Hybrid powertrains that use compressed air to help power a vehicle could dramatically improve the fuel economy, particularly in cities and urban areas where the traffic conditions involve a lot of starts and stops. In such conditions, a large amount of fuel is needed to accelerate the vehicle, and much of this is converted to heat in brake friction during decelerations. Capturing, storing and reusing this braking energy to produce additional power can therefore improve fuel efficiency. In this study, three approaches towards air hybrid powertrains are proposed and analyzed. In the first approach, an energy recovery valve or two shut-off valves connected to a convenient access hole on the engine cylinder is proposed to enable the cylinder to operate as a regenerative compressor and/or expander when required. In the second approach, one of the exhaust valves in an engine equipped with a Fully Variable Valve Actuation (FVVA) system is pneumatically or hydraulically operated as a dedicated gas transfer valve connected to an air reservoir. The third approach combines the advantages of the conventional valvetrain’s simplicity with emerging production technologies. In order to achieve this, two well established technologies are used in addition to valve deactivation; Variable Valve Timing (VVT) and/or Cam Profile Switching (CPS). Provided that a conventional, camshaft-operated variable valvetrain is used, the need of adopting fully variable valve actuation is eliminated and thus only minor modifications to the engine architecture are required. The aforementioned concepts are described in details. Some basic principles of their operation are also discussed in order to provide a better understanding on how fuel economy is achieved by means of engine hybridization and regenerative braking. Both experimental and computational results are presented and compared. Finally, a vehicle and driveline model, which simulates the operation of a typical passenger vehicle in urban driving conditions and predicts the efficiency of the energy regeneration, has been set up and used to study the effects of the application of each air hybrid concept on the vehicle’s energy usage throughout the New European Driving Cycle (NEDC) and the 10-15 driving cycle. The results have shown that each concept involves the optimization of valve timing for the best regenerative energy recovery and its subsequent usage. For the modelled vehicle, it has been shown that any of the three concept engines is capable of providing more braking power than needed during every deceleration and braking process, especially throughout the urban driving part of each cycle. The recovered braking energy in the form of compressed air has proved to be always sufficient to start the engine, if stop-and-start engine operation strategy is to be adopted.

Burning joss paper and incense is a significant Taoist ceremonial practice in Asian countries such as Taiwan and China. The burning of joss paper has been demonstrated to significantly create particulate matters (PM) and to cause air pollution problems. PM in the atmosphere is among the primary air pollutants, and their sources are factories, vehicles, construction fields, combustion, vehicle exhaust dust, and aerosols derived from photochemical reactions. Numerous sources of environmental PM exist. Thus, the ability to rapidly determine the particulate type and source to adjust the controls and develop policies is an important issue for air quality management. This dissertation consists of two parts on the particulate emission control and characteristic identification. In the first part, we study investigates feasible options of air pollution control devices (APCD) for joss paper furnaces in temples, and used a 40 kg/hr joss paper furnace for testing. This paper examined particulate removal efficiencies of two options: a bag house (capacity 30 m3/min at 108 ¢J) and a wet scrubber (capacity 40 m3/min at 150 ¢J). The results indicate that PM in the diluted flue gas at the bag-house inlet were 76.6 ¡Ó 32.7 mg/Nm3 (average ¡Ó standard deviation), and those at the outlet of the bag-house could be reduced to as low as 0.55 ¡Ó 1.28 mg/Nm3. An average PM removal efficiency of 99.3 % could be obtained with a filtration speed of approximately 2.0 m/min evaluated at 108 ¢J. The wet scrubber removed approximately 70 % of PM, with scrubbing intensities higher than 4.0 L/m2.s across the scrubber cross-section. For the duration of the experiment, no visual white smoke (water mist) was observed at the exit of the wet scrubber with a combustion rate of 16 kg/hr of joss paper, and the scrubbing water temperature was automatically sustained at lower than 61 ¢J. The study concluded that both bag filtration and wet scrubbing are suitable techniques to control particulate emission from joss paper furnaces in Taiwanese temples. The bag filtration technique, while achieving higher efficiencies than the wet scrubbing technique, requires more space and cost. Examinations of bottom and fly ashes of combusted joss paper with X-ray diffraction (XRD) revealed the presence of calcium oxide in the fly ash, while certain metals were found in the bottom ash. The second part aimed at the investigates surface characteristics of airborne PM sampled from air pollution control devices of a number of industrial operations. The PM sources selected for this study comprise the following operations or processes: a coke oven, iron ore sintering furnace, blast furnace, and basic oxygen furnace from an integrated steelmaking plant; electric arc furnaces of two secondary steelmaking plants; a municipal solids waste incinerator; two oil-fired boilers; and a coal-fired power plant boiler. The collected PM samples were analyzed using a scanning electronic microscope (SEM) and energy-dispersive X-ray spectroscope (EDS) to determine their chemical composition and surface characteristics. Results for each PM sample regarding size, surface characteristics, and chemical compositions can be used to trace the related emission industrial sources.

Emission of hazardous gases such as hydrogen sulphide (H2S) by a variety of industrial processes and as a result of agricultural activities has become an issue of great concern over the years. The control of these gases is needed to ensure public safety, to protect the environment, and lastly to comply with occupational and environmental regulations. Several techniques including biological and physicochemical methods have been applied to remove these gases from contaminated air streams. In this work, Zinc oxide (ZnO) nanoparticles were used to adsorb H2S gas at ambient temperatures. The effects of H2S concentration (80-1700 mg L-1), nanoparticle size (18, 80-200 nm), gas flow rate (200 and 450 mL min-1), temperature (1-41C) and adsorbent quantity (0.2-1.5 g) were investigated in the laboratory scale. A semi-pilot system was also developed and used to treat H2S emission from stored swine manure. The results show that when H2S concentration was increased the adsorption capacities (both breakthrough and equilibrium) increased and the nanoparticles reached the saturation state faster. When nanoparticles of different sizes were tested, it was observed that 80-200 nm particles got saturated with H2S faster than 18 nm particles. The adsorption capacities were higher with 18 nm particles than those with 80-200 nm. Temperatures did not have an effect on how fast the nanoparticles got saturated and on breakthrough adsorption capacity, but equilibrium adsorption capacity increased due to increase in temperature. The breakthrough and equilibrium adsorption capacities increased with increased quantity of nanoparticles. BET isotherm described the equilibrium data with higher accuracy as compared to other adsorption isotherms which were tested. Semi-pilot scale tests proved the effectiveness of 18 nm ZnO nanoparticles in capture of H2S emitted from stored swine manure. For an experimental period of approximately 100 minutes the level of H2S was reduced from an average initial value of 235.785.2 mg L-1 to a negligible level (an average value of 0.26 mg L-1) corresponding to an H2S removal of at least 99%. Semi pilot tests also showed that 18 nm ZnO nanoparticles were able to capture about 74% of NH3 that passed through the adsorption column.

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Indiana University-Purdue University Indianapolis (IUPUI) / Stringent regulatory requirements and modern diesel engine technologies have engaged automotive manufacturers and researchers in accurately predicting and controlling diesel engine-out emissions. As a result, engine control systems have become more complex and opaquer, increasing the development time and costs. To address this challenge, Model-based control methods are an effective way to deal with the criticality of the system study and controls. And physics-based combustion engine modeling is a key to achieve it. This thesis focuses on development and validation of a physics-based model for both engine and emissions using model-based design tools from MATLAB & Simulink. Engine model equipped with exhaust gas circulation and variable geometry turbine is adopted from the previously done work which was then integrated with the combustion and emission model that predicts the heat release rates and NOx emission from engine. Combustion model is designed based on the mass fraction burnt from CA10 to CA90 and then NOx predicted using the extended Zeldovich mechanism. The engine models are tuned for both steady state and dynamics test points to account for engine operating range from the performance data. Various engine and combustion parameters are estimated using parameter estimation toolbox from MATLAB and Simulink by applying the least squared solver to minimize the error between measured and estimated variables. This model is validated against the virtual engine model developed in GT-power for Cummins 6.7L turbo diesel engine. To account for the harmonization of the testing cycles to save engine development time globally, a world harmonized stationary cycle (WHSC) is used for the validation. Sub-systems are validated individually as well as in a loop with a complete model for WHSC. Engine model validation showed promising accuracy of more than 88.4 percent on average for the desired parameters required for the NOx prediction. NOx estimation is accurate for the cycle except the warm-up and cool-down phase. However, NOx prediction during these phases is limited due to actual NOx measured data for tuning the model for real-time NOx estimation. Results are summarized at the end to compare the trend of NOx estimation from the developed combustion and emission model to show the accuracy of in-cylinder parameters and required for the NOx estimation.

Vattenfall operates a cogeneration plant where household and industrial waste is incinerated to generate electricity and district heating. The waste incineration generates flue gases, and the energy in the hot flue gases is recovered by condensation. Both flue gases and the flue gas condensate are treated by emission control systems before being released into nature. The emission control system is planned to be updated with better technologies currently applied in Sweden. In this study, a comparison of the overall environmental impact of the current emission control system and the new system for emission control is performed. Vattenfall will perform a comparative life cycle assessment, LCA, of the two emission control systems. A part of the LCA is an inventory analysis. In this study, data required for the inventory analysis will be collected and quantified. The parameters considered are emissions to air and water, consumption of chemicals, produced solid residue, and water utilization. The objectives with the planned upgrade of the emission control system, which are evaluated in this study, are to obtain a cleaner condensate stream that can be reused in the system, to reach a higher tolerance of sulphur content in the fuel, and to reach a better reduction of emissions, for future stricter regulation. From the perspective of this study, the new system for emission control system seems to be the choice for emission control system with the least environmental impact. The results show that the reasons for upgrading the emission control system are met with the new system. The condensate is significantly cleaner with the new alternative emission control system than in the current one, the total amount of emissions decreases by 99,98 w%. The significantly smaller amount of emissions results in a condensate flow that can be reused in the system, which could save a considerable amount of raw water each year. The SO2 emissions are reduced by 99,5 w%, which show that a higher sulphur content in the fuel could be tolerated with the new emission control system. Furthermore, the total amount of emission content in the flue gas decreases with 61,9 w% with the new emission control system. The emission parameters that are deemed likely to be more strictly regulated in coming regulations, NOx and Hg, are both significantly reduced with the new emission control system. On the other hand, both the consumption of chemicals and the production of solid residue increases in the new emission control system, compared to the current one. These aspects are important drawbacks with the new system, and the environmental impact of these aspects needs to be further investigated in the planned LCA. / Vattenfall driver ett kraftvärmeverk där avfall från hushåll och industrier förbränns för att generera el och fjärrvärme. Avfallsförbränningen genererar rökgaser, och energin i rökgaserna utvinns genom kondensering. Rökgaserna och kondensatet renas från föroreningar innan de släpps ut i naturen. Systemet för rökgas- och kondensatrening ska uppdateras till nyare tekniker. I det här arbetet jämförs den totala miljöpåverkan av det nuvarande och det nya systemet för rökgas- och kondensatrening. Vattenfall kommer i framtiden att utföra en jämförande livscykelanalys av de två rökgas- och kondensatreningssystemen. En del i en livscykelanalys är en inventeringsanalys. Syftet med det här arbetet är att samla in och kvantifiera den data som behövs för inventeringsanalysen. Parametrarna som tas med i inventeringsanalysen är utsläpp till luft och vatten, kemikalieförbrukning, restprodukter samt vattenförbrukning. Målen med uppdateringen av rökgas- och kondensatreningssystemen är att erhålla ett renare kondensat som kan återanvändas i systemet, att kunna elda bränsle med en högre halt svavel och fortfarande hålla utsläppen under utsläppsgränserna, samt att få en bättre rening av föroreningar för att kunna möta framtida utsläppskrav. Målet med detta arbete är att utvärdera hur väl dessa aspekter möts i det nya systemet för rökgas- och kondensatrening. Utifrån de aspekter som utvärderats i denna studie verkar det nya systemet för rökgas- och kondensatrening ha en mindre miljöpåverkan än det nuvarande. Resultaten visar att alla målen med att uppdatera rökgas- och kondensatreningssystemet nås med det nya systemet. Kondensatet blir signifikant renare med det nya systemet jämfört med det nuvarande, den totala mängden föroreningar i kondensatet minskar med 99,98 vikts%. Det innebär att kondensatet kan återanvändas i systemet, och en betydande mängd råvatten kan sparas varje år. Utsläppen av SO2 minskar med 99,5 vikts%, vilket visar att en högre svavelhalt i bränslet skulle kunna tolereras. Vidare minskar den totala mängden föroreningar i rökgaserna med 61,9 vikts%. De föroreningsparametrar som bedöms bli mer strikt reglerade inom en snar framtid, NOx och Hg, reduceras signifikant med det nya systemet för rökgas- och kondensatrening. Däremot ökar både kemikalieförbrukningen och mängden producerad restprodukt. Ökningarna är betydande nackdelar för det nya systemet, och miljöpåverkan av detta bör undersökas vidare i den planerade livscykelanalysen.

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No description available.

Doctor of Philosophy / Department of Biological & Agricultural Engineering / Ronaldo G. Maghirang / Emissions of particulate matter (PM) are an increasing concern for large open beef cattle feedlots. Research is needed to develop science-based information on PM emissions and abatement measures for mitigating those emissions. This research was conducted to (1) measure PM concentrations emitted from large cattle feedlots, (2) compare different samplers for measuring concentrations of PM with equivalent aerodynamic diameter of 10 µm or less (PM10), (3) evaluate the relative effectiveness of pen surface treatments in reducing PM10 emissions, and (4) predict PM control efficiency of vegetative barriers. Concentrations of PM with equivalent aerodynamic diameter of 2.5 µm or less (PM2.5), PM10, and total suspended particulates (TSP) upwind and downwind of two large cattle feedlots (KS1, KS2) in Kansas were measured with gravimetric samplers. The downwind and net concentrations generally decreased with increasing water content (WC) of the pen surface; for effective control of PM emissions from feedlots, it appears that pen surface WC should be at least 20% (wet basis). Three types of samplers for measuring PM10 concentrations in feedlots KS1 and KS2 were compared: Tapered Element Oscillating Microbalance™ (TEOM), high-volume (HV), and low-volume (LV) PM10 samplers. Measured PM10 concentration was generally largest with the TEOM PM10 sampler and smallest with the LV PM10 sampler. A laboratory apparatus was developed for measuring the PM10 emission potential of pen surfaces as affected by surface treatments. The apparatus was equipped with a simulated pen surface, mock cattle hooves that moved horizontally across the pen surface, and PM10 samplers that collected emitted PM10. Of the surface treatments evaluated, application of water (6.4 mm) and hay (723 g/m2) exhibited the greatest percentage reduction in PM10 emission potential (69% and 77%, respectively) compared with the untreated manure layer. Computational fluid dynamics (CFD) was applied to predict airflow and particle collection by a row of trees (2.2 m high × 1.6 m wide). Predicted particle collection efficiencies generally agreed with published data and ranged from less than 1% for 0.875-µm particles to approximately 32% for 15-µm particles.

The work reported in this thesis explores innovative control structures and controller design for a heavy duty Caterpillar C6.6 diesel engine. The aim of the work is not only to demonstrate the optimisation of engine performance in terms of fuel consumption, NOx and soot emissions, but also to explore ways to reduce lengthy calibration time and its associated high costs. The test engine is equipped with high pressure exhaust gas recirculation (EGR) and a variable geometry turbocharger (VGT). Consequently, there are two principal inputs in the air-path: EGR valve position and VGT vane position. The fuel injection system is common rail, with injectors electrically actuated and includes a multi-pulse injection mode. With two-pulse injection mode, there are as many as five control variables in the fuel-path needing to be adjusted for different engine operating conditions.