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A variety of energy models and tools have been used for an comprehensive analysis of the complex energy systems and the design of pathway to sustainable energy world. This thesis analyzes three interesting problems in the electricity sector by developing and using suitable energy models. Chapter 2 investigates how to incorporate demand responsiveness for policy analysis in the electricity sector using a least-cost model. This study develops its own least-cost model which includes some characteristics for two important policies in the electricity sector, and suggests an iterative approach for incorporating the demand response to price change under new policy. Based on a case study, the state of Georgia, this chapter shows the effects of including demand response on the evaluation of policy. Chapter 3 is about new technology adoption pathways in the electric power system. In this chapter, by investigating the related status of policies and specifications of electric vehicles and wind power technologies in the U.S., several adoption pathways of the technologies in the U.S. eastern interconnection have been developed. This study develops four-serial models for the estimation of future economic and environmental impacts of the technologies' penetration. The results show that the total greenhouse gas emissions of the entire energy system do not substantially decrease even with a high level of electric vehicle adoption. The combination of two technologies, even more with appropriate policies, can notably decrease the total greenhouse gas emissions. Chapter 4 is a study about demand response programs, particularly optional time-based rates, for residential customers. This chapter analyzes the main reason that the participation of the current programs is low even though the programs have benefits. This study investigates two policy tools, a subsidy for flexible residential demand and a shared-savings mechanism based on consumption pattern changes, and examines the implementation of the tools and their potential to overcome the current inefficient operation.

Thesis (MPhil)--Stellenbosch University, 2015. / ENGLISH ABSTRACT: The South African Government developed the REIPPPP to ensure the implementation of Green Economy and job creation policies, while mitigating the current power crises with the short lead times of RE technologies. Current South African literature is ambiguous when discussing the legitimacy of the REIPPPP and the overall understanding of the programme and its associated outcomes in terms of job creation, are therefore, vague. A need therefore exists to unpack the quantitative job creation submissions of the REIPPPP and to carry out an investigation into the opportunities and challenges associated with meaningful job creation. Through a non-linear iterative exploratory design, hinging on the researcher’s position within industry, this empirical research comprises of two components. Firstly, a literature study informs the development of a meaningful job creation framework which is used to analyse the programme’s bid documentation and publicly available data. Secondly, mixed-methods are utilised to collect quantitative data from the DoE and qualitative data from job creation stakeholders. The result is an enriched understanding of the REIPPPP in terms of meaningful job creation, identifying trends, similarities and unexpected outcomes across methods. The study concludes that the programme does create meaningful jobs yet data is misaligned and currently unavailable to the public. Secondly, since job creation is a feature of South African Government development policy, a more robust emphasis is required in the REIPPPP weighting and auditing process, which includes further research of intended benefits and suggested improvements to align job creation data. / AFRIKAANSE OPSOMMING: Die Suid-Afrikaanse regering het die hernubare energie onafhanklike kragprodusent verkrygingsprogram ontwikkel om die voorsiening van die werksskeppingsbeleid en groen-ekonomiebelied te verseker. Huidige Suid-Afrikaanse letterkunde is dubbelsinnig wanneer die wettigheid van die program bespreek word. Die algehele begrip van die program en sy geassosieerde uitkoms is dus vaag. Daar is n behoefte om die kwantitatiewe werkskeppingvoorleggings te analiseer en om ondersoek in te stel in die geleenthede en uitdagings wat geassosieer word met betekenisvolle werkskepping. Deur n nie- lineêre iteratiewe ondersoekende ontwerp, wat gebaseer is op die navorser se posisie in die industrie, bestaan hieride empiriese navorsing, uit twee komponente. Eerstens, lig n literatuurstudie die ontwikkeling van n betekenisvolle werkskeppingsraamwerk in, en word gebruik om die program se boddokumentasie en publieke data te analiseer. Tweedens, word gemengde metodes gebruik om kwantitatiewe data van die departement van energie te versamel asook kwalitatiewe data van werkskeppingbelanghebbendes. Die resultaat is n meer verrykende verstandhouding van die hernubare energie onafhanklike kragprodusent verkrygingsprogram in terme van betekenisvolle werkskepping asook die identifisering van tendense en onverwagse uitkomste. Die studie kom tot die gevolgtrekking dat die program nie betekenisvolle werk skep nie en is tans onbeskikbaar vir die publiek. Tweedens, aangesien werkskepping 'n kenmerk is van die Suid-Afrikaanse regering se ontwikkelingsbeleid, word 'n meer robuuste klem vereis op die hernubare energie onafhanklike kragprodusent verkrygingsprogram se ouditeringsproses en verdere navorsing van die beoogde voordele word voorgestel.

At present, the use of other sources of energy other than energy source from crude oil has accelerated. This is due to limited resources of fossil fuel, increasing prices of crude oil and environmental concerns. Alternative fuels such as biofuel are becoming more important because it can serve as a replacement for petroleum diesel due to its comparable fuel properties and cleaner emission. For use in a standard diesel engine, biodiesel can be blended (mixed) with petroleum diesel at any concentration. In this study, transesterification of waste cooking oil with methanol was catalyzed by heterogeneous catalyst TiO2-supported-MgO and the biodiesel produced was characterised. Waste cooking oil (WCO) was used because it is regarded as one of the cheapest feedstock for biodiesel production in that most oils from oil crops are used as food. Waste cooking oil is available in vast amounts each day in every restaurants and fast food outlets worldwide. The waste cooking oil used in this study was laboratory prepared by the addition of 5 wt. % of oleic acid into 95 wt. % of soybeans oil.10 wt. % of titanium-supported-magnesium oxide catalyst (MgO/TiO2) used was prepared by incipient wetness impregnation and characterized using XRF, BET and XRD. These materials were tested with the catalyst for the conversion of waste vegetable oil to biodiesel in presence of methanol and hexane co-solvent. Methanol to oil mole ratio of 18:1 was employed in the transesterification process. When hexane was used as cosolvent, methanol to oil mole ratio of 18:1 and methanol to hexane mole ratio of 1:1 was used. The effects of reaction time, reaction temperature and hexane co-solvent on the waste vegetable oil conversion has been established. The 1HNMR analysis was used to estimate the structure of FAME produced. It was observed that the oil conversion increases with the increased reaction time, reaction temperature and use of hexane as co-solvent. / Chemical Engineering / M. Tech. (Chemical Engineering)

At present, the use of other sources of energy other than energy source from crude oil has accelerated. This is due to limited resources of fossil fuel, increasing prices of crude oil and environmental concerns. Alternative fuels such as biofuel are becoming more important because it can serve as a replacement for petroleum diesel due to its comparable fuel properties and cleaner emission. For use in a standard diesel engine, biodiesel can be blended (mixed) with petroleum diesel at any concentration. In this study, transesterification of waste cooking oil with methanol was catalyzed by heterogeneous catalyst TiO2-supported-MgO and the biodiesel produced was characterised. Waste cooking oil (WCO) was used because it is regarded as one of the cheapest feedstock for biodiesel production in that most oils from oil crops are used as food. Waste cooking oil is available in vast amounts each day in every restaurants and fast food outlets worldwide. The waste cooking oil used in this study was laboratory prepared by the addition of 5 wt. % of oleic acid into 95 wt. % of soybeans oil.10 wt. % of titanium-supported-magnesium oxide catalyst (MgO/TiO2) used was prepared by incipient wetness impregnation and characterized using XRF, BET and XRD. These materials were tested with the catalyst for the conversion of waste vegetable oil to biodiesel in presence of methanol and hexane co-solvent. Methanol to oil mole ratio of 18:1 was employed in the transesterification process. When hexane was used as cosolvent, methanol to oil mole ratio of 18:1 and methanol to hexane mole ratio of 1:1 was used. The effects of reaction time, reaction temperature and hexane co-solvent on the waste vegetable oil conversion has been established. The 1HNMR analysis was used to estimate the structure of FAME produced. It was observed that the oil conversion increases with the increased reaction time, reaction temperature and use of hexane as co-solvent. / Chemical Engineering / M. Tech. (Chemical Engineering)