Earthquakes are natural calamities that occur as a result of sudden release of strain energy stored in fault planes. Earthquakes have been observed to cause huge damage to infrastructures and lives. Earthquakes result in development of fissures, abnormal or unequal movement of foundations, and loss of strength and stiffness of the soils. Liquefaction is attributed as a major cause for the loss of strength and stiffness of soil during earthquakes. In the past, liquefaction was attributed only to coarse-grained to medium-grained sand and was extensively studied but the fine-grained soils were generally considered as non-liquefiable. However, from observations during recent earthquakes, fine-grained soils having low plasticity (plasticity index (PI) <20) have experienced ground failures due to liquefaction or large deformations. Moreover, laboratory experiments show that not only saturated cohesionless soils but also fine-grained soils may liquefy if certain criteria are met. One of the parameters which influences the liquefaction characteristics of fine-grained soils is its plasticity. This study may become helpful in understanding the effect of plasticity on liquefaction resistance of fine-grained soils. The objective of this study were to investigate the (1) effect of plasticity on pore pressure built up and deformation characteristics of fine-grained soils, and (2) effects of cyclic shear stress on liquefaction resistance of fine-grained soils. A total of 24 tests were conducted using a stress controlled cyclic triaxial testing machine on identically prepared specimens at an initial effective confining pressure of 5.0psi. The plasticity index (PI) was varied from non-plastic (NP) to 14.53. Sil-Co-Sil #40, a non-plastic commercial silt (product of US Silica Company) and EPK Kaolin clay (product of Edgar Minerals Inc.) were used as base materials. These materials were mixed in different proportions to obtain desired plasticity index. Out of the twenty-four tests, eleven tests were conducted on clean silt samples. Among the tests on clean silt samples, four tests were conducted on specimens having a post consolidation void ratio of 0.74 to 0.76. Further, six tests were conducted on specimens having a post consolidation void ratio of 0.74 to 1.04 by using a cyclic stress ratio (CSR) of 0.2 and 0.25. Seventeen tests were grouped to study the influence of plasticity on liquefaction characteristics of fine-grained soil. The PI of specimens tested ranged from non-plastic (NP) to 14.53. Each of the specimens with a definite PI was tested at an initial confining pressure of 5.0 psi using a CSR of 0.2, 0.3, and 0.4. The results obtained from the tests were used to compare the effects of plasticity on liquefaction characteristics of fine-grained soils. Based on the limited tests conducted, it was observed that plasticity index had distinct influence on the cyclic strength of the samples. It was found that CSR required to cause a pre-determined strain in a given number of loading cycles reduces as the plasticity index increases from non-plastic (NP) to 3.46, but increases for soils having PI greater than 3.46. Moreover, the liquefaction resistance decreases with the increase in cyclic shear stress for all soils regardless of plasticity indices (PIs). The critical PI value corresponds to 15% of EPK clay content in the specimen which gives a PI of 3.46.

After a major flooding disaster, construction materials will be scarce during early recovery stages and any material of reasonable quality would be useful. Instead of importing higher quality material from sites a considerable distance away, on-site material may be useable. This thesis explores usage of specialty portland cements, and in some cases polymer fibers, as stabilization additives to fine grained soils with elevated moisture contents. The primary objective of this thesis is to develop strength, modulus, and ductility trends for a variety of soil types, cementitious materials, cementitious material contents, and moisture contents, and to use the data to compare specialty grind portland cements to commercially available portland cement from the same production facility. The secondary objective is to evaluate the effect of polymer fibers combined with portland cement for the same mixtures. Over 1300 Unconfined Compression (UC) tests were conducted to complete these two objectives.

Recent ground failure case histories after 1994 Northridge, 1999 Kocaeli and 1999 Chi-Chi earthquakes revealed that low-plasticity silt-clay mixtures generate significant cyclic pore pressures and can exhibit a strain-softening response, which may cause significant damage to overlying structural systems. These observations accelerated research studies on liquefaction susceptibility of fine-grained soils. Alternative approaches to Chinese Criteria were proposed by several researchers (Seed et al. 2003, Bray and Sancio 2006, Boulanger and Idriss 2006) most of which assess liquefaction triggering potential based on cyclic test results compared on the basis of index properties of soils (such as LL, PI, LI, wc/LL). Although these new methodologies are judged to be major improvements over Chinese Criteria, still there exist unclear issues regarding if and how reliably these methods can be used for the assessment of liquefaction triggering potential of fine grained soils. In this study, results of cyclic tests performed on undisturbed specimens (ML, CL, MH and CH) were used to study cyclic shear strain and excess pore water pressure generation response of fine-grained soils. Based on comparisons with the cyclic response of saturated clean sands, a shift in pore pressure ratio (ru) vs. shear strain response is observed, which is identified to be a function of PI, LL and (wc/LL). Within the confines of this study, i) probabilistically based boundary curves identifying liquefaction triggering potential in the ru vs. shear strain domain were proposed as a function of PI, LL and (wc/LL), ii) these boundaries were then mapped on to the normalized net tip resistance (qt,1,net) vs. friction ratio (FR) domain, consistent with the work of Cetin and Ozan (2009). The proposed framework enabled both Atterberg limits and CPT based assessment of liquefaction triggering potential of fine grained low plasticity soils, differentiating clearly both cyclic mobility and liquefaction responses.

No description available.

No description available.

The strain rate dependent behaviour of fine grained soils is an important aspect of geotechnical engineering. During dynamic or rapid events such as earthquakes and rapid pile testing, a fine grained soil will display significantly different behaviour than may be observed over the long life span of a structure. There is currently little understanding of the factors which influence the behaviour of fine grained soils during dynamic events (extremely high strain rates), making their response difficult to predict. This research investigates the behaviour of fine grained soils subjected to a wide range of constant strain rates in monotonic triaxial compression testing. Each test is conducted under drained conditions to observe the behaviour of soils as they transition from a drained response at lower strain rates, through to an undrained or viscous response at higher strain rate tests. Where the response of soils is drained or partially drained, higher strain rate tests measure a decrease in strength. The point of transition from partially drained to undrained behaviour corresponds to the lowest strain rate dependent strength. Further tests at higher strain rates measure consistently greater strength. The strain rate dependence of three fine grained soils is investigated, enabling a comparison of strain rate effects with soil index properties. The influence of initial state on the strain rate dependence of these Kaolin based model soils is also evaluated. The drained to partially drained response of the soils to strain rate increase is controlled by the coefficient of consolidation. Tests at high strain rates show the undrained or viscous strain rate effect on strength is related to liquidity index. Local strain instrumentation allowed comparison of strain rate effects on small strain stiffness. At higher strain rate the soils display increasingly linear behaviour. At non-linear elastic strains, liquidity index appears to control the magnitude of the strain rate effects on stiffness.

Prediction as a tool in engineering has been used in taking right judgement in many of the professional activities. This being the fact, the role and significance of prediction in geotechnical practice needs no emphasis. Bulk of all man made structures are either made of soil or are resting on natural soil, involving large quantities of soil. Thus, it is often necessary for the geotechnical engineer to quickly characterize the soil and determine their engineering properties, so as to assess the suitability of the soil for any specific purpose. Obtaining these properties requires undisturbed samples, which involves time and money, and also elaborate laboratory procedures. Thus, it is desirable to find simpler and quicker methods of testing, using the data of which the engineering properties can be predicted satisfactorily especially so, for preliminary design purposes. Most often this can be achieved from simple tests known as inferential tests, and the engineering properties namely, compressibility, swell/collapse, hydraulic conductivity, strength and compaction characteristics can be obtained from empirical/semi-empirical correlations. The index tests namely the Atterberg limits form the most important inferential soil tests with very wide universal acceptance. These tests are relatively simple to perform and have provided a basis for explaining most engineering properties of soils in geotechnical practice. In this direction, this investigation has been carried out to correlate the engineering properties with the simple index properties and their indices, namely, the liquid limit, plastic limit, shrinkage limit, plasticity index and shrinkage index (liquid limit - shrinkage limit). Any good correlation in the prediction of engineering properties with the index properties will enhance the use of simple test for prediction purposes. This thesis is an attempt towards this direction. It is often necessary to identify the basic mechanisms controlling the engineering properties from a micro-mechanistic point of view and correlate with the index properties, thereby facilitating prediction of engineering properties better. Though attempts have been made in the past to predict the engineering properties of soils from the index properties/indic­es, they are not quite satisfactory. This thesis is an attempt to predict the engineering properties of fine-grained soils from the index properties taking into consideration the mechanisms controlling them. Since, the index properties are used for prediction of engineering properties, the existing methods of determining the same have been examined carefully and critically. It's satisfactory determination is found important because other indices namely plasticity index, Ip and shrinkage index, Is = (wL - ws), are determined based on it. Also the liquid limit is one of the important and widely used parameter in various existing correlations. In this direction, two new methods of determining the liquid limit have been developed, namely (i) absorption water content and liquid limit of soils and (ii) liquid limit from equilibrium water content under Ko-stress. In the absorption water content method, the water absorbed by an oven dried soil pat at equilibrium gives a good correlation with the liquid limit of soils. Here, the water holding capacity at equilibrium goes well with the mechanism of liquid limit, which is also the water holding capacity of a soil at a particular small but measurable shear strength. A good relationship is found to exit between the absorption water content, wA and the liquid limit, wL, and it is given as : WA = 0.92 wL (i) In the second method, namely, the liquid limit from equilibrium water content under K0-stress, which is the equilibrium water content under a Ko stress of 0.9 kPa is found to be equal to the liquid limit obtained from the cone penetration method of determining the liquid limit It is found that this method of determining the liquid limit overcomes the limitations of the conventional methods of determining the liquid limit, also easy to determine with a simple apparatus and has good repeatability. Determination of plastic limit of the soils by the rolling thread method often poses a problem especially when the soil is less plastic. Hence, to overcome this problem, a new method has been proposed to predict the plasticity index in terms of the flow index. The relationship between the plasticity index and the flow index by the cone penetration cup method is found to be better than by the percussion cup method. Since, the cone penetration method of the liquid limit determination is more popular than the percussion cup method, the flow index from the cone method is recommended to determine the plasticity index from the correlation as given below: (/p)c = 0.74 Ifc (ii) Thus, the plastic limit can be determined with the plasticity index, thereby dispensing with the determination of plastic limit by the thread method. The determination of consolidation characteristics form an important aspect in the design of foundations and other earth retaining structures. The determination of consolidation characteristics namely the compression index, the coefficient of consolidation and the coefficient of secondary compression is time consuming. So, researchers have resorted to correlating the compressibility behaviour with simple index properties. While attempts have been made in the past to correlate the compressibility behaviour with various index properties individually, all the important properties affecting the compressibility behaviour has not been considered together in any single study to examine which of the index property/properties of the soils correlates better with the compressibility behaviour, especially with the same set of test results. Number of existing correlations with the liquid limit alone as a primary index property correlating with the compression index have limitations in that they do not consider the plasticity characteristics of the soils fully. The index parameter, shrinkage index, Is has a better correlation with the compression index, Cc and also the coefficient of volume change, mv than plasticity index. Coefficient of consolidation, Cv has also shown to correlate well with shrinkage index than the plasticity index. Even the coefficient of secondary compression, Cαε has shown to have a better correlation with shrinkage index than the plasticity index. However, liquid limit has a poor correlation with all the compressibility characteristics. The correlation of Cc and Cv with shrinkage index, Is is as given below: Cc = 0.007 (Is + 18) (iii) Cv = 3x10-2 (Is)-3.54 (in m2/sec) Further, to reduce the testing time of conventional consolidation test in order to obtain the compressibility characteristics, a new method known as rapid method of consolidation has been proposed, which is very effective in enormously reducing the time of consolidation without sacrificing the accuracy of the end results. The time required in the rapid method of consolidation testing could be as low as 4 to 5 hours to complete the whole test as compared to 1 to 2 weeks as the case may be by the conventional consolidation test. Using any curve fitting procedure the degree of consolidation, U for any pressure increment can be found out. Thus, the effective pressure at that stage can be calculated and further the pressure incremented without further delay. This procedure is repeated for every pressure increment with a load increment ratio of unity till the desired pressure level is reached. Even for a highly compressible soil like BC soil with a liquid limit of 73.5 %, the consolidation test could be completed within 5 hours by the rapid method, without any sacrifice of the accuracy of the results as compared to 7 days by the conventional method to reach a pressure of 800 kPa. Hydraulic conductivity is one of the basic engineering properties of soils. Of late hydraulic conductivity of fine-grained soils has assumed greater importance in waste disposal facilities. From the present investigation it is found that hydraulic conductivity with water for each pair of soils having nearly the same liquid limit but different plasticity properties is found to be vastly different, but found to correlate well with shrinkage index. A method to predict the hydraulic conductivity of fine -grained soils as a function of void ratio is proposed with the use of shrinkage index as given below: k = C [ ] (in m/sec) (v) 1 + e C = 2.5 x 10-4 (/s)-5.89 and n = 4 (vi) It has also been brought out that as the dielectric constant of the pore fluid decreases; there is a drastic increase in the intrinsic permeability of soil. These changes are attributed to the significant reduction in the thickness of diffuse double layer, which in turn is mainly dependent on the dielectric constant of the pore fluid. The quantification of the change in the hydraulic conductivity with the change in the pore fluids of extreme dielectric constant, i.e., from water to carbon tetrachloride could be expressed in terms of the volume of water held in the diffuse double layer and the same has a good correlation with shrinkage index. With the advancement in the knowledge of the engineering behaviour of fine-grained soils, there is an increasing trend toward larger involvement of fine-grained soils in earth structures and foundations. Though extensive work has been done in the past to understand the swelling behaviour of expansive soils and the mechanisms involved therein, it is yet not satisfactory. From the literature it can be seen that lot of work has been done to correlate the swell potential with various physical properties. The simple means of identifying the swelling type of soils is by means of free swell tests with the ratio of free swell with carbon tetrachloride to the free swell of water. The same has found to correlate well with the percent swell/collapse of the ten soils used in the present investigation. However, it was found that shrinkage index has a better correlation with the swell/collapse behaviour of fine-grained soils, compared to the liquid limit or the plasticity index. In this study, it is also shown that neither the liquid limit nor the plasticity index can qualitatively describe the swell/collapse behaviour of fine-grained soils. This has been attributed primarily to two different mechanisms governing montmorillonitic and kaolinitic soils separately. Even swelling pressure has shown to have a good correlation with shrinkage index. It is found that the compression index of the samples consolidated from the swollen condition correlates well with the shrinkage index. Laboratory determination of the compaction characteristics are very much important for use in earth work constructions. It is found that only the plastic limit bears a good correlation with the compaction characteristics namely optimum moisture content and maximum dry unit weight. This conclusion is also supported by the data from the literature. The correlations are given as: OMC = 0.92 wp (in percent) (viii) and ydmax = 0.23 (93.3 - wp) (inkN/m3) (ix) Liquid limit, plasticity index and shrinkage index do not bear any correlation with the compaction characteristics. It is quite possible that, the plastic limit, which is the optimum water content of a saturated soil at which it behaves as a plastic material, and thus can be moulded to any shape, thereby the soil can be compacted or moulded to the densest possible state at that water content. Hence, possibly the good correlation. A simple method to predict the compaction curve is proposed based on the plastic limit of the soils. Of all the important engineering properties, both volume change (compressibility and swelling) and hydraulic conductivity have good correlation with the shrinkage index. However, the compaction characteristics correlate well with the plastic limit. Herein, an hypothesis is proposed to possibly explain why shrinkage index has shown to be a better parameter to correlate with most of the engineering properties with the exception of the compaction characteristics. The liquid limit is a parameter which takes part of the plasticity characteristics of a soil. Recently it has been well brought out that shrinkage limit is primarily a function of how the varying grain sizes are distributed in a soil. Thus, shrinkage limit takes care of the gradation of the soil fractions in it. Thus, by considering the shrinkage index, which is the difference of the liquid limit water content on one end and shrinkage limit water content on the other end, the primary physical properties of the soils namely the plasticity and the grain size distribution are considered. This possibly explains the good correlation of shrinkage index with the engineering properties of fine-grained soils. However, compaction being a moulding of the soils into a compact state, it has a good correlation with the plastic limit, which is the optimum water content of a saturated soil at which it behaves as a plastic material, and thus can be moulded to any shape, thereby the soil can be compacted or moulded to the densest possible state at that water content. Hence, the good correlation. As the present investigation gives the correlative equations to predict the engineering properties of fine-grained soils from the appropriate index properties, which are obtained from simple and quick laboratory tests, it is hoped that this will go a long way in being a handy tool for a practicing geotechnical engineer in the preliminary assessment of fine-grained soils and thereby take appropriate judgement in various aspects of geotechnical constructions with it.

No description available.

No description available.

The aim of the thesis has been to evaluate and understand the effect of caustic alkali solution of varying composition on the behaviour of expansive soil containing mixed layered minerals. Mixed layered minerals are formed of two or more kinds of inter grown layers, not physical mixtures. Illite - smectite is the most abundant and wide spread of the mixed layered clay minerals in sedimentary rocks and soils and also more common than either discrete illite or smectite. In geotechnical engineering much attention has not been paid to the behaviour of soils containing mixed layered minerals. Much less is known about the behaviour of these soils in polluted environment. Mixed layered minerals are more susceptible to environmental changes as the structural linkages between the layer minerals are weak compared to normal layered phyllosilicates. One important pollutant that can have considerable effect on the behaviour of soils is the caustic alkali contamination released from various industries. Recent studies have shown that the behaviour of even stable minerals is affected by alkali contamination. However, the effect of caustic alkali contamination on the behaviour of soils containing mixed layered minerals is not known and has been chosen for detailed study. Also to understand the mechanism of their interaction with alkali, it is necessary to study the effect of alkali solutions on the constituent clay minerals viz., montmorillonite and illite under similar conditions. To elucidate the mechanism of soil alkali interaction limited tests were conducted with simple electrolyte solution, as the alkali solution also acts as electrolyte apart from being alkaline. To confirm the mechanism of interaction, tests are also conducted on these soils with industrial spent liquor containing high caustic alkali and suspended alumina obtained from an alumina extraction plant treating bauxite with high alkali solutions at high temperatures. The results obtained in the laboratory are compared with the soil samples contaminated with leaking industrial Bayer's liquid in the field. Studies are also conducted to suggest remedial measures to control the adverse effects of alkali solutions on soil containing mixed layer minerals. The content of the thesis is broadly divide into 8 Chapters - viz., Introduction, Background and overview, Experimental program and procedures, Behaviour of soils containing mixed layer mineral illite - smectite (BCSI), Behaviour of montmorillonite and illite, Influence of Bayer's liquor and study on the field contaminated soils, Measures to control the influence of alkali contamination on BCSI and Summary and conclusions. The broad outline of these chapters is given in Chapter 1. A review of literature on the behaviour of soils containing different types of clay minerals with emphasis on mixed layer minerals has been presented in Chapter 2. The influence of different inorganic contaminants on the properties of soils in terms of their physical and chemical characteristics as well as their concentration has been summarized. The importance of changes in surface characteristics of soil particles and the changes in the thickness of diffuse double layer in altering the property of soils at low concentration of contaminants and changes in the mineralogy with high concentrated contaminants such as acids and alkalis has been highlighted. This forms the background information necessary to bring out the scope of the study. Four soils having different mineralogy have been used in this study. These soils are, black cotton soil containing predominantly mixed layer mineral illite - smectite mineral called rectorite, illite, montmorillonite (common smectite) and black cotton soil containing predominantly montmorillonite. The properties of the soils used are described in Chapter 3. Caustic alkali solutions of 1N, 4N concentration prepared in the laboratory and industrial alkali-spent liquor are used as contaminants. The spent Bayer's liquor had about 4N alkali concentration and 10% alumina in suspension. To simulate the effect of suspended alumina, two more caustic alkali solutions of 1N and 4N solutions containing 10% alumina by weight of solutions are also prepared. To isolate the effect of electrolyte solutions from that of alkali solution, two electrolyte solutions of 1N and 4N sodium chloride solutions are also used. Test procedures for conducting various tests such as pH, water adsorption characteristics, X-ray diffraction studies, SEM studies, thermal characteristics and geotechnical properties such as Atterberg limits, Oedometer tests and Shear Strength are given in this chapter. The test procedures are modified, wherever necessary, to bring out the effect of contaminants, particularly the effect of duration of interaction on the properties of soils. The source and properties of black cotton soil are presented in Chapter 4. Detailed x-diffraction studies have confirmed the presence of inter layered illite-smectite mineral viz., rectorite, which is uncommon in Indian expansive soils, and is classified as CH (Clay of high compressibility) as per ASTM soil classification. Effect of alkali and salt solutions of 1N and 4N concentration on all physico chemical and geotechnical properties are studied in this chapter. As it is known that presence of certain elements such as aluminium influence the soil alkali interaction, the effect of suspended alumina along with alkali solution has also been investigated. The effect of contaminating fluids such as 1N NaOH, 4N NaOH with and without alumina, 1N NaCl and 4N NaCl on the geotechnical properties of the soil has been studied. Mineralogical changes were observed by XRD and thermal studies in the soil treated with 4N NaOH solution and 4N NaOH + 10% alumina. The interlayer potassium of illite is released and potassium hydroxide is formed in soil treated with 4N NaOH. Swelling compounds such as sodium aluminium silicate hydroxide hydrate (SASH) has formed due to attack of 4N NaOH + 10% alumina on silica rather than on rectorite. Thus the studies clearly bring out that the rectorite present in the soil is dissociated only in the presence of strong alkali solutions of concentration of about 4N. The liquid limit of soil decreased with increase in the electrolyte concentration in the case of NaCl solutions. With 1N NaOH, the liquid limit of soil increased due to increase in the thickness of diffuse double layer due to increased pH. However, Proctor's maximum dry density increased and optimum moisture content decreased with 1N NaOH. With increase in the concentration of alkali solution to 4N, the rectorite dissociates into constituent minerals with the formation potassium hydroxide. The liquid limit of soil decreased probably due to the dominating influence of electrolyte nature of hydroxide solution over the effect of increased negative charge on clay particles due increase in the pH on the constituent minerals. Proctor's maximum dry density decreased and optimum moisture content increased with 4N NaOH. Sediment volume and oedometer free swell at seating/nominal surcharge load of 6.25 kPa of soil increased in 1N and 4N caustic alkali solutions, though by different mechanisms. The increase with 1N solution is essentially due to increased negative charges on clay mineral surface. However, the increase in swelling with 4N solution is associated with the dissociation of rectorite mineral and occurs in two distinct phases unlike in the case of 1N solution. While the first phase can be attributed to the effect of alkaline nature of the solution after reduction in its concentration due to reaction with rectorite and the consequent reduction in its electrolyte nature. The second phase is due to the swelling of the separated constituent minerals in the presence of excess of alkali and occurs after much delay. Consolidation behaviour of rectorite in 1N and 4N alkali solutions has been studied in two ways: 1). Loading without waiting for the second stage of swelling to occur, as in standard consolidation procedure and 2). Loading after completion of second stage of swelling which is occurring after considerable delay as explained earlier. Normally one would initiate loading after equilibrium is reached at the end of first stage of swelling and second stage of swelling is not suspected. As there is no second stage of swelling with 1N solutions, these two types of consolidation tests produced the same results. Abnormal rebound is observed during unloading with 4N solution in which loading cycle is initiated without waiting for second stage of swelling to complete. It is interesting to note that while the liquid limit of soil decreased with increase in the concentration of alkali solution, the swelling increased. The testing procedure and period of interaction as well as the concentration of alkali solution during the test in these two tests are different. The effects of alkali solution are more severe in case of liquid limit because of thorough mixing and consequent effective reaction during testing. Similarly, the volume changes in soil that has already reacted with 4N alkali solution when exposed to further to alkali contamination are considerably less compared to uncontaminated soil exposed to fresh contamination. The shear strength of soil treated with 4N-alkali solution has increased particularly after long period of interaction. This indicates that the soil after mineralogical changes posses good strength. Chapter 5 presents the effect of alkali and salt solutions on the physico chemical and geotechnical properties of component minerals of mixed layered illite/smectite. For this study, commercially obtained montmorillonite (bentonite), naturally occurring black soil containing montmorillonite and commercially pure illite are used. It was observed that montmorillonite alkali reactions would not produce significant mineralogical changes where as illite is dissociated into smectite with the formation of potassium silicate by the interaction of released potassium with soluble silica. This confirms that the ultimate products of rectorite with alkali solutions would be smectite and compounds of potassium. In the absence of mineralogical alterations the liquid limit of montmorillonite decreases due to suppression of diffuse double layer thickness due to dominating influence of alkali solutions on this highly active clay. However a small increase in liquid limit is observed in illite with alkali solutions. Thus the net effect of alkali on rectorite is to decrease the liquid limit with increase in alkali concentration. While the free swell and oedometer swelling of montmorillonite generally decreases with increase in the alkali concentration, they increase in illite. However, in both the minerals the swelling occurs only in one phase. Thus the second phase of swelling that has been observed in rectorite can be attributed to delayed swelling of montmorillonite that has been released by the attack of alkali on rectorite. The behaviour of black soil containing mixed layer mineral contaminated in the field and laboratory by leaking Bayer's spent liquor in an alumina extraction plant has been studied in Chapter 6. The Atterberg limits of the samples treated with liquor are reduced and sediment volume increased. Similarly the swelling at seating load in consolidation test is higher in sample compacted with water and inundated with liquor. X-ray diffraction studies showed that the mineralogical changes are similar to those occurred with 4N caustic alkali solution. The mineralogical and micro structural changes in the soil samples that are contaminated by leaked spent liquor in the field are relatively more marked. Also the behavior of highly montmorillonite clay, bentonite, has been studied contaminated with liquor in the laboratory. The study on the effect of high concentrated alkali solutions on montmorillonite can be useful to study the effect of interaction on the dissociated montmorillonite. These studies are helpful to suggest some possible remedial measures to control the adverse effect of alkali on soils. Possible Remedial schemes that can be adopted before and after contamination of the soil to control the adverse effect of alkali solutions on the black cotton soil containing mixed layered mineral are listed and their effectiveness examined in Chapter 7. The suggested remedial measures include flushing with water to dilute the effect of alkali, neutralisation with dilute hydrochloric acid, stabilisation of soil with lime and calcium chloride and use of impervious membrane to separate the foundation soil from alkali solution. The effectiveness of different measures as well as the method of their application has been described. Efforts are made to understand the mechanism of remedial action. Consolidation tests conducted on soil contaminated with 4N alkali solution and inundated with water showed increased swelling due to dilution of the alkali concentration. Though the swelling of contaminated soil can be controlled by passing dilute hydrochloric acid (1N), the method is not advocated as it can lead to ground water contamination. Mixing the soil with solutions containing up to 5% by weight of calcium compound in water could not prevent the alkali induced heave in the long run when inundated with 4N alkali solution. This was due to dissolution of silica by the strong alkali solutions and formation of swelling compounds such as sodium aluminium silicate hydroxide hydrate (SASH). The formation of sodium aluminates occurred only when the alkali solution contained alumina or soil contained calcium compounds. There are no significant variations in the effects of calcium chloride or calcium hydroxide on contaminated soil. Replacing the foundation soil with soil thoroughly contaminated with 4N alkali solutions and controlling the migration of contaminants into the foundation soil using high-density polyethylene (HDPE) geosynthetic membranes can be an effective measure to control the heaving in alkali contaminated foundation soil containing interstratified illite – smectite. Summary and the major conclusions of the thesis are presented in Chapter 8.