Modern mining explosives employ solutions of ammonium nitrate, where the solution is the oxidising component of a fuel/oxidiser mixture. This thesis is primarily concerned with the shock response of water and of aqueous solutions of ammonium nitrate. Of particular interest are the temperatures induced through shock compression. An experimental facility, using a single stage gas gun in the 'plate impact' configuration, is described, along with associated experimental diagnostics. Measurements of, and improvements to, the tilt at impact are reported. The problem of shock temperature is discussed, including a brief review of the relevant literature. It is demonstrated that direct measurement of shock temperature is a complex issue that is not yet fully understood, whereas determination of temperature from an equation of state is an established technique. In a series of experiments, plate impact techniques were utilised to determine the Hugoniot and, through shock/reload experiments, the equation of state of water and aqueous solutions of ammonium nitrate. In-situ manganin gauges were used to measure stresses in the liquids and, from the arrival times of the shock wave, determine the shock velocity. Linear shock velocity-particle velocity Hugoniots for the liquids were determined, up to particle velocities of 1km/s, with uncertainties on the intercept and slope of these Hugoniots of 5%. A Mie-Grûneisen equation of state was used to describe the shock/reload experiments. Approximate calculations of shock temperature are reported. Increasing ammonium nitrate concentrations resulted in greater calculated temperatures. It was demonstrated that the liquids investigated in this thesis show a temperature dependence of the Grûneisen parameter, ?, which cannot be accommodated in the model. The present work is believed to be the first demonstration of this effect in shock compressed liquids. The data presented provide constraints on future theoretical development of equations of state.

No description available.

The quasiparticle model, based on quark and gluon degrees of freedom, has been developed for the description of the thermodynamics of a hot plasma of strongly interacting matter which is of enormous relevance in astrophysics, cosmology and for relativistic heavy-ion collisions as well. In the present work, this phenomenological model is extended into the realm of imaginary chemical potential and towards including, in general, different and independent quark flavour chemical potentials. In this way, nonzero net baryon-density effects in the equation of state are self-consistently attainable. Furthermore, a chain of approximations based on formal mathematical manipulations is presented which outlines the connection of the quasiparticle model with the underlying gauge field theory of strong interactions, QCD, putting the model on firmer ground. A comparison of quasiparticle model results with available lattice QCD data for, e. g., basic bulk thermodynamic quantities and various susceptibilities such as diagonal and off-diagonal susceptibilities, which provide a rich and sensitive testing ground, is found to be successful. Furthermore, different thermodynamic quantities and the phase diagram for imaginary chemical potential are faithfully described. Thus, the applicability of the model to extrapolate the equation of state known from lattice QCD at zero baryon density to nonzero baryon densities is shown. In addition, the ability of the model to extrapolate results to the chiral limit and to asymptotically large temperatures is illustrated by confrontation with available first-principle lattice QCD results. These extrapolations demonstrate the predictive power of the model. Basing on these successful comparisons supporting the idea that the hot deconfined phase can be described in a consistent picture by dressed quark and gluon degrees of freedom, a reliable QCD equation of state is constructed and baryon-density effects are examined, also along isentropic evolutionary paths. Scaling properties of the equation of state with fundamental QCD parameters such as the number of active quark flavour degrees of freedom, the entering quark mass parameters or the numerical value of the deconfinement transition temperature are discussed, and the robustness of the equation of state in the regions of small and large energy densities is shown. Uncertainties arising in the transition region are taken into account by constructing a family of equations of state whose members differ from each other in the specific interpolation prescription between large energy density region and a realistic hadron resonance gas equation of state at low energy densities. The obtained family of equations of state is applied in hydrodynamic simulations, and the implications of variations in the transition region are discussed by considering transverse momentum spectra and differential elliptic flow of directly emitted hadrons, in particular of strange baryons, for both, RHIC top energy and LHC conditions. Finally, with regard to FAIR physics, implications of the possible presence of a QCD critical point on the equation of state are outlined both, in an exemplary toy model and for an extended quasiparticle model.

No description available.

In this research, we study how a finite-temperature nuclear equation of state suitable for astrophysical simulations impacts the oscillation modes of neutron stars. We chose the Shen equation of state (EOS) because it accurately describes both stable and unstable nuclei as well as nuclear incompressibilities. I modified the existing MHD code at BYU, the HAD code, to call a lookup table for the Shen EOS for use at run time, and added a Newton-Raphson method algorithm to convert conserved variables to primitive variables. The algorithm was tested and verified by evolving a stable neutron star for several dynamical times and evolving the same star at different resolutions. The normal mode frequency of the neutron star with the Shen EOS was measured and compared to those for neutron stars with an ideal gas EOS found by Font et. al. We found that the fundamental mode of the neutron star using the Shen EOS was slightly larger than that of the ideal gas EOS. This difference is due to the Shen EOS producing stars that are stiffer, increasing the sound speed.

Yes / Carbon capture and storage (CCS) has attracted renewed interest in the re-evaluation of the equations of state (EoS) for the prediction of thermodynamic properties. This study also evaluates EoS for Peng–Robinson (PR) and Soave–Redlich–Kwong (SRK) and their capability to predict the thermodynamic properties of CO2-rich mixtures. The investigation was carried out using machine learning such as an artificial neural network (ANN) and a classified learner. A lower average absolute relative deviation (AARD) of 7.46% was obtained for the PR in comparison with SRK (AARD = 15.0%) for three components system of CO2 with N2 and CH4. Moreover, it was found to be 13.5% for PR and 19.50% for SRK in the five components’ (CO2 with N2, CH4, Ar, and O2) case. In addition, applying machine learning provided promise and valuable insight to deal with engineering problems. The implementation of machine learning in conjunction with EoS led to getting lower predictive AARD in contrast to EoS. An of AARD 2.81% was achieved for the three components and 12.2% for the respective five components mixture.

This thesis is concerned with the numerical simulation of mixtures of chemically reacting fluids at high pressures. Mixture rules are established, accommodating components that do not follow the thermally perfect Equation of State (EoS), and including formulas for the fugacities. Particular attention has been given to the species EoS originally developed by Hirschfelder, Buehler, McGee and Sutton. The Law of Mass Action that governs chemical equilibrium of mixtures of fluids is presented. The common assumption of neglecting fugacities contributions when calculating the equilibrium composition is assessed by comparing complete thermochemical predictions with those obtained by reduced models. For air mixtures at high pressures and moderate temperatures, species thermally imperfect EoS effects are significant. However, the contribution of fugacities to the Law of Mass Action is found to be small, at least for mixtures of super-critical dissociating gases. Similar conclusions apply to combustion mixtures (involving hydrogen and oxygen).

Feldspars are one of the archetypical families of framework silicates. They not only comprise around 60% volumetrically of the Earth's crust, but are among some of the most structurally complicated minerals. Investigation into the structural behavior of various intermediate plagioclases at pressure has been undertaken with the intent of categorizing the elastic behavior with pressure across the solid solution series and establishing a conceptual model to characterize feldspar compression. Complex behavior has been observed in the Equation of State for plagioclase feldspars in excess of 3 GPa, including an anomalous softening of ordered albite in excess of 8.4 GPa (Benusa et al 2005: Am Min 90:1115-1120). This softening was not observed in the EoS for the more intermediate plagioclase compositions containing between 20 and 40 mol% of end-member anorthite. The calculated elastic compliance tensor sums at room pressure show a general stiffening with increasing anorthite component, small elastic changes at the C-1 to I-1 transition, and a dominantly first-order response at the P-1 to I-1 transition near end-member anorthite. The crystal structure of An37 plagioclase was determined by single-crystal X-ray diffraction. The compression mechanisms in An37 are similar to those in albite at lower pressures. The softening in albite at higher pressures is therefore attributed to the structural shearing in albite that is absent in An37 plagioclase up to 9.5 GPa. / Master of Science

La connaissance des propriétés critiques des mélanges binaires est importante pour la conception et le développement des procédés des industries chimiques, mais également, pour l'amélioration et l'extension des modèles thermodynamiques prédictifs. Cependant, des données expérimentales critiques liquide - vapeur de mélanges binaires sont relativement rare dans la littérature. C'est la raison pour laquelle, nous avons acquis un nouvel appareil permettant de mesurer les points critiques de corps purs et de mélanges. Dans une première étape, nous avons mis au point et validé le protocole expérimental, en comparant les résultats de nos mesures aux données de la littérature. Dans une deuxième étape, nous montrons l'intérêt que la mesure de points critiques de mélanges binaires peut présenter pour le développement de deux types de procédés : i) la production de biodiesel par voie supercritique et ii) l'étude de comportement de phases de nouveaux réfrigérants. Les résultats expérimentaux obtenus ont été également utilisés pour déterminer les paramètres d'interactions entre groupes du modèle PPR78 / Knowledge of mixture critical data is not only important for the design and the improvement of chemical processes but also to extend the range of applicability of predictive equations of state. However, mixture critical data comprise only a small percentage of the fluid phase equilibria data available in the open literature. This is the reason why it was decided to acquire a new synthetic-dynamic apparatus capable of determining the critical points of pure substances and multi-component mixtures. In a first step, the validation of the experimental procedure for critical point measurements was performed by comparing the experimental results obtained in this work with literature data. In a second step, the application of mixture critical data to the development of two types of process: i) biodiesel production via supercritical process and ii) phase behaviour of new refrigerants is presented. The experimental critical points measured in this work were also used for determining new group interaction parameters of the PPR78 model

Late-time cosmic acceleration is one of the most interesting unsolved puzzles in modern cosmology. The explanation most accepted nowadays, dark energy, raises questions about its own nature, e.g. what exactly is dark energy, and implications to the observations, e.g. how to handle fine tuning problem and coincidence problem. Hence, dark energy evolution through cosmic history, together with its equation of state, are subjects of research in many current experiments. In this dissertation, using Markov Chain Monte Carlo sampling, we try to constrain the evolution of the dark energy equation of state in a nearly model-independent approach by combining different datasets coming from observations of baryon acoustic oscillations, cosmic chronometers, cosmic microwave background anisotropies and type Ia supernovae. We found no strong evidence that could indicate deviations from LCDM model, which is the standard model in cosmology accepted today. / A aceleração cósmica atual é um dos mais interessantes enigmas não resolvidos da cosmologia moderna. A explicação mais aceita hoje em dia, a energia escura, levanta questões acerca de sua própria natureza, como o que é exatamente a energia escura, e as implicações para as observações, por exemplo como lidar com o problema do ajuste fino e o problema da coincidência. Por isso, a evolução da energia escura durante a história cósmica, juntamente com sua equação de estado, são objetos de pesquisa em inúmeros experimentos atuais. Nesta dissertação, usando amostragem por cadeias de Markov de Monte Carlo, tentamos restringir a evolução da equação de estado da energia escura em uma abordagem quase independente de modelo ao combinar diferentes conjuntos de dados provenientes de observações de oscilações acústicas de bárions, cronômetros cósmicos, anisotropias da radiação cósmica de fundo e supernovas tipo Ia. Não encontramos evidências fortes que pudessem indicar desvios do modelo LCDM, o qual é o modelo padrão aceito hoje na cosmologia.