fossil energy. The sequestration requires the injection formation to have adequate storage capability, injectivity, and impermeable caprock overlain. Also, the injected CO2 plumes should be monitored in real-time to prevent any migration of CO2 to the surface. Therefore, pre-injection formation characterization and post-injection CO2 saturation monitoring are two critical and challenging tasks to guarantee the sequestration effect and security, which can be accomplished using the combination of pore-scale core analyses and reservoir-scale well-logging technologies. This work applied machine learning (ML) and deep learning (DL) methods to GCS-related studies across multiple spatial scales. We developed supervised and unsupervised DL-based workflows to segment the X-ray computed-tomography (CT) image of digital rocks for the pore-scale studies. Image segmentation is a crucial step in the digital rock physics (DRP) framework, and the following analyses and simulations are conducted on the segmented images. We also developed ML and DL models for well-logging data interpretation to analyze the mineralogy and estimate CO2 saturation. Compared with the traditional well-logging analysis methods, which are usually time-consuming and prior knowledge-dependent, the ML and DL methods achieved comparable accuracy and much shorter processing time. The performance of developed workflows and models was validated regarding comprehensive evaluation metrics, achieving excellent accuracies and high efficiency simultaneously. We are at the early stage of CO2 sequestration, and relevant knowledge and tools are inadequate. In addition, the main challenge of CO2 sequestration field projects is the large-scale and real-time data processing for fast decision-making. The findings of this dissertation fill the knowledge gap in GCS-related formation evaluation and fluid behavior simulations across multiple spatial scales. The developed ML and DL workflows provide efficient and reliable tools for massive data processing, which can be widely used in future GCS projects.
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Nuclear magnetic resonance and digital rock in oil industry: well logging applications / Ressonância magnética nuclear e rocha digital na indústria do petróleo: aplicações em perfilagem de poçosTrevizan, Willian Andrighetto 28 March 2017 (has links)
This thesis discusses Nuclear Magnetic Resonance (NMR) techniques for formation evaluation in well log analysis for the oil/gas industry. We present the standard ingredients for NMR data processing and interpretation, and develop a methodology that extends the determination of surface relaxivity from the laboratory to the well site. The methodology consists of a processing algorithm for diffusion editing data, which enables surface relaxivity determination for conditions close to those found in well logging (regarding data availability and noise levels). At moderate noise levels, lower relaxivity values (below 10μm/s) can be determined solely from NMR diffusion data, while higher values (∼30μm/s) can be separated from intermediate ones. Application for actual logging data still requires some noise reduction techniques such as stationary measurements downhole or data stacking among different depths. However, it provides a way of converting T2 distributions into actual pore size distributions even for downhole acquisitions, before the samples get to the laboratory for routine analysis. Besides the logging analysis, we also developed a theoretical approximation to the diffusion equation with partial absorptive contour conditions, by calculating appropriate transition rates between cells in an arbitrary grid, allowing a simple methodology for obtaining the NMR data based on pore imaging. Calculated rates can in principle be used for modeling/understanding different diffusion phenomena, such as exchange between pores or relaxation sites. / Neste trabalho são discutidas técnicas de Ressonância Magnética Nuclear (RMN) aplicadas à avaliação de formações por meio da perfilagem de poços pela indústria de óleo e gás. São apresentados os conceitos básicos para processamento e interpretação dos dados de RMN, e desenvolvida uma metodologia para determinação da relaxatividade superficial em poço. O método consiste em um algoritmo de processamento de dados de diffusion editing, que permite a obtenção da relaxatividade superficial em condições próximas as encontradas na perfilagem de poços de petróleo (em relação à disponibilidade de dados e nível de ruído). Para níveis moderados de ruído, as relaxatividades mais baixas (menores que 10μm/s) podem ser determinadas através das medidas de difusão por RMN, enquanto valores mais altos (∼30μm/s) podem ser separados dos intermediários. Aplicações em dados de perfilagem ainda requerem técnicas de redução de ruído como aquisições estacionárias em poço ou empilhamento de dados ao longo de um intervalo de profundidades. Entretanto, o método possibilita uma forma de converter as distribuições de T2 em distribuições de tamanhos de poros ainda em poço, antes que as amostras sejam enviadas para o laboratório em análises de rotina. Além da perfilagem, foi desenvolvido também uma aproximação para a equação de difusão com condições de contorno absortivas, através de equações de taxas. A forma das taxas de transição permite o desenvolvimento de metodologias simples para obtenção dos dados de RMN através de imagens dos poros das rochas. As taxas de transição podem ser utilizadas também para a modelagem de outros fenômenos que envolvam difusão, como fenômenos de troca entre poros ou entre sítios com diferentes valores de relaxação.
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Nuclear magnetic resonance and digital rock in oil industry: well logging applications / Ressonância magnética nuclear e rocha digital na indústria do petróleo: aplicações em perfilagem de poçosWillian Andrighetto Trevizan 28 March 2017 (has links)
This thesis discusses Nuclear Magnetic Resonance (NMR) techniques for formation evaluation in well log analysis for the oil/gas industry. We present the standard ingredients for NMR data processing and interpretation, and develop a methodology that extends the determination of surface relaxivity from the laboratory to the well site. The methodology consists of a processing algorithm for diffusion editing data, which enables surface relaxivity determination for conditions close to those found in well logging (regarding data availability and noise levels). At moderate noise levels, lower relaxivity values (below 10μm/s) can be determined solely from NMR diffusion data, while higher values (∼30μm/s) can be separated from intermediate ones. Application for actual logging data still requires some noise reduction techniques such as stationary measurements downhole or data stacking among different depths. However, it provides a way of converting T2 distributions into actual pore size distributions even for downhole acquisitions, before the samples get to the laboratory for routine analysis. Besides the logging analysis, we also developed a theoretical approximation to the diffusion equation with partial absorptive contour conditions, by calculating appropriate transition rates between cells in an arbitrary grid, allowing a simple methodology for obtaining the NMR data based on pore imaging. Calculated rates can in principle be used for modeling/understanding different diffusion phenomena, such as exchange between pores or relaxation sites. / Neste trabalho são discutidas técnicas de Ressonância Magnética Nuclear (RMN) aplicadas à avaliação de formações por meio da perfilagem de poços pela indústria de óleo e gás. São apresentados os conceitos básicos para processamento e interpretação dos dados de RMN, e desenvolvida uma metodologia para determinação da relaxatividade superficial em poço. O método consiste em um algoritmo de processamento de dados de diffusion editing, que permite a obtenção da relaxatividade superficial em condições próximas as encontradas na perfilagem de poços de petróleo (em relação à disponibilidade de dados e nível de ruído). Para níveis moderados de ruído, as relaxatividades mais baixas (menores que 10μm/s) podem ser determinadas através das medidas de difusão por RMN, enquanto valores mais altos (∼30μm/s) podem ser separados dos intermediários. Aplicações em dados de perfilagem ainda requerem técnicas de redução de ruído como aquisições estacionárias em poço ou empilhamento de dados ao longo de um intervalo de profundidades. Entretanto, o método possibilita uma forma de converter as distribuições de T2 em distribuições de tamanhos de poros ainda em poço, antes que as amostras sejam enviadas para o laboratório em análises de rotina. Além da perfilagem, foi desenvolvido também uma aproximação para a equação de difusão com condições de contorno absortivas, através de equações de taxas. A forma das taxas de transição permite o desenvolvimento de metodologias simples para obtenção dos dados de RMN através de imagens dos poros das rochas. As taxas de transição podem ser utilizadas também para a modelagem de outros fenômenos que envolvam difusão, como fenômenos de troca entre poros ou entre sítios com diferentes valores de relaxação.
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Wettability study through x-ray micro-ct pore space imaging in eor applied to lsb recovery process / Etude de la mouillabilité par imagerie micro-ct de l’espace inter poral appliquée au procédé de récupération d’injection d’eau douceNazarova Cherriere, Marfa 30 October 2014 (has links)
La thèse a pour but d’étudier les effets de changements de mouillabilité de roches dans des conditions d’injections d’eau douce en tant que méthode de récupération d’hydrocarbures. Afin d’identifier le ou les mécanismes à l’origine du gain additionnel de récupération nous avons utilisé un microtomographe RX. Nous avons ainsi imagé les états de saturations finales d’un milieu poreux rempli de saumures et d’huiles. Une fois le drainage primaire réalisé nous avons effectué deux phases d’imbibitions : avec une saumure (récupération secondaire) puis une imbibition d’eau douce (récupération tertiaire). L’analyse de la mouillabilité à l’échelle du pore a permis de mettre en évidence l’effet de la température et de la salinité sur la mouillabilité. Nous avons montré que les changements de mouillages des roches n’étaient pas occasionnées par la seule expansion de la couche électrique en revanche des changements de mouillabilité ont été montrés. Ces changements s’expliquant par des transitions de mouillages de second ordre observées non seulement pour des gouttes d’huiles sur de l’eau mais également sur un substrat en verre. Au final, la mouillabilité en milieux poreux doit être mise en évidence à une échelle sous-Micrométrique ce qui est relativement nouveau dans le domaine pétrolier. / The aim of the thesis is to study rock wettability change effects caused by Low Salinity brine injection as tertiary recovery method. To identify the underlying mechanism or mechanisms of additional oil recovery X-Ray imaging technology was applied. We have also imaged the end-Point saturations of filled by brine and water core samples. Once the primary drainage is realized we carried out two phases imbibitions: with high salinity brine (waterflooding) and with low salinity brine (tertiary recovery mode). The wettability analysis at pore scale permitted to put in evidence the thermal and saline effects playing a decisive role in rock wettability. We have showed wettability changes are not caused by only electrical double layer expansion, however wettability changes was shown. These changes are explained by wettability transition of second order and observed not only for oil droplet on brine, but also for oil deposited on glass substrate. Finally, the pore space wettability needs to be evidenced at sub-Micrometric scale that is new for the petroleum domain.
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Geophysics for the Evaluation of Reactive SystemsBörner, Jana 23 August 2024 (has links)
The field of geosciences, including geophysics, plays a crucial role in addressing society's pressing concerns related to energy demand, climate change, resource preservation, and environmental protection. Reactive systems encountered in this context are characterized by intricate interactions among various phases, environmental conditions, physical and chemical processes. Achieving a comprehensive understanding of these processes and quantitatively evaluating reactive systems necessitates a holistic scientific approach. This approach encompasses efficient categorization of reactive systems, the development of appropriate experimental and computational tools, and the collection and dissemination of relevant data. In this context, this thesis contributes to geophysics and petrophysics with a focus on reactive systems.
It presents and interprets laboratory datasets that address various complex aspects of rock behavior, including the presence of graphite, resulting anisotropy, and the challenging petrophysical characteristics of carbonate rocks. This compilation of research results provides a multifaceted perspective on the complex nature of rocks, including their mineralogical, physical, and chemical properties. It thus contributes to a deeper comprehension of electrical rock properties and their practical utility. Upon examining carbonate rocks and the response of graphitic schist to CO$_\mathrm{2}$ under reservoir conditions, it becomes clear that the impact of increased reactivity in a system on geophysical parameters varies depending on the specific characteristics of the rocks and systems under investigation. Consequently, geophysical methods aiming at a quantitative assessment of reactive systems must exhibit robustness and efficiency in order to be effectively applied in a site- and system-specific manner.
Expanding on this foundation, computational methods have been developed to aid in the quantitative analysis of reactive processes in laboratory experiments. These methods also serve as tools for gaining insights into the origin of rock properties and the impact of microstructure variation. Furthermore, inversion techniques are introduced in conjunction with custom-designed experiments within the field of petrophysics. The resultant software tool is made publicly accessible. The research further delves into the exploration of how physical properties of rocks are influenced by their microstructure, as well as how the stochastic nature of pore space geometry can introduce variability and uncertainty in rock physics data. This investigation was carried out through microstructure modeling and finite element simulations.
Leveraging these tailored computational techniques allowed for a comprehensive understanding of laboratory data, facilitating robust generalizations and contextualization for field applications and site-specific integrated interpretation. To illustrate the application in a complex natural reactive system, a field study focusing on coastal fumarolic vents in volcanic terrain was carried out and is presented. The challenges, prospects and visualization strategies for integrating simulation or inversion results from different methods are examined. Effective evaluation of complex sites requires open access to existing knowledge, including laboratory datasets. Consequently, this work documents and provides openly accessible examples of complex multi-method laboratory datasets to facilitate better understanding, re-evaluation and application in the field.
Finally, the handling of multi-reactive systems in field applications is discussed. It involves the integration of three-dimensional subsurface models with petrophysical insights related to multi-reactive systems. These models are calibrated using additional complementary data from surface or borehole sources. This integrated approach enables a quantitative assessment of site-specific multi-reactive systems.
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