<p>A colloid of magnesium hydroxide is used to stabilize droplets of monomers before suspension polymerisation. The characteristics of precipitated magnesium hydroxide changes significantly during the first hours. The viscosity is high and flucctuating at first but decreases and becomes low and stable after a few hours. When the colloid ages the primary particles agglomerate into larger particles which increases in size by time due to, among other things, Oswald ripening and aggregation. This can cause problems with poor reproducibility in the production. Therefore, the purpose of this study was finding a way to age the colloid without an increase in particle size and without changing any other features. Several experiments were made to optimize the precipitation procedure and to find out what parameters that are most important. The results showed that the stirring rate and colloidal concentration have big influence.</p><p>Small amounts of chemicals that modifies the surface of the colloid was added. This made the particle size near constant over time and the colloid was aged for two months without increasing in size or changing other properties. This was confirmed by making microspheres that had the same characteristics as microspheres made with a fresh colloid.</p>

<p>Two new specification tests for overidentifying restrictions proposed by Hahn and Hausman (2002:b) are here tested and compared to the classical Sargan test. Power properties are found to be very similar in overall performance, while Sargan generally has better size than the new tests. Also, size is distorted for one of the new tests, thus a tendency to reject prevails. In addition, sometimes severe bias is found which affects the tests’ performances, something that differs from earlier studies.</p>

Many sediments, including the fine-grained pelagic deposits, possess polymodal grain size distributions. Resolution of individual modes show them to be related either to compositional fractions or to depositional processes or both, and sometimes permits the tracing of dispersal patterns. The Cahn sedimentation balance provides a means of obtaining continuous cumulative size distribution curves of fine-grained sediments. The resultant cumulative curve is processed by computer to yield a size frequency curve which is often found to be polymodal. This frequency curve is resolved into its individual components by means of an analog computer. The method is discussed in detail and illustrated by means of a test study of pelagic sediments from the Northwest Pacific. Samples collected nearest land have the most components and the best sorted components. Fifteen modes were decanted from five samples and X-rayed. Similar components from different samples were found to have similar compositions when plotted on a feldspar-kaolinite-mica ternary diagram. Based on like composition and nearly identical mean size values, it is possible to trace the sedimentary components from sample to sample. / Graduation date: 1972

We study the effects of vibrations in the Pd₃ system using first-principles pseudopotential calculations. We find that upon disordering from the DO₂₂ phase, the decreases by 0.07kB. We explain our results in terms of atomic relaxations and size effects. / Singapore-MIT Alliance (SMA)

Thesis (D. Ed.)--University of Oregon, 2006. / Typescript. Includes vita and abstract. Includes bibliographical references (leaves 146-152). Also available for download via the World Wide Web; free to University of Oregon users.

To achieve predictive capability for complex environmental systems with coagulation and arsenic sorption, a unified improved coagulation model coupled with arsenic sorption was developed. A unified coagulation model coupled with arsenic sorption was achieved by the following steps: (1) an improved discretized population balance equation (PBE) was developed to obtain the exact solution of conventional coagulation, (2) the improved PBE was extended to an adjustable geometric size interval having higher numerical stability, accuracy, and computational efficiency than existing models for fractal aggregate coagulation that includes agglomeration and fragmentation, (3) a surface complexation equilibrium model and a sorption kinetic model was introduced to predict arsenic sorption behavior onto hydrous metal oxide surfaces, and (4) an improved discretized PBE was coupled with arsenic sorption kinetics and equilibrium models by aid of collision efficiency ?? depending on surface charge (potential) on the hydrous metal oxide particles, colliding particle size ratio, and fluid strain-rate in applied flow system. The collision efficiency ?? into the improved (r,r)ij(r,r)ijdiscretized coagulation model for fractal aggregate yielded a unified improved coagulation model coupled with arsenic sorption kinetics and the equilibrium model. Thus, an improved unified coagulation model could provide high statistical accuracy, numerical stability, and computational efficiency to enhance predictive capability for behavior of arsenic sorption and fractal colloid particle aggregation and break-up, simultaneously. From the investigation, it is anticipated that the unified coagulation model coupled with arsenic sorption kinetics and equilibrium will provide a more complete understanding of the arsenic removal mechanism and its application to water/wastewater treatment. Further, this coupled model can be applied to other water and wastewater treatment systems combined with sorption and filtration processes. These combined processes can be optimized by the coupled model that was developed in this study. By simulating the arsenic sorption and particle size distribution as a pretreatment before filtration (sand filtration or membrane filtration), the overall arsenic removal efficiency and operation cost can be estimated.

Marine aggregates are an important means of carbon transfers downwards to the deep ocean as well as an important nutritional source for benthic organism communities that are the ultimate recipients of the flux. During these last 10 years, data on size distribution of particulate matter have been collected in different oceanic provinces using an Underwater Video Profiler. The cruise data include simultaneous analyses of particle size distributions as well as additional physical and biological measurements of water properties through the water column. First, size distributions of large aggregates have been compared to simultaneous measurements of particle flux observed in sediment traps. We related sediment trap compositional data to particle size (d) distributions to estimate their vertical fluxes (F) using simple power relationships (F=Ad^b). The spatial resolution of sedimentation processes allowed by the use of in situ particle sizing instruments lead to a more detailed study of the role of physical processes in vertical flux. Second, evolution of the aggregate size distributions with depth was related to overlying primary production and phytoplankton size-distributions on a global scale. A new clustering technique was developed to partition the profiles of aggregate size distributions. Six clusters were isolated. Profiles with a high proportion of large aggregates were found in high-productivity waters while profiles with a high proportion of small aggregates were located in low-productivity waters. The aggregate size and mass flux in the mesopelagic layer were correlated to the nature of primary producers (micro-, nano-, picophytoplankton fractions) and to the amount of integrated chlorophyll a in the euphotic layer using a multiple regression technique on principal components. Finally, a mesoscale area in the North Atlantic Ocean was studied to emphasize the importance of the physical structure of the water column on the horizontal and vertical distribution of particulate matter. The seasonal change in the abundance of aggregates in the upper 1000 m was consistent with changes in the composition and intensity of the particulate flux recorded in sediment traps. In an area dominated by eddies, surface accumulation of aggregates and export down to 1000 m occured at mesoscale distances (<100 km).

<p>This paper tries to find the relationship between the compensation given to the chief executive officer and the performance of the company. Further, it tries to determine the influence of the size of the Board members on the pay scale of the executive. The data consisted of the largest thirty companies in Sweden for the period of 2004-2008. After controlling for firm size and growth opportunities, I find a negative and insignificant relationship between pay and performance. Contradictory to previous studies no correlation between large board size and chief executive officers compensation was found. This paper adds more empirical evidence to the idea of chief executives pay being independent of his performance.</p>

Plastic deformation processes transform material fromas-received state to products meeting certain requirements inproperties, microstructure and shape. To achieve thistransformation, the relationship between material response andprocess conditions should be understood. This is usuallycomplicated by the complex conditions describing the actualprocess. Numerous techniques including empirical, physical,analytical and numerical can be employed. In this thesis, numerical technique supported by lab- andfull-scale experiments has been employed to analyse the formingparameters. The first part of the thesis is focused on the useof such parameters to predict occurrence of material poresduring manufacturing of bearing rings. The second part dealswith the influence of forming parameters on the grain sizeduring fabrication of large copper canisters for encapsulationof nuclear waste. The primary task has been to study with thehelp of commercial FE-codes the magnitude and distribution offorming parameters such as accumulated effective strain,temperature, instantaneous hydrostatic pressure and materialflow at different stages of the forming process. In the firstpart, two types of ring manufacturing routes, which result inpore free and pore loaded rings are studied and compared.Material elements located in different areas of the workpiecehave been traced throughout the process. Results of theaccumulated strain and instant hydrostatic pressure have beenanalysed and presented in pressure-strain space. It’sassumed that high hydrostatic pressures together with higheffective strains are favourable for pore closure. Area of theworkpiece with unfavourable parameters have been identified andcompared with ultrasonic test results. Good agreement has beenobtained. Based on the results of this analysis, a new conceptfor avoiding pores in manufacturing of yet heavier rings hasbeen presented. The concept proposes a lighter upsetting in theinitial stage of the process and a more efficient piercingwhich results in higher hydrostatic pressure and bigger andbetter distributed effective strain. In the second part of the thesis, the influence of formingparameters such as effective strain and temperature on thefinal grain size of the product has been studied in laboratoryscale. As-cast billets of cylindrical shape were extruded atdifferent temperatures and reductions. It has been shown thatthe grain size in the final product should be small in order toenable ultrasonic tests and to guarantee resistance towardscreep and corrosion. Simulations for different materialelements located at different distances from the axis ofsymmetry of the initial cylindrical workpiece have been carriedout. In this way, the parameters describing the deformationhistory of the elements have been determined as functions oftime. Experimentally obtained pre- and post deformation grainsize in the corresponding locations of the material weredetermined. It’s concluded that low temperature coupledwith high effective strain are conducive for obtaining a smallgrain size. Based on the beneficial conditions for extrusion ofcopper, a more detailed FE-analysis of a full-scale industrialprocess is carried out. A coarse-grained cast ingot of purecopper is heated and by upset forging formed into a cylinder,which is then punched into a hollow blank for subsequentextrusion. The blank is extruded over a mandrel through a45-degree semi-angle die. Accumulated effective strain andtemperatureas functions of the tubular wall thickness havebeen studied at five different locations along the tubularaxis. Forming load requirement as function of tool displacementfor each stage of the process has been determined. Strain andtemperature levels obtained have been related to the grain sizeinterval obtained in the earlier work. It has been concludedthat the levels reached are within the interval that ensures asmall grain size. A similar analysis has been carried out forforging of large copper lids and bottoms. Die designmodifications to improve the grain size in the lid and tooptimise the forging process with respect to forging load andmaterial yield have been proposed. A method requiring a smallforging load for fabrication of the lids has been analysed <b>Keywords:</b>Pores; grain size; low forging load; effective strain;temperature; hydrostatic pressure; extrusion; forging;canister; lid; rings

This paper tries to find the relationship between the compensation given to the chief executive officer and the performance of the company. Further, it tries to determine the influence of the size of the Board members on the pay scale of the executive. The data consisted of the largest thirty companies in Sweden for the period of 2004-2008. After controlling for firm size and growth opportunities, I find a negative and insignificant relationship between pay and performance. Contradictory to previous studies no correlation between large board size and chief executive officers compensation was found. This paper adds more empirical evidence to the idea of chief executives pay being independent of his performance.