International standards establish criteria for size-selective aerosol sampling for industrial hygiene. Commercially available aerosol samplers are designed to conform to these criteria. This study uses semi-monodispersed aerosols generated in a vertically aligned test chamber to compare the performance of three commercially available respirable dust samplers, one of which can, in addition, simultaneously sample for thoracic and inhalable dust fractions. Comparison methods are used to calculate a theoretical fractional value based on the appropriate sampling conventions of the total dust concentration and size distribution of test materials. Performance of actual samplers can be conducted by comparing observed results to the theoretical value. Results show the design of the test chamber and use of fused aluminum oxide is appropriate to conduct simplified performance verification tests for inhalable and respirable dust samplers. This study showed the TSI RespiCon followed the inhalable and respirable conventions closely, but results for the thoracic fraction required the use of a correction factor. The SKC aluminum cyclone tended to undersample the respirable fraction, while the BGI CAS4 cyclone and the TSI RespiCon appear to most closely follow the convention. Improved selection of test material and characterization of particle sizes are recommended to further develop this method of performance verification.

published_or_final_version / Medicine / Master / Doctor of Medicine

All classes of Active Galactic Nuclei (AGN) are fundamentally powered by accretion of gas onto a supermassive black hole. The process converts the potential energy of the infalling matter to X-ray and ultraviolet (UV) radiation, releasing up to several 1012 solar luminosities. Observations show that the accreting "central engines" in AGN are surrounded by dusty matter. The dust occupies a "torus" around the AGN which is comprised of discrete clumps. If the AGN radiation is propagating through the torus on its way to an observer, it will be heavily re-processed by the dust, i.e. converted from UV to infrared (IR) wavelengths. Much of the information about the input radiation is lost in this conversion process while an imprint of the dusty torus is left in the released IR photons. Our group was the first to formulate a consistent treatment of radiative transfer in a clumpy medium an important improvement over simpler models with smooth dust distributions previously used by researchers. Our code CLUMPY computes spectral energy distributions (SED) for any set of model parameters values. Fitting these models to observed AGN SEDs allows us to determine important quantities, such as the torus size, the spatial distribution of clumps, the torus covering factor, or the intrinsic AGN luminosity. Detailed modeling also permits us to study the complex behavior of certain spectral features. IR radiative transfer introduces degeneracies to the solution space: different parameter values can yield similar SEDs. The geometry of the torus further exacerbates the problem. Knowing the amount of parameter degeneracy present in our models is important for quantifying the confidence in data fits. When matching the models to observed SEDs we must employ modern statistical methods. In my research I use Bayesian statistics to determine the likely ranges of parameter values. I have developed all tools required for fitting observed SEDs with our large model database: the latest implementation of CLUMPY, the fit algorithms, the Markov Chain Monte Carlo sampler, and the Bayesian estimator. In collaboration with observing groups we have applied our methods to a multitude of real-life AGN.

To this date, estimates of the climate response to mineral dust remain largely uncertain because of our limited capability to quantify dust distribution in the atmosphere. Focusing on the Central and East Asian dust source regions, this thesis aims to develop a coupled regional dust modeling system to provide an improved modeling capability of atmospheric dust as well as to aid the integration of ground-based and satellite observations. The objectives of this study are as follows: 1) evaluate the capabilities of the available data to detect and quantify mineral dust in the atmosphere; 2) develop and test a coupled regional dust modeling system able to simulate size resolved dust concentrations accounting for the regional specifics of Central and East Asia; and 3) outline a methodology for data and modeling integration. The capabilities of ground-based and satellite data to characterize dust in the atmosphere are examined in great details. Based on analysis of MODIS data reflectance and radiances, we found evidence for regional signature of dust in near-IR and proposed a new probabilistic dust-cloud mask that explicitly takes into account the spatial variability characteristics of dust aerosols. We developed a coupled regional dust modeling system (WRF-DuMo) by incorporating a dust emission module (DuMo) into the NCAR WRF model. The WRF-DuMo unique capabilities include explicit treatment of land surface properties in Central and East Asia, a suite of dust emission schemes with different levels of complexity, multiple options for dust injection in the atmosphere and flexible parameters of the initial size distribution of emitted dust. Two representative dust events that originated in East Asia in the springs of 2001 and 2007 have been modeled with WRF-DuMo. Simulations with different initial size distribution of dust, injection and emission parameterizations have been performed to investigate their relative role on the modeled dust fields. We performed an integrated analysis of modeled dust fields and satellite observations by introducing an ensemble model dust index, which used in conjunction with satellite dust retrievals improves the capability to characterize dust fields. Finally, we provide recommendations for the development of an integrated observational and modeling dust framework.

Doctor of Philosophy(PhD) / Complex (dusty) plasmas are a subject of growing interest. They areionized gases containing charged dust particles. In capacitively-coupled RF discharges, dust growth can occur naturally and two methods can be used to grow dust particles: chemically active plasmas or sputtering. The growth of dust particles in argon discharges by RF sputtering and the effect of dust particles on theplasma have been investigated from the plasma ignition to the afterglow. It was shown that plasma and discharge parameters are greatly affected by the dust particles. Furthermore, plasma instabilities can be triggered by the presence of the dust particles. These instabilities can be due to dust particle growth or they can be instabilities of a well established dust cloud filling the interelectrode space. When the discharge is switched off, the dust particles act like a sink for the charge carrier and consequently affect the plasma losses. It was shown that the dust particles do keep residual chargeswhich values are greatly affected by the diffusion of the charge carriers and especially the transition from ambipolar to free diffusion.

Title: The Role of Secondary Electron Emission in Dust Grain Charging Author: Ivana Richterová Department: Department of Surface and Plasma Science Supervisor: Prof. RNDr. Zdeněk Němeček, DrSc. Abstract: This work presents a secondary emission model focused on micron and submicron dust grains. The results allowed us to predict surface potentials of grains charged by 50 eV -- 15 keV electron beams. The probability that such electrons penetrate through grains increases with their energy and decreases with a grain size and depends on a grain shape. Model predictions were experimentally verified for glass, gold, and carbon spherical grains and for lunar regolith simulants. In dusty plasmas, charge accumulated on dust grains and plasma parameters govern the ensemble dynamics. The model can be thus utilised in calculations of phenomenon in planet magnetospheres (e.g. spokes in Saturn's rings), in tokamak edge plasmas, etc. Keywords: Secondary emission, dust grains, dust charging

The use of Type Ia supernovae (SNe Ia) as distance indicators is essential for studying the expansion history of the Universe and for exploring the nature of dark energy. However, a lack of understanding of the progenitor systems and the empirically derived colour-brightness corrections represent severe limitations for SNe Ia as cosmological probes. In this thesis, we study how dust along the line of sight towards SNe Ia affects the observed light over a wide range of wavelengths; from X-rays to infrared. Unless properly corrected for, the existence of intergalactic dust will introduce a redshift dependent magnitude offset to standard candle sources and bias the cosmological parameter estimates as derived from observations of SNe Ia. We model the optical extinction and X-ray scattering properties of intergalactic dust grains to constrain the intergalactic opacity using a combined analysis of observed quasar colours and measurements of the soft X-ray background. We place upper limits on the extinction AB(z = 1) &lt; 0.10 - 0.25 mag, and the dust density parameter Ωdust &lt; 10−5 − 10−4 (ρgrain/3 g cm−3), for models with RV &lt; 12 − ∞, respectively. Dust in the host galaxies, and dust that may reside in the circumstellar (CS) environment, have important implications for the observed colours of SNe Ia. Using the Hubble Space Telescope and several ground based telescopes, we measure the extinction law, from UV to NIR, for a sample of six nearby SNe Ia. The SNe span a range of E(B − V ) ≈ 0.1 − 1.4 mag and RV  ≈ 1.5 − 2.7, showing a diversity of dust extinction parameters. We present mid- and far-infrared (IR) observations for a number of SNe Ia, obtained with the Herschel Space Observatory and Spitzer Space Telescope, addressing CS dust as an explanation for “peculiar” extinction towards some SNe Ia. No excess IR emission is detected, limiting CS dust masses, Mdust &lt; 10−5 solar masses. In particular, the timely appearance of SN 2014J in M82 - the closest SN Ia in several decades - allows for detailed studies, across an unprecedented wavelength range, of its lightcurve and spectral evolution along with the host galaxy and CS environment. / <p>At the time of the doctoral defense, the following papers were unpublished and had a status as follows: Paper 5: Manuscript. Paper 6: Manuscript.</p>

Title: Dust - UV interaction Author: Libor Nouzak Department: Department of Surface and Plasma Science Supervisor: RNDr. Jiri Pavlu, Ph.D. Supervisor's e-mail address: jiri.pavlu@mff.cuni.cz Abstract: Micrometer objects (dust grains) are an integral part of the universe. As other objects in the plasma, these dust grains charge to potencial close to the potencial of the plasmas (in this case, interplanetary plasma). In the universe, the photoelectric charging dust grain dominantes all other charging processes. In general, the resulting charge of dust grain is given by a balance of all processes, which haven't been mostly jet theoretically described. In our laboratory, we are simulating space conditions and measure resulting charge and his changes on a single separated dust grain. This work is partly focused to UV source application and to finishing its electronics, and partly on test measurements and model calculations, connected with newly built experiment (e.g., to estimate effects of backgound currents, surfaces, and the geometry of the dust trap electrodes). The work is finished by the first measurements of glass grain charge under electron bombardment with provisional detection optics. Obtained results are compared with previous measurements on the same type of dust grains. Key words: dust, dusty plasma,...

The current cosmological paradigm of an accelerating cosmic expansion issupported by observations of Type Ia supernovae. However, the light emittedby these and other cosmological sources is not only redshifted by cosmicexpansion but will also interact with matter along the light path. Especiallyintergalactic dust can lead to additional reddening and dimming of distantsources due to light scattering or absorption. This yields systematiccontaminations to cosmological measurements. This project builds afoundation and some of the tools that will be used in a master’s thesis withthe aim of analysing the spatial distribution and the properties of this cosmicdust. While previous studies assumed cosmic dust to be homogeneouslydistributed, it is expected to follow the spatial distribution of galaxies fromwhich it was expelled. This project also starts to recreate previous models ofhomogeneous dust models and measurements which will be used the futuremaster’s thesis. An analysis of the methods and tools used, along with some ofthe dust properties, is also made in this project.

Windblown dust events can be defined as windblown dust emitted from the Earth's surface to the atmosphere. These events have significant impact on local air quality. Predicting the location and magnitude of these events is vital for Utah air quality assessment and planning. Previous modeling studies have focused only on past dust events. This work utilized a state-of-the-science software framework based on the Community Multiscale Air Quality (CMAQ) v5.3.1 modeling system to predict dust events in Utah. The framework was verified using previous studies for dust events in April 2017 and March 2010. Once verified, the framework was used to predict the impact of future land use properties on dust events. Two scenarios were studied – shrinking of the Great Salt Lake and the addition of large-scale solar farms west of the Wasatch Front. Both showed increases in dust concentrations overpopulated areas using the meteorological conditions from the April 2017 dust event. Such information from future impact studies can assess potential impacts from climate change and can guide government water and land use policies to mitigate dust event impacts.