This thesis describes an experimental investigation of lean blowoff for H2/CO/CH4 mixtures in a swirling combustor. This investigation consisted of three thrusts. The first thrust focused on correlations of the lean blowoff limits of H2/CO/CH4 mixtures under different test conditions. It was found that a classical Damköhler number approach with a diffusion correction could correlate blowoff sensitivities to fuel composition over a range of conditions. The second part of this thesis describes the qualitative flame dynamics near blowoff by systematically characterizing the blowoff phenomenology as a function of hydrogen level in the fuel. These near blowoff dynamics are very complex, and are influenced by both fluid mechanics and chemical kinetics; in particular, the role of thermal expansion across the flame and extinction strain rate were suggested to be critical in describing these influences. The third part of this thesis quantitatively analyzed strain characteristics in the vicinity of the attachment point of stable and near blowoff flames. Surprisingly, it was found that in this shear layer stabilized flame, flow deceleration is the key contributor to flame strain, with flow shear playing a relatively negligible role. Near the premixer exit, due to strong flow deceleration, the flame is negatively strained i.e., compressed. Moving downstream, the strain rate increases towards zero and then becomes positive, where flames are stretched. As the flame moves toward blowoff, holes begin to form in the flame sheet, with a progressively higher probability of occurrence as one moves downstream. It is suggested that new holes form with a more uniform probability, but that this behavior reflects the convection of flame holes downstream by the flow. It has been shown in prior studies, and affirmed in this work, that flames approach blowoff by first passing through a transient phase manifested by local extinction events and the appearance of holes on the flame. A key conclusion of this work is that the onset of this boundary occurs at a nearly constant extinction strain rate. As such, it is suggested that Damköhler number scalings do not describe blowoff itself, but rather the occurrence of this first stage of blowoff. Given the correspondence between this first stage and the actual blowoff event, this explains the success of classical Damköhler number scalings in describing blowoff, such as shown in the first thrust of this thesis. The physics process associated with the actual blowoff event is still unclear and remains a key task for future work.

Alternative fuels and technologies for truckload carriers can provide significant environmental and social benefits over traditional heavy duty diesel vehicles by reducing petroleum-based fuel consumption and vehicle tailpipe emissions. These alternative fuels and technologies, however, often carry a cost premium or require significant capital investment. Dedicating vehicles, equipment, and infrastructure to an alternative fuel or technology also represents a significant risk in the extremely volatile trucking business. A Triple-Bottom-Line analysis, which includes economic, social, and environmental impacts of an alternative fuel or technology will strengthen the business case by incorporating the benefits of emissions reduction. A stronger business case will promote the use of alternative fuels and technologies while mitigating the risk. This thesis proposes a method for identifying alternative fuels and technologies that provide the best Triple-Bottom-Line benefit and provides a structure for modeling the emissions of the target application, quantifies the value of emissions reduction, and constructs a Triple-Bottom-Line business case. The Triple-Bottom-Line business case proposed by this method is incremental. It presupposes an existing or planned truckload carrier business already exists and only investigates the changes which occur with implementation of an alternative fuel or technology. This method may be useful for any carrier business or any company with an extensive shipping and logistics network. A case study, which was created for large automotive manufacturer, details the Triple-Bottom-Line business case for an on-site compressed natural refueling system and vehicles.

Thesis (M.S.)--Ohio University, March, 2008. / Title from PDF t.p. Includes bibliographical references.

Thesis (PH.D.)--Michigan State University. Chemical Engineering, 2008. / Title from PDF t.p. (viewed on Aug. 11, 2009) Includes bibliographical references (p. 179-189). Also issued in print.

Thesis (MTech (Mechanical Engineering))--Cape Peninsula University of Technology, 2016. / The high cost of fossil fuels and the fact that the world has arguably reached its peak oil production, has driven the need to seek alternative fuel sources. The main objective of the current study is to determine the performance of a laboratory-mounted diesel engine when fuelled with varying laboratory prepared biofuel and biodiesel and whether the advancement of the injection timing parameters will improve the engine power output and improve the smoke effect of these different fuel blends. The laboratory prepared biofuels used in this project range from 100% bio-fuel (BF100) to 50%, 30% and 10% biodiesel blends (BF50, BF30 and BF10, respectively). It should be noted that these blends are not commercially available, since they were blended in the laboratory specifically for these tests. The overall results of the study show that there is a distinct opportunity for using certain bio-fuel blends in specific applications as the power outputs are no more than one quarter less than that of base diesel. Concomitantly, the smoke opacity in all of the blends is lower than that of base diesel, which is a significant benefit in terms of their overall air emissions.

This study considered the potential use of lignin as possible renewable fuel and chemical feedstock source. Among the various polymers present in lignocellulosic biomass, the polyaromatic lignin is the one component that is most chemically similar to petroleum. However, it still contains a much larger amount of oxygen compared to crude oil. As such, two strategies were employed in this study: (1) studying the lignin depolymerization in the presence of high temperature and base catalysts; and, (2) employing hydrodeoxygenation as a means to decrease the O/C ratio in lignin-derived model compounds. The base-catalyzed depolymerization (BCD) of organosolv lignin was done in a 500-mL Monel Parr reactor at temperatures ranging from 165°C to 350°C. Complete solubilization of lignin derivatives was possible in the presence of NaOH and KOH, except at 350°C. NMR experiments revealed formation of oxidized groups (carboxylic and hydroxyl groups) as well as alkyl groups. On the other hand, the use of NH4OH showed N incorporation. Identified and quantified DCM-soluble monomeric compounds were at most 6% of the starting material and are mainly phenolic. This study revealed the apparent susceptibility of syringyl units over guaiacyl units in BCD. This could in turn guide the choice of substrate on which base-catalyzed depolymerization could be applied. Syringaldehyde was used as the starting material to study batch hydrodeoxygenation (HDO) using several non-cobalt/molybdenum based catalysts. A 50-ml Parr reactor was used, pressurized by 1000 psig of H2 and heated to 300°C. Nickel based catalysts (nickel phosphide, nickel oxide and nickel phosphate) as well as supported precious metals (Pt and Pd) were tested as HDO catalysts. Of the three O-containing functional groups of syringaldehyde, the aldehydic group was found to be the most susceptible. In the presence of the Al2O3-supported catalysts, the methyl groups liberated were found to be incorporated back into the aromatic ring, forming alkylated compounds. In the last section of this dissertation, hydrothermally synthesized supported Ni on mesoporous silica (MCF) and acid catalysts (HY and H-Al-MCF) were used for probing the effect of bifunctional metal-acid catalysis on phenol hydrodeoxygenation/hydrogenation. Catalyst configurations were varied from the previously studied wet-impregnated Pt/HY catalyst. Based on a hypothesis that coking catalyzed by the acidic zeolite in the wet impregnated Pt/HY catalyst was the main cause of catalyst deactivation and decreased phenol conversion, separately synthesized metal and acid catalyst systems were tested. Complete phenol conversion was sustained for at least three times longer in a continuous flow reactor operated at 200°C and 0.79 MPa of flowing H2. The separation of the metal and acid sites generated a tunable system capable of producing cyclohexanol, cyclohexane or cyclohexene at very high selectivities, even achieving 99% selectivities for cyclohexane.

Thesis (Ph.D.)--Mississippi State University. Department of Political Science and Public Administration. / Title from title screen. Includes bibliographical references.

published_or_final_version / Environmental Management / Master / Master of Science in Environmental Management

This thesis investigates relationships between the European Union Emission Trading Scheme (EU ETS) and energy markets. A special focus is given to fuel switching, the main shortterm abatement measure within the EU ETS. This consists in substituting Combined Cycle Gas Turbines (CCGTs) for hard-coal plants in off-peak power generation. Thereby coal plants run for shorter periods, which allows power producers to reduce their CO2 emissions. In Chapter 1, we outline different approaches explaining relationships between carbon and energy markets. We also review the literature relating to these issues. Next, we further describe the fuel switching process and, in particular, we analyze the influence of energy and environmental efficiency of thermal power plants (coal and gas) on fuel switching. In Chapter 2, we provide a theoretical analysis that shows how differences in the efficiency of CCGTs can rule interactions between gas and carbon prices. The main result shows that the allowance price becomes more sensitive to the gas price when the level of CO2 emissions increases. In Chapter 3, we examine interactions between carbon, coal, gas and electricity prices in an empirical study. Among the main results, we find that there is a significant link between carbon and gas prices in the long-run equilibrium.In Chapter 4, we analyze the cross-market price discovery process between gas and CO2 markets. We identified in previous chapters that there is a robust significant link between gas and CO2 markets. They are linked commodities, and their prices are affected by the same information. In an empirical analysis, we find that the carbon market is the leader in cross-market price discovery process.

M.Sc. (Environmental Management) / Please refer to full text to view abstract